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WO2001064763A3 - Process for producing polypropylene from c3 olefins selectively produced in a fluid catalytic cracking process - Google Patents

Process for producing polypropylene from c3 olefins selectively produced in a fluid catalytic cracking process Download PDF

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Publication number
WO2001064763A3
WO2001064763A3 PCT/US2001/006687 US0106687W WO0164763A3 WO 2001064763 A3 WO2001064763 A3 WO 2001064763A3 US 0106687 W US0106687 W US 0106687W WO 0164763 A3 WO0164763 A3 WO 0164763A3
Authority
WO
WIPO (PCT)
Prior art keywords
zone
stream
catalyst
olefins
stripping
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2001/006687
Other languages
French (fr)
Other versions
WO2001064763A2 (en
Inventor
Paul K Ladwig
John E Asplin
Gordon F Stuntz
Tan-Jen Chen
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
ExxonMobil Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US09/517,551 external-priority patent/US6258257B1/en
Priority claimed from US09/517,554 external-priority patent/US6388152B1/en
Priority claimed from US09/517,497 external-priority patent/US6258990B1/en
Priority claimed from US09/517,503 external-priority patent/US6339180B1/en
Priority to CA002400598A priority Critical patent/CA2400598A1/en
Priority to EP01913235A priority patent/EP1261648A2/en
Priority to AU2001241916A priority patent/AU2001241916A1/en
Application filed by ExxonMobil Chemical Patents Inc filed Critical ExxonMobil Chemical Patents Inc
Priority to JP2001564255A priority patent/JP2003525323A/en
Priority to MXPA02008552A priority patent/MXPA02008552A/en
Publication of WO2001064763A2 publication Critical patent/WO2001064763A2/en
Publication of WO2001064763A3 publication Critical patent/WO2001064763A3/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G57/00Treatment of hydrocarbon oils, in the absence of hydrogen, by at least one cracking process or refining process and at least one other conversion process
    • C10G57/02Treatment of hydrocarbon oils, in the absence of hydrogen, by at least one cracking process or refining process and at least one other conversion process with polymerisation
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G51/00Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more cracking processes only
    • C10G51/02Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more cracking processes only plural serial stages only
    • C10G51/026Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more cracking processes only plural serial stages only only catalytic cracking steps
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/20C2-C4 olefins

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Polymerisation Methods In General (AREA)
  • Polymerization Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Catalysts (AREA)

Abstract

A process for producing polymers from olefins selectively produced from a catalytically cracked or thermally cracked naphtha stream is disclosed herein. The naphtha stream is introduced into a process unit comprised of a reaction zone, a stripping zone, a catalyst regeneration zone, and a fractionation zone. The naphtha feedstream is contacted in the reaction zone with a catalyst containing from about 10 to 50 wt. % of a crystalline zeolite having an average pore diameter less than about 0.7 nanometers at reaction conditions which include temperatures ranging from about 500° to 650 °C and a hydrocarbon partial pressure from about 10 to 40 psia. Vapor products are collected overhead and the catalyst particles are passed through the stripping zone on the way to the catalyst regeneration zone. Volatiles are stripped with stream in the stripping zone and the catalyst particles are sent to the catalyst regeneration zone where coke is burned from the catalyst, which is then recycled to the reaction zone. Overhead products from the reaction zone are passed to a fractionation zone where a stream of C3 products is recovered and a stream rich in C4 and/or C5 olefins is recycled to the stripping zone. The olefins can be further processed and polymerized to form a variety of polymer materials.
PCT/US2001/006687 2000-03-02 2001-03-01 Process for producing polypropylene from c3 olefins selectively produced in a fluid catalytic cracking process Ceased WO2001064763A2 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
MXPA02008552A MXPA02008552A (en) 2000-03-02 2001-03-01 Process for producing polypropylene from c3.
JP2001564255A JP2003525323A (en) 2000-03-02 2001-03-01 Process for producing polypropylene from C3 olefins selectively produced from naphtha / steam feed in a fluid catalytic cracking process
CA002400598A CA2400598A1 (en) 2000-03-02 2001-03-01 Process for producing polypropylene from c3 olefins selectively produced in a fluid catalytic cracking process
AU2001241916A AU2001241916A1 (en) 2000-03-02 2001-03-01 Process for producing polypropylene from C3 olefins selectively produced in a fluid catalytic cracking process
EP01913235A EP1261648A2 (en) 2000-03-02 2001-03-01 Process for producing polypropylene from c3 olefins selectively produced in a fluid catalytic cracking process

Applications Claiming Priority (8)

Application Number Priority Date Filing Date Title
US09/517,554 2000-03-02
US09/517,551 US6258257B1 (en) 1998-05-05 2000-03-02 Process for producing polypropylene from C3 olefins selectively produced by a two stage fluid catalytic cracking process
US09/517,551 2000-03-02
US09/517,503 US6339180B1 (en) 1998-05-05 2000-03-02 Process for producing polypropylene from C3 olefins selectively produced in a fluid catalytic cracking process
US09/517,497 US6258990B1 (en) 1998-05-05 2000-03-02 Process for producing polypropylene from C3 olefins selectively produced in a fluid catalytic cracking process from a naphtha/steam feed
US09/517,554 US6388152B1 (en) 1998-05-05 2000-03-02 Process for producing polypropylene from C3 olefins selectively produced in a fluid catalytic cracking process
US09/517,503 2000-03-02
US09/517,497 2000-03-02

Publications (2)

Publication Number Publication Date
WO2001064763A2 WO2001064763A2 (en) 2001-09-07
WO2001064763A3 true WO2001064763A3 (en) 2002-01-31

Family

ID=27504537

Family Applications (4)

Application Number Title Priority Date Filing Date
PCT/US2001/006687 Ceased WO2001064763A2 (en) 2000-03-02 2001-03-01 Process for producing polypropylene from c3 olefins selectively produced in a fluid catalytic cracking process
PCT/US2001/006685 Ceased WO2001064761A2 (en) 2000-03-02 2001-03-01 Process for producing polypropylene from c3 olefins selectively produced in a fluid catalytic cracking process from a naphtha/steam feed
PCT/US2001/006684 Ceased WO2001064760A2 (en) 2000-03-02 2001-03-01 Process for producing polypropylene from c3 olefins selectively produced in a fluid catalytic cracking process
PCT/US2001/006686 Ceased WO2001064762A2 (en) 2000-03-02 2001-03-01 Process for producing polypropylene from c3 olefins selectively produced by a two stage fluid catalytic cracking process

Family Applications After (3)

Application Number Title Priority Date Filing Date
PCT/US2001/006685 Ceased WO2001064761A2 (en) 2000-03-02 2001-03-01 Process for producing polypropylene from c3 olefins selectively produced in a fluid catalytic cracking process from a naphtha/steam feed
PCT/US2001/006684 Ceased WO2001064760A2 (en) 2000-03-02 2001-03-01 Process for producing polypropylene from c3 olefins selectively produced in a fluid catalytic cracking process
PCT/US2001/006686 Ceased WO2001064762A2 (en) 2000-03-02 2001-03-01 Process for producing polypropylene from c3 olefins selectively produced by a two stage fluid catalytic cracking process

Country Status (7)

Country Link
EP (3) EP1261648A2 (en)
JP (3) JP2004516334A (en)
CN (3) CN1406252A (en)
AU (4) AU2001239991A1 (en)
CA (3) CA2400524A1 (en)
MX (3) MXPA02008553A (en)
WO (4) WO2001064763A2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8920630B2 (en) 2007-04-13 2014-12-30 Shell Oil Company Systems and methods for making a middle distillate product and lower olefins from a hydrocarbon feedstock

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7267759B2 (en) 2003-02-28 2007-09-11 Exxonmobil Research And Engineering Company Fractionating and further cracking a C6 fraction from a naphtha feed for propylene generation
US7425258B2 (en) 2003-02-28 2008-09-16 Exxonmobil Research And Engineering Company C6 recycle for propylene generation in a fluid catalytic cracking unit
WO2009048920A1 (en) * 2007-10-10 2009-04-16 Shell Oil Company Systems and methods for making a middle distillate product and lower olefins from a hydrocarbon feedstock
RU2474605C2 (en) * 2007-11-29 2013-02-10 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Plants and methods for obtaining middle-distillate product and low molecular weight olefins from initial hydrocarbon raw material
CN101747129B (en) * 2008-11-28 2013-09-04 中国石油化工股份有限公司 Method for producing light olefins through catalytic conversion
CN102531821B (en) 2010-12-28 2015-03-25 中国科学院大连化学物理研究所 Method for catalyzing catalytic cracking reaction of methanol coupled with naphtha using modified ZSM-5 molecular sieve based catalyst
CN103121894A (en) * 2011-11-18 2013-05-29 中国石油化工股份有限公司 Combined method for producing low-carbon olefin
CN105582997B (en) * 2014-10-21 2018-05-18 中国石油化工股份有限公司 The method of catalyst of naphtha catalytic cracking production propylene and preparation method thereof and naphtha catalytic cracking production propylene
USRE50515E1 (en) 2015-12-22 2025-08-05 Sabic Global Technologies B.V. Methods for producing ethylene and propylene from naphtha
CN113646081B (en) * 2019-03-18 2024-01-09 埃克森美孚科技工程公司 Mesoporous catalyst compounds and their uses
KR20220117899A (en) * 2019-12-23 2022-08-24 셰브런 유.에스.에이.인크. Circular Economy of Plastic Waste to Polypropylene Through Refining FCC Units
JP7623380B2 (en) * 2019-12-23 2025-01-28 シェブロン ユー.エス.エー. インコーポレイテッド Circular economy of waste plastics to polypropylene and lubricants via refined FCC and isomerization dewaxing units

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999057225A1 (en) * 1998-05-05 1999-11-11 Exxon Research And Engineering Company Process for selectively producing c3 olefins in a fluid catalytic cracking process

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6118035A (en) * 1998-05-05 2000-09-12 Exxon Research And Engineering Co. Process for selectively producing light olefins in a fluid catalytic cracking process from a naphtha/steam feed
US6069287A (en) * 1998-05-05 2000-05-30 Exxon Research And Engineering Co. Process for selectively producing light olefins in a fluid catalytic cracking process
US6106697A (en) * 1998-05-05 2000-08-22 Exxon Research And Engineering Company Two stage fluid catalytic cracking process for selectively producing b. C.su2 to C4 olefins

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999057225A1 (en) * 1998-05-05 1999-11-11 Exxon Research And Engineering Company Process for selectively producing c3 olefins in a fluid catalytic cracking process

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
ELVERS B. ET AL.: "ULLMANN'S ENCYCLOPEDIA OF INDUSTRIAL CHEMISTRY", 1992, VCH VERLAG., WEINHEIM, DE, XP002174091 *
MOORE E.P.: "Polypropylene handbook", 1996, HANSER PUBL., MUNICH, DE, XP002174092 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8920630B2 (en) 2007-04-13 2014-12-30 Shell Oil Company Systems and methods for making a middle distillate product and lower olefins from a hydrocarbon feedstock

Also Published As

Publication number Publication date
WO2001064760A3 (en) 2002-01-03
AU2001241916A1 (en) 2001-09-12
MXPA02008552A (en) 2003-03-12
EP1261648A2 (en) 2002-12-04
JP2004516334A (en) 2004-06-03
CA2400598A1 (en) 2001-09-07
WO2001064760A2 (en) 2001-09-07
WO2001064762A3 (en) 2002-01-24
CN1406254A (en) 2003-03-26
JP2004516335A (en) 2004-06-03
CA2400524A1 (en) 2001-09-07
EP1259555A2 (en) 2002-11-27
CA2400382A1 (en) 2001-09-07
WO2001064761A3 (en) 2002-01-03
WO2001064761A2 (en) 2001-09-07
AU2001239991A1 (en) 2001-09-12
JP2003525323A (en) 2003-08-26
AU2001243379A1 (en) 2001-09-12
EP1261649A2 (en) 2002-12-04
CN1406253A (en) 2003-03-26
CN1406252A (en) 2003-03-26
WO2001064762A2 (en) 2001-09-07
MXPA02008553A (en) 2003-03-12
AU2001239990A1 (en) 2001-09-12
MXPA02008554A (en) 2003-04-22
WO2001064763A2 (en) 2001-09-07

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