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WO2001027927A1 - Dispositif photocatalytique destine a reduire la contamination d'un lecteur de disque - Google Patents

Dispositif photocatalytique destine a reduire la contamination d'un lecteur de disque Download PDF

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Publication number
WO2001027927A1
WO2001027927A1 PCT/US2000/028295 US0028295W WO0127927A1 WO 2001027927 A1 WO2001027927 A1 WO 2001027927A1 US 0028295 W US0028295 W US 0028295W WO 0127927 A1 WO0127927 A1 WO 0127927A1
Authority
WO
WIPO (PCT)
Prior art keywords
photocatalytic material
housing
contaminant reduction
reduction system
lamp
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2000/028295
Other languages
English (en)
Inventor
Gregory I. Rudd
Karl H. Scheppers
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Seagate Technology LLC
Original Assignee
Seagate Technology LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Seagate Technology LLC filed Critical Seagate Technology LLC
Priority to KR1020027004697A priority Critical patent/KR20020039681A/ko
Priority to DE10085089T priority patent/DE10085089T1/de
Priority to GB0208476A priority patent/GB2374466B/en
Priority to JP2001530860A priority patent/JP2003527720A/ja
Publication of WO2001027927A1 publication Critical patent/WO2001027927A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • G—PHYSICS
    • G11—INFORMATION STORAGE
    • G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B33/00—Constructional parts, details or accessories not provided for in the other groups of this subclass
    • G11B33/14—Reducing influence of physical parameters, e.g. temperature change, moisture, dust
    • G—PHYSICS
    • G11—INFORMATION STORAGE
    • G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B33/00—Constructional parts, details or accessories not provided for in the other groups of this subclass
    • G11B33/14—Reducing influence of physical parameters, e.g. temperature change, moisture, dust
    • G11B33/1446—Reducing contamination, e.g. by dust, debris
    • G11B33/1453—Reducing contamination, e.g. by dust, debris by moisture
    • G—PHYSICS
    • G11—INFORMATION STORAGE
    • G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B33/00—Constructional parts, details or accessories not provided for in the other groups of this subclass
    • G11B33/14—Reducing influence of physical parameters, e.g. temperature change, moisture, dust
    • G11B33/1446—Reducing contamination, e.g. by dust, debris

Definitions

  • the present invention relates generally to hard disk drives, and more particularly, to the reduction of contamination in hard disk drives.
  • HDD hard disk drive
  • HDI head-disk interface
  • the gap (height at which the head flies above the disk) is so small.
  • the amount of data that can be stored on a disk is proportional to this gap.
  • the gap is less than 30 nanometers (30 x 10 "9 meters).
  • the disks also must be very smooth.
  • Most present designs require the head to land on the disk when the disk drive is shut off. Upon start up, it must easily lift off the disk and leave no residue or damage behind.
  • Liquid or gaseous contamination can cause failure by several modes: •
  • Corrosion of the disks can roughen the surface; corrosion of the heads can affect electrical performance.
  • the fly height can be impacted by build-up of liquid or solid residue on the head, making data reading and writing unreliable. Vapor concentrations as low as parts per billion of some common chemicals can cause catastrophic failure by one of these means. Changes in HDD technology such as lower flying heights, smoother disk surfaces, and lower power consumption by the spindle motor have all contributed to the greater sensitivity of new designs to these problems.
  • Some necessary components are intrinsically vapor generating (e.g., bearing grease).
  • a third commonly used scheme is to include a sorbent or adsorbent material, e.g., activated charcoal, inside the HDD. This is highly beneficial but demonstrably limited in its success.
  • the sorbent is necessarily limited in its capacity for contaminants; it will eventually become saturated if continuously exposed.
  • the principal of sorption, whether physical or chemical, is reversible to varying degrees. Contaminants adsorbed at one temperature will be desorbed as the temperature rises.
  • the present invention provides a solution to this and other problems as it comprises a device for purifying the internal atmosphere of an HDD.
  • the present invention comprises an assembly that includes a photocatalytic material and a device for activating photocatalytic material.
  • an assembly of appropriate size and shape for mounting within a sealed or semi-sealed hard disk drive is provided. More specifically, a photocatalytic surface is provided in close proximity or in contact with a light source which may be utilized as a means for activation.
  • the photocatalytic surface is preferably titanium dioxide (TiO 2 ); it may be other metal oxide catalyss that can be photochemically activated such as zinc oxide (ZnO).
  • the invention comprises an assembly that contains a photocatalytic material and a means for activating thereof.
  • the assembly is of appropriate size and shape for mounting within a sealed or semisealed HDD.
  • the catalytic activity of the photocatalytic material is engineered to cause chemical reactions of the vapor contaminants within the disk drive enclosure, which impinge on it, converting them to harmless gaseous species.
  • the most important photocatalytic process for this purpose is photocatalytic oxidation. This approach has many inherent advantages over the current state of the art. The catalytic surface would never be exhausted, as would an absorbent.
  • Elevated temperature would not cause re-release of contaminants because they would be destroyed.
  • the HDD could be almost or entirely hermetically sealed against humidity and other environmental contaminants without concern that the HDD component outgassing would poison the drive. This could allow an inert atmosphere (e.g., helium) to be maintained in the drive to lower power consumption, reduce disk vibration and flutter, or reduce chemical reactions on the disk.
  • the use of the catalyst could also permit the use of "dirtier" components, reducing manufacturing costs. Alternately, lifetime of a drive could be increased with the same quality and cleanliness of components presently used.
  • the capacity of the catalyst would only be limited by the surface area, which could comprise a great portion of the interior illuminated surface, and the illumination power available.
  • the location of the catalyst is chosen to allow maximum exposure to the atmosphere in the drive; preferably it is located in the flow paths to the drive consisting of a photocatalytic surface in close proximity or contact with a light source as a means for activation.
  • a non-friable, high surface area TiO 2 (titanium dioxide) coating is applied to a fluorescent lamp with substantial light output in the UN spectrum (below 400 nm wavelength, and most preferably below 300 nm wavelength) and of a size to fit within a disk drive.
  • a coating can be applied by e.g., dipping the lamp in a sol-gel dispersion of TiO 2 and curing at elevated temperature.
  • Another preferred embodiment is substantially the same as above except the catalytic surface consists of a sheath of porous TiO 2 -containing ceramic that fits over the lamp.
  • the catalytic surface consists of particulate TiO 2 enclosed in a mesh or porous material that wraps or slips around the lamp, preventing the particulate catalyst from escaping but allowing free exchange of gases.
  • the catalytic surface consists of a mesh (glass or fabric) impregnated with TiO 2 -catalyst.
  • the fluorescent lamp with substantial output below 300 nm could be replaced by one with substantial output below 400 nm but not 300 nm.
  • the fluorescent lamp could be replaced by an incandescent lamp with substantial output below 400 nm.
  • the lamp could also be replaced, in whole or in part, by a transparent window in the drive to allow ambient light or light from an external source to illuminate the catalytic surface(s) as described above.
  • Banks of disk drives could be kept catalytically clean by this means.
  • the method of illumination could be one such as described above, but the catalytic surface could be painted or attached to an area of the drive that could be illuminated.
  • One such surface could be the cavity of the sliders, those hard ceramic structures that provide the air-bearing surface and to which the heads are attached. The advantage of having the catalytic surface on the slider would be the destruction of contaminants in an area where they ordinarily do great harm to the disk drive function.
  • Figure 1 is a plan view of a disk drive in which the present invention is useful
  • FIGS. 2 through 4 illustrate various exemplary embodiments of the present invention.
  • Figure 5 illustrates the results of a test conducted using the present invention which demonstrates the effectiveness at eliminating contaminants of the present invention.
  • FIG. 1 shows a plan view of a disk drive in which the present invention is useful.
  • the features of the disk drive are clearly only exemplary, and the present invention is useful in any size or configuration of disk drive in which internal contamination potentially presents a problem.
  • the disk drive 2 includes a base member 4 in which internal components are mounted. Base member 4 couples to a top cover 6 which forms a sealed environment or cavity within the housing so established for critical parts of disk drive 2.
  • Disk drive 2 includes one or more disks 8 which are mounted for rotation on a spindle motor generally indicated at 10. A plurality of magnetic read write heads (not shown) are supported each on a slider twelve which is mounted to an actuator 14.
  • actuator 14 is rotary actuator which is mounted for pivoting about a pivot axis 16.
  • Actuator 16 includes one or more head mounting arms 18, each of which couples a head to the actuator arm via a load gim-beam/gimbal assembly 20 which supports the slider to fly over the surface of the disk.
  • the actuator motor 22 is also coupled to actuator 14 to provide a force to move these sliders 12 and the heads supported thereon to a desired position on the surface of the disk 8.
  • the present invention incorporates an assembly that includes a photocatalytic material and a device for activating photocatalytic material within the disk drive housing.
  • an assembly of appropriate size and shape for mounting within a sealed or semi-sealed hard disk drive (HDD) is provided as shown at 20 in Fig. 2.
  • a photocatalytic surface is provided in close proximity or in contact with a light source 22 which may be utilized as a means for activation.
  • the photocatalytic surface may be titanium dioxide (TiO 2 ) or zinc oxide (ZnO) which is a metal oxide catalyst that can be photochemically activated.
  • the invention consists of an assembly that includes a photocatalytic material and a means for activation.
  • the assembly is of appropriate size and shape for mounting within the sealed or semisealed HDD.
  • the catalytic activity of the photocatalytic material is engineered to cause chemical reactions of the vapor contaminants within the disk drive enclosure, which impinge on it, converting them to harmless gaseous species.
  • the most important photocatalytic process for this purpose is photocatalytic oxidation.
  • the catalytic surface would not be exhausted, as would an absorbent. Elevated temperature would not cause re-release of contaminants because they would be destroyed.
  • the HDD could be almost or entirely hermetically sealed against humidity and other environmental contaminants without concern that the HDD component outgassing would poison the drive. This could allow an inert atmosphere (e.g., helium) to be maintained in the drive to lower power consumption, reduce disk flutter, or reduce chemical reactions on the disk.
  • the use of the catalyst could also permit the use of "dirtier" components, reducing manufacturing costs. Alternately, lifetime of a drive could be increased with the same quality and cleanliness of components presently used.
  • the capacity of the catalyst would only be limited by the surface area, which could comprise a great portion of the interior illuminated surface, and the illumination power available.
  • the location of the catalyst would be chosen to allow maximum exposure to the atmosphere in the drive; preferably it is located in the flow path around the rotating disc.
  • a preferred embodiment of the scheme consists of an assembly internal to the drive in a region close to the disk and where air flow over the photocatalytic surface is maximized, comprising a photocatalytic surface in close proximity or contact with a light source as a means for activation.
  • a non-friable, high surface area TiO 2 (titanium dioxide) coating is applied to a fluorescent lamp 22 with substantial light output in the UN spectrum (below 400 nm wavelength, and most preferably below 300 nm wavelength) of a size to fit within a disk drive.
  • Such a coating can be applied by e.g., dipping the lamp in a sol-gel dispersion of TiO 2 and curing at elevated temperature.
  • the device is shown located adjacent the rotating disc to maximize the air flow over the photocatalyst.
  • catalytic surface consists of a sheath 24 (Fig. 3) of porous TiO 2 -containing ceramic that fits over the lamp 22.
  • the catalytic surface consists of particulate TiO 2 enclosed in a mesh or porous material 24 that wraps or slips around the lamp, preventing the particulate catalyst from escaping but allowing free exchange of gases.
  • the catalytic surface comprises mesh
  • the fluorescent lamp 22 with substantial output below 300 nm could be replaced by one with substantial output below 400 nm.
  • the fluorescent lamp 22 could be replaced by an incandescent lamp with substantial output below 400 nm.
  • the lamp could be replaced entirely by a transparent window 22 (Fig. 4) in the drive to allow ambient light or light from an external source to illuminate a catalytic surface(s) 32 in the air flow region as described above.
  • a transparent window 22 Fig. 4
  • Banks of disk drives could be kept catalytically clean by this means; also the window could be used in combination with an internal lamp.
  • the method of illumination could be one such described above, but the catalytic surface could be painted or attached to an area of the drive that could be illuminated.
  • One such surface could be a surface of the sliders 12, those hard ceramic structures that provide the air-bearing surface and to which the heads are attached. The advantage of having the catalytic surface on the slider would be the destruction of contaminants in an area where they ordinarily do great harm to the disk drive function.
  • the TiO 2 catalyst could be replaced by another metal oxide catalyst that can be photochemically activated, e.g., ZnO.
  • the photocatalytic technology most applicable to this invention uses TiO 2
  • TiO 2 adsorbs water and other vapors onto its surface.
  • the electronic defects created by illumination of TiO 2 convert water (only traces of water are required) to hydroxyl radicals. Hydroxyl radicals are highly reactive, and will oxidize any organic (carbon-containing) vapor, which is also adsorbed on the TiO 2 .
  • This oxidation process which is essentially burning, converts the adsorbed organic vapor into water vapor and CO 2 (carbon dioxide), both of which are harmless to the drive in the small amounts that would be created. Since the vapor phase drive contaminants, which have caused reliability problems, are almost exclusively organic, they would be subj ect to destruction continuously, or whenever the photocatalyst was illuminated.
  • the lamps most appropriate are between 3 and 9 mm in diameter and between 25 and 100 mm long. The smallest uses about 0.7 watt of power and has a lifetime of 3,000 hours nominal, up to 8,000 hours for larger lamps. Lowering the voltage (and output) can extend lifetime. Lamps that emit in the 250-300 nm wavelength and 300-400 nm wavelength are available in some sizes. The lamp would probably not have to be in continuous use; for example it could be activated when the drive temperature rises (increasing the likelihood of outgassing), when stiction was detected (changes in fly height or motor starting torque) or some other contamination sensor was triggered (e.g., by light scattered off of a disk surface). All of these could be implemented by a sensor 60 (Fig. 3) well-known in this field. The catalytic activity would linger for some time after the illumination ceased.
  • Fig. 5 illustrates a test run using the photocatalyst described above.
  • the line marked "UV OFF" 50 shows the presence of contaminants; the line marked "UV ON", conducted in substantially the same atmosphere, shows the dramatic absence thereof.
  • the present invention comprises a contaminant reduction system for an electronic device of the type having a housing 6 such as shown in Fig. 1 with a closed interior and having at least one critical component such as disc 8 or transducer 12 located within the housing which would be adversely affected by vapor contaminants within the housing.
  • the contamination reduction system comprises, as shown in Fig.
  • a photocatalytic material 2 located within the closed interior of the housing, the photocatalytic material being located for chemically reacting with the vapor contaminants within the housing, and a device such as lamp 22 for activating the photocatalytic material so that the catalytic activity of the activated photocatalytic material causes a chemical reaction with the vapor contaminants which impinge on the photocatalytic material.
  • the lamp preferably has an output below 400 nm.
  • the lamp may comprise a fluorescent lamp with a substantial light output in the UV spectrum or an incandescent lamp with a substantial output below 400 nm.
  • the device for activating the photocatalytic material may comprise a transparent window 30 in the drive housing which allows ambient light or light from an external source below 400 nm to illuminate the photocatalytic material.
  • the photocatalytic material preferably comprises a metal oxide catalyst that can be photochemically activated. It may be chosen from the group comprising TiO 2 and ZnO.
  • the photocatalytic material may be applied to a surface of the lamp, or to a surface of the housing which can be illuminated by the lamp, or to a surface on or near the critical component which is subject to adverse effect by vapor contaminants.
  • the photocatalytic material may be supported on the head assembly 12, or more specifically on a slider included in the head disk assembly.
  • the invention can also be considered as a contaminant reduction method for an electronic device of the type having a housing with a closed interior and having at least one critical component located within the housing which would be adversely affected by vapor contaminants within the housing.
  • the contamination reduction method comprises locating a photocatalytic material located within the closed interior of the housing, the photocatalytic material being located for chemically reacting with the vapor contaminants within the housing, and activating the photocatalytic material so that the catalytic activity of the activated photocatalytic material causes a chemical reaction with the vapor contaminants which impinge on the photocatalytic material.
  • the photocatalytic material is activated only by sensing certain predefined conditions (See Fig. 3, 60) .
  • the photocatalytic material is preferably TiO.
  • the activating step preferably includes activating a lamp with a substantial output below 400 nm to illuminate the photocatalytic material.

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  • Catalysts (AREA)

Abstract

Ce système de réduction de contaminants comprend un ensemble de dimension et forme adéquates, destiné à être monté dans un lecteur de disque dur, scellé ou partiellement scellé. Ce système comprend une surface photocatalytique montée au proche voisinage d'une source lumineuse ou en contact avec cette source, laquelle peut s'employer en tant que moyen d'activation. De préférence, la surface photocatalytique est en dioxyde de titane (TiO2), ou elle peut être à base d'autres catalyseurs d'oxydes métalliques susceptibles d'être activés de manière photochimique, comme l'oxyde de zinc (ZnO). Cette activation s'obtient par emploi d'une lampe qui éclaire le photocatalyseur et possède une valeur de sortie inférieure à 100 nm.
PCT/US2000/028295 1999-10-12 2000-10-12 Dispositif photocatalytique destine a reduire la contamination d'un lecteur de disque Ceased WO2001027927A1 (fr)

Priority Applications (4)

Application Number Priority Date Filing Date Title
KR1020027004697A KR20020039681A (ko) 1999-10-12 2000-10-12 디스크 드라이브 오염 감소를 위한 광촉매 장치
DE10085089T DE10085089T1 (de) 1999-10-12 2000-10-12 Photokatalytische Vorrichtung zur Kontaminationsverringerung eines Plattenlaufwerks
GB0208476A GB2374466B (en) 1999-10-12 2000-10-12 Photocatalytic device for disk drive contamination reduction
JP2001530860A JP2003527720A (ja) 1999-10-12 2000-10-12 ディスクドライブ汚染物減少のための光触媒装置

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US15883899P 1999-10-12 1999-10-12
US60/158,838 1999-10-12

Publications (1)

Publication Number Publication Date
WO2001027927A1 true WO2001027927A1 (fr) 2001-04-19

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PCT/US2000/028295 Ceased WO2001027927A1 (fr) 1999-10-12 2000-10-12 Dispositif photocatalytique destine a reduire la contamination d'un lecteur de disque

Country Status (6)

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US (1) US6433957B1 (fr)
JP (1) JP2003527720A (fr)
KR (1) KR20020039681A (fr)
DE (1) DE10085089T1 (fr)
GB (1) GB2374466B (fr)
WO (1) WO2001027927A1 (fr)

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US6643093B2 (en) * 2002-01-15 2003-11-04 Hitachi Global Storage Technologies Netherlands, B.V. Magnetic recording device with improved reliability
US7365937B2 (en) * 2003-07-24 2008-04-29 Seagate Technology Llc Inert gas atmosphere replenishment structure
US7420778B2 (en) * 2003-12-22 2008-09-02 Seagate Technology Llc Suspension component with sealed damping layer
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US7329877B2 (en) * 2004-12-15 2008-02-12 Honeywell International, Inc. Photoelectrocatalytic sensor for measuring oxidizable impurities in air
CN100490615C (zh) * 2005-03-25 2009-05-20 鸿富锦精密工业（深圳）有限公司 便携式电子装置外壳
DE102005036427A1 (de) * 2005-08-03 2007-02-08 Schott Ag Substrat, umfassend zumindest eine voll- oder teilflächige makrostrukturierte Schicht, Verfahren zu deren Herstellung und deren Verwendung
US7811539B2 (en) * 2005-11-03 2010-10-12 Seagate Technology Llc Device and method for filtering contaminants
US20100310441A1 (en) * 2009-06-05 2010-12-09 Basf Corporation Catalytic Article for Removal of Volatile Organic Compounds in Low Temperature Applications
WO2012003505A2 (fr) 2010-07-02 2012-01-05 Donaldson Company, Inc. Catalyseur basse température pour article de lecteur de disque et son procédé
US9142229B2 (en) 2013-03-15 2015-09-22 Seagate Technology Llc Heat assisted magnetic recording head having thermal sensor with high-TCR transparent conducting oxide
US8885287B1 (en) 2014-01-06 2014-11-11 HGST Netherlands B.V. Method and apparatus for prevention of Fe contamination with oxygen mixture in a hard disk drive
US9978412B1 (en) 2015-11-06 2018-05-22 Seagate Technology Llc Transparent thermocouple for heat-assisted magnetic recording device
US10446180B1 (en) 2018-03-21 2019-10-15 Seagate Technology Llc Multi-actuator interconnector

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Also Published As

Publication number Publication date
US6433957B1 (en) 2002-08-13
DE10085089T1 (de) 2002-11-21
JP2003527720A (ja) 2003-09-16
KR20020039681A (ko) 2002-05-27
GB2374466B (en) 2003-11-12
GB2374466A (en) 2002-10-16
GB0208476D0 (en) 2002-05-22

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