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WO2000000540A1 - Stabilisant contenant de la vitamine pour materiau polymere organique - Google Patents

Stabilisant contenant de la vitamine pour materiau polymere organique Download PDF

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Publication number
WO2000000540A1
WO2000000540A1 PCT/JP1998/005829 JP9805829W WO0000540A1 WO 2000000540 A1 WO2000000540 A1 WO 2000000540A1 JP 9805829 W JP9805829 W JP 9805829W WO 0000540 A1 WO0000540 A1 WO 0000540A1
Authority
WO
WIPO (PCT)
Prior art keywords
tert
organic polymer
butyl
polymer material
antioxidant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP1998/005829
Other languages
English (en)
Japanese (ja)
Inventor
Takeshi Inoue
Shoichi Horie
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
API Corp
Original Assignee
Yoshitomi Fine Chemicals Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to EP98945590A priority Critical patent/EP1024165B1/fr
Application filed by Yoshitomi Fine Chemicals Ltd filed Critical Yoshitomi Fine Chemicals Ltd
Priority to PCT/JP1999/001999 priority patent/WO1999054394A1/fr
Priority to JP2000544732A priority patent/JP3501124B2/ja
Publication of WO2000000540A1 publication Critical patent/WO2000000540A1/fr
Priority to JP2000099499A priority patent/JP2001049127A/ja
Priority to US09/549,495 priority patent/US6465548B1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/15—Heterocyclic compounds having oxygen in the ring
    • C08K5/151—Heterocyclic compounds having oxygen in the ring having one oxygen atom in the ring
    • C08K5/1545—Six-membered rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/13—Phenols; Phenolates

Definitions

  • Japanese Patent Application Publication No. 6-504457 discloses a radiation-resistant resin composition using a chroman compound containing vitamin E and a specific phosphorus compound and a polyhydroxy compound such as glycerol.
  • the compounding ratio of the specific phosphorous compound to the 6-hydroxychroman compound is described as 0.5 to 20, preferably 1 to 10, more preferably 1 to 5, and most preferably 4. In the examples, examples in which the compounding ratio is 1, 2, 4, and 9 are described.
  • the amount of the 6-hydroxychroman derivative is about 67% by weight to about 4.76% by weight, preferably about 6% by weight, based on the total amount of the 6-hydroxycycloman compound and the phosphorus-based antioxidant.
  • 50% by weight to about 9.52% by weight more preferably 50% by weight to 16.7% by weight, and most preferably 20% by weight. Examples of 3% by weight, 33.3% by weight, 20.0% by weight, and 10.0% by weight are described.
  • the content of the invention described in these publications is that "the chroman compound containing vitamin E is an excellent antioxidant or processing stabilizer even though the resin is colored, but it is used together with other antioxidants.”
  • the problem is solved by preventing the coloring or by using a chroman compound containing vitamin E in such a small amount that the coloring does not occur.
  • the organic polymer is a polyethylene resin, a polypropylene resin, a mixture or a compatible polymer of the polyethylene resin and the polypropylene resin, or a polyethylene.
  • Examples of the acryl-based resin include polyacrylate and polymethacrylate.
  • the phenolic antioxidant used in the present invention is represented by the following general formula (2)
  • R 7 represents an alkyl group having 1 to 4 carbon atoms
  • R 8 represents a hydrogen atom or a methyl group
  • R 9 represents a direct bond or an alkylene group having 1 to 4 carbon atoms.
  • an organic polymer material having more excellent stability By combining the stabilized synthetic resin composition of the present invention with an ultraviolet stabilizer or a light stabilizer, an organic polymer material having more excellent stability can be obtained.
  • ultraviolet absorbers and light stabilizers include salicylic acid compounds, benzofunone compounds, benzotriazole compounds, benzoate compounds, cyanoacrylate compounds, nickel compounds, and pyrididine compounds.
  • Salicylic acid-based compounds that can be used as an absorbent include phenylsalicylate,

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

L'invention concerne une composition de stabilisant pour matériaux polymères organiques, comprenant un composé représenté par la formule générale (1) (dans laquelle R?1, R2 et R3¿ sont identiques ou différents et représentent chacun hydrogène ou méthyle), un anti-oxydant phénolique, et un antioxydant à composé phosphoré, le composé représenté par la formule (1) étant présent en une quantité spécifique par rapport à la somme des trois ingrédients. L'utilisation de la composition de l'invention comme stabilisant pour matériau polymère organique, permet la production d'un matériau polymère organique stabilisé, présentant une excellente résistance à la chaleur et notamment une excellente stabilité au traitement.
PCT/JP1998/005829 1997-10-02 1998-12-21 Stabilisant contenant de la vitamine pour materiau polymere organique Ceased WO2000000540A1 (fr)

Priority Applications (5)

Application Number Priority Date Filing Date Title
EP98945590A EP1024165B1 (fr) 1997-10-02 1998-10-02 Composition stabilisante pour materiaux polymeres organiques contenant des composes 6-hydroxychroman et compositions de materiaux polymeres organiques correspondantes
PCT/JP1999/001999 WO1999054394A1 (fr) 1998-04-17 1999-04-14 Stabilisant et composition de materiau polymere organique
JP2000544732A JP3501124B2 (ja) 1998-04-17 1999-04-14 有機高分子材料用安定剤および有機高分子材料組成物
JP2000099499A JP2001049127A (ja) 1998-04-17 2000-03-31 有機高分子材料用安定剤および有機高分子材料組成物
US09/549,495 US6465548B1 (en) 1997-10-02 2000-04-14 Stabilizer for organic polymer material and organic polymer material composition

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP10/181174 1998-06-26
JP18117498 1998-06-26

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP1998/004462 Continuation-In-Part WO1999018154A1 (fr) 1997-10-02 1998-10-02 Composition stabilisante pour materiaux polymeres organiques contenant des composes 6-hydroxychroman et compositions de materiaux polymeres organiques correspondantes

Related Child Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP1999/001999 Continuation-In-Part WO1999054394A1 (fr) 1997-10-02 1999-04-14 Stabilisant et composition de materiau polymere organique

Publications (1)

Publication Number Publication Date
WO2000000540A1 true WO2000000540A1 (fr) 2000-01-06

Family

ID=16096188

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP1998/005829 Ceased WO2000000540A1 (fr) 1997-10-02 1998-12-21 Stabilisant contenant de la vitamine pour materiau polymere organique

Country Status (1)

Country Link
WO (1) WO2000000540A1 (fr)

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000109617A (ja) * 1998-10-02 2000-04-18 Sumitomo Chem Co Ltd 安定化ポリオレフィン系樹脂組成物
JP2000290503A (ja) * 1999-04-08 2000-10-17 Tosoh Corp ポリフェニレンスルフィド樹脂組成物
JP2001081250A (ja) * 1999-07-14 2001-03-27 Mitsui Chemicals Inc ポリオレフィン樹脂組成物
JP2002194141A (ja) * 2000-12-22 2002-07-10 Sumitomo Chem Co Ltd ブタジエン重合体成形品の製造法
JP2002201396A (ja) * 2001-01-09 2002-07-19 Riso Kagaku Corp 孔版印刷用エマルションインキ
US6756432B2 (en) 2000-12-22 2004-06-29 Sumitomo Chemical Company, Limited Polybutadiene composition
JP2005511879A (ja) * 2001-12-14 2005-04-28 ビーエーエスエフ アクチェンゲゼルシャフト 安定剤組成物
WO2009007265A1 (fr) * 2007-07-10 2009-01-15 Basf Se Compositions de stabilisateurs
WO2013088135A1 (fr) 2011-12-14 2013-06-20 Astrazeneca Ab Diagnostic de gabr-a2
JP2018053252A (ja) * 2012-06-13 2018-04-05 サイテク・テクノロジー・コーポレーシヨン 置換クロマン化合物を含む安定剤組成物および使用方法
WO2024160242A1 (fr) * 2023-02-03 2024-08-08 天津利安隆新材料股份有限公司 Composition d'agent antivieillissement, son utilisation et matériau polymère antivieillissement

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5420056A (en) * 1977-07-18 1979-02-15 Mitsui Petrochem Ind Ltd Thermoplastic polymer composition
JPS5455043A (en) * 1977-10-12 1979-05-01 Mitsui Petrochem Ind Ltd Polyolefin compound
JPS6286036A (ja) * 1985-10-12 1987-04-20 Sumitomo Chem Co Ltd ポリオレフイン組成物
JPH02225542A (ja) * 1988-08-16 1990-09-07 Chisso Corp 安定化されたポリオレフイン組成物

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5420056A (en) * 1977-07-18 1979-02-15 Mitsui Petrochem Ind Ltd Thermoplastic polymer composition
JPS5455043A (en) * 1977-10-12 1979-05-01 Mitsui Petrochem Ind Ltd Polyolefin compound
JPS6286036A (ja) * 1985-10-12 1987-04-20 Sumitomo Chem Co Ltd ポリオレフイン組成物
JPH02225542A (ja) * 1988-08-16 1990-09-07 Chisso Corp 安定化されたポリオレフイン組成物

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000109617A (ja) * 1998-10-02 2000-04-18 Sumitomo Chem Co Ltd 安定化ポリオレフィン系樹脂組成物
JP2000290503A (ja) * 1999-04-08 2000-10-17 Tosoh Corp ポリフェニレンスルフィド樹脂組成物
JP2001081250A (ja) * 1999-07-14 2001-03-27 Mitsui Chemicals Inc ポリオレフィン樹脂組成物
JP2002194141A (ja) * 2000-12-22 2002-07-10 Sumitomo Chem Co Ltd ブタジエン重合体成形品の製造法
US6756432B2 (en) 2000-12-22 2004-06-29 Sumitomo Chemical Company, Limited Polybutadiene composition
JP2002201396A (ja) * 2001-01-09 2002-07-19 Riso Kagaku Corp 孔版印刷用エマルションインキ
JP2005511879A (ja) * 2001-12-14 2005-04-28 ビーエーエスエフ アクチェンゲゼルシャフト 安定剤組成物
US7199181B2 (en) 2001-12-14 2007-04-03 Basf Aktiengesellschaft Stabilising composition II
WO2009007265A1 (fr) * 2007-07-10 2009-01-15 Basf Se Compositions de stabilisateurs
WO2013088135A1 (fr) 2011-12-14 2013-06-20 Astrazeneca Ab Diagnostic de gabr-a2
US20130197041A1 (en) * 2011-12-14 2013-08-01 Astrazeneca Ab Gabr-a2 diagnostic
US20150057317A1 (en) * 2011-12-14 2015-02-26 Astrazeneca Ab Gabr-a2 diagnostic
JP2018053252A (ja) * 2012-06-13 2018-04-05 サイテク・テクノロジー・コーポレーシヨン 置換クロマン化合物を含む安定剤組成物および使用方法
EP2864310B1 (fr) * 2012-06-13 2022-10-26 Cytec Technology Corp. Compositions stabilisatrices contenant des composés chromanne substitués et méthodes d'utilisation associées
WO2024160242A1 (fr) * 2023-02-03 2024-08-08 天津利安隆新材料股份有限公司 Composition d'agent antivieillissement, son utilisation et matériau polymère antivieillissement

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