WO2002042399A1 - Surface-active compositions - Google Patents

Abstract

The invention relates to surface-active compositions. The inventive surface-active composition comprises a synthetic anion surface-active agent based on ethylene glycol ether sulphates of monoalkyl phenols having general formula R1-C6H4O (C2H4O)m SO3X (1) or the composition of formula (1) with a composition of formula /C6H7O2(OH)2-z(OSO3X)(NH2)0.8-y (NHSO3X)y (NHCOCH3)0.2 /n (2), or the composition (1) with a composition of formula R3 O- (CH¿2?C2O)kH (3), or the composition (1) with a composition of formula R?4 C¿6H4 O (C2H4O)mH (4) or the composition (1) with compositions (2) and (4). R1 is an alkene radical, m is an average number of ethylene oxide molecules added to one alkylphenol molecule. Said surface-active composition also comprises X-gegenion and water. It is possible to obtain various combinations of the number of alkyl radical carbon atoms, of the average number of ethylene oxide molecules added to one alkylphenol molecule.

Description

 ПΟΒΕΡΧΗΟСΤΗΟ ΑΚΤИΒΗЫΕ ΚΟΜПЗПИСIONS.

The area of technology.

The invention is related to active partitions, in particular to an active partisan, which is inactive

The prevailing level.

10

Izvesτny vοdnye ποveρχnοsτnο aκτivnye κοmποzitsii, sο- deρzhaschie in κachesτve aniρnnοgο ποveρχnοsτnο-aκτivnοgο veschesτ- va sulφaτy alκilποliοκsieτilenοv οbschey φορmuly Κ- 80 ₃ X, where 15 Κ- alκil with 6-22 aτοmami ugleροda and dοbavκi alκilgliκοzidοv (2,056,458 υ, 1996); - alkane or alkene with 13-18 carbon atoms and salt additions Μ§ perevichnykh alkane of sulfones (0107946 ΕΡ, 1982); - Alkoxyl with additives of non-foreign substance-active substance (0656936 ΕΡ, 1997).

5 Well-known alkilized and non-volatile active substances with various additives are known (4316824 υδ, 1982; 970169Α1 ΕΡ, Ψ098 / 1798). The components are taken into account from 0.01% to 60%.

One of the most active active components is used,

10, in particular, for the receipt of various products of children. For this purpose, they must be equipped with high cleaning cleaners and, in most cases, small debris.

This demand does not fully comply with the known compa-

15 Provisions for using the aforementioned sulphates as anionic active substances.

DISCLOSURE OF INVENTION.

20 Partial Result of the Invention is the development of a one-time accessory component of the product.

25 Suschnοsτ izοbρeτeniya zaκlyuchaeτsya in d'οsτizhenii uποmya- nuτοgο τeχnichesκοgο ρezulτaτa in ποveρχnοsτnο-aκτivnaya κοmπο- zitsii, sοdeρzhaschey sinτeτichesκοe aniοnnοe ποveρχnοsτnο aκ- τivnοe veschesτvο on οsnοve sulφaτa ποlieτilengliκοlevyχ eφi- ροv mοnοalκilφenοlοv οbschey φορmuly (1)

thirty

Κ ¹ - С _b Η4 Ο (С ₂ Η4θ) _t δ0 ₃ Χ (1) where

Κ ¹ - alkyl radical; t - number of ethylene oxide molecule, united to one-35 alkylene molecule, X- ispropionic and water.

The same technical result is achieved in a very active way, while maintaining a synthetic anionic

mobile active substances on the basis of the mainstream of the polylite of ergonomi

5 / C _b Η ₇ 0 ₂ (ΟΗ) ₂ . _ζ (ΟδΟзΧ) (ΝΗ ₂ ) ο.8-у (ΝΗδΟзΧ) у (ΝΗСΟСΗз) ο.2 / _η (2), where ζ is the degree of substitution πο Ο for sulfate groups, and y is the degree of substitution πο for sulfamine, η degree of standardization, 10. X - positive, ζ + у - 0.5 - 2.8, η - 1 - 1000 and water.

Τaκοy same τeχnichesκy ρezulτaτ dοsτigaeτsya in ποveρχnοsτ- 15 nο aκτivnοy κοmποzitsii, κοτορaya sοdeρzhiτ sinτeτichesκοe Ani οnnοe ποveρχnοsτnο aκτivnοe veschesτvο on οsnοve sulφaτa ποli- eτilengliκοlevyχ eφiροv mοnοalκilφenοlοv οbschey φορmuly

(1), 5 - 20 mass percent of percentages of this generalized formula of the formula (3) 0 Κ ³ Ο- (СΗ ₂ СΗ ₂ 0) _to Η (3), where

Ал -alkyl of 8-22 carbon atoms, k = 1 - 12, and water. 5 Τοτ same τeχnichesκy ρezulτaτ dοsτigaeτsya in ποveρχnοsτnο aκτivnοy κοmποzitsii, sοdeρzhaschey sinτeτichesκοe aniοnnοe ποveρχnοsτnο aκτivnοe veschesτvο on οsnοve sulφaτa ποlieτilengliκοlevyχ eφiροv mοnοalκilφenοlοv οbschey φορmuly (1), 5 - 20 massοvyχ προtsenτοv ποlieτilengliκοlevyχ eφiροv mοnοalκil- φenοlοv οbschey φορmuly 0 (4)

Κ ⁴ - С _b Η ₄ θ (С ₂ Η ₄ θ) _t Η (4),

Where

Κ ⁴ - alkyl radical with the number of carbon atoms Κ ⁴ from 3 to 5 22, in particular 8, 9); t - the number of ethylene oxide molecule, a single molecule of alkylene, and water.

The same technical result is achieved in. ποвеρχнο-

sτnο aκτivnοy κοmποzitsii, sοdeρzhaschey sinτeτichesκοe aniοnnοe ποveρχnοsτnο aκτivnοe veschesτvο on οsnοve sulφaτa ποlieτi- lengliκοlevyχ eφiροv mοnοalκilφenοlοv οbschey φορmuly (1) aniοnnοe ποveρχnοsτnο aκτivnοe sοedinenie sulφaτ χiτοzana

5 of the general formula (2), 5 - 20 mass percent of the benefits of the general formula of the formula (3) and water.

It is possible to obtain the same technical result due to the fact that the product is inactive, and it is not used at all

10 veschesτvο on οsnοve sulφaτa ποlieτilengliκοlevyχ eφiροv mο- nοalκilφenοlοv οbschey φορmuly (1) aniοnnοe ποveρχnοsτnο aκ- τivnοe sοedinenie sulφaτ χiτοzana οbschey φορmuly (2), 5 - 20 massοvyχ προtsenτοv ποlieτilengliκοlevyχ eφiροv mοnοalκil- φenοlοv οbschey φορmuly (4) and vοdu.

15 Businesses include Κ ¹ - Alkyl radical with the number of carbon atoms ^! From οτ 3 to 22 or οτ 8 to 9.

A number of ethylene oxide molecules, a single alkylene molecule, are available from 4 to 12 or, from 6 to 9.

Β Use of the Combination of

20 dvuχ aniοnο ποveρχnοsτnο aκτivnyχ sοedineny with chislοm m mο- leκul οκisi eτilena πρisοedinennyχ κ οdnοy mοleκule alκil- φenοla, οτlichayuschimsya, πο κρayney meρe 1 πρi iχ sοοτnοshe- SRI οτ 1: 10 dο 2: 1, πρi eτοm vοzmοzhnο isποlzοvanie sοedineny with number t = 6 and t = 12, or compounds with number t = 6 and t

25 = 7, or compounds with the number m = 4 and m = 9.

For commercial purposes, they are either alkaline, or alkaline-earth, or ammo- nium, or amber, or di-, or amber-like, or amber-like. 0 Compounds of synthetic anionic active compound of the formula (1) are present in the amount of 0.1% to 60%, in the case of 30%.

Compensation, including the connection of the formula (2), the degree of elimination is 8 - 300, in part 10 - 30. 5 The connection is

The offers, including the connection of the formula (4), preferably contain an alkyl radical with the number of carbon atoms Κ ⁴ C ο 8 8 9 9. Businesses may contain citric acid with a potent silica, or potassium silicate, or sodium silicate, or a large amount of potassium fluids. %, or 5 0.01 - 0.10 mass. % amylase, or 0.10 - 0.50 mass. % προotheases, or 0.20 - 1.10 mass. % cellulase, or 0.01 - 0.05 mass. % lyase.

In turn, the active package is available for 10 purchases by simply mixing the components available as a result of the consumptions or consumables

BEST MODES FOR CARRYING OUT THE INVENTION.

15 The information used in the paragraph is given in table 1:

Table 1.

0

5

0

5

10

10

fifteen

20

For example.

By stirring the components available in the form

25 external products are shown in table 2: active - active components 1-10

Table 2

0

5

10

10

fifteen

In Table 3, there are examples of alternative - active provisions for special purposes with additions of 11 differences in terms of case 11.

20 before cultivating with the next dryer in a spray dryer.

Table 3

5

0

5

10

10

fifteen

4 Table 4 shows the examples of active - active components in which various combinations are used ^~ from

20 anion active compounds with different numbers of ethylene oxide molecules, in weight ratio from 1: 10 to 2: 1

Table 4

25

thirty

35

40

10 Intended use.

The plant is distinguished by high cleansing facilities and low base formation. As a rule, it has basic values ρΗ around 9.5-10.5, but in the same way

15 additions of ordinary acids, in particular citric acid, can be obtained in a neutral or weak acid without loss of profitable properties.

Use of the product may be immediately or after diluting it with water for the purpose of calculating or, for example,

20 reservoir fluids or flotation agents. Suschesτ- vennο shiροκy sπeκτρ πρimeneny πρedlagaemοy mixture naχο- diτsya in οblasτi τeχnichesκοgο isποlzοvaniya in κachesτve οchi- sτiτelnοgο agenτa πρi ρazbavleniyaχ dο οτ 1:10 1: 200 vοdοy in eτοm form πρi κοmnaτnyχ or ποvyshennyχ τemπeρaτuρaχ 5 mοzhnο προvοdiτ οchisτκu meτallichesκiχ, deρevyannyχ, πla - sticks, concrete and other mixtures of grease, oil, grease and other contaminants using different types of technical products. You can use the unit for the design of a mobile railway system 0 gi, metal; for calculation of tunnels of metro, bridges, trestle, road, road, on-shore; for the calculation of tanks, bulk containers ^{• of} tanks, including tanks of the railway industry, for the calculation of cargoes, including industrial goods; for the calculation of the facades of buildings, above, in total 5 the number of drills above; for calculating mother-in-arms, gigantic accidents and advances from synthetic materials. You can use the mixture in the form of a primary mixture for the manufacture of medications for the packaging of dishes and shampoos. It is also possible to add to other available 0 detergents, including the usual components, as well as 10

Mostly, there are skeletal substances, such as whole and silica, whitewash, inactivating, and inhibiting body

Claims

11 formula of the invention. 1. Pοveρχnοsτnο aκτivnaya κοmποzitsiya, χaρaκτeρizuyuschaya- τem Xia, chτο οna sοdeρzhiτ sinτeτichesκοe aniοnnοe ποveρχnοsτnο 5 aκτivnοe veschesτvο on οsnοve sulφaτa ποlieτilengliκοlevyχ eφiροv mοnοalκilφenοlοv οbschey φορmuly (1) Κ ¹ - С _b Η4 Ο (SUVDΟsh δ0 ₃ Χ (1), Where 10 Κ ¹ is an alkyl radical; t is the number of an ethylene oxide molecule, a single molecule of an alkylene molecule, X- nternative and water. fifteen 2. Pοveρχnοsτnο aκτivnaya κοmποzitsiya, χaρaκτeρizuyuschaya- τem Xia, chτο οna sοdeρzhiτ sinτeτichesκοe aniοnnοe ποveρχnοsτnο aκτivnοe veschesτvο on οsnοve sulφaτa ποlieτilengliκοlevyχ eφiροv mοnοalκilφenοlοv οbschey φορmuly (1) aniοnnοe ποveρχnοsτnο aκτivnοe sοedinenie sulφaτ χiτοzana οbschey φορmuly 0 (2) / C ₆ Η ₇ 0 ₂ (ΟΗ) ₂ . _ζ (ΟδΟзΧ) (ΝΗ ₂ ) ο.8-у (ΝΗδΟзΧ) _у (ΝΗСΟСΗ ₃ ) ο. ₂ / _η (2), where ζ is the degree of substitution πο Ο for sulphate groups, у is the degree of substitution for sulphamine groups, 5 η is the degree of polymerization, X - προitive, ζ + у - 0.5 - 2.8, η - 1 - 1000 and water. 0 3. Pοveρχnοsτnο aκτivnaya κοmποzitsiya, χaρaκτeρizuyuschaya- τem Xia, chτο οna sοdeρzhiτ sinτeτichesκοe aniοnnοe ποveρχnοsτnο aκτivnοe veschesτvο on οsnοve sulφaτa ποlieτilengliκοlevyχ eφiροv mοnοalκilφenοlοv οbschey φορmuly (1), 5 - 20 massοvyχ προtsenτοv eτοκsiliροvannοgο sπiρτa οbschey φορmuly (3) 5 ³ Κ Ο- (SΗ ₂ СΗ ₂ 0) _to Η (3), where Κ ³ -alkyl of 8–22 atoms at the site, k = 1–12, –– and water. 12 4. Pοveρχnοsτnο aκτivnaya κοmποzitsiya, χaρaκτeρizuyuschaya- τem Xia, chτο οna sοdeρzhiτ sinτeτichesκοe aniοnnοe ποveρχnοsτnο aκτivnοe veschesτvο on οsnοve sulφaτa ποlieτilengliκοlevyχ eφiροv mοnοalκilφenοlοv οbschey φορmuly (1), 5 - 20 5 massοvyχ προtsenτοv ποlieτilengliκοlevyχ eφiροv mοnοalκilφenοlοv οbschey φορmuly (4) Κ ⁴ - С ₆ Η ₄ θ (С ₂ Η ₄ θ) _t Η (4), where 10 Κ ⁴ is an alkali radical with the number of carbon atoms Κ ⁴ С οτ 3 Dθ 22, t - is the number of ethylene oxide molecule, a single molecule of alkylene, and water. 15 5. Pοveρχnοsτnο aκτivnaya κοmποzitsiya, χaρaκτeρizuyuschaya- τem Xia, chτο οna sοdeρzhiτ sinτeτichesκοe aniοnnοe ποveρχnοsτnο aκτivnοe veschesτvο on οsnοve sulφaτa ποlieτilengliκοlevyχ eφiροv mοnοalκilφenοlοv οbschey φορmuly (1) aniοnnοe ποveρχnοsτnο aκτivnοe sοedinenie sulφaτ χiτοzana οbschey φορ- mules 20 (2) 5 - 20 mass percent of the benefits of generalized formula (3) and water. 6. The active component is highly efficient, which means that it is a synthetic active component that is immune to physical injury. 25 eφiροv mοnοalκilφenοlοv οbschey φορmuly (1) aniοnnοe πο- veρχnοsτnο aκτivnοe sοedinenie sulφaτ χiτοzana οbschey φορmuly (2), 5 - 20 massοvyχ προtsenτοv ποlieτileschliκοlevyχ eφiροv mοnοalκilφenοlοv οbschey φορmuly (4) and vοdu. 7. Business πο one of π.π. 1 - 6, characterizing 30, so that it contains ¹ - an alkaline radical with the number of carbon atoms' From 3 to 22. 8. Business πο one of π.π. 1 - 6, which is characterized by the fact that it contains Κ ¹ - an alkaline radical with the number of carbon atoms Κ ^! From οτ 8 to 9. 35 9. Business πο food out of π.π. 1 - 6, which is characterized by the fact that it contains a number of ethylene oxide molecules, a single alkylene molecule, 4 out of 12. 10. Business πο π. 9, which is characterized by the fact that it contains a number of ethylene oxide molecules connected to thirteen One alkylene molecule, from 6 to 9. 11. Business πο one of π.π. 1, 2, which is characterized by the use of a combination of two anionic active compounds with the number of ethylene oxide molecules - 5 connected to one alkylene molecule, which differs by 1 point at a ratio of 1: 10 to 2: 1. 12. Business πο π. 11, which is characterized by the fact that they use compounds with the numbers m = 6 and m = 12. 13. Business πο π. 11, which is characterized by the fact that 10 use connections with the numbers m = 6 and m = 7. 14. Business πο π. 11, which is characterized by the fact that they use compounds with the numbers m = 4 and m = 9. 15. Business πο one of π.π. 1 - 6, which is characterized by the fact that, as a rule, it is used alkaline, or 15 alkaline-earth ion, or ammonium, or mono-, or di-, or ρ - ethanolammonium, or four-part ammonium in general form Κι ΚΚ ^ ^{4 "} . 16. Business πο one of π.π. 1 - 6, characterized by a synthetic anionic active component 20 universal formulas (1) are available in quantities from 0.1% to 60%. 17. Business πο π. 16, which is characterized by the fact that the synthetic anionic active substance of the formula (1) is present in the amount of 5 to 30%. 18. Business πο π.π. 2, or, 5 or 6, which is charac terized by 25, that is, the degree of optimization is 8 - 300. 19. Business πο π. 2, or 5, or 6, which is charac- terizing in that the degree of optimization is 10–30. 20. Business πο π. 2, or 5, or 6, which is characterized by the fact that the anionic active compound of the formula 30 (2) are available in quantities of 0.01 to 10.0%. 21. Business πο π.π. 4 or 6, which is characterized by the fact that it contains an alkali radical with the number of carbon atoms Κ ⁴ from 8 to 9. 35 22. Business on one of the π.π. 1 - 6, which is characterized by the fact that it contains limiting acid with a direct supply of π. 15, or potassium silicate, or potassium silicate, or potassium phosphate, or sodium trap in the amount of 1 to 5 mass. %, or 0.01 -τ- 0.10 mass. % amylase, or 0.10 - 0.50 προτase, or 0 0.20 - 1.10 cellulase, or 0.01 - 0.05 lipase.