[go: up one dir, main page]

WO2001087585A1 - Papiers pour impression a jet d'encre contenant des sels de zirconium - Google Patents

Papiers pour impression a jet d'encre contenant des sels de zirconium Download PDF

Info

Publication number
WO2001087585A1
WO2001087585A1 PCT/US2000/027561 US0027561W WO0187585A1 WO 2001087585 A1 WO2001087585 A1 WO 2001087585A1 US 0027561 W US0027561 W US 0027561W WO 0187585 A1 WO0187585 A1 WO 0187585A1
Authority
WO
WIPO (PCT)
Prior art keywords
ink
coating composition
paper
recording paper
impact printers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2000/027561
Other languages
English (en)
Inventor
J. Craig White
Scott C. Peterson
Bernard W. Wolff
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hopton Technologies Inc
Original Assignee
Hopton Technologies Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hopton Technologies Inc filed Critical Hopton Technologies Inc
Priority to AU86380/01A priority Critical patent/AU8638001A/en
Publication of WO2001087585A1 publication Critical patent/WO2001087585A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/5218—Macromolecular coatings characterised by inorganic additives, e.g. pigments, clays
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/38—Coatings with pigments characterised by the pigments
    • D21H19/385—Oxides, hydroxides or carbonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/5227—Macromolecular coatings characterised by organic non-macromolecular additives, e.g. UV-absorbers, plasticisers, surfactants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/5236—Macromolecular coatings characterised by the use of natural gums, of proteins, e.g. gelatins, or of macromolecular carbohydrates, e.g. cellulose
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/5245—Macromolecular coatings characterised by the use of polymers containing cationic or anionic groups, e.g. mordants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/5254—Macromolecular coatings characterised by the use of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds, e.g. vinyl polymers
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/46—Non-macromolecular organic compounds

Definitions

  • This invention relates to a new color recording paper for non-impact
  • printers more particularly a color recording paper coated with a coating
  • composition which comprises a zirconium salt, and a method of making the
  • the new color recording paper has improved color
  • This invention also relates to an ink jet recording paper for
  • the main characteristics required of the paper used in ink jet recording are as follows: (1) Permits fast ink drying; (2) permits high
  • Ink jet recording papers are mainly divided into -two groups; one is the plain type ink jet recording paper, which- consists of only cellulosic fibers or
  • coated type ink jet recording paper which consists of paper, a
  • inks may be absorbed in a fine void of the coating layer.
  • the coated type recording paper provides a small spread and a circular form
  • the color inks do not
  • composition is not desirable for multiple application paper sheets due to its
  • pigments are added in a coating composition which requires non-traditional
  • Silica based pigments also present problems. Not only they
  • the non-traditional pigment binders are not typically used in paper making and they are
  • additives is higher compared with paper produced with standard additives.
  • composition can improve the surface sizing property in paper making.
  • the paper is treated with
  • a salt of a polyvalent metal such as zirconium.
  • composition containing zirconyl complex salt and a method of applying the
  • aqueous surface sizing composition containing a compound selected from alkenyl succinic anhydrides, alkyl ketene dimers and mixtures thereof and a
  • metal salt such as zirconium salt.
  • paper making provides paper products with superior liquid storage
  • zirconium salts in unpigmented or pigmented surface sizing composition or
  • a still further object of the invention is to provide a method for
  • Another object of the present invention is to provide a coating
  • composition comprising a zirconium salt, an alkaline carbonate, a binder,
  • the present invention relates to a color recording paper for non ⁇
  • printers comprised of a paper substrate coated with a coating
  • the instant invention is also directed to a method for improving the process
  • printers which comprises coating said ink jet paper with a composition
  • the present invention further relates to the use of zirconium salts to
  • the bonding action immobilizes the ink carriers when the ink is applied to
  • the ink is held more closely to the surface through the immobilization
  • the ink jet recording paper of the present invention contains one or
  • the layer is mainly to prevent inks coming into the ink-receptive layer from
  • the opacity is desirable to be 75% and over, and the sizing degree
  • the sizing degree is extremely high, and a large amount of ink is applied, the
  • the sizing degree is
  • the ink-receptive layer has to be provided with good ink-absorbency
  • the ink-receptive layer should consist of
  • the ink not be absorbed but also its drying is retarded, and accordingly the
  • the ink-receptive layer deteriorates the penetration and the drying of water as
  • the receptive layer i.e., the more transparent the ink-receptive layer is, the better
  • the light energy is sufficiently absorbed.
  • the ink-receptive layer of this invention comprises pulp, filler,
  • a zirconium salt and auxiliary agent such as water-soluble
  • ink-receptive layer includes wood pulp, linter pulp, and recycled pulp from
  • waste paper Unlike the base layer, such pulp or fiber that has not affinity
  • glass fiber or synthetic pulp which may be mixed in the base layer, should not be mixed in the ink-receptive layer.
  • transparency means an extent to which incident light in the ink-receptive layer is scattered
  • wood pulp is 200-700 cm /g
  • synthetic pulp is 900-
  • Alumina, aluminum hydroxide, silicate, and silica are desirable for alumina, aluminum hydroxide, silicate, and silica
  • the vapor phase process can be used as fine silica. In any case, when the
  • a water-soluble resin or latex as a binder can be added
  • additives as a viscosity control agent, an agent for adjusting the viscosity of a viscosity of a viscosity of a viscosity of a viscosity of a viscosity control agent, an agent for adjusting the viscosity of a viscosity of a viscosity of a viscosity of a viscosity of a viscosity control agent
  • the spread of dots can also be mixed in their coating color.
  • water-soluble resin examples include starch, cationic
  • starch polyvinyla ohol, gelatin, alginate, hydroxyethylcellulose,
  • carboxymethylcellulose polyacrylamide, polystyrene sulfonate,
  • polyacrylate polyvinylpyridine, polyvinylpyrrolidone, polyethyleneoxide,
  • hydrolysis product of starch-acrylonitrile graftpolymer and the like hydrolysis product of starch-acrylonitrile graftpolymer and the like.
  • zirconium salts improves color printing with non-impact printers
  • the ink pigments and dyes when the ink is applied to the sheet surface.
  • composition make the ink held more closely to the surface through the
  • zirconium salts examples include ammonium zirconium
  • the amount used in the coating composition is from 0.01 to 15 % by weight based on the dry weight
  • the preferred amount is from 0.05 to 10 % by
  • the base layer of this invention can comprise a cationic polymer
  • materials such as vegetable gums, cationic starches,
  • the pulp mainly includes plant pulps,
  • an inorganic fiber such as glass fiber, or synthetic
  • acid sizing agents such as
  • neutral sizing agents used in the paper manufacturing such as alkylketene
  • ketene dimers used in the invention are known per se and have the following general formula:
  • R f and R 2 each individually represents an organic hydrophobic
  • hydrocarbon group having about 8-40 carbon atoms examples of some
  • suitable hydrophobic hydrocarbon groups include alkyl groups, alkenyl
  • 8 to about 40 carbon atoms are decyl, undecyl, dodecyl, tridecyl, tetradecyl,
  • the preferred alkyl groups contain from about 12 to about 30 carbon
  • alkenyl groups containing about 8 and 40
  • carbon atoms include decenyl, tridecenyl, heptadecenyl, octadecnyl,
  • substituted cycloalkyl groups having at least about 8 carbon atoms include 4-
  • alkyl alkenyl, alkaryl, aralkyl and
  • alkycycloalkyl groups can contain non-interfering, inert substituents as is
  • Each Ri and R 2 individually is preferably an alkyl
  • ketene dimers can be used when desired.
  • the ketene dimers can be prepared by previously
  • the ketene dimers can be obtained by reacting
  • Cationic starch dosage with AKD also is typically above what is
  • the ink-receptive layer becomes so
  • cationic resin is desirable for this invention.
  • the coating composition used for the present invention furthermore is selected from:
  • Examples for the pu ⁇ ose include starches and gums.
  • ethylated corn starch is preferred for the present invention.
  • the coating composition is from 25 to 48 % by weight based on the dry
  • the preferred amount is from 30 to 45% by
  • a synthetic water soluble polymer such as a salt of a styrene maleic anhydride inte ⁇ olymer (SMA) can be used in combination with a starch.
  • SMA styrene maleic anhydride inte ⁇ olymer
  • the amount used in the coating composition is from 0.05 to 0.5 % by
  • polydimethyldiallylammonium chloride, and polyvinylpyrrolidone are examples of polydimethyldiallylammonium chloride, and polyvinylpyrrolidone.
  • cationic polymer is typically present in an amount of 0.2 to 0.5 % by weight
  • the coating composition may contain other pigments, such as calcium
  • the amount used can be up to 70
  • pigments which can used in this invention include clay, activated clay,
  • such fillers as titanium oxide and calcium carbonate that have high refractive index and can be atomized easily are preferable, and, in
  • the surface coating composition used in the present invention also contains
  • alkyl ketene dimer (AKD) and/or an alkenyl succinic anhydride (ASA).
  • ASA alkenyl succinic anhydride
  • the AKD is as defined above.
  • this invention is a hydrophobic molecule. Usually it will have one
  • the substituent will be an alkyl, alkenyl or aralkyl
  • a preferred substituent size is between 10 and 30 carbon atoms.
  • More preferred is between 12 and 25 carbon atoms.
  • nonadecene-7 n-eicosene-4; n-eicosene- 10; n-heneicosene-3 ; n-
  • surface sizing agents include, for example, acid sizing agents such as
  • surface sizing agents can be applied with water-soluble resins, such as
  • the viscosity of the coating material is
  • An emulsion of AKD was prepared as follows:
  • An emulsion of ASA was prepared as follows:
  • the ingredients were mixed and homogenized to form an emulsion.
  • a surface sizing compound was prepared by adding AZC
  • the 70 gsm sheet is used for photocopy applications.
  • Both sheets use alkyl ketene dimer (AKD) for internal sizing, and both
  • the 70 gsm sheet has a more "open", absorbent surface due to
  • 80 gsm sheet has a more "closed” surface, with a higher dosage of AKD (3
  • SMA styrene maleic anhydride
  • the present invention thus allows all paper grades to be produced from
  • a paper mill produced a 75 gsm sheet, sized with alkyl succinic anhydride, with a low cost corn starch modified on site with ammonium
  • the sheet was tested for improvement of color inkjet printing by
  • ammonium carbonate to 8% to 10% achieved acceptable color inkjet
  • the present invention was tested in a pig nented surface size applied
  • a surface size applied to the sheet was prepared using
  • the color density of the paper approached premium i jet quality, with minimum bleeding.
  • the color densities and bleed was improved by
  • Example 6 resulted in a very high cost for the formula. As a result, another
  • the objective of the experiment was to allow for a reduced dosage of AZC

Landscapes

  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Ink Jet Recording Methods And Recording Media Thereof (AREA)
  • Paper (AREA)

Abstract

Cette invention se rapporte à un papier d'impression couleur pour imprimantes sans impact, qui est constitué par un substrat de papier recouvert d'une composition d'encollage contenant du sel de zirconium. L'utilisation du sel de zirconium améliore la qualité d'impression couleur avec des imprimantes sans impact, notamment des imprimantes à jet d'encre. La composition d'encollage contient en outre du carbonate de calcium, de l'amidon et du sel anhydrique maléique de styrène.
PCT/US2000/027561 1999-10-05 2000-10-05 Papiers pour impression a jet d'encre contenant des sels de zirconium Ceased WO2001087585A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU86380/01A AU8638001A (en) 1999-10-05 2000-10-05 Inkjet papers incorporating zirconium salts

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US41295399A 1999-10-05 1999-10-05
US09/412,953 1999-10-05

Publications (1)

Publication Number Publication Date
WO2001087585A1 true WO2001087585A1 (fr) 2001-11-22

Family

ID=23635162

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2000/027561 Ceased WO2001087585A1 (fr) 1999-10-05 2000-10-05 Papiers pour impression a jet d'encre contenant des sels de zirconium

Country Status (2)

Country Link
AU (1) AU8638001A (fr)
WO (1) WO2001087585A1 (fr)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010071797A1 (fr) * 2008-12-18 2010-06-24 Nalco Company Papier pour l'impression à jet d'encre
WO2017192281A1 (fr) * 2016-05-03 2017-11-09 Solenis Technologies, L.P. Agents d'encollage biopolymères
CN107446164A (zh) * 2017-08-30 2017-12-08 华南理工大学 一种用于填充生物可降解塑料的改性碳酸钙及其制备方法
EP3260598A1 (fr) * 2016-06-23 2017-12-27 BillerudKorsnäs AB Carton recouvert de pigments

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4732786A (en) * 1985-12-17 1988-03-22 James River Corporation Ink jet printable coatings
JPH0617399A (ja) * 1992-06-30 1994-01-25 New Oji Paper Co Ltd 印刷用塗工紙用原紙
JPH0632046A (ja) * 1992-07-15 1994-02-08 New Oji Paper Co Ltd インクジェット記録用紙
US5405678A (en) * 1993-05-07 1995-04-11 Otis Specialty Papers Inc. Ink jet recording sheet
US5824190A (en) * 1995-08-25 1998-10-20 Cytec Technology Corp. Methods and agents for improving paper printability and strength
US5958579A (en) * 1995-05-31 1999-09-28 Mitsubishi Paper Mills Limited Ink jet recording sheet

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4732786A (en) * 1985-12-17 1988-03-22 James River Corporation Ink jet printable coatings
JPH0617399A (ja) * 1992-06-30 1994-01-25 New Oji Paper Co Ltd 印刷用塗工紙用原紙
JPH0632046A (ja) * 1992-07-15 1994-02-08 New Oji Paper Co Ltd インクジェット記録用紙
US5405678A (en) * 1993-05-07 1995-04-11 Otis Specialty Papers Inc. Ink jet recording sheet
US5958579A (en) * 1995-05-31 1999-09-28 Mitsubishi Paper Mills Limited Ink jet recording sheet
US5824190A (en) * 1995-08-25 1998-10-20 Cytec Technology Corp. Methods and agents for improving paper printability and strength

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010071797A1 (fr) * 2008-12-18 2010-06-24 Nalco Company Papier pour l'impression à jet d'encre
WO2017192281A1 (fr) * 2016-05-03 2017-11-09 Solenis Technologies, L.P. Agents d'encollage biopolymères
US10865525B2 (en) 2016-05-03 2020-12-15 Solenis Technologies, L.P. Biopolymer sizing agents
US10865526B2 (en) 2016-05-03 2020-12-15 Solenis Technologies, L.P. Method for improving the resistance of paper and paperboard to aqueous penetrants
EP3260598A1 (fr) * 2016-06-23 2017-12-27 BillerudKorsnäs AB Carton recouvert de pigments
WO2017220644A1 (fr) * 2016-06-23 2017-12-28 Billerudkornsäs Ab Plaque revêtue de pigment
EP4411065A3 (fr) * 2016-06-23 2024-10-23 Billerud Aktiebolag (publ) Panneau revêtu de pigment
CN107446164A (zh) * 2017-08-30 2017-12-08 华南理工大学 一种用于填充生物可降解塑料的改性碳酸钙及其制备方法

Also Published As

Publication number Publication date
AU8638001A (en) 2001-11-26

Similar Documents

Publication Publication Date Title
US5302437A (en) Ink jet recording sheet
US5180624A (en) Ink jet recording paper
JP4624549B2 (ja) 改良されたインクジェット印刷性能のための組成物及び方法
JP2521896B2 (ja) インクジェット記録シ―ト
US8678543B2 (en) Composition and print medium
EP0600245B1 (fr) Feuille pour l'enregistrement à jet d'encre et procédé pour sa préparation
US9981288B2 (en) Process for manufacturing recording sheet
CA1308593C (fr) Papier deux epaisseurs pour procedes d'impression a jet d'encre
GB2050866A (en) Ink-jet recording sheets
EP2467263A1 (fr) Support d'impression pour une impression à jet d encre numérique haute vitesse
MXPA00000900A (en) Composition and method for improved ink jet printing performance
JPH0720727B2 (ja) インクジェット記録用塗工シ−ト
US4335184A (en) Recording paper
EP0655346A1 (fr) Feuille permettant la reproduction par jet d'encre
US5637196A (en) Ink jet recording sheet
WO2001087585A1 (fr) Papiers pour impression a jet d'encre contenant des sels de zirconium
JP3374511B2 (ja) インクジェット記録用紙
JPH0717127A (ja) インクジェット記録シート
JPH1134483A (ja) インクジェット記録用紙
JPH07214892A (ja) 転写用シート
JPH0768921A (ja) インクジェット記録シート及びその製造方法
JPH08120592A (ja) 非塗工印刷用紙
JPH07214893A (ja) 転写用シート
JPH07214894A (ja) 転写用シート
JP2004074451A (ja) インクジェット記録用紙

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A1

Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BY BZ CA CH CN CR CU CZ DE DK DM DZ EE ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NO NZ PL PT RO RU SD SE SG SI SK SL TJ TM TR TT TZ UA UG UZ VN YU ZA ZW

AL Designated countries for regional patents

Kind code of ref document: A1

Designated state(s): GH GM KE LS MW MZ SD SL SZ TZ UG ZW AM AZ BY KG KZ MD RU TJ TM AT BE CH CY DE DK ES FI FR GB GR IE IT LU MC NL PT SE BF BJ CF CG CI CM GA GN GW ML MR NE SN TD TG

121 Ep: the epo has been informed by wipo that ep was designated in this application
REG Reference to national code

Ref country code: DE

Ref legal event code: 8642

DFPE Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101)
122 Ep: pct application non-entry in european phase
NENP Non-entry into the national phase

Ref country code: JP