WO2001060578A1 - Procede et appareil de production de feuilles composites - Google Patents
Procede et appareil de production de feuilles composites Download PDFInfo
- Publication number
- WO2001060578A1 WO2001060578A1 PCT/DK2001/000109 DK0100109W WO0160578A1 WO 2001060578 A1 WO2001060578 A1 WO 2001060578A1 DK 0100109 W DK0100109 W DK 0100109W WO 0160578 A1 WO0160578 A1 WO 0160578A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- weave
- hot
- temperature
- pressing
- rollers
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
- B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
- B32B5/26—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
- B29C70/28—Shaping operations therefor
- B29C70/40—Shaping or impregnating by compression not applied
- B29C70/50—Shaping or impregnating by compression not applied for producing articles of indefinite length, e.g. prepregs, sheet moulding compounds [SMC] or cross moulding compounds [XMC]
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/02—Layered products comprising a layer of synthetic resin in the form of fibres or filaments
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/04—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the partial melting of at least one layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
- B32B5/10—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer characterised by a fibrous or filamentary layer reinforced with filaments
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H13/00—Other non-woven fabrics
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/02—Synthetic macromolecular fibres
- B32B2262/0253—Polyolefin fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/10—Inorganic fibres
- B32B2262/101—Glass fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2309/00—Parameters for the laminating or treatment process; Apparatus details
- B32B2309/14—Velocity, e.g. feed speeds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/10—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
- B32B37/1054—Regulating the dimensions of the laminate, e.g. by adjusting the nip or platen gap
Definitions
- the present invention relates to a method for production of composite sheets as described in the introductory part of claim 1.
- the invention is also relates to an apparatus for production of the composite sheets.
- weave This term not only covers matrices that are woven but also matrices where long, arranged threads are assembled by stitching.
- the term "weave” is used for composites with long fibres in contrast to "non-woven" materials, which are mixtures of short fibres and are used, for example, in insulation mats.
- a so-called belt press can be used, which is known, for example, from international patent application W097/26397.
- a matrix of threads is passed through a heating process and a pressing process, where the pressing process takes place between pressure rollers with belts around them arranged in such a way, that the composite sheet in the form of a continuos web is pro- cuted between the belts on each side of the sheet.
- belt presses are very ex-
- This method has a lot of disadvantages.
- To achieve a complete melting of the weave it is exposed to a strong thermal radiation on a preheating stage.
- the disadvantage of the preheating stage is that a temperature is reached on the external side of the weave, which is close to the decomposition temperature for the polymer, for example, 230°C for polypropylene, abbreviated PP, while the temperature in the centre of the weave is much lower, for example, 140°C, and often below melting point, which for PP is 165°C. Consequently, a decomposition of external polymer fibres takes place in the weave, which is extremely inappropriate, but accepted in order to obtain necessary heating to the final temperature, where the polymer is melted to form the composite.
- the purpose of the invention is to provide a method and an apparatus for production of composite sheets from a weave, where the above-described disadvantages are avoided, and where heating of the weave preferably takes place without thermal radiation preheating.
- the void volume is that volume of the composite which consists of air. The bigger the void volume, the less strength has the composite.
- the invention is characterised in that the weave comprises polymer threads, preferably PP, PET or PTFE plus threads of a reinforcing material, preferably glass fibres, but carbon fibres or fibres of other materials could be used as well.
- polymer threads preferably PP, PET or PTFE plus threads of a reinforcing material, preferably glass fibres, but carbon fibres or fibres of other materials could be used as well.
- the invention is characterised in that the share of glass threads in the weave is between 55% and 75%, preferably between 60% and 70%, and most preferably 60%.
- the share of reinforcing material like glass
- a further embodiment of the invention is characterised in that the hot rolling tempera- ture is between 0° and 20° below the decomposition temperature for that of the at least two materials that has the lowest decomposition temperature, preferably between 0° and 10° below the decomposition temperature and most preferably between 0° and 6° below the decomposition temperature.
- the decomposition temperature for PP is 220°. At heating above that temperature, a decomposition process of the fibres begins. Therefore, it is important that the polymer is not heated up to a temperature higher than the decomposition temperature. On the other hand, it is important that the polymer is as viscous as possible, so that it finally can settle around the reinforcing fibres to a sufficient extent.
- the invention is characterised in that the process rate is be- tween 0.5 m/min and 2 m/min, preferably between 1.4 and 1.6 m/min. It is appropriate to have a high production rate, as in this case the product can be manufactured in a shortest possible time.
- a pressing process which includes both hot rollers and cold rollers, it is important, that the composite sheet is transported from the hot process to the cold pressing process before the material is cooled off so much, that a sufficient homogenisation and shaping of the material can not take place during the final pressing process with cold rollers.
- the production must not be so fast, that a sufficient homogenisation, that is flowing of the polymer and enclosure of the glass fibres, does not occur.
- the stiffness is expressed with a so-called Young's modulus, which is a ratio between a compressive or tensile stress on the material in the composite sheet's longitudinal direction and the corresponding relative linear expansion. At a certain tensile stress on the composite sheet, the Young's modulus is the bigger, the less the sheet is extended as a result of tension.
- the invention is characterised in that the heating process in- eludes heating with thermal radiation. This is a possibility, which can be used in connection with the invention. It has however turned out that the stage can be omitted.
- the invention is characterised in that the heating by thermal radiation provides a temperature of the weave between 1 10° and 170°C, preferably between 120°C and 160°C, and most preferably 140°C. Provided that preheating is used, this temperature has proven to be advantageous. However, it is important that during the thermal radiation treatment, the surface of the weave is not supplied with so much heat that it decomposes. In general, it is not necessary to preheat the weave, but it is not impossible in certain cases that an advantage can be obtained by heating in addition to the hot pressing rollers.
- the invention is characterised in that during the pressing process the weave is subjected to a rolling pressure only where the thickness of the composite sheet is larger than a certain adjustable minimum thickness.
- the minimum thickness is adjusted to an appropriate value with regard for the weave's thickness and the number of the weaves melted and pressed together.
- the invention is characterised in that during the cooling down process, the weave is subjected to a cold rolling pressure of at least one rotating cold roller.
- a cold rolling pressure of at least one rotating cold roller After the first step of the pressing process, where the composite sheet is formed with the weave as a starting material, one or more subsequent pressing stages can be used with advantage, where the co ⁇ esponding rollers have a much lower temperature than the hot rolling temperature.
- the not yet hardened composite sheet can be shaped in accordance with predetermined profiles. The sheet can, for example, be given a wavy or serrated shape depending on the required final product.
- the cold rollers must therefore be appropriately designed for such special purposes.
- the invention is characterised in that the weave is subjected to surface structuring during the pressing process in hot conditions and/or by pressing during the cooling down process.
- surface structuring of the weave can, for example, be carried out by cold rollers if they have a surface design which after pressing is trans- ferred to the composite sheet surface.
- the weave it can be furnished with holes of different shapes to supplement specific structuring of the weave.
- An apparatus for production of composite sheets comprising one or more mediums for feeding in of at least one matrix of threads, preferably a weave with polymer threads and glass threads, at least one device for heating of the matrix, at least one heated rotating roller, over which the matrix is passed, and where the rotating roller is heated up to a hot rolling temperature which is above melting point for that of the at least two materials in the matrix with the lowest melting point and below melting point for that of the at least two materials with the highest melting point, and where the hot rolling temperature is below the decomposition temperature for any of the at least two materials, at least one arrangement for pressing the matrix together, and at least one device for cooling the matrix down is according to the invention characterised in that the matrix pressing arrangement includes at least one rotating hot roller, which is heated up to the hot rolling temperature.
- the apparatus is characterised in that said at least one arrangement for pressing said at least one matrix comprises at least one set of two hot rollers with parallel rotation axes and rotating in opposite directions with equal surface speed, wherein said two hot rollers are heated up to said hot rolling temperature, wherein said hot rollers are arranged with a mutual spacing, preferably adjustable, and with a pressure, preferably adjustable, between said two hot rollers directed towards their rotation axes in such a way that said at least one matrix passing through said hot rollers is simultaneously subjected to both heating and pressing.
- the apparatus is characterised in that said arrangement for pressing said at least one matrix comprises at least one set of two cold rollers with parallel rotation axes and rotating in opposite directions with equal surface speed, wherein said cold rollers have a surface temperature, which is below melting tempera- ture of the materials in the weave, wherein said cold rollers are placed behind said hot rollers and arranged with a mutual spacing, preferably adjustable, and a pressure, pref- erably adjustable, between said two cold rollers directed towards their rotation axes in such a way that said at least one matrix passing through said cold rollers is subjected to additional pressing.
- the apparatus is characterised in that said at least one device for heating up said at least one matrix comprises at least one rotating preheating roller, which is heated up to said hot rolling temperature and which is placed before said at least one arrangement for pressing said at least one matrix.
- the apparatus is characterised in that the diameter of said hot rollers is between 300 mm and 500 mm, preferably between 350 mm and 450 mm, most preferably 400 mm. It is advantageous, that the hot rollers have a relatively large diameter, as it gives the possibility for the weave to get in contact with the rollers surface over a larger area, which results in a thorough penetration of heat into the mate- rial. With small diameters, for example 40 mm, the heat penetration into the material is so insufficient that there occurs a significant temperature difference between the surface of the formed composite sheet and the centre plane of the composite sheet. Due to the fact that during melting and pressing, the polymer must completely enclose the reinforcing threads, it is advantageous to use bigger rollers for contact heating of the weave.
- the apparatus is characterised in that said hot rollers and or said cold rollers are provided as a solid of revolution with a surface profile deviating from cylindrical shape such that the resulting composite sheet is given a shape deviat- ing from a planar shape.
- the apparatus is characterised in that said at least one arrangement for pressing said at least one matrix has an adjustable minimum opening for the passage of said matrix though this arrangement, wherein said minimum opening defines a limit for the pressing of said at least one composite sheet.
- said at least one heating device contain at least one station with thermal radiation. Testing of the invention has shown, that heating of the weave with thermal radiation is not necessary. However, the invention is not restricted to not using this form of heating, and in special cases it may be an advantage to apply this heating stage.
- Composite sheets produced in accordance with the invention can with advantage be used in complex structures, where the sheets are included as a replacement for aluminium sheets.
- Composite sheets have better weight to stiffness ratio than aluminium sheets, and much higher impact strength. These parameters are often key components for the selection of the material.
- the composite sheets produced according to the invention can replace aluminium surfaces in food production industry, for example in refrigeration trucks.
- Composite sheets are already used in refrigeration trucks, but those composite sheets are made of thermosetting plastic material based on hardening resin and, possibly, embedded glass as reinforcing material.
- Composite sheets produced under the invention contain a thermoplastic material plus a reinforcing material, like glass. They can be produced much faster, cheaper and can even be reshaped and thus tailored to fit very specific tasks.
- refrigeration containers dry cargo containers
- body parts for agricultural machines components for aeroplanes, boats or automobiles
- reinforced cabinets for electronic industry components for weapons industry
- components for construction industry for example coverings for facades and partition walls, as well as components for furniture industry.
- preheating has been applied, which, however, proved to be unnecessary for the particular weave.
- example 3 in the table it has even been possible to increase the process rate, when the preheating was not used. In such case, it was not necessary to apply higher pressure, however, the temperature was close to the weave's decomposition temperature, which is about 220° C.
- FIG.1 is a sketch of an apparatus for the production method according to the invention
- FIG.2 is another embodiment of an apparatus according to the invention
- FIG.3 illustrates various embodiments of roller profiles
- FIG.4 is a third embodiment of an apparatus according to the invention.
- FIG.1 is a sketch of an apparatus for a production method according to the invention.
- Weave 1 which is a long fibre composite, for example a woven or stitched matrix of polypropylene fibres and glass fibres, is transported from roll 2 to a hot roller 3, which is heated up to a hot rolling temperature T l5 where the hot rolling temperature T, is a temperature above the melting point for that of the at least two materials which has the lowest melting point and below melting point for that of the at least two materials which has the highest melting point, and where the hot rolling temperature is below the decomposition temperature for any one of the materials.
- the weave is heated up to the temperature above melting point for one or more composite materials, after which the weave under pressure Pj from the roller, normally against another hot roller 3', is shaped to a composite sheet 5, which is partially melted.
- another set of rollers 6 and 6' which are cold rollers, is used for further pressing with pressure P 2 and shaping of the composite sheet 5, 7.
- the cold rollers 6, 6' have a temperature T 2 , which is considerably lower than the hot rolling temperature T,, for example room temperature. Cooling of the composite sheet 5, 7 can take place during the second pressing as well as during additional active cooling afterwards; or cooling can be done by passive cooling, that is by emission of heat to surroundings.
- FIG. 1 two sheets of the weave 1 and 1 ' are shown, which are pressed together to form one composite sheet. It is possible to use only one sheet. By using two sheets with a certain thickness, which are melted together, instead of one sheet with double thickness, a better penetration of heat into the weaves before pressing is achieved. Alternatively, a larger number of the weaves can be pressed together, possibly with several pressing stages in a more complex design of the apparatus.
- FIG. 2 is another design version of an apparatus according to the invention, where one hot roller 3 and one preheating roller 8 are used for heating up the weave 1 to a hot rolling temperature.
- the preheating roller 8 has a temperature T 0 , which can be equal to or different from the hot roller temperature.
- T 0 The contact surface 4 with the hot rollers will then be larger, which ensures heat penetration into the weave before pressing with pressure Pj. This is a big advantage especially for thicker weaves 1.
- pressure P 0 which is variable.
- the different hot rollers can have equal or different temperature. Furthermore, between individual set of rollers, the weave is subjected to pressure of different strengths. An apparatus according to the invention can thus be designed in different ways depending on the required process stages.
- Rollers rotation speed, wO, w0', wl, wl ', w2 and w2' is mutually adjusted to the di- ameters of rollers 3, 3', 6, 6' in such a way that the weave is not subjected to an inappropriate stretching, but is yet transported through the apparatus in stretched conditions.
- FIG. 1 also illustrates other devices 9 for heating of the weave 1.
- the devices 9 consist of heating units with thermal radiation. In most of the cases there will be no need for the heating units 9, as heating by hot rollers is sufficient. However, in certain cases it can appear to be useful to heat the weave first in this heating unit.
- FIG. 3 illustrates different profiles for the rollers in the direction perpendicular to the rotation axes 10, 10' o the rollers 6, 6'.
- the rollers 6, 6' are placed opposite to each other with a certain minimum spacing 11, which can be adjusted depending on the weave's thickness. Further, the rollers 6, 6' can be provided with a surface structure which is transferred to the weave during pressing.
- FIG. 4 Weave 1 can during composite sheet formation also be coated with a surface layer 12, 12', for example, a smooth synthetic sheet, a metal sheet or other material, which is sketched in FIG. 4.
- the surface sheet 12 will normally be fed in between the hot rollers 3, 3' and cold rollers 6, 6'.
- the surface sheet 12, 12' is fed in while the composite sheet 5 has not yet hardened. It is also possible to heat the cold rollers 6,6' up to a temperature such that the surface sheet 12, 12' is heated prior to coming into contact with the composite sheet 5.
- the thermal radiation heating 13 of the surface sheet 12, 12' can be applied.
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Composite Materials (AREA)
- Mechanical Engineering (AREA)
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
Abstract
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AU2001233616A AU2001233616A1 (en) | 2000-02-17 | 2001-02-16 | Method and apparatus for production of composite sheets |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DKPA200000252 | 2000-02-17 | ||
| DK200000252A DK173918B1 (da) | 2000-02-17 | 2000-02-17 | Fremgangsmåde og apparat til fremstilling af kompositplader |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2001060578A1 true WO2001060578A1 (fr) | 2001-08-23 |
Family
ID=8159158
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/DK2001/000109 Ceased WO2001060578A1 (fr) | 2000-02-17 | 2001-02-16 | Procede et appareil de production de feuilles composites |
Country Status (3)
| Country | Link |
|---|---|
| AU (1) | AU2001233616A1 (fr) |
| DK (1) | DK173918B1 (fr) |
| WO (1) | WO2001060578A1 (fr) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2002030657A1 (fr) * | 2000-10-13 | 2002-04-18 | Barsmark A/S | Procede, appareil et matrice de fabrication de plaques composites |
| DE102014017807B3 (de) * | 2014-12-04 | 2016-03-31 | Freundes- und Förderkreis des Institutes für Textiltechnik der RWTH Aachen e.V. | Flechtpultrusionsanlage |
| RU190142U1 (ru) * | 2019-04-01 | 2019-06-21 | Федеральное государственное бюджетное образовательное учреждение высшего образования "Кубанский государственный технологический университет" (ФГБОУ ВО "КубГТУ") | Устройство для получения композитного материала |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2093768A (en) * | 1981-02-26 | 1982-09-08 | Fothergill & Harvey Ltd | Composite woven fabric laminate |
| FR2704477A1 (fr) * | 1993-04-26 | 1994-11-04 | Hainaut Sa Fibres | Procédé de fabrication de plaques planes ondulées ou nervurées à base de résine thermodurcissable et dispositif pour la mise en Óoeuvre de ce procédé. |
| WO1997026397A2 (fr) * | 1996-01-19 | 1997-07-24 | Vetrotex France S.A. | Procede et dispositif de fabrication d'un materiau composite |
| WO1998031857A1 (fr) * | 1997-01-16 | 1998-07-23 | Vetrotex France | Procede et dispositif de fabrication de plaques composites |
| FR2797892A1 (fr) * | 1999-08-27 | 2001-03-02 | Vetrotex France Sa | Procede et dispositif de fabrication de plaques composites |
-
2000
- 2000-02-17 DK DK200000252A patent/DK173918B1/da not_active IP Right Cessation
-
2001
- 2001-02-16 AU AU2001233616A patent/AU2001233616A1/en not_active Abandoned
- 2001-02-16 WO PCT/DK2001/000109 patent/WO2001060578A1/fr not_active Ceased
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2093768A (en) * | 1981-02-26 | 1982-09-08 | Fothergill & Harvey Ltd | Composite woven fabric laminate |
| FR2704477A1 (fr) * | 1993-04-26 | 1994-11-04 | Hainaut Sa Fibres | Procédé de fabrication de plaques planes ondulées ou nervurées à base de résine thermodurcissable et dispositif pour la mise en Óoeuvre de ce procédé. |
| WO1997026397A2 (fr) * | 1996-01-19 | 1997-07-24 | Vetrotex France S.A. | Procede et dispositif de fabrication d'un materiau composite |
| WO1998031857A1 (fr) * | 1997-01-16 | 1998-07-23 | Vetrotex France | Procede et dispositif de fabrication de plaques composites |
| FR2797892A1 (fr) * | 1999-08-27 | 2001-03-02 | Vetrotex France Sa | Procede et dispositif de fabrication de plaques composites |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2002030657A1 (fr) * | 2000-10-13 | 2002-04-18 | Barsmark A/S | Procede, appareil et matrice de fabrication de plaques composites |
| DE102014017807B3 (de) * | 2014-12-04 | 2016-03-31 | Freundes- und Förderkreis des Institutes für Textiltechnik der RWTH Aachen e.V. | Flechtpultrusionsanlage |
| RU190142U1 (ru) * | 2019-04-01 | 2019-06-21 | Федеральное государственное бюджетное образовательное учреждение высшего образования "Кубанский государственный технологический университет" (ФГБОУ ВО "КубГТУ") | Устройство для получения композитного материала |
Also Published As
| Publication number | Publication date |
|---|---|
| DK200000252A (da) | 2001-08-18 |
| DK173918B1 (da) | 2002-02-18 |
| AU2001233616A1 (en) | 2001-08-27 |
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