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WO2001077186A3 - Procede de fabrication d'un catalyseur sur support destine a la polymerisation des olefines - Google Patents

Procede de fabrication d'un catalyseur sur support destine a la polymerisation des olefines Download PDF

Info

Publication number
WO2001077186A3
WO2001077186A3 PCT/EP2001/003779 EP0103779W WO0177186A3 WO 2001077186 A3 WO2001077186 A3 WO 2001077186A3 EP 0103779 W EP0103779 W EP 0103779W WO 0177186 A3 WO0177186 A3 WO 0177186A3
Authority
WO
WIPO (PCT)
Prior art keywords
polymerisation
olefins
production
supported catalyst
q1q2q3q4
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2001/003779
Other languages
German (de)
English (en)
Other versions
WO2001077186A2 (fr
Inventor
Marc Oliver Kristen
Gerhard Hauck
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Publication of WO2001077186A2 publication Critical patent/WO2001077186A2/fr
Publication of WO2001077186A3 publication Critical patent/WO2001077186A3/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Procédé de fabrication d'un catalyseur sur support destiné à la polymérisation des oléfines, caractérisé en ce qu'un ou plusieurs composés de formule générale Ia ou Ib sont déposés, conjointement avec un activateur défini moléculairement, de formules générales IIa à IIc [(L-H)]?+[M')Q1Q2Q3Q4¿]- IIa [(Car¿3?)]?+[(M') Q1Q2Q3Q4¿]- IIb [(M')Q1Q2Q3] IIc, sur un matériau support poreux renfermant 2 à 10 % en poids d'eau.
PCT/EP2001/003779 2000-04-08 2001-04-03 Procede de fabrication d'un catalyseur sur support destine a la polymerisation des olefines Ceased WO2001077186A2 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10017663.1 2000-04-08
DE2000117663 DE10017663A1 (de) 2000-04-08 2000-04-08 Verfahren zur Herstellung eines geträgerten Katalysators zur Polymerisation von Olefinen

Publications (2)

Publication Number Publication Date
WO2001077186A2 WO2001077186A2 (fr) 2001-10-18
WO2001077186A3 true WO2001077186A3 (fr) 2002-04-11

Family

ID=7638153

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2001/003779 Ceased WO2001077186A2 (fr) 2000-04-08 2001-04-03 Procede de fabrication d'un catalyseur sur support destine a la polymerisation des olefines

Country Status (2)

Country Link
DE (1) DE10017663A1 (fr)
WO (1) WO2001077186A2 (fr)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10107045A1 (de) * 2001-02-13 2002-08-14 Basf Ag Verfahren zur Polymerisation von Olefinen
EP1403288A1 (fr) * 2002-09-27 2004-03-31 ATOFINA Research Système catalytique à double site comprenant un composant hafnocène pour la production de polyoléfines bimodales
EP1496069A1 (fr) * 2003-07-09 2005-01-12 Total Petrochemicals Research Feluy Procédé de polymerisation
EP1496068A1 (fr) * 2003-07-09 2005-01-12 Total Petrochemicals Research Feluy Procédé de preparation des polyolefines bimodales avec des catalysateurs de metallocenes ayant deux zones de réaction
EP1650231A1 (fr) * 2004-10-21 2006-04-26 Total Petrochemicals Research Feluy Polyoléfines préparés par une combination de nouveaux catalyseurs à site unique et de metallocènes dans un seul réacteur
DE102010009493A1 (de) 2010-02-26 2011-09-29 Clariant International Limited Polymere und ihre Verwendung als Dispergiermittel mit schaumhemmender Wirkung
JP6466652B2 (ja) * 2013-04-17 2019-02-06 中国石油化工股▲ふん▼有限公司 エチレンオリゴマー化のための触媒組成物及び方法

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999012981A1 (fr) * 1997-09-05 1999-03-18 Bp Chemicals Limited Catalyseurs de polymerisation

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999012981A1 (fr) * 1997-09-05 1999-03-18 Bp Chemicals Limited Catalyseurs de polymerisation

Also Published As

Publication number Publication date
DE10017663A1 (de) 2001-10-11
WO2001077186A2 (fr) 2001-10-18

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