WO2001064061A1 - Item for smoking - Google Patents
Item for smoking Download PDFInfo
- Publication number
- WO2001064061A1 WO2001064061A1 PCT/EP2001/001913 EP0101913W WO0164061A1 WO 2001064061 A1 WO2001064061 A1 WO 2001064061A1 EP 0101913 W EP0101913 W EP 0101913W WO 0164061 A1 WO0164061 A1 WO 0164061A1
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- WO
- WIPO (PCT)
- Prior art keywords
- filter
- cigarette according
- ventilated
- den
- core
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
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Classifications
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/062—Use of materials for tobacco smoke filters characterised by structural features
- A24D3/063—Use of materials for tobacco smoke filters characterised by structural features of the fibers
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/04—Tobacco smoke filters characterised by their shape or structure
- A24D3/043—Tobacco smoke filters characterised by their shape or structure with ventilation means, e.g. air dilution
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/02—Manufacture of tobacco smoke filters
- A24D3/0275—Manufacture of tobacco smoke filters for filters with special features
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/08—Use of materials for tobacco smoke filters of organic materials as carrier or major constituent
- A24D3/10—Use of materials for tobacco smoke filters of organic materials as carrier or major constituent of cellulose or cellulose derivatives
Definitions
- the invention relates to a ventilated filter cigarette according to the preamble of patent claim 1.
- Filter constructions for use in tobacco smoke filters which consist of several filter parts with different material properties, are used in the prior art to solve various tasks.
- the ventilation of filters is used to ensure a milder smoke and a lower pollutant supply.
- EP 474 940 B2 and EP 608 047 B1 describe smoke filters in which a middle core segment consists of a filter material different from the jacket. These smoke filters are also called core or coaxial filters.
- the filter consists of two longitudinal filter sections. namely the ventilated strand-side core filter part and a mouth-side monofilter part, the mouth-side monofilter part having an aesthetic effect.
- the disadvantage of the smoke filters mentioned is that in any case the covering of the inner core of the core filter section consists of a material which is permeable to the smoke, so that the smoke can flow perpendicular to the interface between the core and the jacket of the core filter.
- EP 0 558 166 B1 describes a ventilated filter cigarette which likewise has a monofilter section at the mouth end and a core filter section on the strand side.
- this filter cigarette has a hollow chamber between the two filter elements, which is filled with an adsorbent (e.g. activated carbon).
- an adsorbent e.g. activated carbon
- EP 0 880 904 AI and DE 39 01 226 Cl accomplish the task of using a cigarette with a coaxial arrangement of both the tobacco rod and the filter to realize low condensate values, which is primarily achieved by the coaxial structure of the tobacco rod.
- a disadvantage of this design is the high cost of special manufacturing units that are necessary for the production of the coaxial strand.
- EP 539 191 B1 sets itself the task of providing a ventilated filter cigarette with a particularly light weight.
- the disadvantage here is that the densities of the materials used (both tobacco rod and filter) have to be minimized in order to realize a particularly light-weight cigarette, which extremely limits the possibilities of varying the equipment of the cigarette.
- the ventilation zone is located in the filter section on the side of the line.
- the object of the invention is to provide a ventilated filter cigarette which does not have the disadvantages mentioned above and whose filter elements bring about a reduction in the particle phase of the smoke (such as nicotine) and at the same time achieve a disproportionate reduction in the gas phase smoke components, the filtered smoke should retain a composition that is acceptable in terms of taste to the consumer.
- the filter should allow a wide range of variation for the sensory, haptic and optical configuration.
- Another task is to decouple the tensile resistance of the filter from the retention of the filter, i.e. to achieve an increase in the retention capacity for smoke constituents without having to accept a strong increase in the draft resistance, which is inevitable with conventional filter designs.
- Another object of the invention is to provide a product with the advantages mentioned above for markets in which chamber filters and in particular those which are filled with activated carbon are rejected for both sensory and haptic reasons.
- a filter cigarette of the type mentioned at the outset serves to achieve this object and also has the characterizing features of patent claim 1.
- FIG. 1 shows the schematic illustration of a filter cigarette according to the invention.
- FIG. 2 shows the schematic illustration of a further embodiment of the filter cigarette according to the invention.
- This filter cigarette consists of a strand part 10 and a filter 20.
- the strand part 10 is formed by a one-piece tobacco rod 11 and a casing 12 surrounding the tobacco rod 11.
- the filter 20 consists of at least two filter parts 22 and 23 and is connected to the strand part 10 by a wrapping paper 13 which is at least 3 mm longer than the filter 20.
- the tobacco rod 11 is usually between 55 and 75 mm long, while the length of the filter 20 is between 21 and 27 mm.
- the filter 20 is ventilated in the area of the mouth-side filter part.
- the degree of ventilation can be selected in the range from 10 to 90%.
- the wrapping paper 13 is provided with ventilation holes 14 as ventilation means, which are arranged in the form of 1 to 3 rows, preferably 2 rows of holes, around the filter 20, in the area of the strand-side filter part 23, however, is the wrapping paper 13 completely impermeable. Ventilation air is sucked into the filter 20 through the ventilation holes 14 when smoking, which leads to a disproportionate reduction in the gas phase components of the tobacco smoke being achieved in comparison with the reduction in the particle phase.
- the ventilation means can also protrude slightly, up to about 2 mm, beyond the mouth-side filter part into the strand-side filter part. After a deflection, the ventilation air is also drawn into the mouth-side filter part 22.
- Ventper holes are to be produced, for example mechanically or electrostatically or by laser perforations.
- Other also known ventilation means are tubes, cannulas or material savings.
- the mouth-side filter part 22 consists of at least one filter segment.
- the mouth-side filter part 22 can also consist of two or more filter plugs, as shown in FIG. 2. This gives a higher possibility of variation of the filter materials, e.g. the possibility, in addition to the ventilated filter element 22b, of using a further filter element 22a on the mouth side, which can have an embossing or coloring on its visible cross-sectional area.
- the strand-side filter part 23 forming a coaxial filter has a core 24 and a jacket 26 coaxially surrounding the core.
- the pressure drop of the core 24 can be between 10 and 50 mmWS lie.
- the jacket 26 is designed such that its pressure drop is at least a factor of 2 greater than that of the core 24.
- the jacket 26 can also be essentially impermeable to smoke.
- the surface 25 of the core 24 is made essentially smoke-proof or is smoke-impermeable.
- the construction of the filter part 23 on the strand side causes the smoke to flow primarily through the core 24.
- the narrowing of the cross-section significantly increases the smoke flow velocity within this core segment, which inherently includes an increase in draft resistance with a relatively low retention.
- An analogous effect is achieved if the narrowing of the cross section of the material through which the smoke flows is caused by the fact that the core of the coaxial filter plug is designed to be almost impermeable and the entire smoke then flows exclusively through the jacket.
- the design options are extremely numerous within the specified objective, since the filter cigarette according to the invention allows the gas phase to be lowered proportionally without significantly influencing the speed, so that e.g. there is no typical effect which smokers call "yeast taste".
- Suitable filter materials for the filter 20 are sheet-like, fibrous or granular filter materials, such as cellulose, cellulose esters, preferably cellulose acetate, meltblown filter material e.g. manufactured according to WO97 / 33026, airlaid filter material e.g. manufactured according to US 4,375,447, additive filter materials, tobacco e.g. according to DE 19925 968, reconstituted tobacco, other easily decomposable filter materials or thermoplastic filter fibers.
- sheet-like, fibrous or granular filter materials such as cellulose, cellulose esters, preferably cellulose acetate, meltblown filter material e.g. manufactured according to WO97 / 33026, airlaid filter material e.g. manufactured according to US 4,375,447, additive filter materials, tobacco e.g. according to DE 19925 968, reconstituted tobacco, other easily decomposable filter materials or thermoplastic filter fibers.
- a filter element of the filter part 22 can be provided with activated carbon particles in order to increase the gas phase adsorption.
- the mouth-side filter plug can be colored.
- the pH values of the particle spectra and thus the taste impression can be influenced by adding acids or bases.
- the addition of the additives can be done by sprinkling or spraying on the filter materials, e.g. Fibers, or by direct injection into the material strand.
- Possible additives for the filter material are: flavoring agents, acids or bases in suspended or dissolved form, or additives with a selective retention effect adsorbents such as activated carbon or SiO 2.
- Other additives with a selective retention effect are organic acid bases e.g. Hydroxycarboxylic acids and their salts, metals and metal oxides, nitrogen components, ion exchange systems (e.g. zeolites), alcohols, polyphenols and polyphyrin derivatives.
- additives such as plasticizers e.g. Triacetiti, triethylene glycol diacetate or citric acid diethyl ester, additives which accelerate photo degradation e.g. Titanium dioxide, additives that promote biodegradability, vitamins and / or color pigments can be used for the individual design of the desired filter construction.
- plasticizers e.g. Triacetiti, triethylene glycol diacetate or citric acid diethyl ester
- additives which accelerate photo degradation e.g. Titanium dioxide
- additives that promote biodegradability e.g. Titanium dioxide
- vitamins and / or color pigments can be used for the individual design of the desired filter construction.
- Possible areas for embodiments of the cellulose acetate specification are: For the core 24, a single titer in the range from 3.0 to 8.0 den, preferably 8.0 den and a total titer in the range from 15,000 to 50,000 den, preferably 17,000 den. For the jacket 26 a single titer in the range from 1.5 to 3.0 den, preferably 2.1 den and a total titer in the range from 40,000 to 75,000 den, preferably 55,000 den.
- the range of the individual titers for the mouth-side filter part 22 in the case of cellulose acetate as filter material, which can consist of two or more identical or different segments 22a and 22b, is 1.5 to 5 den and for the total titre 15000 to 60,000 den.
- Example 1 The range of the individual titers for the mouth-side filter part 22 in the case of cellulose acetate as filter material, which can consist of two or more identical or different segments 22a and 22b, is 1.5 to 5 den and for the total titre 15000 to 60,000 den.
- the cigarette A had a 63 mm long tobacco rod 11 and a 21 mm long multi-part filter 20.
- the core 24 of the strand-side filter part 23 had a diameter of 5.5 mm and a length of 8.0 mm. It consisted of cellulose acetate with a single titer of 6.0 den and a total titer of 17,000 den. The tensile resistance or pressure drop of the core 24 was 27 mmWS.
- the jacket 26 coaxially surrounding the core 24 had an inner diameter of 5.5 mm and an outer diameter of 7.8 mm with a length of likewise 8.0 mm.
- the coaxial filter part had a length of 8.0 mm with a diameter of 7.8 mm.
- the mouth-side filter part 22 was designed in one piece and consisted of cellulose acetate. It had a diameter of 7.8 mm and a length of 13 mm. A ventilation zone in the form of a series of laser perforations was provided in the area of the mouth-side filter part. The filter ventilation of cigarette A was 35%.
- the cigarette B had a 59 mm long tobacco rod and a 25 mm long multi-part filter 20.
- the core 24 of the strand-side filter part 23 had a diameter of 5.5 mm and a length of 10.0 mm. It consisted of cellulose acetate with a single titer of 6.0 den and a total titer of 17,000 den. The tensile resistance or pressure drop of the core 24 was 25 mmWS.
- the jacket 26 coaxially surrounding the core 24 had an inner diameter of 5.5 mm and an outer diameter of 7.8 mm with a length of likewise 10.0 mm.
- the coaxial filter part 23 had a length of 10.0 mm with a diameter of 7.8 mm.
- the mouth-side filter part 22 was designed in one piece and consisted of cellulose acetate. It had a diameter of 7.8 mm and a length of 15 mm. In the area of the mouth-side filter part 22, a ventilation zone in the form of a series of ventilation holes 14 was provided, which were produced by laser perforations. The filter ventilation of cigarette B was 51%.
- Example 4
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Cigarettes, Filters, And Manufacturing Of Filters (AREA)
- Manufacture Of Tobacco Products (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Compounds Of Unknown Constitution (AREA)
Abstract
Description
Rauchartikel A smoking article
Die Erfindung betrifft eine ventilierte Filtercigarette gemäß Oberbegriff des Patentanspruchs 1.The invention relates to a ventilated filter cigarette according to the preamble of patent claim 1.
Filterkonstruktionen zum Einsatz in Tabakrauchfiltern, welche aus mehreren Filterteilen mit verschiedenen Materialeigenschaften bestehen, werden im Stand der Technik zur Lösung verschiedener Aufgabenstellungen eingesetzt. Zudem wird die Ventilation von Filtern genutzt, um einen milderen Rauch und eine geringere Schadstoffzufuhr zu gewährleisten.Filter constructions for use in tobacco smoke filters, which consist of several filter parts with different material properties, are used in the prior art to solve various tasks. In addition, the ventilation of filters is used to ensure a milder smoke and a lower pollutant supply.
Die EP 474 940 B2 sowie die EP 608 047 Bl beschreiben Rauchfilter, bei denen ein mittleres Kernsegment aus einem zum Mantel unterschiedlichen Filtermaterial besteht. Diese Rauchfilter werden auch als Core- oder Koaxialfilter bezeichnet. In einer Ausfuhrungsform der EP 474 940 B2 (Fig.5) besteht der Filter aus zwei longitudinalen Filterabschnitten. nämlich dem ventilierten strangseitigen Core-Filterteil und einem mundseitigen Monofilterteil, wobei der mundseitige Monofilterteil eine ästhetische Wirkung zur Aufgabe hat. Nachteil der genannten Rauchfilter ist, dass in jedem Fall die Umhüllung des Innenkerns des Core-Filter-Abschnittes aus einem Material besteht, welches für den Rauch durchlässig ist, so dass der Rauch senkrecht zur Grenzfläche zwischen Kern und Mantel des Core-Filters strömen kann.EP 474 940 B2 and EP 608 047 B1 describe smoke filters in which a middle core segment consists of a filter material different from the jacket. These smoke filters are also called core or coaxial filters. In one embodiment of EP 474 940 B2 (FIG. 5), the filter consists of two longitudinal filter sections. namely the ventilated strand-side core filter part and a mouth-side monofilter part, the mouth-side monofilter part having an aesthetic effect. The disadvantage of the smoke filters mentioned is that in any case the covering of the inner core of the core filter section consists of a material which is permeable to the smoke, so that the smoke can flow perpendicular to the interface between the core and the jacket of the core filter.
Die EP 0 558 166 Bl beschreibt eine ventilierte Filtercigarette, die ebenfalls einen Monofilterabschnitt am Mundende und einen strangseitigen Corefilterabschnitt besitzt. Diese Filtercigarette besitzt jedoch zwischen den zwei Filterelementen eine Hohlkammer, welche mit einem Adsorptionsmittel (z.B. Aktivkohle) gefüllt ist. Dies hat zur Folge, dass sich durch das Adsoφtionsmittel der Rauchgeschmack und die Zusammensetzung der Rauchbestandteile drastisch ändert, was von vielen Rauchern nicht akzeptiert wird.EP 0 558 166 B1 describes a ventilated filter cigarette which likewise has a monofilter section at the mouth end and a core filter section on the strand side. However, this filter cigarette has a hollow chamber between the two filter elements, which is filled with an adsorbent (e.g. activated carbon). The consequence of this is that the smoke flavor and the composition of the smoke components change drastically as a result of the adsorbent, which is not accepted by many smokers.
Die EP 0 880 904 AI und die DE 39 01 226 Cl erfüllen mit Hilfe einer koaxialen Anordnung sowohl des Tabakstranges als auch des Filters die Aufgabe, eine Cigarette mit besonders niedrigen Kondensatwerten zu realisieren, was in erster Linie durch den koaxialen Aufbau des Tabakstrangs erzielt wird. Ein Nachteil dieser Konstruktion ist aber der hohe Kostenaufwand für spezielle Fertigungsaggregate, die für die Herstellung des koaxialen Stranges notwendig sind.EP 0 880 904 AI and DE 39 01 226 Cl accomplish the task of using a cigarette with a coaxial arrangement of both the tobacco rod and the filter to realize low condensate values, which is primarily achieved by the coaxial structure of the tobacco rod. A disadvantage of this design is the high cost of special manufacturing units that are necessary for the production of the coaxial strand.
Die EP 539 191 Bl stellt sich zur Aufgabe, eine ventilierte Filtercigarette mit besonders leichtem Gewicht bereitzustellen. Hier ist der Nachteil, dass die Dichten der eingesetzten Materialien (sowohl Tabakstrang als auch Filter) minimiert werden müssen, um eben eine besonders leichtgewichtige Cigarette zu realisieren, womit die Variationsmöglichkeiten der Ausstattung der Cigarette extrem eingeschränkt sind. Hier befindet sich die Ventilationszone im strangseitigen Filterteil.EP 539 191 B1 sets itself the task of providing a ventilated filter cigarette with a particularly light weight. The disadvantage here is that the densities of the materials used (both tobacco rod and filter) have to be minimized in order to realize a particularly light-weight cigarette, which extremely limits the possibilities of varying the equipment of the cigarette. Here the ventilation zone is located in the filter section on the side of the line.
Aufgabe der Erfindung ist es, eine ventilierte Filtercigarette zu schaffen, die die oben erwähnten Nachteile nicht besitzt und deren Filterelemente eine Reduzierung der Partikelphase des Rauches (wie z.B. Nikotin) bewirken und dabei gleichzeitig eine überproportionale Absenkung der Gasphasen-Rauchbestandteile erzielen, wobei der filtrierte Rauch eine für den Konsumenten geschmacklich akzeptable Zusammensetzung behalten soll.The object of the invention is to provide a ventilated filter cigarette which does not have the disadvantages mentioned above and whose filter elements bring about a reduction in the particle phase of the smoke (such as nicotine) and at the same time achieve a disproportionate reduction in the gas phase smoke components, the filtered smoke should retain a composition that is acceptable in terms of taste to the consumer.
Außerdem soll der Filter bei oben genannten Vorteilen eine hohe Variationsbreite für die sensorische, haptische und optische Ausgestaltung ermöglichen.In addition, with the advantages mentioned above, the filter should allow a wide range of variation for the sensory, haptic and optical configuration.
Eine weitere Aufgabe besteht darin, den Zugwiderstand des Filters von der Retention des Filters zu entkoppeln, d.h. eine Erhöhung des Rückhaltevermögens für Rauchinhaltsstoffe zu erzielen, ohne dabei einen starken Anstieg des Zugwiderstandes, wie er bei herkömmlichen Filterkonstruktionen zwangsläufig ist, in Kauf nehmen zu müssen.Another task is to decouple the tensile resistance of the filter from the retention of the filter, i.e. to achieve an increase in the retention capacity for smoke constituents without having to accept a strong increase in the draft resistance, which is inevitable with conventional filter designs.
Eine weitere Aufgabe der Erfindung ist es, ein Produkt mit oben genannten Vorteilen für Märkte bereitzustellen, in denen Kammerfilter und insbesondere solche, die mit Aktivkohle gefüllt sind, sowohl aus sensorischen als auch aus haptischen Gründen abgelehnt werden.Another object of the invention is to provide a product with the advantages mentioned above for markets in which chamber filters and in particular those which are filled with activated carbon are rejected for both sensory and haptic reasons.
Zur Lösung dieser Aufgabe dient eine Filtercigarette der eingangs genannten Art, die außerdem die kennzeichnenden Merkmale des Patentanspruchs 1 aufweist.A filter cigarette of the type mentioned at the outset serves to achieve this object and also has the characterizing features of patent claim 1.
Die Erfindung wird nachfolgend anhand von Ausführungsbeispielen beschrieben:The invention is described below using exemplary embodiments:
Die Figur 1 zeigt die schematische Abbildung einer erfindungsgemäßen Filtercigarette. Die Figur 2 zeigt die schematische Abbildung einer weiteren Ausfuhrungsform der erfindungsgemäßen Filtercigarette.FIG. 1 shows the schematic illustration of a filter cigarette according to the invention. FIG. 2 shows the schematic illustration of a further embodiment of the filter cigarette according to the invention.
Diese Filtercigarette besteht aus einem Strangteil 10 und einem Filter 20. Der Strangteil 10 wird von einem einteiligen Tabakstrang 11 und einer den Tabakstrang 11 umgebenden Umhüllung 12 gebildet. Der Filter 20 besteht aus mindestens zwei Filterteilen 22 und 23 und ist mit dem Strangteil 10 durch ein Umwickelpapier 13 verbunden, das mindestens 3 mm länger als der Filter 20 ist. Üblicherweise ist der Tabakstrang 11 zwischen 55 und 75 mm lang, während die Länge des Filters 20 von 21 bis 27 mm beträgt.This filter cigarette consists of a strand part 10 and a filter 20. The strand part 10 is formed by a one-piece tobacco rod 11 and a casing 12 surrounding the tobacco rod 11. The filter 20 consists of at least two filter parts 22 and 23 and is connected to the strand part 10 by a wrapping paper 13 which is at least 3 mm longer than the filter 20. The tobacco rod 11 is usually between 55 and 75 mm long, while the length of the filter 20 is between 21 and 27 mm.
Der Filter 20 ist Bereich des mundseitigen Filterteils ventiliert. Das Maß der Ventilation kann im Bereich von 10 bis 90% gewählt werden.The filter 20 is ventilated in the area of the mouth-side filter part. The degree of ventilation can be selected in the range from 10 to 90%.
Im Bereich des mundseitigen Filterteils 22 ist das Umwickelpapier 13 mit Ventilationslöchern 14 als Ventilationsmitteln versehen, die in Form von 1 bis 3 Reihen, vorzugsweise 2 Reihen von Löchern rund um den Filter 20 angeordnet sind, im Bereich des strangseitigen Filterteils 23 ist das Umwickelpapier 13 hingegen vollständig undurchlässig. Durch die Ventilationslöcher 14 wird beim Abrauchen Ventilationsluft in den Filter 20 gesogen, was dazu führt, dass im Vergleich zur Absenkung der Partikelphase eine übeφroportionale Absenkung der Gasphasenbestandteile des Tabakrauches erzielt wird. In einer Ausführungsform kann das Ventilationsmittel auch wenig, bis zu etwa 2 mm, über den mundseitigen Filterteil in den strangseitigen Filterteil hinausragen. Dabei wird die Ventilationsluft nach einer Umlenkung ebenfalls in den mundseitigen Filterteil 22 eingesogen.In the area of the mouth-side filter part 22, the wrapping paper 13 is provided with ventilation holes 14 as ventilation means, which are arranged in the form of 1 to 3 rows, preferably 2 rows of holes, around the filter 20, in the area of the strand-side filter part 23, however, is the wrapping paper 13 completely impermeable. Ventilation air is sucked into the filter 20 through the ventilation holes 14 when smoking, which leads to a disproportionate reduction in the gas phase components of the tobacco smoke being achieved in comparison with the reduction in the particle phase. In one embodiment, the ventilation means can also protrude slightly, up to about 2 mm, beyond the mouth-side filter part into the strand-side filter part. After a deflection, the ventilation air is also drawn into the mouth-side filter part 22.
Es ist dem Fachmann bekannt, wie Ventilationslöcher herzustellen sind, beispielsweise auf mechanischem oder elektrostatischem Wege oder durch Laseφerforierungen. Andere ebenfalls bekannte Ventilationsmittel sind Röhren, Kanülen oder Materialeinsparungen.It is known to the person skilled in the art how ventilation holes are to be produced, for example mechanically or electrostatically or by laser perforations. Other also known ventilation means are tubes, cannulas or material savings.
Das mundseitige Filterteil 22 besteht aus mindestens einem Filtersegment. Das mundseitige Filterteil 22 kann auch aus zwei oder mehr Filterstöpseln bestehen, wie es in Figur 2 gezeigt ist. Hierdurch ist eine höhere Variationsmöglichkeit der Filtermaterialien gegeben, wie z.B. die Möglichkeit, zusätzlich zu dem ventilierten Filterelement 22b mundseitig ein weiteres > Filterelement 22a einzusetzen., das an seiner sichtbaren Querschnittsfläche eine Prägung oder Färbung aufweisen kann.The mouth-side filter part 22 consists of at least one filter segment. The mouth-side filter part 22 can also consist of two or more filter plugs, as shown in FIG. 2. This gives a higher possibility of variation of the filter materials, e.g. the possibility, in addition to the ventilated filter element 22b, of using a further filter element 22a on the mouth side, which can have an embossing or coloring on its visible cross-sectional area.
Das einen Koaxialfilter bildende strangseitige Filterteil 23 weist einen Kern 24 und einen den Kern koaxial umgebenden Mantel 26 auf. Der Druckabfall des Kerns 24 kann zwischen 10 und 50 mmWS liegen. Der Mantel 26 ist so ausgestaltet, dass sein Druckabfall mindestens um den Faktor 2 größer ist als der des Kerns 24. Der Mantel 26 kann auch im wesentlichen rauchundurchlässig sein. Die Oberfläche 25 des Kerns 24 ist im wesentlichen rauchundurchlässig gemacht oder rauchundurchlässig umhüllt.The strand-side filter part 23 forming a coaxial filter has a core 24 and a jacket 26 coaxially surrounding the core. The pressure drop of the core 24 can be between 10 and 50 mmWS lie. The jacket 26 is designed such that its pressure drop is at least a factor of 2 greater than that of the core 24. The jacket 26 can also be essentially impermeable to smoke. The surface 25 of the core 24 is made essentially smoke-proof or is smoke-impermeable.
Die Konstruktion des strangseitigen Filterteils 23 bewirkt, dass der Rauch vornehmlich durch den Kern 24 strömt. Durch die Querschnittsverengung wird die Rauchstromgeschwindigkeit innerhalb dieses Kernsegments deutlich erhöht, was inhärent eine Zugwiderstandserhöhung bei relativ geringer Retention beinhaltet. Eine analoge Wirkung wird erzielt, wenn die Querschnittsverengung des vom Rauch durchströmten Materials dadurch bedingt wird, dass der Kern des Koaxialfilterstöpsels nahezu undurchlässig gestaltet ist und dann der gesamte Rauch ausschließlich durch den Mantel strömt.The construction of the filter part 23 on the strand side causes the smoke to flow primarily through the core 24. The narrowing of the cross-section significantly increases the smoke flow velocity within this core segment, which inherently includes an increase in draft resistance with a relatively low retention. An analogous effect is achieved if the narrowing of the cross section of the material through which the smoke flows is caused by the fact that the core of the coaxial filter plug is designed to be almost impermeable and the entire smoke then flows exclusively through the jacket.
Erst nach der vielfachen Erhöhung der Rauchstromgeschwindigkeit im strangseitigen Filterteil 23 wird im mundseitigen Filterteil 22 in hohem Maße Ventilationsluft mit Hilfe der Ventilationsmittel 14 zugeführt. Dadurch wird eine in bezug auf die Partikelphase übeφroportionale Absenkung der Gasphasenbestandteile erzielt, wobei gleichzeitig akzeptable Zugwiderstände für den Raucher gewährleistet werden.Only after the multiple increase in the smoke flow speed in the line-side filter part 23 is ventilation air supplied to a large extent in the mouth-side filter part 22 with the aid of the ventilation means 14. As a result, a reduction in the gas phase constituents which is disproportionate to the particle phase is achieved, while at the same time ensuring acceptable draft resistances for the smoker.
Im Gegensatz zum Stand der Technik sind die Variationsmöglichkeiten der Ausgestaltung innerhalb der vorgegebenen Zielsetzung extrem zahlreich, da bei der erfindungsgemäßen Filtercigarette die übeφroportionale Absenkung der Gasphase ohne wesentliche Beeinflussung der Zügigkeit stattfindet, so dass z.B. ein typischer von Rauchern als ,J uftgeschmack" bezeichneter Effekt ausbleibt.In contrast to the state of the art, the design options are extremely numerous within the specified objective, since the filter cigarette according to the invention allows the gas phase to be lowered proportionally without significantly influencing the speed, so that e.g. there is no typical effect which smokers call "yeast taste".
Als Filtermaterialien für den Filter 20 kommen flächenformige, faserförmige oder granulatfbrmige Filtermaterialien in Frage, wie Cellulose, Celluloseester, vorzugsweise Celluloseacetat, Meltblown-Filtermaterial z.B. hergestellt nach WO97/33026, Airlaid- Filtermaterial z.B. hergestellt nach US 4,375,447, mit Additiven versetzbare Filtermaterialien, Tabak z.B. nach der DE 19925 968, rekonstituierter Tabak, andere leicht verrottbare Filtermaterialien oder thermoplastische Filterfasern.Suitable filter materials for the filter 20 are sheet-like, fibrous or granular filter materials, such as cellulose, cellulose esters, preferably cellulose acetate, meltblown filter material e.g. manufactured according to WO97 / 33026, airlaid filter material e.g. manufactured according to US 4,375,447, additive filter materials, tobacco e.g. according to DE 19925 968, reconstituted tobacco, other easily decomposable filter materials or thermoplastic filter fibers.
Die Zugabe von Additiven kann zur sensorischen, haptischen oder optischen Verbesserung der erfindungsgemäßen Cigarette dienen und/oder eine zusätzliche Wirkung auf die selektive Retention haben. So kann z.B. ein Filterelement des Filterteils 22 mit Aktivkohlepartikeln versehen sein um die Gasphasenadsoφtion zu erhöhen. Um die Akzeptanz der Cigarette durch den Konsumenten zusätzlich mit Hilfe optischer Mittel zu steigern, kann z.B. der mundseitige Filterstöpsel farbig ausgestattet sein. Durch die Zugabe von Säuren oder Basen lassen sich die pH-Werte der Partikelspektren und damit der geschmackliche Eindruck beeinflussen.The addition of additives can serve for the sensory, haptic or optical improvement of the cigarette according to the invention and / or have an additional effect on the selective retention. For example, a filter element of the filter part 22 can be provided with activated carbon particles in order to increase the gas phase adsorption. To the acceptance of the cigarette To increase the consumer with the help of optical means, for example, the mouth-side filter plug can be colored. The pH values of the particle spectra and thus the taste impression can be influenced by adding acids or bases.
Die Zugabe der Additive kann durch Streuen oder Aufsprühen auf die Filtermaterialien, z.B. Fasern, oder aber durch direkte Injektion in den Materialstrang erfolgen.The addition of the additives can be done by sprinkling or spraying on the filter materials, e.g. Fibers, or by direct injection into the material strand.
Als Additive für das Filtermaterial kommen in Frage: Aromastoffe, Säuren oder Basen in suspendierter oder gelöster Form, oder Additive mit selektiver Retentionswirkung Adsorbentien wie Aktivkohle oder Siθ2. Weitere Additive mit selektiver Retentionswirkung sind organische Säuren Basen z.B. Hydroxycarbonsäuren und deren Salze, Metalle und Metalloxide, StickstoiB omponenten, Ionenaustauschersysteme (z.B. Zeolithe), Alkohole, Polyphenole und Poφhyrinderivate.Possible additives for the filter material are: flavoring agents, acids or bases in suspended or dissolved form, or additives with a selective retention effect adsorbents such as activated carbon or SiO 2. Other additives with a selective retention effect are organic acid bases e.g. Hydroxycarboxylic acids and their salts, metals and metal oxides, nitrogen components, ion exchange systems (e.g. zeolites), alcohols, polyphenols and polyphyrin derivatives.
Weitere Additive wie Weichmacher z.B. Triacetiti, Triethylenglycoldiacetat oder Citrone säurediethylester, den Photoabbau beschleunigende Additive z.B. Titandioxid, die biologische Abbaubarkeit begünstigende Additive, Vitamine und/oder Farbpigmente kommen zur individuellen Ausgestaltung der gewünschten Filterkonstruktion in Frage.Other additives such as plasticizers e.g. Triacetiti, triethylene glycol diacetate or citric acid diethyl ester, additives which accelerate photo degradation e.g. Titanium dioxide, additives that promote biodegradability, vitamins and / or color pigments can be used for the individual design of the desired filter construction.
Als Bereich für Ausfuhrungsformen der Celluloseacetatspezifikation kommen in Frage: Für den Kern 24 ein Einzeltiter im Bereich von 3,0 bis 8,0 den, vorzugsweise 8,0 den und ein Gesamttiter im Bereich von 15.000 bis 50.000 den, vorzugsweise 17.000 den. Für den Mantel 26 ein Einzeltiter im Bereich von 1,5 bis 3,0 den, vorzugsweise 2,1 den und ein Gesamttiter im Bereich von 40.000 bis 75.000 den, vorzugsweise 55.000 den.Possible areas for embodiments of the cellulose acetate specification are: For the core 24, a single titer in the range from 3.0 to 8.0 den, preferably 8.0 den and a total titer in the range from 15,000 to 50,000 den, preferably 17,000 den. For the jacket 26 a single titer in the range from 1.5 to 3.0 den, preferably 2.1 den and a total titer in the range from 40,000 to 75,000 den, preferably 55,000 den.
Der Bereich der Einzeltiter für den mundseitigen Filterteil 22 im Falle von Celluloseacetat als Filtermaterial, welcher aus zwei oder mehreren gleich- oder verschiedenartigen Segmenten 22a und 22b bestehen kann, beträgt 1,5 bis 5 den und für den Gesamttiter 15000 bis 60000 den. Beispiel 1:The range of the individual titers for the mouth-side filter part 22 in the case of cellulose acetate as filter material, which can consist of two or more identical or different segments 22a and 22b, is 1.5 to 5 den and for the total titre 15000 to 60,000 den. Example 1:
Die Cigarette A hatte einen 63 mm langen Tabakstrang 11 und einen 21 mm langen mehrteiligen Filter 20.The cigarette A had a 63 mm long tobacco rod 11 and a 21 mm long multi-part filter 20.
Der Kern 24 des strangseitigen Filterteils 23 hatte einen Durchmesser von 5,5 mm bei einer Länge von 8,0 mm. Er bestand aus Celluloseacetat mit einem Einzeltiter von 6,0 den und einem Gesamttiter von 17.000 den. Der Zugwiderstand oder Druckabfall des Kerns 24 lag bei 27 mmWS.The core 24 of the strand-side filter part 23 had a diameter of 5.5 mm and a length of 8.0 mm. It consisted of cellulose acetate with a single titer of 6.0 den and a total titer of 17,000 den. The tensile resistance or pressure drop of the core 24 was 27 mmWS.
Der den Kern 24 koaxial umgebende Mantel 26 hatte einen Innendurchmesser von 5,5 mm und einen Außendurchmesser von 7,8 mm bei einer Länge von ebenfalls 8,0 mm. Als Material wurde Celluloseacetat mit einem Einzeltiter von 2,1 den und einem Gesamttiter von 55.000 den verwendet.The jacket 26 coaxially surrounding the core 24 had an inner diameter of 5.5 mm and an outer diameter of 7.8 mm with a length of likewise 8.0 mm. Cellulose acetate with a single titer of 2.1 den and a total titer of 55,000 den was used as the material.
In der Summe hatte der Koaxialfilterteil also eine Länge von 8,0 mm bei einem Durchmesser von 7,8 mm.In total, the coaxial filter part had a length of 8.0 mm with a diameter of 7.8 mm.
Der mundseitige Filterteil 22 war einteilig ausgestaltet und bestand aus Celluloseacetat. Er besaß einen Durchmesser von 7.8 mm bei einer Länge von 13 mm. Im Bereich des mundseitigen Filterteils war eine Ventilationszone in Form einer Reihe von Laseφerforationen vorgesehen. Die Filterventilation der Cigarette A betrug 35%.The mouth-side filter part 22 was designed in one piece and consisted of cellulose acetate. It had a diameter of 7.8 mm and a length of 13 mm. A ventilation zone in the form of a series of laser perforations was provided in the area of the mouth-side filter part. The filter ventilation of cigarette A was 35%.
Beispiel 2:Example 2:
Zur Beurteilung der Cigarette A aus Beispiel 1 wurden Rauchanalysedaten ermittelt und mit denen einer Cigarette VI verglichen, welche mit einem herkömmlichen Celluloseacetatfilter von 21 mm Länge und einem Einzeltiter von 3.0 den sowie einer Filterventilation von 18% ausgestattet war und nach ISO abgeraucht wurde. Die Tabelle 1 zeigt Ergebnisse der Rauchdaten. Tabelle 1:To evaluate the cigarette A from example 1, smoke analysis data were determined and compared with that of a cigarette VI, which was equipped with a conventional cellulose acetate filter of 21 mm in length and a single titer of 3.0 den and a filter ventilation of 18% and was smoked according to ISO. Table 1 shows results of the smoke data. Table 1:
Beispiel 3:Example 3:
Die Cigarette B hatte einen 59 mm langen Tabakstrang und einen 25 mm langen mehrteiligem Filter 20.The cigarette B had a 59 mm long tobacco rod and a 25 mm long multi-part filter 20.
Der Kern 24 des strangseitigen Filterteils 23 hatte einen Durchmesser von 5,5 mm bei einer Länge von 10,0 mm. Er bestand aus Celluloseacetat mit einem Einzeltiter von 6,0 den und einem Gesamttiter von 17.000 den. Der Zugwiderstand oder Druckabfall des Kerns 24 lag bei 25 mmWS.The core 24 of the strand-side filter part 23 had a diameter of 5.5 mm and a length of 10.0 mm. It consisted of cellulose acetate with a single titer of 6.0 den and a total titer of 17,000 den. The tensile resistance or pressure drop of the core 24 was 25 mmWS.
Der den Kern 24 koaxial umgebende Mantel 26 hatte einen Innendurchmesser von 5,5 mm und einen Außendurchmesser von 7,8 mm bei einer Länge von ebenfalls 10,0 mm. Als Material wurde Celluloseacetat mit einem Einzeltiter von 2,1 den und einem Gesamttiter von 55.000 den verwendet.The jacket 26 coaxially surrounding the core 24 had an inner diameter of 5.5 mm and an outer diameter of 7.8 mm with a length of likewise 10.0 mm. Cellulose acetate with a single titer of 2.1 den and a total titer of 55,000 den was used as the material.
In der Summe hatte der koaxiale Filterteil 23 also eine Länge von 10,0 mm bei einem Durchmesser von 7,8 mm.In total, the coaxial filter part 23 had a length of 10.0 mm with a diameter of 7.8 mm.
Der mundseitige Filterteil 22 war einteilig ausgestaltet und bestand aus Celluloseacetat. Er besaß einen Durchmesser von 7.8 mm bei einer Länge von 15 mm. Im Bereich des mundseitigen Filterteils 22 war eine Ventilationszone in Form einer Reihe von Ventilationslöchern 14 vorgesehen, die durch Laseφerforationen hergestellt waren. Die Filterventilation der Cigarette B betrug 51%. Beispiel 4:The mouth-side filter part 22 was designed in one piece and consisted of cellulose acetate. It had a diameter of 7.8 mm and a length of 15 mm. In the area of the mouth-side filter part 22, a ventilation zone in the form of a series of ventilation holes 14 was provided, which were produced by laser perforations. The filter ventilation of cigarette B was 51%. Example 4:
Zur Beurteilung der Cigarette B aus Beispiel 3 wurden Rauchanalysedaten ermittelt und mit denen einer Cigarette V2 verglichen, welche mit herkömmlichen Celluloseacetatfilter von 25 mm Länge und einem Einzeltiter von 3.0 den sowie einer Filterventilation von 38% ausgestattet war und nach ISO abgeraucht wurde. Die Tabelle 2 zeigt Ergebnisse der Rauchdaten.To evaluate the cigarette B from example 3, smoke analysis data were determined and compared with that of a cigarette V2, which was equipped with conventional cellulose acetate filters of 25 mm in length and a single titer of 3.0 den and a filter ventilation of 38% and was smoked according to ISO. Table 2 shows results of the smoke data.
Tabelle 2:Table 2:
Aus den Beispielen wird deutlich, dass die Absenkung der Gasphasenbestandteile des Cigarettenrauches gegenüber denen der Partikelphase, mit Hilfe der neuen Filterkonstruktion übeφroportional hoch ist. From the examples it becomes clear that the reduction in the gas phase components of the cigarette smoke compared to that of the particle phase is disproportionately high with the help of the new filter construction.
Claims
Priority Applications (13)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE50100499T DE50100499D1 (en) | 2000-03-01 | 2001-02-20 | SMOKING ARTICLE |
| HU0300441A HUP0300441A3 (en) | 2000-03-01 | 2001-02-20 | Item for smoking |
| PL01365130A PL365130A1 (en) | 2000-03-01 | 2001-02-20 | Item for smoking |
| AT01907545T ATE246882T1 (en) | 2000-03-01 | 2001-02-20 | SMOKING ITEMS |
| UA2002097765A UA71062C2 (en) | 2000-03-01 | 2001-02-20 | Smoking article |
| HK03106609.7A HK1054300B (en) | 2000-03-01 | 2001-02-20 | Smoking article |
| SK1412-2002A SK286989B6 (en) | 2000-03-01 | 2001-02-20 | Item for smoking |
| KR1020027011326A KR20020075459A (en) | 2000-03-01 | 2001-02-20 | Item for Smoking |
| SI200130037T SI1259130T1 (en) | 2000-03-01 | 2001-02-20 | Item for smoking |
| EP01907545A EP1259130B1 (en) | 2000-03-01 | 2001-02-20 | Item for smoking |
| AU2001235485A AU2001235485A1 (en) | 2000-03-01 | 2001-02-20 | Item for smoking |
| JP2001562966A JP2003525043A (en) | 2000-03-01 | 2001-02-20 | Smoking equipment |
| EA200200934A EA003912B1 (en) | 2000-03-01 | 2001-02-20 | Item for smoking |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10009829.0 | 2000-03-01 | ||
| DE10009829A DE10009829A1 (en) | 2000-03-01 | 2000-03-01 | Filter cigarette has two part filter with ventilator, core, casing and length of tobacco. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2001064061A1 true WO2001064061A1 (en) | 2001-09-07 |
Family
ID=7633015
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/EP2001/001913 Ceased WO2001064061A1 (en) | 2000-03-01 | 2001-02-20 | Item for smoking |
Country Status (21)
| Country | Link |
|---|---|
| US (1) | US20030140932A1 (en) |
| EP (1) | EP1259130B1 (en) |
| JP (1) | JP2003525043A (en) |
| KR (1) | KR20020075459A (en) |
| CN (1) | CN1232192C (en) |
| AT (1) | ATE246882T1 (en) |
| AU (1) | AU2001235485A1 (en) |
| BG (1) | BG65496B1 (en) |
| CZ (1) | CZ299205B6 (en) |
| DE (2) | DE10009829A1 (en) |
| EA (1) | EA003912B1 (en) |
| ES (1) | ES2204833T3 (en) |
| HK (1) | HK1054300B (en) |
| HU (1) | HUP0300441A3 (en) |
| PL (1) | PL365130A1 (en) |
| PT (1) | PT1259130E (en) |
| RS (1) | RS50150B (en) |
| SK (1) | SK286989B6 (en) |
| TW (1) | TW544288B (en) |
| UA (1) | UA71062C2 (en) |
| WO (1) | WO2001064061A1 (en) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102005005175A1 (en) * | 2005-02-01 | 2006-08-10 | Reemtsma Cigarettenfabriken Gmbh | Filter cigarette |
| GB0713905D0 (en) † | 2007-07-17 | 2007-08-29 | British American Tobacco Co | Cellulose acetate thread in filter |
| GB0816933D0 (en) * | 2008-09-16 | 2008-10-22 | British American Tobacco Co | Filter for a smoking article |
| GB0816937D0 (en) * | 2008-09-16 | 2008-10-22 | British American Tobacco Co | Filter for a Smoking Article |
| CN101926509B (en) * | 2009-06-23 | 2012-05-30 | 湖北中烟工业有限责任公司 | Method and equipment for producing longitudinal multi-circle filter tip rod |
| CN101708072B (en) * | 2009-12-23 | 2011-04-13 | 川渝中烟工业公司 | Composite filter tip containing biological composition |
| US9226524B2 (en) | 2010-03-26 | 2016-01-05 | Philip Morris Usa Inc. | Biopolymer foams as filters for smoking articles |
| GB201110863D0 (en) * | 2011-06-27 | 2011-08-10 | British American Tobacco Co | Smoking article filter and insertable filter unit thereof |
| JP2014230489A (en) * | 2011-09-20 | 2014-12-11 | 日本たばこ産業株式会社 | Cigarette |
| SG11201407870WA (en) * | 2012-05-31 | 2014-12-30 | Philip Morris Products Sa | Smoking article with concentric filter |
| GB201217894D0 (en) * | 2012-10-05 | 2012-11-21 | British American Tobacco Co | A smoking article |
| WO2014091605A1 (en) * | 2012-12-13 | 2014-06-19 | 日本たばこ産業株式会社 | Cigarette |
| CN103238931A (en) * | 2013-05-22 | 2013-08-14 | 广东中烟工业有限责任公司 | Composite cigarette filter rod capable of automatically guiding flow and composite cigarette |
| GB201421803D0 (en) * | 2014-12-08 | 2015-01-21 | British American Tobacco Co | A smoking article, a filter and a method of manufacturing a smoking article |
| GB201608931D0 (en) | 2016-05-20 | 2016-07-06 | British American Tobacco Co | Article for use in apparatus for heating smokeable material |
| JP2017136084A (en) * | 2017-04-05 | 2017-08-10 | 日本たばこ産業株式会社 | cigarette |
| CN111712143B (en) * | 2018-03-08 | 2022-11-25 | 菲利普莫里斯生产公司 | Aerosol-generating article |
| WO2019170449A1 (en) * | 2018-03-08 | 2019-09-12 | Philip Morris Products S.A. | Aerosol generating articles |
| KR102815679B1 (en) * | 2018-03-08 | 2025-06-04 | 필립모리스 프로덕츠 에스.에이. | Aerosol generating items |
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- 2000-03-01 DE DE10009829A patent/DE10009829A1/en not_active Withdrawn
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2001
- 2001-02-20 EP EP01907545A patent/EP1259130B1/en not_active Expired - Lifetime
- 2001-02-20 AT AT01907545T patent/ATE246882T1/en not_active IP Right Cessation
- 2001-02-20 RS YUP-648/02A patent/RS50150B/en unknown
- 2001-02-20 DE DE50100499T patent/DE50100499D1/en not_active Expired - Lifetime
- 2001-02-20 KR KR1020027011326A patent/KR20020075459A/en not_active Ceased
- 2001-02-20 AU AU2001235485A patent/AU2001235485A1/en not_active Abandoned
- 2001-02-20 HU HU0300441A patent/HUP0300441A3/en unknown
- 2001-02-20 ES ES01907545T patent/ES2204833T3/en not_active Expired - Lifetime
- 2001-02-20 PL PL01365130A patent/PL365130A1/en unknown
- 2001-02-20 CZ CZ20023262A patent/CZ299205B6/en not_active IP Right Cessation
- 2001-02-20 UA UA2002097765A patent/UA71062C2/en unknown
- 2001-02-20 SK SK1412-2002A patent/SK286989B6/en not_active IP Right Cessation
- 2001-02-20 HK HK03106609.7A patent/HK1054300B/en not_active IP Right Cessation
- 2001-02-20 CN CNB018059597A patent/CN1232192C/en not_active Expired - Fee Related
- 2001-02-20 EA EA200200934A patent/EA003912B1/en not_active IP Right Cessation
- 2001-02-20 PT PT01907545T patent/PT1259130E/en unknown
- 2001-02-20 JP JP2001562966A patent/JP2003525043A/en active Pending
- 2001-02-20 US US10/220,555 patent/US20030140932A1/en not_active Abandoned
- 2001-02-20 WO PCT/EP2001/001913 patent/WO2001064061A1/en not_active Ceased
- 2001-04-09 TW TW090104587A patent/TW544288B/en not_active IP Right Cessation
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- 2002-09-30 BG BG107159A patent/BG65496B1/en unknown
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| EP0539191A1 (en) * | 1991-10-23 | 1993-04-28 | Rothmans International Services Limited | Lightweight cigarette filter and cigarettes incorporating such filters |
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Also Published As
| Publication number | Publication date |
|---|---|
| UA71062C2 (en) | 2004-11-15 |
| CZ299205B6 (en) | 2008-05-14 |
| DE10009829A1 (en) | 2001-09-20 |
| PT1259130E (en) | 2003-12-31 |
| CN1232192C (en) | 2005-12-21 |
| EP1259130A1 (en) | 2002-11-27 |
| HK1054300A1 (en) | 2003-11-28 |
| ATE246882T1 (en) | 2003-08-15 |
| EP1259130B1 (en) | 2003-08-13 |
| JP2003525043A (en) | 2003-08-26 |
| HK1054300B (en) | 2006-08-25 |
| EA200200934A1 (en) | 2003-02-27 |
| HUP0300441A3 (en) | 2005-11-28 |
| SK286989B6 (en) | 2009-08-06 |
| AU2001235485A1 (en) | 2001-09-12 |
| KR20020075459A (en) | 2002-10-04 |
| YU64802A (en) | 2005-03-15 |
| RS50150B (en) | 2009-05-06 |
| HUP0300441A2 (en) | 2003-08-28 |
| PL365130A1 (en) | 2004-12-27 |
| ES2204833T3 (en) | 2004-05-01 |
| US20030140932A1 (en) | 2003-07-31 |
| SK14122002A3 (en) | 2003-02-04 |
| CZ20023262A3 (en) | 2003-03-12 |
| EA003912B1 (en) | 2003-10-30 |
| BG65496B1 (en) | 2008-10-31 |
| TW544288B (en) | 2003-08-01 |
| DE50100499D1 (en) | 2003-09-18 |
| CN1407861A (en) | 2003-04-02 |
| BG107159A (en) | 2003-06-30 |
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