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WO2001009242A1 - Composition de polyol polymere, son procede de production et procede de production de resine polyurethanne - Google Patents

Composition de polyol polymere, son procede de production et procede de production de resine polyurethanne Download PDF

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Publication number
WO2001009242A1
WO2001009242A1 PCT/JP2000/004999 JP0004999W WO0109242A1 WO 2001009242 A1 WO2001009242 A1 WO 2001009242A1 JP 0004999 W JP0004999 W JP 0004999W WO 0109242 A1 WO0109242 A1 WO 0109242A1
Authority
WO
WIPO (PCT)
Prior art keywords
polymer
polyol
mass
polyol composition
acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2000/004999
Other languages
English (en)
Japanese (ja)
Inventor
Tetsuji Kawamoto
Tomio Kawazoe
Kiyoshi Ikeda
Munekazu Satake
Futoshi Kitatani
Tsuyoshi Tomosada
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sanyo Chemical Industries Ltd
Original Assignee
Sanyo Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sanyo Chemical Industries Ltd filed Critical Sanyo Chemical Industries Ltd
Priority to JP2001514040A priority Critical patent/JP3686372B2/ja
Publication of WO2001009242A1 publication Critical patent/WO2001009242A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
    • C08F283/06—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polyethers, polyoxymethylenes or polyacetals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/04—Polymerisation in solution
    • C08F2/06—Organic solvent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/63—Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers
    • C08G18/632—Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers onto polyethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2101/00—Manufacture of cellular products
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0041—Foam properties having specified density
    • C08G2110/005—< 50kg/m3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0083—Foam properties prepared using water as the sole blowing agent

Definitions

  • Methods for obtaining (I) include, for example, the following (i) and (ii): It is.
  • aromatic mono- or polyamines having 6 to 20 carbon atoms for example, aniline, phenylenediamine, tolylene diamine, xylylene diamine, methylene dianiline and diphenyl ether diamine); Alicyclic amines (isophorone diamine, cyclohexylene diamine Amine and dicyclohexylmethanediamine); and C4-C15 complex cyclic amines (eg, aminoethylpiperazine).
  • another polyol (A2) can be used in combination with the compound (A1) having a structure in which an alkylene oxide is added to the active hydrogen-containing compound.
  • the usage ratio of (A l) / (A2) is usually 100 to 0 Z 80 by mass ratio.
  • a graft-type dispersant in which a polyol and an oligomer such as a graft-type polymer having a polymer-affinity segment as a main chain (for example, see Japanese Patent Application Laid-Open No. 05-09134) are used; Modified polyols obtained by reacting at least a part of the hydroxyl groups of a polyol with methylene dihalide and Z or ethylene dihalide to increase the molecular weight (for example, Japanese Patent Application Laid-Open No.
  • aminocarboxylic acid that forms an amide bond examples include aminocarboxylic acids having 2 to 18 carbon atoms, such as glycine, alanine, valine, leucine, isoleucine, and phenylalanine; Acids, ⁇ -aminoenanthic acid, ⁇ -aminocaprylic acid, ⁇ _aminobergonic acid, ⁇ -aminocapric acid, 11-aminoundecanoic acid, and 12-aminododecanoic acid.
  • aminocarboxylic acids having 2 to 18 carbon atoms such as glycine, alanine, valine, leucine, isoleucine, and phenylalanine
  • Acids ⁇ -aminoenanthic acid, ⁇ -aminocaprylic acid, ⁇ _aminobergonic acid, ⁇ -aminocapric acid, 11-aminoundecanoic acid, and 12-aminododecanoic acid.
  • a known isocyanate compound used for synthesizing an ordinary polyurethane resin can be used.
  • 2,4- or 2,6-tolylene diisocyanate (TD I) crude TDI, 2,4 'one or 4,4'-diphenylmethane diisocyanate (MD I) and crude MD I ⁇ Crude diaminodiphenylmethane (condensation product of formaldehyde and aromatic amine, aniline or a mixture thereof; mixture of diaminodiphenylmethane and a small amount (for example, 5 to 20% by mass) of trifunctional or higher polyamine) Phosgenated product; polyallyl polyisocyanate (PAP I) ⁇ etc.
  • TD I 2,4- or 2,6-tolylene diisocyanate
  • MD I crude TDI, 2,4 'one or 4,4'-diphenylmethane diisocyanate
  • MD I crude MD I ⁇ Crude diaminodiphenylmethane
  • the active hydrogen-containing compounds used to form urethane or urea bonds are (Al), (A2) and polyols described above.
  • the active hydrogen-containing compound described in the description of (A) can be used.
  • an ester bond, an amide bond In (bl) used in the production method of the present invention, an ester bond, an amide bond.
  • a urethane bond, a urea bond or an imide bond may be formed by a commonly known esterification reaction, amidation reaction, urethanization reaction, urea bond. It can be obtained by a chemical reaction or an imidization reaction.
  • the polymerization of the radical polymerizable compound can be performed in the same manner as in the polymerization of a conventional polymer polyol.
  • a method of polymerizing an ethylenically unsaturated compound (b) in a polyol (A) containing a dispersant (D) in the presence of a polymerization initiator US Pat. No. 3,338,351) Etc.
  • the polymerization can be carried out in a batch system or a continuous system, and can be carried out under normal pressure, under pressure or under reduced pressure. If necessary, a solvent and a chain transfer agent can be used.
  • the solvent examples include toluene, xylene, acetonitrile, ethyl acetate, hexane, heptane, octene, nonene, decene, dioxane, N, N-dimethylformamide, N, N-dimethylacetamide, isopropyl alcohol and n —Buynool and the like.
  • the amount of the solvent used is usually 0 to 50% by mass based on the amount of (b) used.
  • organic solvent to be used examples include the same organic solvents as those exemplified in the sixth invention.
  • low molecular weight polyols particularly diols
  • ethylene glycol, 1,4-butanediol, neopentyl alcohol, 1,6-hexanediol is preferred.
  • ethylene glycol, 1,4-butanediol, neopentyl alcohol, 1,6-hexanediol is a mixture of more than one species.
  • density 1 5-5 0 range of k gZm 3 are preferred, 2 5% I LD, tensile strength, tear strength, elongation at break, modulus of resilience and breathability, The larger the value, the better. The smaller the numerical value of the compression set, the better.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Polymerisation Methods In General (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Graft Or Block Polymers (AREA)

Abstract

L'invention concerne une composition de polyol polymère (I) comprenant un polyol (A) et, dispersées dans (A), des particules polymères (B) formées par la polymérisation d'un composé (b) éthyléniquement insaturé dans un polyol. La teneur de (B) est de 35 à 75 % en poids par rapport à (I) et la dose d'un polymère (P), qui se dissout dans (A), n'excède pas 5 % en poids par rapport à (A). L'invention concerne également un procédé de production d'une résine de polyuréthanne alvéolaire ou non expansé qui consiste à faire réagir un ingrédient polyol avec un ingrédient polyisocyanate en présence ou en l'absence d'un agent gonflant. La composition de polyol polymère est utilisée au moins comme partie de l'ingrédient polyol. Ladite composition présente une faible viscosité et une excellente stabilité de dispersion même dans le cas où la teneur en particules polymères est plus importante. Elle est utile dans la production efficace d'une résine polyuréthanne excellente en ILD 25 % (dureté) et compression ou une mousse de celle-ci.
PCT/JP2000/004999 1999-07-30 2000-07-26 Composition de polyol polymere, son procede de production et procede de production de resine polyurethanne Ceased WO2001009242A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2001514040A JP3686372B2 (ja) 1999-07-30 2000-07-26 ポリマーポリオール組成物、その製造方法およびポリウレタン樹脂の製造方法

Applications Claiming Priority (10)

Application Number Priority Date Filing Date Title
JP21817199 1999-07-30
JP11/218171 1999-07-30
JP22411999 1999-08-06
JP11/224119 1999-08-06
JP11/339234 1999-11-30
JP33923499 1999-11-30
JP2000015109 2000-01-24
JP2000/15109 2000-01-24
JP2000182351 2000-06-16
JP2000/182351 2000-06-16

Related Child Applications (2)

Application Number Title Priority Date Filing Date
US09806609 A-371-Of-International 2001-03-28
US10/068,182 Continuation-In-Part US6624209B2 (en) 1999-07-30 2002-02-06 Polymer polyol composition, process for producing the same, and process for producing polyurethane resin

Publications (1)

Publication Number Publication Date
WO2001009242A1 true WO2001009242A1 (fr) 2001-02-08

Family

ID=27529652

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2000/004999 Ceased WO2001009242A1 (fr) 1999-07-30 2000-07-26 Composition de polyol polymere, son procede de production et procede de production de resine polyurethanne

Country Status (3)

Country Link
JP (1) JP3686372B2 (fr)
CN (1) CN1142980C (fr)
WO (1) WO2001009242A1 (fr)

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007007592A1 (fr) * 2005-07-07 2007-01-18 Sanyo Chemical Industries, Ltd. Composition de polyol contenant de fines particules dispersées, procédé de fabrication de polyols polymères, et procédé de fabrication de résines de polyuréthane
WO2009041452A1 (fr) 2007-09-28 2009-04-02 Sanyo Chemical Industries, Ltd. Polyol polymère, son procédé de fabrication et procédé de fabrication d'une résine de polyuréthane
WO2009048007A1 (fr) 2007-10-10 2009-04-16 Sanyo Chemical Industries, Ltd. Procédé de fabrication d'un polyol à fines particules dispersées et procédé de fabrication d'une résine de polyuréthane
WO2018174188A1 (fr) 2017-03-23 2018-09-27 三洋化成工業株式会社 Agent d'amélioration d'indice de viscosité, et composition d'huile lubrifiante
US10808062B2 (en) 2016-02-22 2020-10-20 Kaneka Corporation Polyol composition and thermosetting resin
WO2020262088A1 (fr) 2019-06-26 2020-12-30 三洋化成工業株式会社 Composition d'amélioration d'indice de viscosité et composition d'huile lubrifiante
FR3118630A1 (fr) 2021-01-06 2022-07-08 Total Marketing Services Composition lubrifiante ayant une stabilité à froid et des propriétés fuel eco améliorées
WO2023031417A1 (fr) 2021-09-03 2023-03-09 Totalenergies Onetech Composition lubrifiante présentant des propriétés d'épaississement à froid améliorées
DE112021003394T5 (de) 2020-08-20 2023-04-20 Sanyo Chemical Industries, Ltd. Viskositätsindex-Verbesserer-Zusammensetzung undSchmieröl-Zusammensetzung
DE112021004098T5 (de) 2020-09-14 2023-07-06 Sanyo Chemical Industries, Ltd. Viskositätsindex-Verbesserer und Schmieröl-Zusammensetzung
WO2023238603A1 (fr) 2022-06-10 2023-12-14 三洋化成工業株式会社 Composition améliorant l'indice de viscosité et composition d'huile lubrifiante

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100376616C (zh) * 2005-12-21 2008-03-26 中国科学院山西煤炭化学研究所 一种制备聚酯型聚合物多元醇的方法
JP4861972B2 (ja) * 2007-01-10 2012-01-25 三洋化成工業株式会社 ポリマーポリオール、その製造方法及びポリウレタンの製造方法
JP6246235B2 (ja) * 2013-12-24 2017-12-13 三洋化成工業株式会社 自動車用内装材及びその製造方法
CN109422910B (zh) * 2017-08-24 2021-04-13 补天新材料技术有限公司 包含原甲酸醇胺盐和碳酸醇胺盐的发泡剂及用于聚氨酯连续板泡沫体材料中的用途
CN112225873B (zh) * 2020-09-15 2022-04-22 万华化学集团股份有限公司 一种高透明快成型的可降解热塑性聚氨酯弹性体及其制备方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4111865A (en) * 1974-11-13 1978-09-05 Union Carbide Corporation Polymer/polyols and polyurethane forms and elastomers therefrom
US4198488A (en) * 1978-06-26 1980-04-15 Union Carbide Corporation Polymer-polyols and polyurethanes based thereon
JPS61115919A (ja) * 1984-11-13 1986-06-03 Asahi Glass Co Ltd 重合体分散ポリオ−ルの製造方法

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4111865A (en) * 1974-11-13 1978-09-05 Union Carbide Corporation Polymer/polyols and polyurethane forms and elastomers therefrom
US4198488A (en) * 1978-06-26 1980-04-15 Union Carbide Corporation Polymer-polyols and polyurethanes based thereon
JPS61115919A (ja) * 1984-11-13 1986-06-03 Asahi Glass Co Ltd 重合体分散ポリオ−ルの製造方法

Cited By (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007007592A1 (fr) * 2005-07-07 2007-01-18 Sanyo Chemical Industries, Ltd. Composition de polyol contenant de fines particules dispersées, procédé de fabrication de polyols polymères, et procédé de fabrication de résines de polyuréthane
US8394899B2 (en) 2005-07-07 2013-03-12 Sanyo Chemical Industries, Ltd. Fine particle-dispersed polyol composition, method for producing polymer polyol, and method for producing polyurethane resin
US8455591B2 (en) 2005-07-07 2013-06-04 Sanyo Chemical Industries, Ltd. Fine particle-dispersed polyol composition, method for producing polymer polyol, and method for producing polyurethane resin
EP3342825A1 (fr) 2005-07-07 2018-07-04 Sanyo Chemical Industries, Ltd. Procédé de production d'un polymère polyol
WO2009041452A1 (fr) 2007-09-28 2009-04-02 Sanyo Chemical Industries, Ltd. Polyol polymère, son procédé de fabrication et procédé de fabrication d'une résine de polyuréthane
US8772405B2 (en) 2007-09-28 2014-07-08 Sanyo Chemical Industries, Ltd. Polymer polyol, method for producing the same, and method for producing polyurethane resin
US9109078B2 (en) 2007-09-28 2015-08-18 Sanyo Chemical Industries, Ltd. Polymer polyol, method for producing the same, and method for producing polyurethane resin
WO2009048007A1 (fr) 2007-10-10 2009-04-16 Sanyo Chemical Industries, Ltd. Procédé de fabrication d'un polyol à fines particules dispersées et procédé de fabrication d'une résine de polyuréthane
US9062148B2 (en) 2007-10-10 2015-06-23 Sanyo Chemical Industries, Ltd. Method for producing fine-particle-dispersed polyol, and method for producing polyurethane resin
US10808062B2 (en) 2016-02-22 2020-10-20 Kaneka Corporation Polyol composition and thermosetting resin
WO2018174188A1 (fr) 2017-03-23 2018-09-27 三洋化成工業株式会社 Agent d'amélioration d'indice de viscosité, et composition d'huile lubrifiante
WO2020262088A1 (fr) 2019-06-26 2020-12-30 三洋化成工業株式会社 Composition d'amélioration d'indice de viscosité et composition d'huile lubrifiante
DE112021003394T5 (de) 2020-08-20 2023-04-20 Sanyo Chemical Industries, Ltd. Viskositätsindex-Verbesserer-Zusammensetzung undSchmieröl-Zusammensetzung
DE112021003394B4 (de) 2020-08-20 2024-06-06 Sanyo Chemical Industries, Ltd. Viskositätsindex-Verbesserer-Zusammensetzung und Schmieröl-Zusammensetzung
DE112021004098T5 (de) 2020-09-14 2023-07-06 Sanyo Chemical Industries, Ltd. Viskositätsindex-Verbesserer und Schmieröl-Zusammensetzung
FR3118630A1 (fr) 2021-01-06 2022-07-08 Total Marketing Services Composition lubrifiante ayant une stabilité à froid et des propriétés fuel eco améliorées
WO2022148753A1 (fr) 2021-01-06 2022-07-14 Totalenergies Onetech Composition lubrifiante ayant une stabilité à froid et des propriétés fuel eco améliorées
WO2023031417A1 (fr) 2021-09-03 2023-03-09 Totalenergies Onetech Composition lubrifiante présentant des propriétés d'épaississement à froid améliorées
FR3126711A1 (fr) 2021-09-03 2023-03-10 Totalenergies Marketing Services Composition lubrifiante présentant des propriétés d’épaississement à froid améliorées
WO2023238603A1 (fr) 2022-06-10 2023-12-14 三洋化成工業株式会社 Composition améliorant l'indice de viscosité et composition d'huile lubrifiante

Also Published As

Publication number Publication date
JP3686372B2 (ja) 2005-08-24
CN1142980C (zh) 2004-03-24
CN1327465A (zh) 2001-12-19

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