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WO2000020399A2 - Utilisation de 5-hydroxypyrazoles substitues, nouveaux 5-hydroxypyrazoles, procedes permettant de les preparer et agents les contenant - Google Patents

Utilisation de 5-hydroxypyrazoles substitues, nouveaux 5-hydroxypyrazoles, procedes permettant de les preparer et agents les contenant Download PDF

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Publication number
WO2000020399A2
WO2000020399A2 PCT/EP1999/007125 EP9907125W WO0020399A2 WO 2000020399 A2 WO2000020399 A2 WO 2000020399A2 EP 9907125 W EP9907125 W EP 9907125W WO 0020399 A2 WO0020399 A2 WO 0020399A2
Authority
WO
WIPO (PCT)
Prior art keywords
alkyl
subst
formula
methyl
compounds
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP1999/007125
Other languages
German (de)
English (en)
Other versions
WO2000020399A3 (fr
Inventor
Andreas Gypser
Reinhard Kirstgen
Hubert Sauter
Herbert Bayer
Oliver Cullmann
Markus Gewehr
Wassilios Grammenos
Bernd Müller
Arne Ptock
Jordi Tormo I Blasco
Eberhard Ammermann
Thomas Grote
Gisela Lorenz
Siegfried Strathmann
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Priority to AU61965/99A priority Critical patent/AU6196599A/en
Priority to JP2000574516A priority patent/JP2002526536A/ja
Priority to EP99948860A priority patent/EP1117650A2/fr
Publication of WO2000020399A2 publication Critical patent/WO2000020399A2/fr
Publication of WO2000020399A3 publication Critical patent/WO2000020399A3/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/04—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings directly linked by a ring-member-to-ring-member bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/06—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
    • C07D231/08—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with oxygen or sulfur atoms directly attached to ring carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/06—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a carbon chain containing only aliphatic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D405/00—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom
    • C07D405/02—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings
    • C07D405/04—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings directly linked by a ring-member-to-ring-member bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D409/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms
    • C07D409/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings
    • C07D409/04—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings directly linked by a ring-member-to-ring-member bond

Definitions

  • R 4 is hydrogen, halogen, nitro, cyano, N (R '), C ⁇ . -C 4 alkyl, -C-C 4 haloalkyl, COOR ', hetaryl or heterocyclyl;
  • the invention also relates to new 5-hydroxypyrazoles and processes for their preparation.
  • the starting materials are generally reacted with one another in equimolar amounts. It can be advantageous for the yield to use III in an excess based on II.
  • Halogen fluorine, chlorine, bromine and iodine
  • Alkoxy straight-chain or branched alkyl groups with 1 to 10 carbon atoms (as mentioned above) which are bonded to the skeleton via an oxygen atom (-0-);
  • Haloalkynyl unsaturated, straight-chain or branched hydrocarbon radicals with 2 to 10 carbon atoms and a triple bond in any position (as mentioned above), the hydrogen atoms in these groups being partially or completely replaced by halogen atoms as mentioned above, in particular fluorine, chlorine and bromine can;
  • Arylcarbonylthio a mono- to trinuclear aromatic ring system (as mentioned above) which is bonded to the skeleton via a carbonylthio group (-COS-);
  • Arylaminosulfonyl a mono- to trinuclear arylamino group (as mentioned above) which is bonded to the skeleton via a sulfonyl group (-S0 2 -);
  • alkyl, alkenyl and alkynyl groups can be partially or completely halogenated [i.e. the hydrogen atoms of these groups can be partially or completely replaced by identical or different halogen atoms as mentioned above (preferably fluorine, chlorine or bromine) and / or can carry one to three (preferably one) of the following radicals:
  • cycloalkyl cycloalkoxy, cycloalkylthio, cycloalkylamino, cycloalkyl-N-alkylamino, heterocyclyl, heterocyclyloxy, heterocyclylthio, heterocyclylamino or heterocyclyl-N-alkylamino, preferably 12 to 8, the cyclic systems 3 to 12, the cyclic systems, 3 to 12, the cyclic systems Contain ring members, in particular 3 to 6 ring members and the alkyl groups in these radicals preferably 1 to 6
  • Phenyl is in particular to be understood as a phenyl ring which is substituted by halogen, cyano, nitro, hydroxy, amino, carboxyl, aminocarbonyl, C 1 -C 4 -alkyl or halogen-C 1 -C 4 -alkyl.
  • Botrytis cinerea (gray mold) on strawberries, vegetables, ornamental plants and vines, • Cercospora arachidicola on peanuts,
  • Oils of various types, herbicides, fungicides, other pesticides, bactericides can be added to the active compounds, if appropriate also only immediately before use (tank mix). These agents can be added to the agents according to the invention in a weight ratio of 1:10 to 10: 1.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

L'invention concerne l'utilisation pour lutter contre des champignons nuisibles, de 5-hydroxypyrazoles de la formule (I) dans laquelle les substituants ont la signification suivante: B désigne aryle ou hétaryle; A désigne C=O, C=S ou SO2; R1 désigne alkyle, halogénure d'alkyle, alkényle, halogénure d'alkényle, alkinyle ou halogénure d'alkinyle, cycloalkyle, cycloalkényle C¿3?-C10, cycloalkinyle, ou aryle, hétérocyclyle ou hétaryle; R?2¿ désigne hydrogène; R3 désigne hydrogène, nitro, cyano, N(R')¿2?, alkyle, halogénure d'alkyle, alcoxy, halogénure d'alcoxy, alkényle, halogénure d'alkényle, alkinyle ou halogénure d'alkinyle, les restes R' désignent indépendamment les uns des autres hydrogène ou alkyle; ou R?2 et R3¿ désignent conjointement un groupe =O, =S ou =N-O-R5, R5 désignant hydrogène, alkyle, halogénure d'alkyle, alkényle, halogénure d'alkényle, alkinyle ou halogénure d'alkynyle; R4 désigne hydrogène halogène, nitro, cyano, N(R')¿2?, alkyle, halogénure d'alkyle, COOR', hétaryle ou hétérocyclyle. L'invention concerne également des agents contenant lesdits composés, ainsi que de nouveaux 5-hydroxypyrazoles et des procédés permettant de les préparer.
PCT/EP1999/007125 1998-10-02 1999-09-24 Utilisation de 5-hydroxypyrazoles substitues, nouveaux 5-hydroxypyrazoles, procedes permettant de les preparer et agents les contenant Ceased WO2000020399A2 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
AU61965/99A AU6196599A (en) 1998-10-02 1999-09-24 Use of substituted 5-hydroxypyrazoles, novel 5-hydroxypyrazoles, methods for theproduction thereof and agents containing the same
JP2000574516A JP2002526536A (ja) 1998-10-02 1999-09-24 置換５−ヒドロキシピラゾールの使用、新規５−ヒドロキシピラゾール、それらの製造法、およびそれらを含有する組成物
EP99948860A EP1117650A2 (fr) 1998-10-02 1999-09-24 Utilisation de 5-hydroxypyrazoles substitues, nouveaux 5-hydroxypyrazoles, procedes permettant de les preparer et agents les contenant

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19845509.7 1998-10-02
DE19845509 1998-10-02

Publications (2)

Publication Number Publication Date
WO2000020399A2 true WO2000020399A2 (fr) 2000-04-13
WO2000020399A3 WO2000020399A3 (fr) 2000-07-27

Family

ID=7883246

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP1999/007125 Ceased WO2000020399A2 (fr) 1998-10-02 1999-09-24 Utilisation de 5-hydroxypyrazoles substitues, nouveaux 5-hydroxypyrazoles, procedes permettant de les preparer et agents les contenant

Country Status (4)

Country Link
EP (1) EP1117650A2 (fr)
JP (1) JP2002526536A (fr)
AU (1) AU6196599A (fr)
WO (1) WO2000020399A2 (fr)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006128823A1 (fr) * 2005-05-31 2006-12-07 Basf Aktiengesellschaft N-benzyl-5-hydroxy-5-phenylpyrazolines fongicides, procede de production de ces composes et agents contenant lesdits composes
WO2006128815A1 (fr) * 2005-05-31 2006-12-07 Basf Aktiengesellschaft Utilisation de 5-hydroxypyrazolines bicycliques, procede de fabrication et agents contenant ces composes
WO2006128817A1 (fr) * 2005-05-31 2006-12-07 Basf Aktiengesellschaft Utilisation de 5-hydroxypyrazolines fongicides, procede de fabrication et agents contenant ces composes
WO2006128824A1 (fr) * 2005-05-31 2006-12-07 Basf Aktiengesellschaft 5-hydroxypyrazolines fongicides, procede de production de ces composes et agents contenant lesdits composes

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0532662A (ja) * 1990-11-09 1993-02-09 Nissan Chem Ind Ltd 置換ピラゾール誘導体および農園芸用殺菌剤

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006128823A1 (fr) * 2005-05-31 2006-12-07 Basf Aktiengesellschaft N-benzyl-5-hydroxy-5-phenylpyrazolines fongicides, procede de production de ces composes et agents contenant lesdits composes
WO2006128815A1 (fr) * 2005-05-31 2006-12-07 Basf Aktiengesellschaft Utilisation de 5-hydroxypyrazolines bicycliques, procede de fabrication et agents contenant ces composes
WO2006128817A1 (fr) * 2005-05-31 2006-12-07 Basf Aktiengesellschaft Utilisation de 5-hydroxypyrazolines fongicides, procede de fabrication et agents contenant ces composes
WO2006128824A1 (fr) * 2005-05-31 2006-12-07 Basf Aktiengesellschaft 5-hydroxypyrazolines fongicides, procede de production de ces composes et agents contenant lesdits composes

Also Published As

Publication number Publication date
AU6196599A (en) 2000-04-26
EP1117650A2 (fr) 2001-07-25
JP2002526536A (ja) 2002-08-20
WO2000020399A3 (fr) 2000-07-27

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