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WO2001009051A1 - Decorative coating - Google Patents

Decorative coating Download PDF

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Publication number
WO2001009051A1
WO2001009051A1 PCT/CZ2000/000051 CZ0000051W WO0109051A1 WO 2001009051 A1 WO2001009051 A1 WO 2001009051A1 CZ 0000051 W CZ0000051 W CZ 0000051W WO 0109051 A1 WO0109051 A1 WO 0109051A1
Authority
WO
WIPO (PCT)
Prior art keywords
coating
decorative coating
decorative
substrate
protective layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/CZ2000/000051
Other languages
French (fr)
Inventor
Jindřich MUSIL
Jaromír KUBIŠTA
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ZIMA AS
Original Assignee
ZIMA AS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ZIMA AS filed Critical ZIMA AS
Priority to AU61467/00A priority Critical patent/AU6146700A/en
Publication of WO2001009051A1 publication Critical patent/WO2001009051A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
    • C23C14/0605—Carbon
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/06—Surface treatment of glass, not in the form of fibres or filaments, by coating with metals
    • C03C17/09—Surface treatment of glass, not in the form of fibres or filaments, by coating with metals by deposition from the vapour phase
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
    • C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
    • C03C17/3605—Coatings of the type glass/metal/inorganic compound
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
    • C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
    • C03C17/3684—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the multilayer coating being used for decoration purposes
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C23/00—Other surface treatment of glass not in the form of fibres or filaments
    • C03C23/0005—Other surface treatment of glass not in the form of fibres or filaments by irradiation
    • C03C23/0065—Other surface treatment of glass not in the form of fibres or filaments by irradiation by microwave radiation
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/02—Pretreatment of the material to be coated
    • C23C14/021—Cleaning or etching treatments
    • C23C14/022—Cleaning or etching treatments by means of bombardment with energetic particles or radiation
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00—Coatings on glass
    • C03C2217/20—Materials for coating a single layer on glass
    • C03C2217/25—Metals
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2218/00—Methods for coating glass
    • C03C2218/10—Deposition methods
    • C03C2218/15—Deposition methods from the vapour phase
    • C03C2218/154—Deposition methods from the vapour phase by sputtering
    • C03C2218/156—Deposition methods from the vapour phase by sputtering by magnetron sputtering
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2218/00—Methods for coating glass
    • C03C2218/30—Aspects of methods for coating glass not covered above
    • C03C2218/31—Pre-treatment

Definitions

  • This invention relates to the area of technology of creating a decorative coating on solid materials using a magnetron sputtering method, particularly on glass, producing textured glass in such a way
  • the substrate is divided from the decorative layer by an interlayer, e g by a titanic interlayer of Ti paint which is a metallic titanium colour, or by an interlayer of TiN -titanium nitride which is a golden colour
  • Deficiencies in the present state of technology have been solved by a method for creating a decorative coating on the solid substrate using a magnetron sputtering method according to the invention
  • the gist of the invention resides in pre-treating the substrate surface in a microwave discharge and consequently applying the decorative coating without heating the substrate up
  • the substrate is pre-treated in a microwave discharge, burning in oxygen, or a gas mixture containing oxygen, nitrogen, and/or fluorine, at a pressure ranging from 0 1 to 1000 Pa
  • the decorative coating is sputtered on the substrate, which has been pre- treated in this way, in an inert atmosphere, e g in argon, or in the presence of a reactive medium, from a cathode made of one element, or of an alloy of two or more elements, at a pressure ranging from 0 05 Pa to several Pa
  • a protective layer transparent in the optic range of the frequency spectrum, preferentially by a protective layer of Ti ⁇ 2, or Si ⁇ 2, or AI2O3, or Si3N4 or by a carbon-based protective layer
  • a protective layer transparent in the optic range of the frequency spectrum, may be used to control the resulting colour shade of the whole decorative layer consisting in this case of a decorative coating and protective layer
  • a decorative coating may be applied on the surface of a substrate, partially covered by a masking varnish, which has to be removed after a coating or, as the case may be, a protective optically transparent layer has been created.
  • textured glass with a decorative coating of stainless steel which may be covered by a protective layer made, for instance, of stainless steel nitride.
  • a protective layer made, for instance, of stainless steel nitride.
  • Another significant result is having textured glass with a decorative coating made of brass or aluminium bronze, which may be covered by a protective layer transparent in the optic range of the frequency spectrum.
  • the basic advantage of the method of this invention is the good adhesion of the coating applied on an unheated substrate. This is achieved by exposing the substrate surface to the influence of the plasma of a microwave discharge.
  • the microwave discharge is generated by microwave performance, usually at a frequency of 2.45 GHz in the working gas, i.e.
  • the activated atoms, excited molecules, and radicals are generated very effectively in comparison with other kinds of low-pressure discharges. They effectively interact with the surfaces of objects inserted into the microwave discharge. Their activation occurs when the plasma comes into contact with the surfaces of objects. The impact of their influence is manifested in a significant change of properties, particularly in the wet ability of the activated surface.
  • a layer which is transparent in the optic range e.g. of T1O2, or Si ⁇ 2, or AI2O3, or Si3N4, or one which is carbon-based.
  • This layer may be created by reactive magnetron sputtering in a mixture of argon and oxygen in the case of layers based on oxides.
  • the protective layer is sputtered from the same disk as a decorative coating and only oxygen or nitrogen is added to the argon. If a protective layer is thinner than - 4 -
  • Example of Invention Here is one example of this method being performed according to the invention described.
  • the technology for creating decorative coating consists in this example of the following three steps:
  • the invention can be applied in any industry where the decorative treatment of solid materials is required, particularly in the production of glass objects involving the decorative treatment of glass.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • General Chemical & Material Sciences (AREA)
  • Metallurgy (AREA)
  • Mechanical Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Inorganic Chemistry (AREA)
  • Physical Vapour Deposition (AREA)
  • Surface Treatment Of Glass (AREA)

Abstract

A method for creating a decorative coating on a solid substrate using a magnetron sputtering technique, which is characterized by pre-treating the substrate surface in a microwave discharge, and consequently applying the decorative coating on the substrate without the substrate heating up. A protective layer that is transparent in the optic range of the frequency spectrum may cover the decorative coating. The thickness of the transparent protective layer may be used for controlling the resulting colour shade of the decorative layer. Textured glass with a coating created by this method, with the said coating made e.g. of stainless steel, or with the said coating made of brass or aluminium bronze, which may, if it is required, be covered by a transparent protective layer.

Description

Description
Decorative Coating
Technical Field
This invention relates to the area of technology of creating a decorative coating on solid materials using a magnetron sputtering method, particularly on glass, producing textured glass in such a way
Background Art
At the present time, physical processes caught under a vacuum, particularly by evaporating or sputtering solid material, usually create decorative coatings However, ensuring good adhesion of the decorative layer to the coated object-substrate is a major problem as is protecting the surface of the decorative layer against mechanical damage - scratching as well as against chemical degradation due to contact with an atmosphere of varying humidity and with various cleaning agents, e g detergents, while it is being cleaned and polished The adhesion of layers is better when
1) depositing layers proceeds at temperatures of about 400°C and higher, and/or
2) the substrate is divided from the decorative layer by an interlayer, e g by a titanic interlayer of Ti paint which is a metallic titanium colour, or by an interlayer of TiN -titanium nitride which is a golden colour
However, both these solutions are characterized by serious limitations in mam applications For instance, a high temperature cannot be used when depositing decorative layers in case it will only be deposited on a selected part of the surface, l e on an object, which has a surface that is partially covered by masking vamish. and which cannot be exposed to high temperatures and must be removed after the decorative surface has been deposited For example, this interlayer cannot be used for depositing decorative layers on optically transparent materials like glass when a decorative layer of the same colour is required on both sides, i e on the surface of the layer as well as on surface of the glass, e g in the case of cups, vases, etc Moreover, at present, a protective coating for protecting a decorative layer against mechanical damage and chemical degradation is not satisfactorily managed
Therefore, some new and simple methods are being sought, which would allow for decorative layers to form on the surface of objects with good adhesion without heating up the object to be coated, thereby protecting the decorative coating with a high-quality optically transparent layer These solutions are needed for creating decorative layers, particularly on glass, ceramics, plastics, varnishes, cloth, thin dielectric foils and on other materials sensitive to heat
Disclosure of Invention
Deficiencies in the present state of technology have been solved by a method for creating a decorative coating on the solid substrate using a magnetron sputtering method according to the invention The gist of the invention resides in pre-treating the substrate surface in a microwave discharge and consequently applying the decorative coating without heating the substrate up
The substrate is pre-treated in a microwave discharge, burning in oxygen, or a gas mixture containing oxygen, nitrogen, and/or fluorine, at a pressure ranging from 0 1 to 1000 Pa The decorative coating is sputtered on the substrate, which has been pre- treated in this way, in an inert atmosphere, e g in argon, or in the presence of a reactive medium, from a cathode made of one element, or of an alloy of two or more elements, at a pressure ranging from 0 05 Pa to several Pa
For protecting the decorative coating from external damage, if such protection is needed, it should be coated by a protective layer, transparent in the optic range of the frequency spectrum, preferentially by a protective layer of Tiθ2, or Siθ2, or AI2O3, or Si3N4 or by a carbon-based protective layer
The thickness of a protective layer, transparent in the optic range of the frequency spectrum, may be used to control the resulting colour shade of the whole decorative layer consisting in this case of a decorative coating and protective layer A decorative coating may be applied on the surface of a substrate, partially covered by a masking varnish, which has to be removed after a coating or, as the case may be, a protective optically transparent layer has been created.
By using this invention, it is even possible to have textured glass with a decorative coating of stainless steel, which may be covered by a protective layer made, for instance, of stainless steel nitride. Another significant result is having textured glass with a decorative coating made of brass or aluminium bronze, which may be covered by a protective layer transparent in the optic range of the frequency spectrum. The basic advantage of the method of this invention is the good adhesion of the coating applied on an unheated substrate. This is achieved by exposing the substrate surface to the influence of the plasma of a microwave discharge. The microwave discharge is generated by microwave performance, usually at a frequency of 2.45 GHz in the working gas, i.e. in oxygen, nitrogen, or a gas mixture containing oxygen, nitrogen, and/or fluorine, at a pressure ranging from 0.1 to 1000 Pa. In the plasma of the microwave discharge, the activated atoms, excited molecules, and radicals are generated very effectively in comparison with other kinds of low-pressure discharges. They effectively interact with the surfaces of objects inserted into the microwave discharge. Their activation occurs when the plasma comes into contact with the surfaces of objects. The impact of their influence is manifested in a significant change of properties, particularly in the wet ability of the activated surface.
Its own decorative coating may be protected by a layer which is transparent in the optic range, e.g. of T1O2, or Siθ2, or AI2O3, or Si3N4, or one which is carbon-based. This layer may be created by reactive magnetron sputtering in a mixture of argon and oxygen in the case of layers based on oxides. In applications where a decorative or reflexive coating is made of Ti, Si, Al, C, the protective layer is sputtered from the same disk as a decorative coating and only oxygen or nitrogen is added to the argon. If a protective layer is thinner than - 4 -
approximately 1 μm, it is possible to control by its thickness the colour of the whole decorative coating.
Example of Invention Here is one example of this method being performed according to the invention described. The technology for creating decorative coating consists in this example of the following three steps:
1 ) Pre-treating the glass substrate surface in a microwave discharge generated by a 500 W microwave performance at a frequency of 2.45 GHz in a working gas of N2O2: at a pressure of approximately 22 Pa for a period of 5 minutes.
2) Magnetron sputtering the decorative coating from a disk, made of stainless steel, on the glass surface, pre-treated in the way outlined above without the substrate surface heating up.
3) Covering the decorative coating, sputtered in the way outlined above, by an optically transparent layer of carbon deposited from a spray graphite magnetron disk in an argon discharge at a pressure of 0.5 Pa.
Industrial Applicability
The invention can be applied in any industry where the decorative treatment of solid materials is required, particularly in the production of glass objects involving the decorative treatment of glass.
(End of description)

Claims

Claims
1 A method for creating a decorative coating on a solid substrate using a magnetron sputtering method characterized by pre-treating the substrate surface in a microwave discharge and consequently applying the decorative coating on the substrate without the substrate heating up
2 A method according to claim 1 characterized by pre-treating the substrate in a microwave discharge burning in oxygen or a gas mixture containing oxygen. nitrogen, and/ or fluorine, at a pressure ranging from 0 1 to 1000 Pa
3 A method according to claims 1 and 2 characterized by sputtering a decorative coating on the pre-treated substrate in an inert atmosphere from a cathode made of one element, or of an alloy of two or more elements, at a pressure ranging from 0 05 Pa to several Pa
4 A method according to claims 1 and 2 characterized by sputtering a decorative coating on the pre-treated substrate in the presence of a reactive medium
5 A method according to any of claims 1 to 4 characterized by covering a decorative coating using a protective layer that is transparent in the optic range of the frequency spectrum
6 A method according to claim 5 characterized in that the resulting colour shade of the decorative layer is controlled by the thickness of the protective layer that is transparent in the optic range of the frequency spectrum
7 A method according to any of claims 1 to 6 characterized by applying a decorative coating on a substrate surface, partially covered by masking varnish that is removed after the coating and, as the case may be, an optically transparent protective layer have been created
8. Textured glass characterized in that it is provided with a coating created using a method according to any of claims 1 to 7 with the said decorative coating being made of stainless steel.
9. Textured glass according to claim 8 characterized in that the decorative coating is covered by a protective layer made of stainless steel nitride.
10 Textured glass characterized in that it is provided with a coating created using a method according to any of claims 1 to 7 with the said decorative coating being made of brass or aluminium bronze.
11. Textured glass according to any of claims 8 to 10 characterized in that a protective layer that is transparent in the optic range of the frequency spectrum covers the decorative coating.
(End of claims)
PCT/CZ2000/000051 1999-07-29 2000-07-26 Decorative coating Ceased WO2001009051A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU61467/00A AU6146700A (en) 1999-07-29 2000-07-26 Decorative coating

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CZ19992693A CZ287571B6 (en) 1999-07-29 1999-07-29 Method of making decorative coating and glass provided with decoration
CZPV2693-99 1999-07-29

Publications (1)

Publication Number Publication Date
WO2001009051A1 true WO2001009051A1 (en) 2001-02-08

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/CZ2000/000051 Ceased WO2001009051A1 (en) 1999-07-29 2000-07-26 Decorative coating

Country Status (3)

Country Link
AU (1) AU6146700A (en)
CZ (1) CZ287571B6 (en)
WO (1) WO2001009051A1 (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2876370A1 (en) * 2004-10-11 2006-04-14 Saint Gobain Emballage Sa METHOD FOR DEPOSITION ON A SODOCALCIUM GLASS COMPRISING A PRIOR FLUORINATION STEP
WO2010103097A1 (en) * 2009-03-12 2010-09-16 Centre National De La Recherche Scientifique (Cnrs) Decoration by magnetron plasma sputtering onto glass containers for the cosmetic sectors
US20110047175A1 (en) * 2004-04-21 2011-02-24 Kong Eng Cheng Querying Target Databases Using Reference Database Records
EP2097357B1 (en) 2006-12-14 2018-01-10 Vitro, S.A.B. de C.V. Coated non-metallic sheet having a brushed metal appearance
US12442067B2 (en) 2017-02-24 2025-10-14 Valeo North America Ceramic metallic coatings

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63118066A (en) * 1986-11-05 1988-05-23 Hitachi Ltd sputtering device
US5030503A (en) * 1989-09-01 1991-07-09 Ppg Industries, Inc. Reflective patterned glass product and coating method
US5135775A (en) * 1990-11-02 1992-08-04 Thyssen Edelstalhwerke Ag Process for plasma-chemical cleaning prior to pvd or pecvd coating
JPH09255367A (en) * 1996-03-18 1997-09-30 Gunma Toobi:Kk Ornamental glass container and its ornamental finishing method

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63118066A (en) * 1986-11-05 1988-05-23 Hitachi Ltd sputtering device
US5030503A (en) * 1989-09-01 1991-07-09 Ppg Industries, Inc. Reflective patterned glass product and coating method
US5135775A (en) * 1990-11-02 1992-08-04 Thyssen Edelstalhwerke Ag Process for plasma-chemical cleaning prior to pvd or pecvd coating
JPH09255367A (en) * 1996-03-18 1997-09-30 Gunma Toobi:Kk Ornamental glass container and its ornamental finishing method

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
PATENT ABSTRACTS OF JAPAN vol. 012, no. 365 (C - 532) 29 September 1988 (1988-09-29) *
PATENT ABSTRACTS OF JAPAN vol. 1998, no. 01 30 January 1998 (1998-01-30) *

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20110047175A1 (en) * 2004-04-21 2011-02-24 Kong Eng Cheng Querying Target Databases Using Reference Database Records
US8346794B2 (en) * 2004-04-21 2013-01-01 Tti Inventions C Llc Method and apparatus for querying target databases using reference database records by applying a set of reference-based mapping rules for matching input data queries from one of the plurality of sources
FR2876370A1 (en) * 2004-10-11 2006-04-14 Saint Gobain Emballage Sa METHOD FOR DEPOSITION ON A SODOCALCIUM GLASS COMPRISING A PRIOR FLUORINATION STEP
WO2006040495A1 (en) * 2004-10-11 2006-04-20 Saint-Gobain Emballage Method for deposing on soda-lime glass comprising a pre-fluorination stage
EP2097357B1 (en) 2006-12-14 2018-01-10 Vitro, S.A.B. de C.V. Coated non-metallic sheet having a brushed metal appearance
WO2010103097A1 (en) * 2009-03-12 2010-09-16 Centre National De La Recherche Scientifique (Cnrs) Decoration by magnetron plasma sputtering onto glass containers for the cosmetic sectors
FR2943072A1 (en) * 2009-03-12 2010-09-17 Centre Nat Rech Scient MAGNETRON PLASMA SPRAY DECORATION ON GLASS CONTAINERS FOR COSMETIC SECTORS.
US12442067B2 (en) 2017-02-24 2025-10-14 Valeo North America Ceramic metallic coatings

Also Published As

Publication number Publication date
CZ269399A3 (en) 2000-09-13
CZ287571B6 (en) 2000-12-13
AU6146700A (en) 2001-02-19

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