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WO2000012054A1 - Utilisation d'acide polyaspartique dans des produits de traitement capillaire - Google Patents

Utilisation d'acide polyaspartique dans des produits de traitement capillaire Download PDF

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Publication number
WO2000012054A1
WO2000012054A1 PCT/EP1999/006247 EP9906247W WO0012054A1 WO 2000012054 A1 WO2000012054 A1 WO 2000012054A1 EP 9906247 W EP9906247 W EP 9906247W WO 0012054 A1 WO0012054 A1 WO 0012054A1
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WO
WIPO (PCT)
Prior art keywords
hair
acid
polyaspartate
groups
polymers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP1999/006247
Other languages
German (de)
English (en)
Inventor
Susanne Birkel
Angelika Beyer
Harald Wendel
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Deutschland GmbH
Original Assignee
Wella GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wella GmbH filed Critical Wella GmbH
Priority to AU57407/99A priority Critical patent/AU5740799A/en
Publication of WO2000012054A1 publication Critical patent/WO2000012054A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41—Amines
    • A61K8/416—Quaternary ammonium compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
    • A61K8/8176—Homopolymers of N-vinyl-pyrrolidones. Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
    • A61K8/8182—Copolymers of vinyl-pyrrolidones. Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/88—Polyamides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/54—Polymers characterized by specific structures/properties
    • A61K2800/542—Polymers characterized by specific structures/properties characterized by the charge
    • A61K2800/5426—Polymers characterized by specific structures/properties characterized by the charge cationic
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/59—Mixtures
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
    • A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations

Definitions

  • the invention relates to the use of polyaspartic acid or polyaspartates in hair treatment agents to improve the moisturizing ability and hair treatment agents with a combination of polyaspartic acid or polyaspartates with film-forming, hair-fixing polymers.
  • Hair fixatives and hair styling products are used to strengthen, shape and keep the hair in this shape or to give the hair more volume.
  • these agents also have nourishing effects on the treated hair, if possible.
  • Such care effects are, for example, greater moisture retention of the hair, antistatic effect, strengthening the hair, greater shine, etc. Dry hair is rough, brittle, lackluster and easily gets tangled at the ends. It is therefore desirable to improve the moisture retention of hair and to prevent dehydration.
  • the active substances used to achieve a certain effect have disadvantages in another area at the same time, or in a combination of active substances the individual active substances mutually impair one another.
  • a large number of polymers are known which are able to give the hairstyle a firm hold even at a low concentration.
  • Cationic polymers improve combability, but they have little strength.
  • cationic polymers tend to accumulate on the hair even over hair washes, which can result in the hair becoming dull, lackluster.
  • gloss-giving additives such as oils, in particular silicone oils, can be used.
  • these additives often have the disadvantage that they reduce the strengthening of the hairstyle as a plasticizer and additionally give the hair an annoying load.
  • the polyaspartic acid or its salts, the polyaspartates, in particular in combination with film-forming, hair-fixing polymers increase the moisture-holding capacity and can thereby protect the hair from drying out and at the same time give the hair shine, firmness and antistatic properties.
  • the consolidation advantageously proved to be long-lasting, i.e. it can be felt over several washes.
  • the invention relates to the use of polyaspartic acid or polyaspartates in hair treatment agents to improve the moisturizing ability.
  • films made from polyaspartic acid or polyaspartates are able to absorb significant amounts of water vapor (approx. 54%), but only release a small part of the water absorbed (residual moisture approx. 41%). These films therefore show excellent water retention and can serve as a moisture store for hair treated with them.
  • the counterions of the polyaspartates can be any cosmetically acceptable cation.
  • the cationic counterion is preferably selected from metal ions, in particular alkali or alkaline earth metal ions such as sodium, potassium, calcium or magnesium, or ammonium ions of the general formula NR1R2R3R4 + , where the substituents Rl to R4 can be the same or different and are selected from hydrogen and organic groups with 1 to 5 carbon atoms.
  • the usable sodium salt has, for example, the general formula H 2 N- [CH (C0 2 Na) CH 2 CONH-] n CH (C0 2 Na) CH 2 C0 2 Na, wöbei preferably a number from 4 n to 40, more preferably from Is 10 to 30.
  • Another object of the invention is a cosmetic agent containing (A) polyaspartic acid or polyaspartate, the counterions of the polyaspartate being selected from metal ions or ammonium ions of the general type
  • Formula NR1R2R3R4 + where the substituents Rl to R4 may be the same or different and are selected from hydrogen and organic groups with 1 to 5 carbon atoms and (B) at least one film-forming and hair-fixing polymer.
  • Film-forming, hair-fixing polymers are to be understood as meaning those polymers which, when used alone in 0.1 to 5% strength aqueous, alcoholic or aqueous-alcoholic solution, are able to deposit a polymer film on the hair and in this way to strengthen the hair .
  • the hair retains moisture in the dry state and is not charged statically. At the same time, it has a natural feel, silky sheen and volume. Due to the Strengthening the firming properties by adding polyaspartic acid or polyaspartate keeps the hairstyle longer and better. After about 3 washes, the stiffness values are over 4.0, which indicates long-lasting strengthening.
  • the polyaspartic acid or the polyaspartate is preferably present in the agent according to the invention in an amount of 0.01 to 2.5 percent by weight, particularly preferably in an amount of 0.05 to 1 percent by weight.
  • Preferred forms of use of the agent according to the invention contain 0.01 to 50 percent by weight, preferably 0.1 to 25, in particular 0.5 to 20 percent by weight of at least one synthetic or natural, film-forming, hair-fixing polymer.
  • the hair-fixing polymers can be used individually or in a mixture.
  • Suitable synthetic, nonionic, film-forming, hair-fixing polymers are, for example, homopolymers of vinylpyrrolidone and homopolymers of N-vinylformamide.
  • Other suitable synthetic film-forming, nonionic hair-fixing polymers are, for example, copolymers of vinylpyrrolidone and vinyl acetate, terpolymers of vinylpyrrolidone, vinyl acetate and vinyl propionate, polyacrylamides, polyvinyl alcohols and also high molecular weight polyethylene glycol or high molecular weight copolymers of ethylene glycol with propylene properties with solid properties.
  • Suitable natural film-forming polymers with hair-setting action are, for example, various types of saccharides, such as, for example, polysaccharides or mixtures of oligo-, mono- and disaccharides, which for example sold under the trade name C-PUR ® by the company Cerestar, Brussels / Belgium.
  • Further suitable natural polymers include Chinese Balsam resin and cellulose derivatives, for example, hydroxypropylcellulose having a molecular weight of 30,000 to 50,000 g / mol, which is marketed for example under the trade name NISSO SL ® from Lehmann & Voss / Germany.
  • the invention therefore also relates to a composition containing
  • Components (A) and (B) are preferably in a ratio of 20: 1 to 1:20, particularly preferably 1: 1 to 1: 9.
  • the polymer (B) contains acid groups, these are preferably selected from -COOH, -S0 3 H, -OS0 3 H, -OP0 2 H and -OP0 3 H 2 .
  • the acid groups can be unneutralized, partially or completely neutralized. They are preferably 50 to 100% anionic or neutralized form.
  • Organic or inorganic bases suitable for cosmetic purposes can be used as neutralizing agents. Examples of bases are amino alcohols such as, for example, aminomethylpropanol (AMP), triethanolamine or monoethanolamine and ammonia, NaOH and others.
  • the polymer of component (B) can be a natural or a synthetic homo- or copolymer with monomer units containing acid groups, which is optionally copolymerized with comonomers which do not contain acid groups.
  • Suitable acid groups are sulfonic acid, phosphoric acid and carboxylic acid groups, of which the carboxylic acid groups are preferred.
  • Suitable monomers are unsaturated, free-radically polymerizable compounds which carry at least one acid group, in particular carboxyvinyl monomers.
  • Suitable monomers containing acid groups are, for example, acrylic acid, methacrylic acid, crotonic acid, maleic acid or maleic anhydride or the like
  • Comonomers which are not substituted with acid groups are, for example, acrylamide, methacrylamide, alkyl- and dialkyl-acrylamide, alkyl- and dialkyl-methacrylamide, alkyl acrylate, alkyl methacrylate, vinyl caprolactone, vinyl pyrrolidone, vinyl ester, vinyl alcohol, propylene glycol or ethylene glycol, amine-substituted vinyl monoalkylamylamino-acrylate, such as dialyl amyl acrylate, for example dialyl amyl acrylate, such as dialyl amyl acrylate, for example dialyl amyl acrylate, for example dialyl amyl acrylate, such as dialacrylamyl Monoalkylaminoalkyl acrylate and monoalkylaminoalkyl methacrylate, where the alkyl groups of these monomers are preferably Cl to C7 alkyl groups, particularly preferably Cl to C3 alkyl groups.
  • Suitable polymers with acid groups are in particular uncrosslinked or crosslinked with polyfunctional agents, homopolymers of acrylic acid or methacrylic acid, copolymers of acrylic acid or methacrylic acid with monomers selected from acrylic acid or methacrylic acid esters, acrylamides, methacrylamides and vinylpyrrolidone, homopolymers of crotonic acid and copolymers of crotonic acid with monomers selected from vinyl esters, acrylic acid or methacrylic acid esters, acrylamides and methacrylamides.
  • a suitable natural polymer is shellac, for example.
  • Preferred polymers with acid groups are crosslinked or uncrosslinked vinyl acetate / crotonic acid copolymers. Partially esterified copolymers between vinyl methyl ether and maleic anhydride are also preferred.
  • Other suitable anionic polymers are, for example, terpolymers of acrylic acid, alkyl acrylate and N-alkyl acrylamide, in particular acrylic acid / ethyl acrylate / N-t-butylacrylamide terpolymers or terpolymers of vinyl acetate, crotonate and vinyl alkanoate, in particular vinyl acetate / crotonate / vinyl neodecanoate copolymers.
  • preferably used polymers with acidic groups are amphoteric polymers which, in addition to the acidic groups, contain basic or cationic groups as further functional groups, in particular primary, secondary, tertiary or quaternary amine groups.
  • Examples include copolymers formed from alkyl acrylamide (especially octyl acrylamide), alkylaminoalkyl methacrylate (especially t-butylaminoethyl methacrylate) and two or more monomers consisting of acrylic acid, methacrylic acid or their esters, such as National Starch, USA are available, for example under the trade name Amphomer.RTM ® or Amphomer.RTM ® LV 71st
  • suitable as component (B) copolymers with acid groups are copolymers of acrylic acid, methyl acrylate and methacrylamidopropyltrimethylammonium chloride (INCI name: Polyquaternium-47) are described, for example meadow by the company Calgon under the trade name Mer
  • polymers with monomers bearing betaine groups such as, for example, copolymers of methacryloylethyl betaine and two or more monomers of acrylic acid or their simple esters, known under the INCI name methacryloyl ethyl betaine / acrylates copolymer.
  • the zwitterionic amphoteric polymers described in JP 10-29919 or JP 10-25344 are also suitable.
  • Suitable polymers with basic groups have a molecular weight of preferably at least 50,000 g / mol, particularly preferably from 100,000 to 6,000,000 g / mol and contain nitrogen-containing groups such as primary, secondary or tertiary amines.
  • the basic group is either in the polymer chain or preferably as a substituent on one or more Contain monomers.
  • the polymer with basic groups can be a natural or a synthetic homo- or copolymer with amine-substituted monomer units and optionally with non-basic comonomers.
  • Suitable polymers with basic groups are, for example, copolymers of amine-substituted vinyl monomers and non-amine-substituted monomers.
  • Amine-substituted vinyl monomers are, for example, dialkylaminoalkyl acrylate, dialkylaminoalkyl methacrylate, monoalkylaminoalkyl acrylate and monoalkylaminoalkyl methacrylate, the alkyl groups of these monomers preferably being lower alkyl groups such as C1 to C7 alkyl groups, particularly preferably C1 to C3 alkyl groups.
  • Non-amine-substituted comonomers are, for example, acrylamide, methacrylamide, alkyl and dialkyl acrylamide, alkyl and dialkyl methacrylamide, alkyl acrylate, alkyl methacrylate, vinyl caprolactone, vinyl pyrrolidone, vinyl ester, vinyl alcohol, maleic anhydride, propylene glycol or ethylene glycol, the alkyl groups of these monomers preferably - to C7-alkyl groups, particularly preferably C1- to C3-alkyl groups.
  • preferably used polymers with basic groups are the amphoteric polymers mentioned above.
  • Suitable polymers with cationic groups preferably contain quaternary amine groups.
  • the cationic polymers can be homo- or copolymers, the quaternary nitrogen groups being contained either in the polymer chain or preferably as a substituent on one or more monomers.
  • the ammonium groups Monomers containing can be copolymerized with the above-mentioned non-amine-substituted monomers.
  • Suitable ammonium-substituted vinyl monomers are, for example, trialkylmethacryloxyalkylammonium, trialkylacryloxyalkylammonium, dialkyldiallylammonium and quaternary vinylammonium monomers with cyclic, cationic nitrogen-containing groups, such as pyridinium, imidazolium or quaternary pyrrolidones, for example alkylvinylimidazolidolium, alkylcyclidimidazolium, alkylphylimidazolium, or alkylvinylimidazolium, alkylpylimidazolium, alkylpylimidazolium, alkylpylimidazolium, alkylpylimidazolium, alkylpylimidazolium or alkyl vinyl imidazolium, such as alkyl vinyl imidazolium, or alkyl vinyl imidazolium pyrid.
  • Monomers are preferably lower alkyl groups such as, for example, Cl to C7 alkyl groups, particularly preferably Cl to C3 alkyl groups.
  • Suitable polymers with quaternary amine groups are, for example, the polymers described in the CTFA Cosmetic Ingredient Dictionary under the names Polyquaternium, such as methylvinylimidazolium chloride / vinylpyrrolidone copolymer (Polyquaternium-16), quaternized vinylpyrrolidone / dimethylaminoethyl methacrylate copolymer (Polyquaternium-Copol 11), homo- Dirnethyldiallylammonium chloride (Polyquaternium-6 and -7), quaternized hydroxyethyl cellulose (Polyquaternium-10) or quaternized guar derivatives.
  • Polyquaternium such as methylvinylimidazolium chloride / vinylpyrrolidone copolymer (Polyquaternium-16), quaternized vinylpyrrolidone / dimethylaminoethyl methacrylate copolymer (Polyquaternium-Copol 11), homo- Dirnethyl
  • Polyvinylpyrrolidone / dimethylaminoethyl methacrylate copolymer is suitable from the cationic polymers which may be present in the agent according to the invention.
  • Other cationic polymers are, for example, the copolymer of polyvinylpyrrolidone and imidazolimine methochloride, the terpolymer of dimethyldiallylammonium chloride, sodium acrylate and acrylamide, the terpolymer of vinylpyrrolidone, Dimethylaminoethyl methacrylate and vinyl caprolactam, quaternized ammonium salts from hydroxyethyl cellulose and a trimethylammonium substituted epoxide and vinylpyrrolidone / methacrylamidopropyltrimethylammonium chloride copolymers.
  • the agent according to the invention is preferably packaged in an aqueous or in an aqueous-alcoholic medium, the alcohol content preferably being 5 to 90, particularly preferably 5 to 50
  • Weight percent is.
  • the lower alcohols with 1 to 4 carbon atoms usually used for cosmetic purposes such as ethanol and isopropanol, can be included as alcohols.
  • particularly preferred water-soluble solvents are glycerol and propylene glycol in an amount of up to 30 percent by weight.
  • water-insoluble solvents or a mixture of solvents with a boiling point below 400 ° C. in an amount of 0.1 to 90 percent by weight, preferably from 1 to 50
  • Unbranched or branched hydrocarbons such as pentane, hexane, isopentane and cyclic hydrocarbons such as cyclopentane and cyclohexane are particularly suitable.
  • the agent according to the invention can furthermore contain the additional ingredients customary for hair treatment agents, for example wetting agents or emulsifiers from the classes of anionic, amphoteric or nonionic surface-active surfactants, such as fatty alcohol sulfates, alkylbenzenesulfonates, alkyltrimethylammonium salts, alkylbetaines, oxethylated fatty alcohols and oxethylated nonylphenols , Fatty acid alkanolamides, ethoxylated fatty acid esters, in an amount of 0.1 to 30 percent by weight; Humectants; Perfume oils in an amount of 0.1 to 0.5 percent by weight; Opacifiers, such as ethylene glycol distearate, in an amount of about 0.2 to 5.0 percent by weight; Pearlescent agents, such as a mixture of
  • Fatty acid monoalkylolamide and ethylene glycol distearate in an amount of about 1.0 to 10 percent by weight
  • bactericidal and fungicidal active ingredients such as, for example, 2, 4, 4-trichloro-2-hydroxydiphenyl ether or methylchloroisothiazolinone, in an amount of 0.01 to 1.0 percent by weight
  • Thickeners such as, for example, coconut fatty acid diethanolamide, in an amount of about 0.2 to 3.0 percent by weight, buffer substances, such as, for example, sodium citrate or sodium phosphate, in an amount of 0.1 to 1.0 percent by weight
  • Solubilizers such as ethoxylated castor oil, in an amount of about 0.1 to 1.0 percent by weight
  • Stains such as fluorescein sodium salt, in an amount of about 0.1 to 1.0 percent by weight
  • Care substances such as plant and herbal extracts, protein and silk hydrolyzates, cationic resins, lanolin derivatives, in an amount of 0.1 to 5
  • the agent according to the invention can be present in a pH range from 2.0 to 9.5.
  • the pH range between 2.5 and 8 is particularly preferred.
  • the agent according to the invention can contain organic or inorganic acids such as formic acid, tartaric acid, malic acid, maleic acid, fumaric acid, pyrrolidonecarboxylic acid, citric acid, sulfuric acid , Acetic acid, hydrochloric acid, phosphoric acid and others.
  • the agent according to the invention can be used in various application forms. It can be sprayed using a blowing agent or with the aid of a mechanically operated spray device or can be dispensed as foam using a blowing agent or with the aid of a foam generating device. Use in conventional O / W and W / O emulsions is possible as well as in application forms as a gel, wax, lotion, cream, gel foam or micro-emulsion.
  • the agent according to the invention can also be formulated as a coloring or nourishing hair treatment agent, for example as a color fixer and hair conditioner.
  • the agent according to the invention is in the form of an aerosol hairspray or aerosol hair lacquer, it additionally contains 3 to 85 percent by weight, preferably 25 to 75 percent by weight, of a propellant and is filled into a pressure vessel.
  • blowing agents are, for example, lower alkanes, such as n-butane, i-butane and propane or mixtures thereof, and dimethyl ether and fluorocarbons such as F 152 (1, 1-difluoroethane) or F 134 (tetrafluoroethane) and also at the pressures under consideration gaseous present blowing agents, such as N 2 , N 2 0 and C0 2 and mixtures of the above blowing agents are suitable.
  • agent according to the invention is in the form of a sprayable non-aerosol hair spray or a non-aerosol hair lacquer, it is sprayed with the aid of a suitable mechanically operated spray device.
  • Mechanical spraying devices are to be understood as devices which do
  • a suitable mechanical spraying device can be, for example, a spray pump or an elastic container provided with a spray valve, in which the cosmetic agent according to the invention is filled under pressure, the elastic container expanding and from which the agent continuously as a result of the contraction of the elastic container when the spray valve is opened is used.
  • the agent according to the invention is in the form of a setting hair foam (mousse)
  • at least one of the polymers is foam-forming or it additionally contains at least one customary foaming substance known for this purpose.
  • the agent is foamed with or without the help of propellant gases or chemical propellants and incorporated into the hair as a foam and left in the hair without rinsing.
  • the agent according to the invention has an additional
  • Component a mechanical device for foaming the composition.
  • Mechanical foaming devices are to be understood as devices which foam a liquid with or without Allow use of a blowing agent.
  • a commercially available pump foamer or an aerosol foam head, for example, can be used as a suitable mechanical foaming device.
  • the agent according to the invention is in the form of a setting hair gel, it additionally contains at least one gel-forming substance, for example the thickeners listed above in an amount of preferably 0.05 to 10, particularly preferably 0.1 to 2 percent by weight.
  • the viscosity of the gel is preferably from 500 to 50,000 cSt, particularly preferably from 1,000 to 15,000 cSt at 25 ° C.
  • the agent according to the invention is in the form of a hair wax, it additionally contains water-insoluble fatty substances or substances similar to fat or wax in an amount of preferably 0.5 to 30 percent by weight.
  • Suitable water-insoluble substances are, for example, emulsifiers with an HLB value below 7, silicone oils, silicone waxes, waxes (e.g. wax alcohols, wax acids, wax esters, and in particular natural waxes such as beeswax, carnauba wax, etc.), fatty alcohols, fatty acids or fatty acid esters.
  • the agent according to the invention is in the form of a setting hair lotion, it is in the form of a non-viscous solution, dispersion or emulsion containing at least 5 percent by weight, preferably 5 to 95 percent by weight, particularly preferably 20 to 50 percent by weight, of a cosmetically acceptable alcohol.
  • a cosmetically acceptable alcohol preferably the lower alcohols with 1 to 4 which are usually used for cosmetic purposes can be used as alcohols Carbon atoms such as ethanol and isopropanol can be used.
  • the agent according to the invention is in the form of a setting hair cream, for example a coloring cream, it is preferably in the form of an emulsion and either contains additional viscosity-imparting substances such as the above-mentioned thickeners in an amount of 0.1 to 10 percent by weight or the required viscosity and Consistency is built up in the usual way by micelle formation with the aid of suitable emulsifiers, fatty acids, fatty alcohols, waxes etc.
  • additional viscosity-imparting substances such as the above-mentioned thickeners in an amount of 0.1 to 10 percent by weight or the required viscosity and Consistency is built up in the usual way by micelle formation with the aid of suitable emulsifiers, fatty acids, fatty alcohols, waxes etc.
  • the agent according to the invention is applied by distributing a sufficient amount for the desired setting in or on dry hair or after shampooing in or on damp, towel-dried hair.
  • the amount to be used depends on the fullness of the hair and is typically 5 to 30 g.
  • the agent is preferably not rinsed out, so it remains on the hair.
  • the hair is then optionally combed through or shaped into a hairstyle and optionally dried.
  • the hairstyle can also be done before the agent is applied, especially if the agent is in the form of a spray.
  • Copolymer 0.20 g perfume 0.07 g l-amino-4- (2 ', 3' -dehydroxypropyl) amino-

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Cosmetics (AREA)

Abstract

L'invention concerne l'utilisation d'acide polyaspartique ou de polyaspartates dans des produits de traitement capillaire, pour l'amélioration de la capacité de rétention de l'humidité dans les cheveux.
PCT/EP1999/006247 1998-08-31 1999-08-26 Utilisation d'acide polyaspartique dans des produits de traitement capillaire Ceased WO2000012054A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU57407/99A AU5740799A (en) 1998-08-31 1999-08-26 Use of polyaspartic acid in hair-treatment preparations

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19839569.8 1998-08-31
DE1998139569 DE19839569A1 (de) 1998-08-31 1998-08-31 Verwendung von Polyasparaginsäure in Haarbehandlungsmitteln

Publications (1)

Publication Number Publication Date
WO2000012054A1 true WO2000012054A1 (fr) 2000-03-09

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PCT/EP1999/006247 Ceased WO2000012054A1 (fr) 1998-08-31 1999-08-26 Utilisation d'acide polyaspartique dans des produits de traitement capillaire

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AU (1) AU5740799A (fr)
DE (1) DE19839569A1 (fr)
WO (1) WO2000012054A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2025113900A1 (fr) * 2023-11-27 2025-06-05 Henkel Ag & Co. Kgaa (sels d')acide polyaspartique dans des produits cosmétiques pour le traitement capillaire

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Publication number Priority date Publication date Assignee Title
US6426064B1 (en) * 2000-01-05 2002-07-30 Richard F. Stockel Hair treatment compositions
DE10127004B4 (de) 2001-06-01 2005-08-18 Clariant Gmbh Die Verwendung elektrochemisch inhibierter Wasser/Glykolgemische als Enteisungsmittel und Vereisungsschutzmittel

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06157237A (ja) * 1992-11-20 1994-06-03 Ajinomoto Co Inc 保湿剤及びそれを含有する化粧料、皮膚外用剤
JPH07277916A (ja) * 1994-04-08 1995-10-24 Ajinomoto Co Inc 化粧料
JPH0920614A (ja) * 1995-06-30 1997-01-21 Ajinomoto Co Inc ゲル状化粧料
EP0774247A2 (fr) * 1995-11-15 1997-05-21 Ajinomoto Co., Inc. Produits pour le soin des cheveux
EP0821932A1 (fr) * 1996-08-02 1998-02-04 Basf Aktiengesellschaft Dérivés de l'acide polyaspartique, solubles ou dispersibles dans l'eau, leur préparation et leur utilisation
EP0928608A2 (fr) * 1997-12-25 1999-07-14 Ajinomoto Co., Inc. Composition cosmétique

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0841445A (ja) * 1994-07-29 1996-02-13 Mitsui Toatsu Chem Inc 帯電防止剤及びそれを含有する化粧料
DE19631380A1 (de) * 1996-08-02 1998-02-05 Basf Ag Wasserlösliche oder wasserdispergierbare Polyasparaginsäure-Derivate, ihre Herstellung und ihre Verwendung
JPH10101926A (ja) * 1996-09-30 1998-04-21 Mitsubishi Chem Corp ヘヤーセッティング剤組成物

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06157237A (ja) * 1992-11-20 1994-06-03 Ajinomoto Co Inc 保湿剤及びそれを含有する化粧料、皮膚外用剤
JPH07277916A (ja) * 1994-04-08 1995-10-24 Ajinomoto Co Inc 化粧料
JPH0920614A (ja) * 1995-06-30 1997-01-21 Ajinomoto Co Inc ゲル状化粧料
EP0774247A2 (fr) * 1995-11-15 1997-05-21 Ajinomoto Co., Inc. Produits pour le soin des cheveux
EP0821932A1 (fr) * 1996-08-02 1998-02-04 Basf Aktiengesellschaft Dérivés de l'acide polyaspartique, solubles ou dispersibles dans l'eau, leur préparation et leur utilisation
EP0928608A2 (fr) * 1997-12-25 1999-07-14 Ajinomoto Co., Inc. Composition cosmétique

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
PATENT ABSTRACTS OF JAPAN vol. 018, no. 482 (C - 1247) 8 September 1994 (1994-09-08) *
PATENT ABSTRACTS OF JAPAN vol. 1996, no. 02 29 February 1996 (1996-02-29) *
PATENT ABSTRACTS OF JAPAN vol. 1997, no. 05 30 May 1997 (1997-05-30) *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2025113900A1 (fr) * 2023-11-27 2025-06-05 Henkel Ag & Co. Kgaa (sels d')acide polyaspartique dans des produits cosmétiques pour le traitement capillaire

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