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WO2000043137A1 - A process for transforming waste into building material and raw material of organic compositions fertiliser - Google Patents

A process for transforming waste into building material and raw material of organic compositions fertiliser Download PDF

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Publication number
WO2000043137A1
WO2000043137A1 PCT/CN2000/000015 CN0000015W WO0043137A1 WO 2000043137 A1 WO2000043137 A1 WO 2000043137A1 CN 0000015 W CN0000015 W CN 0000015W WO 0043137 A1 WO0043137 A1 WO 0043137A1
Authority
WO
WIPO (PCT)
Prior art keywords
waste
garbage
raw materials
organic compound
building material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/CN2000/000015
Other languages
French (fr)
Chinese (zh)
Inventor
Yongxin Huang
Yong Shi
Shi Qi
Fankun Kong
Jianguo GAN
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hubei Huizhong Holding Co Ltd
Original Assignee
Hubei Huizhong Holding Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hubei Huizhong Holding Co Ltd filed Critical Hubei Huizhong Holding Co Ltd
Priority to AU20912/00A priority Critical patent/AU2091200A/en
Publication of WO2000043137A1 publication Critical patent/WO2000043137A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05FORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F9/00Fertilisers from household or town refuse
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/04Waste materials; Refuse
    • C04B18/30Mixed waste; Waste of undefined composition
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A40/00Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
    • Y02A40/10Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
    • Y02A40/20Fertilizers of biological origin, e.g. guano or fertilizers made from animal corpses
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

Definitions

  • the invention relates to a technology for treating urban domestic garbage.
  • the first is the landfill method. It is to build a pit field several meters deep from the ground on a large area of land in the less populated area. The bottom of the pit field is paved with bentonite to form a thick impervious layer, and an appropriate number of pipes are set to collect the generated Landfill leachate and biogas. After the garbage arrives, the dump site is gradually piled up. When the site is filled, it is filled with earth and rock and compacted. All the garbage is eliminated.
  • the advantages of this method are: short construction period and large processing capacity. However, the unavoidable disadvantages are: 1.
  • the land occupation is large, and because the biogas and geothermal heat generated after the fermentation of the waste, and the large amount of plastic and glass contained in the waste are difficult to decompose, the land after the landfill cannot be used for hundreds of years. For greening and farming, it is not advisable to build houses on it because of poor foundation. 2. There is a hidden danger of groundwater pollution. Once the impervious layer is damaged, as in an earthquake, water pollution is inevitable. 3. The construction investment is large, but the life cycle is not long. For example, to build a landfill with a land area of 60 hectares, an investment of 120 million yuan is required. If the daily waste treatment capacity is 2,000 tons, it can only be used for 11 years. After the expiry, land will be reoccupied and new landfills invested.
  • the garbage is open for a long time before landfilling. During this period, after fermentation and decay, the garbage breeds mosquitoes, flies and rodents, generates harmful gases and organic waste liquids, spreads diseases, and pollutes the air.
  • the second is a classification method. It sorts garbage according to food residues and paper, rubber and plastic chemical fiber waste, glass ceramic mortar, metal, etc., and then uses related processes and equipment to make usable recycled products. For example, food residues and paper are used as compost or organic compound fertilizers, rubber plastic fibers are used to make plastics, glass ceramic lime is used as construction supplies, and metal is recycled into smelting and rolling materials. Adopting this method requires detailed classification of waste, and the pre-processing workload is very large. In fact, it is a sorting process plus multiple specialized factories. In order to reduce the sorting difficulty and workload, it is required to sort the garbage when dumping it. This involves non-technical factors such as social management level and public quality. Since this method can only process the sortable ingredients, there is still no less than 40
  • the third is incineration. It is a relatively advanced and mature method of garbage disposal in the world today. After the garbage is concentrated and dried, it is sent to a special combustion furnace, and a certain proportion of fuel (such as fuel oil) is mixed in the furnace and entered into the combustion chamber for combustion. The heat generated during combustion can be used for heating and power generation, and the slag produced can be used as raw materials for building materials such as hollow bricks and concrete after being crushed.
  • the combustion furnace is a very large-scale equipment, including a large-scale conveying mechanism, a drying mechanism, a mixing chamber, a combustion chamber, an air induction system, a slag discharge system, a circulating water system, a heating system, and a power generation system.
  • the advantages of this method are: 1.
  • the object of the present invention is to provide a method capable of completely treating garbage into building material raw materials and organic compound fertilizer raw materials, so that the treatment of garbage does not need to be sorted, is non-toxic, has a large processing volume and is inexpensive.
  • the method for achieving the above objective includes providing waste to be treated less than the volume of the entire brick, placing such waste in a closed device, maintaining it at a temperature of 120-220'C and 3-15 atmospheric pressure for 1-5 hours, and then decompressing To the atmospheric pressure of 0.5-4, the garbage in the airtight device is ejected outward, and the materials that can be made into building materials and organic compound fertilizers that are naturally classified after being ejected are dried, magnetically separated, crushed, and collected.
  • the volume of waste to be treated is provided less than the volume of the entire brick.
  • a vibrating screen and a pulverizer can be provided on the conveyor belt leading to the closed device.
  • a better way is to set the conveyor belt into two layers, and the upper conveyor belt At the end, it is connected to the vibrating screen that is perpendicular to it and tilts downward.
  • the lower end of the vibrating screen is connected to the inlet of the grinder.
  • the outlet of the grinder comes back and connects to the upper conveyor belt.
  • the lower conveyor belt is placed under the vibrating screen at the front end, and the end is closed
  • the inlet of the device is a sieving and crushing circulation mechanism to ensure that the waste to be treated can be continuously provided with a volume smaller than the entire brick volume. If there are no large pieces in the rubbish, they can be sent directly to the closed device.
  • the required temperature and pressure in the closed device can be provided by the boiler feeding high-pressure steam, and the pressure can be controlled by conventional methods.
  • the ingredients that can be used to make organic compound fertilizer in garbage are organic matter such as food residues and paper, In order to separate them and sterilize and deodorize the whole garbage, measures are taken to keep the pressure of the garbage in a closed device for a period of time.
  • the closed device can use a high-pressure pyrolysis kettle. To achieve the effect, the pressure in the kettle The temperature and holding time are better: temperature 120 ⁇ 220 ° C, atmospheric pressure 3 ⁇ 15, time 1.5 ⁇ 5 hours, and even better: temperature 150 ⁇ 210'C, atmospheric pressure 3 ⁇ 10, Time is 2 ⁇ 5 hours.
  • the pressure difference between the inside and the outside of the device should be maintained until the garbage is completely discharged.
  • both types of garbage should eventually be dried at a humidity of 10% to 20%. Drying can be done with electric heat, infrared and hot air. The better way is to use hot air. If the duct of the hot air drying furnace is led to the boiler flue and a heat exchanger is installed on it, the waste heat of the boiler can also be used.
  • Magnetic sorting can be performed on a magnetically-conveying conveyor.
  • the conveyor belt is made closed, and it is continuously rotated around the center, so that the lower section is not magnetically permeable, and the other sections are magnetically permeable.
  • the garbage enters the upper conveyor belt, the iron pieces are sucked. After the garbage reaches the end and falls, the remaining iron pieces enter the lower magnetic section with the conveyor belt, and the iron pieces are sorted out.
  • Garbage that becomes organic compound fertilizer raw materials is pulverized by a soft and hard material pulverizer to a particle size of more than 100 mesh to become organic compound fertilizer raw materials.
  • a small amount of waste that does not contain nutrients, such as plastic and chemical fiber, contained in the organic fertilizer raw materials can only be smashed after being crushed, and can be classified as raw materials for building materials after screening.
  • the main equipments airtight devices, boilers, drying devices, and hard and soft material grinders can be combined according to different specifications or quantities to form production lines of different scales.
  • 5 8m 3 high-pressure pyrolysis kettles, 4 2 ton boilers, 5 20 kg / min hot-air drying furnaces, and 3 25 kg / min soft and hard material pulverizers can be combined to form 100 tons of waste per day.
  • Production line Combining 10 10m 3 high-pressure pyrolysis kettles, 4 4-ton boilers, 4 60kg / min hot-air drying furnaces, 10 25kg / min soft and hard material crushers, etc., it can form 300 tons of waste per day.
  • the method of the present invention only has low volume requirements for garbage, and does not need to be sorted, and only ordinary equipment is used in the process of disposal, which makes the disposal of garbage much simpler, and sets up production and operation. Both are low-cost and very suitable for countries and regions with complex waste components.
  • the long chains of organic molecules such as animals and plants in the garbage that can be used as raw materials for organic compound fertilizers are decomposed into short chains to cause melting, dehydration, and refinement, so that they are compatible with volume, weight, and morphology.
  • Other garbage components form a large disparity, so that a distinct distribution trend after the ejection is bred. It is obtained that more than 80% of the first 15 meters are organic, and more than 90% of the latter 50 meters are almost fan-shaped.
  • the distribution problem solves the classification problem more easily and accurately, and the two types of garbage (except for the rejected metal) can all be made into building material raw materials and organic compound fertilizer raw materials. Therefore, the method of the present invention has almost a 100% resource recovery rate.
  • the equipment can be combined with multiple configurations, the amount of garbage disposal is large. After the amount of municipal waste rises, adjusting the specifications or quantities of some of the equipment involved in the method can meet a larger amount of waste disposal.
  • Fig. 1 is a schematic diagram of a device according to the present invention.
  • Fig. 2 is a block diagram of a process equipment arrangement according to the present invention.
  • 1 is a sieving and crushing circulation mechanism
  • 2 is a boiler (2 tons)
  • 3 is a high-pressure pyrolysis kettle (2.5m 3 )
  • 4 is a blanking yard
  • 5 is a hot air drying furnace (JBS—LG— RFL).
  • 6 is a magnetic sorting mechanism
  • 7 is a hard and soft material pulverizer (LFH-660)
  • 8 is a powder suction machine
  • 9 is an air compressor
  • 10 is a heat exchanger
  • 11 is a impurity removing screen.
  • dump 20 carts of garbage with a garbage truck for a total of 1 ton. Since there are no large pieces, no screening and coarse crushing are required. They are sent directly to the high-pressure pyrolysis kettle through the elevator. 13:30 After loading, seal the inlet and outlet.
  • the control mechanism is activated, the ejection opening is opened, and the waste in the kettle under the pressure in the kettle forms a fan-shaped distribution area with a length of 80 meters and a width of 15 meters.
  • a fan-shaped range of 18 meters from the ejection opening Medium is basically a finely divided machine that can be used as raw material for organic compound fertilizers, and the rest is other components in the garbage.
  • the humidity is 10% -15%.
  • the metal is removed through a magnetic separator and sent to a soft and hard material pulverizer. According to the requirements of the organic compound fertilizer raw materials, the class is pulverized to 120 meshes; 80-120 mesh.
  • the total weight of the processed waste is 1 ton. After the high-pressure pyrolysis jet, the total volume of the waste is reduced by 68%. After drying, the weight of the waste is 620 kg, which is a total reduction of 32%. Among them, about 420 kg of waste is used as building materials. About 190 kg of garbage is used as raw material for organic compound fertilizer.

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Ceramic Engineering (AREA)
  • Organic Chemistry (AREA)
  • Civil Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Processing Of Solid Wastes (AREA)
  • Fertilizers (AREA)

Abstract

The invention relates to a process for transforming waste into building material and raw materials of organic composition fertiliser, including following steps: 1) the waste is successively fed into a hermetic vessel, heated to 120-220 °C, pressurized to 3-15 atmospheric pressure, and kept for 1-5 hours in this condition, so that the waste is decompounded, sterilized, deodorised and reduced in volume; 2) the waste having been treated in the first step is depressurized and sprayed out, and is separated into two parts to be used for building material and raw materials of organic composition fertiliser; 3) the said two parts are separately dried out, magnetically separated, crushed up, and collected.

Description

将垃圾处理成建材原料及有机复合肥原料的方法  Method for processing garbage into building material raw material and organic compound fertilizer raw material method

■ fe 舰 ■ fe ship

本发明涉及城市生活垃圾的处理技术。  The invention relates to a technology for treating urban domestic garbage.

现有技术 current technology

当前, 对城市垃圾的技术处理, 概括起来有下列几种方法, 分述如下: 第一种是填埋法。 它是在少人区的一块大面积的土地上, 建一个离地面数米 深的坑场, 坑场底部用膨润土铺成厚厚的防渗层, 其中设置适当数量的管道, 以收 集所产生的垃圾渗沥液和沼气。 垃圾运来后, 倾卸坑场内, 逐渐堆积, 当坑场填满 后, 用土石填埋压实。 其中垃圾即全部被消除。 这种方法的优点是: 建设周期短, 处理量大。 但无法避免的缺点是, 1 . 土地占用多, 并且由于垃圾发酵后产生沼气 和地热, 以及垃圾中含有的较大量的塑料和玻璃难于分解, 填埋后的土地, 在上百 年的时间内无法进行绿化和耕种, 因地基差, 也不宜在其上建造房层。 2. 存在地 下水污染的隐患, 一但防渗层被破坏一如出现地震, 水质污染在所难免。 3. 建设 投资大, 而使用周期却不长。 例如建一占地 60公倾的填埋场, 需投资 1亿 2千万 元, 若每日垃圾处理量为 2千吨, 只能使用 11 年。 到期后需要重新占用土地和投 资建设新的填埋场。 这势必导致垃圾处理进入不断破坏土地资源, 不断投资的亚性 循环。 4. 填埋前垃圾长时间处于开放状态, 在此期间, 垃圾在发酵、 腐烂后, 滋 生蚊蝇鼠类, 产生有害气体和有机废液, 传播疾病, 污染空气。  At present, there are several methods for the technical treatment of municipal waste, which are summarized as follows: The first is the landfill method. It is to build a pit field several meters deep from the ground on a large area of land in the less populated area. The bottom of the pit field is paved with bentonite to form a thick impervious layer, and an appropriate number of pipes are set to collect the generated Landfill leachate and biogas. After the garbage arrives, the dump site is gradually piled up. When the site is filled, it is filled with earth and rock and compacted. All the garbage is eliminated. The advantages of this method are: short construction period and large processing capacity. However, the unavoidable disadvantages are: 1. The land occupation is large, and because the biogas and geothermal heat generated after the fermentation of the waste, and the large amount of plastic and glass contained in the waste are difficult to decompose, the land after the landfill cannot be used for hundreds of years. For greening and farming, it is not advisable to build houses on it because of poor foundation. 2. There is a hidden danger of groundwater pollution. Once the impervious layer is damaged, as in an earthquake, water pollution is inevitable. 3. The construction investment is large, but the life cycle is not long. For example, to build a landfill with a land area of 60 hectares, an investment of 120 million yuan is required. If the daily waste treatment capacity is 2,000 tons, it can only be used for 11 years. After the expiry, land will be reoccupied and new landfills invested. This will inevitably lead to a sub-cycle of continuous land destruction and continuous investment. 4. The garbage is open for a long time before landfilling. During this period, after fermentation and decay, the garbage breeds mosquitoes, flies and rodents, generates harmful gases and organic waste liquids, spreads diseases, and pollutes the air.

第二种是分类处理法。 它是先将垃圾按例如食物残渣及纸类、 橡塑化纤废弃 物、 玻璃陶瓷灰土、 金属等类进行分拣, 然后分别采用相关工艺及其设备制成可利 用的再生制品。 如食物残渣及纸做堆肥或有机复合肥, 橡塑化纤类做成塑胶, 玻璃 陶瓷灰土做建筑用品, 金属回炉冶炼轧制成材料等。 采用这种方法要求将垃圾详细 分类, 前处理工作量很大, 实际上是分拣工序加上多个专业工厂。 为了减少分拣难 度和工作量, 在倒垃圾时就要求将垃圾分类, 这做起来涉及到社会管理水平及公众 素质等非技术因素。 由于此种方法只能对可分拣的成份进行处理, 还有不少于 40 The second is a classification method. It sorts garbage according to food residues and paper, rubber and plastic chemical fiber waste, glass ceramic mortar, metal, etc., and then uses related processes and equipment to make usable recycled products. For example, food residues and paper are used as compost or organic compound fertilizers, rubber plastic fibers are used to make plastics, glass ceramic lime is used as construction supplies, and metal is recycled into smelting and rolling materials. Adopting this method requires detailed classification of waste, and the pre-processing workload is very large. In fact, it is a sorting process plus multiple specialized factories. In order to reduce the sorting difficulty and workload, it is required to sort the garbage when dumping it. This involves non-technical factors such as social management level and public quality. Since this method can only process the sortable ingredients, there is still no less than 40

%的剩余物最终只能采取填埋。 这种处理方法, 虽然在很大程度上避免了填埋法的 弊端, 且能回收部分资源, 但对垃圾分拣程度和能达到的分拣量要求高, 在垃圾成 分复杂的国家和地区, 这一点却不易做到。 这一点做不好, 不仅运行成本高, 垃圾 % Of the residue can only be taken to landfill in the end. Although this treatment method largely avoids the disadvantages of the landfill method and can recover some resources, it requires high levels of waste sorting and the amount of sorts that can be achieved. In countries and regions with complex waste components, This is not easy. This can not be done well, not only the high running cost, but also the garbage

1 1

确 认 本 处理量也小。 另外, 分拣工序劳动环境恶劣, 工人须戴卫生防护面具。 Confirm this The throughput is also small. In addition, the sorting process has a harsh working environment, and workers must wear sanitary protective masks.

第三种是焚烧法。 它是当今国际上比较先进且较成熟的处理垃圾方法。 它是 将垃圾集中、 干燥后, 送入一特制燃烧炉, 在炉中混配一定比例的燃料 (如燃油), 进入燃烧室燃烧。 燃烧时产生的热可用于供热、 发电, 产生的炉渣经粉碎后可作为 生产空心砖、混凝土等建材原料。所述燃烧炉是一特大型设备, 包括大型传送机构、 干燥机构、 混配室、 燃烧室、 引风系统、 排渣系统、 循环水系统、 供热系统、 发电 系统。 此方法的优点是: 1 . 垃圾勿需分拣; 2. 做到无剩余处理, 且处理周期短; 3. 资源回收率高; 4. 占地少。 但由于焚烧炉结构复杂庞大, 大大超过同等规模发 电厂的建设, 因而投资巨大。 例如建一个日处理 400吨垃圾的焚烧炉, 需要投资 2 亿元以上。 除此之外, 实施此方法还需消耗大量的燃料。 另一方面, 由于高温燃烧, 垃圾中的化学物质特别是高分子化合物发生裂解, 不断向空中释放有毒物质, 如二 哦等致癌物质, 这使人类健康受到极大威胁, 现已引起严重关注。  The third is incineration. It is a relatively advanced and mature method of garbage disposal in the world today. After the garbage is concentrated and dried, it is sent to a special combustion furnace, and a certain proportion of fuel (such as fuel oil) is mixed in the furnace and entered into the combustion chamber for combustion. The heat generated during combustion can be used for heating and power generation, and the slag produced can be used as raw materials for building materials such as hollow bricks and concrete after being crushed. The combustion furnace is a very large-scale equipment, including a large-scale conveying mechanism, a drying mechanism, a mixing chamber, a combustion chamber, an air induction system, a slag discharge system, a circulating water system, a heating system, and a power generation system. The advantages of this method are: 1. No need to sort garbage; 2. No residual treatment, and short processing cycle; 3. High resource recovery rate; 4. Less land occupation. However, because the structure of the incinerator is complex and huge, it greatly exceeds the construction of power plants of the same size, so the investment is huge. For example, the construction of an incinerator that can handle 400 tons of garbage per day requires investment of more than 200 million yuan. In addition, a large amount of fuel is required to implement this method. On the other hand, due to high-temperature combustion, chemical substances, especially polymer compounds, in the garbage are cracked, and toxic substances, such as carcinogens, are continuously released into the air. This poses a great threat to human health and has caused serious concern.

发明目的 Object of the invention

本发明的目的, 在于提供一种能将垃圾全部处理成建材原料和有机复合肥原 料的方法, 并使垃圾的处理不需分拣, 无毒害, 处理量大又耗资低廉。  The object of the present invention is to provide a method capable of completely treating garbage into building material raw materials and organic compound fertilizer raw materials, so that the treatment of garbage does not need to be sorted, is non-toxic, has a large processing volume and is inexpensive.

本发明的内容 Content of the invention

实现上述目的方法, 包括提供小于整砖体积的待处理垃圾, 将这样的垃圾置 于密闭装置中, 在 120~220'C温度和 3~15个大气压力下保持 1一 5小时, 然后减压 至 0.5— 4 大气压力将密闭装置内的垃圾向外喷出, 对喷出后自然形成分类的可制 作建材原料类物和可制作有机复合肥类物分别进行干燥、 磁分、 粉碎、 收集。  The method for achieving the above objective includes providing waste to be treated less than the volume of the entire brick, placing such waste in a closed device, maintaining it at a temperature of 120-220'C and 3-15 atmospheric pressure for 1-5 hours, and then decompressing To the atmospheric pressure of 0.5-4, the garbage in the airtight device is ejected outward, and the materials that can be made into building materials and organic compound fertilizers that are naturally classified after being ejected are dried, magnetically separated, crushed, and collected.

根据本发明的方法, 提供小于整砖体积的待处理垃圾, 可通过在通往密闭装 置的传送带上设置振动筛和粉碎机的办法, 较好的方式是采用将传送带设置成两 层, 上层传送带于末端与垂直于它并倾斜向下的振动筛相连, 振动筛低端连接粉碎 机进口, 粉碎机出口又回过来与上层传送带相连, 下层传送带于前端置于振动筛之 下, 而末端接近密闭装置的进口这样一种筛分粉碎循环机构, 以保证能连续地提供 小于整砖体积的待处理垃圾。 如果垃圾中无大块, 即可直接送进密闭装置。  According to the method of the present invention, the volume of waste to be treated is provided less than the volume of the entire brick. A vibrating screen and a pulverizer can be provided on the conveyor belt leading to the closed device. A better way is to set the conveyor belt into two layers, and the upper conveyor belt At the end, it is connected to the vibrating screen that is perpendicular to it and tilts downward. The lower end of the vibrating screen is connected to the inlet of the grinder. The outlet of the grinder comes back and connects to the upper conveyor belt. The lower conveyor belt is placed under the vibrating screen at the front end, and the end is closed The inlet of the device is a sieving and crushing circulation mechanism to ensure that the waste to be treated can be continuously provided with a volume smaller than the entire brick volume. If there are no large pieces in the rubbish, they can be sent directly to the closed device.

密闭装置内所需的温度和压力, 可通过锅炉送入高压蒸气来提供, 压力的控 制应用常规方法即可。  The required temperature and pressure in the closed device can be provided by the boiler feeding high-pressure steam, and the pressure can be controlled by conventional methods.

垃圾中能制作有机复合肥原料的成分为食物残渣、 纸等动植物一类有机物, 为了能将它们分离出来, 并对整体垃圾进行灭菌除臭, 采取对密闭装置内的垃圾保 温保压一段时间的措施, 所述密闭装置可采用高压热解釜, 为取得效果, 釜内压力、 温度及保持时间较好的是: 温度 120~220°C, 大气压力 3~15个, 时间 1.5~5小时, 而更好的是: 温度 150~210'C, 大气压力 3~10个, 时间 2~5小时。 The ingredients that can be used to make organic compound fertilizer in garbage are organic matter such as food residues and paper, In order to separate them and sterilize and deodorize the whole garbage, measures are taken to keep the pressure of the garbage in a closed device for a period of time. The closed device can use a high-pressure pyrolysis kettle. To achieve the effect, the pressure in the kettle The temperature and holding time are better: temperature 120 ~ 220 ° C, atmospheric pressure 3 ~ 15, time 1.5 ~ 5 hours, and even better: temperature 150 ~ 210'C, atmospheric pressure 3 ~ 10, Time is 2 ~ 5 hours.

盛接从密闭装置喷出的垃圾, 应有一个不小于 800m2的落料场。 为使密闭装 置内的垃圾全部喷出, 应保持该装置内外压差至垃圾全部喷出。 There should be a dumping area for receiving garbage ejected from the closed device with a size of not less than 800m 2 . In order to completely discharge the garbage in the closed device, the pressure difference between the inside and the outside of the device should be maintained until the garbage is completely discharged.

由于垃圾从密闭装置喷出时带有水份, 而最终要处理为细粒, 为便于粉碎, 两类垃圾烘干最终都应达到 10%~20%的湿度。 烘干可用电热, 红外及热风干燥, 较好的方式是采用热风烘干。 若将热风干燥炉的风管引至锅炉烟道并在其上装置热 交换器, 还可利用锅炉的余热。  Because the garbage is sprayed from the closed device with moisture, and it is finally processed into fine particles, in order to facilitate crushing, both types of garbage should eventually be dried at a humidity of 10% to 20%. Drying can be done with electric heat, infrared and hot air. The better way is to use hot air. If the duct of the hot air drying furnace is led to the boiler flue and a heat exchanger is installed on it, the waste heat of the boiler can also be used.

磁分选可在一段通磁的传送带上进行。 比如将传送带做成闭合的, 并不停地 绕心旋转, 将下层的一段不通磁, 而其它部分通磁。垃圾进入处于上层的传送带时, 其中铁件被吸住, 垃圾走到尽头落下后, 剩下的铁件随传送带进入下层无磁段, 铁 件即被分选出来。  Magnetic sorting can be performed on a magnetically-conveying conveyor. For example, the conveyor belt is made closed, and it is continuously rotated around the center, so that the lower section is not magnetically permeable, and the other sections are magnetically permeable. When the garbage enters the upper conveyor belt, the iron pieces are sucked. After the garbage reaches the end and falls, the remaining iron pieces enter the lower magnetic section with the conveyor belt, and the iron pieces are sorted out.

被烘干后又经过磁分选的垃圾, 软硬物皆有, 如作为建材原料类物中的陶瓷、 尘土、 木块、 橡塑物、 建筑垃圾、 玻璃等, 作为有机复合肥原料类物中的纸类、 菜 类、 肉皮、 骨头等, 所以用于粉碎的设备是软硬物粉碎机。 对己分出的将制作成建 材原料一类的拉圾,按所制建材的需要, 调整软硬物粉碎机内装置,粉碎成 80— 200 目粒度, 即成为各类建材原料; 对将制作成有机复合肥原料一类的垃圾, 经过软硬 物粉碎机粉碎成 100目以上粒度, 成为有机复合肥原料。 夹杂在有机肥原料中的少 数不含营养成份塑料、 化纤等垃圾经粉碎只能成为细条状, 可在随后的筛选中筛出 后归入建材原料。  After being dried and magnetically sorted, there are both hard and soft objects, such as ceramics, dust, wood blocks, rubber and plastics, construction waste, glass, etc. as raw materials for building materials, and organic compound fertilizer raw materials. Paper, vegetables, skins, bones, etc., so the equipment used for pulverization is a soft and hard pulverizer. Regarding the garbage that has been separated and will be made into building materials, adjust the internal and external devices of the hard and soft material pulverizer according to the needs of the building materials, and pulverize it into 80-200 mesh size, which will become all kinds of building materials. Garbage that becomes organic compound fertilizer raw materials is pulverized by a soft and hard material pulverizer to a particle size of more than 100 mesh to become organic compound fertilizer raw materials. A small amount of waste that does not contain nutrients, such as plastic and chemical fiber, contained in the organic fertilizer raw materials can only be smashed after being crushed, and can be classified as raw materials for building materials after screening.

为了形成大规模处理垃圾的能力, 可以将主要设备: 密闭装置、 锅炉、 干燥 装置、 软硬物粉碎机等按不同规格或数量进行配比组合, 形成不同规模的生产线。 如将 8m3高压热解釜 5个, 2吨锅炉 4个, 20kg / min热风干燥炉 5座, 25kg / min 软硬物粉碎机 3台等配比组合, 就可形成日处理 100吨垃圾的生产线; 将 10m3高 压热解釜 10个, 4吨锅炉 4个, 60kg / min热风干燥炉 4座, 25kg / min软硬物粉 碎机 10台等配比组合, 就可形成日处理 300吨垃圾的生产线;。 In order to form a large-scale garbage processing capability, the main equipments: airtight devices, boilers, drying devices, and hard and soft material grinders can be combined according to different specifications or quantities to form production lines of different scales. For example, 5 8m 3 high-pressure pyrolysis kettles, 4 2 ton boilers, 5 20 kg / min hot-air drying furnaces, and 3 25 kg / min soft and hard material pulverizers can be combined to form 100 tons of waste per day. Production line: Combining 10 10m 3 high-pressure pyrolysis kettles, 4 4-ton boilers, 4 60kg / min hot-air drying furnaces, 10 25kg / min soft and hard material crushers, etc., it can form 300 tons of waste per day. Production line;

积极效果 从上述说明可以看出, 本发明的方法只对垃圾有低的体积要求, 不需进行分 拣, 而且处理过程中只需使用普通设备, 这使垃圾的处理大为简单, 而且设产和运 行都耗费低廉, 十分适用于垃圾成份复杂的国家和地区。 Positive effect It can be seen from the above description that the method of the present invention only has low volume requirements for garbage, and does not need to be sorted, and only ordinary equipment is used in the process of disposal, which makes the disposal of garbage much simpler, and sets up production and operation. Both are low-cost and very suitable for countries and regions with complex waste components.

由于该方法使垃圾在密闭状态下经过了高于对人体、 动物、 农作物有害生物 耐受温度的高温 (120— 220'C ), 因而无论在处理过程中还是处理后成为产品的细 粒都是无菌、清洁的 (参照附件: 122种对人体、动物、农作物有害生物耐受温度表); 另一方面, 由于温度不超过 220Ό , 垃圾中的高分子化合物 (如烯、 烃类等) 不能 发生裂解, 因而不会有有毒物质 (如二哦) 释放出来污染大气。  Because this method allows the rubbish to pass the high temperature (120-220'C) higher than the tolerable temperature for human, animal, and crop pests in a closed state, the fine particles that become the product during or after the treatment are all Sterile and clean (refer to the attached table: 122 types of temperature tolerance table for human, animal, and crop pests); On the other hand, because the temperature does not exceed 220Ό, high-molecular compounds (such as olefins, hydrocarbons, etc.) in the garbage cannot Cracking occurs, so no toxic substances (such as two) are released to pollute the atmosphere.

由于该方法中适当的温度和压力, 垃圾中能作为有机复合肥原料的动植物一 类有机物分子长链分解成短链以致熔缩、 脱水、 细化, 使之在体积、 重量、 形态方 面与其它垃圾成份形成较大的悬殊, 从而孕育出喷出后显然不同的分布趋势, 得到 前 15米左右 80%以上为所述有机类, 后至 50米左右 90%以上为其它成份的近乎 扇形的分布, 较轻易和较准确的解决了分类问题, 而分出的两类垃圾 (除剔出的金 属外) 又分别全部可制作成建材原料和有机复合肥原料。 因而本发明的方法几乎具 有 100%的资源回收率。  Due to the proper temperature and pressure in this method, the long chains of organic molecules such as animals and plants in the garbage that can be used as raw materials for organic compound fertilizers are decomposed into short chains to cause melting, dehydration, and refinement, so that they are compatible with volume, weight, and morphology. Other garbage components form a large disparity, so that a distinct distribution trend after the ejection is bred. It is obtained that more than 80% of the first 15 meters are organic, and more than 90% of the latter 50 meters are almost fan-shaped. The distribution problem solves the classification problem more easily and accurately, and the two types of garbage (except for the rejected metal) can all be made into building material raw materials and organic compound fertilizer raw materials. Therefore, the method of the present invention has almost a 100% resource recovery rate.

由于设备可进行多台配置组合, 使垃圾处理量大。 在城市垃圾量上升后, 调 整该方法中涉及的某些设备的规格或数量, 即可满足更大量的垃圾处理。  Because the equipment can be combined with multiple configurations, the amount of garbage disposal is large. After the amount of municipal waste rises, adjusting the specifications or quantities of some of the equipment involved in the method can meet a larger amount of waste disposal.

附图说明 BRIEF DESCRIPTION OF THE DRAWINGS

图 1是根据本发明的设备示意图。  Fig. 1 is a schematic diagram of a device according to the present invention.

图 2是根据本发明的工艺设备布置方框图。  Fig. 2 is a block diagram of a process equipment arrangement according to the present invention.

实施例 Examples

98年 10月 20 日, 按本发明的方法在所组成的小型生产线上进行了小批量生 产。  On October 20, 1998, small batch production was carried out on the small production line formed according to the method of the present invention.

图 1中, 1为筛分粉碎循环机构, 2为锅炉 (2吨), 3为高压热解釜 (2.5m3), 4 为落料场, 5 为热风干燥炉 (JBS— LG— RFL), 6为磁分选机构, 7为软硬物粉 碎机 (LFH— 660), 8为吸粉机, 9为空压机, 10为热交换器, 11为除杂筛。 In Figure 1, 1 is a sieving and crushing circulation mechanism, 2 is a boiler (2 tons), 3 is a high-pressure pyrolysis kettle (2.5m 3 ), 4 is a blanking yard, and 5 is a hot air drying furnace (JBS—LG— RFL). , 6 is a magnetic sorting mechanism, 7 is a hard and soft material pulverizer (LFH-660), 8 is a powder suction machine, 9 is an air compressor, 10 is a heat exchanger, and 11 is a impurity removing screen.

过程:  Process:

13:00 用垃圾车倾倒 20车垃圾, 共 1 吨, 因无大块, 勿需筛分和粗粉碎, 直接经提升机送入高压热解釜。 13:30 装料完毕, 密封进出料口。 At 13:00, dump 20 carts of garbage with a garbage truck for a total of 1 ton. Since there are no large pieces, no screening and coarse crushing are required. They are sent directly to the high-pressure pyrolysis kettle through the elevator. 13:30 After loading, seal the inlet and outlet.

13:35 开进气阀, 升压升温。  13:35 Open the intake valve, boost the temperature.

13:54 压力升至 12个大气压, 温度升至 210°C。  13:54 The pressure rose to 12 atmospheres and the temperature rose to 210 ° C.

13:54-15:40 釜内垃圾在上述压力和温度下热解。  13: 54-15: 40 The waste in the kettle is pyrolyzed at the above pressure and temperature.

15:40 开减压阀  15:40 Open pressure reducing valve

15:45 釜内压力减至 4个大气压。  15:45 The pressure in the kettle was reduced to 4 atmospheres.

15:45-15:56 开动控制机构, 喷射口开放, 釜内垃圾在釜内压力下, 向外形 成长 80米, 宽 15米的扇形分布区, 经鉴别, 从喷射口起 18米的扇形范围中, 基 本上是细碎的可和为有机复合肥原料的机类, 其余部分是垃圾中其它成份。  15: 45-15: 56 The control mechanism is activated, the ejection opening is opened, and the waste in the kettle under the pressure in the kettle forms a fan-shaped distribution area with a length of 80 meters and a width of 15 meters. After identification, a fan-shaped range of 18 meters from the ejection opening Medium is basically a finely divided machine that can be used as raw material for organic compound fertilizers, and the rest is other components in the garbage.

15:56-16:20 按分布区域将各类集中收集, 分别送入热风干燥机干燥。  15: 56-16: 20 Collect all kinds of materials according to the distribution area and send them to the hot air dryer for drying.

16:20-16:30 干燥完毕, 湿度为 10%— 15 %。 出炉后, 经过磁分选机剔除金 属, 送入软硬物粉碎机, 根据有机复合肥原料的要求, 将该类逐级粉碎至 120目; 按制作建材原料的要求将该类逐级粉碎至 80— 120目。  16: 20-16: 30 After drying, the humidity is 10% -15%. After coming out of the furnace, the metal is removed through a magnetic separator and sent to a soft and hard material pulverizer. According to the requirements of the organic compound fertilizer raw materials, the class is pulverized to 120 meshes; 80-120 mesh.

经统计, 处理垃圾总重量 1 吨, 经高压热解喷流后, 垃圾体积共减少 68 %, 经干燥后, 垃圾重量为 620公斤, 共减少 32%, 其中作建材原料的垃圾约 420公 斤, 作有机复合肥原料的垃圾约 190公斤。  According to statistics, the total weight of the processed waste is 1 ton. After the high-pressure pyrolysis jet, the total volume of the waste is reduced by 68%. After drying, the weight of the waste is 620 kg, which is a total reduction of 32%. Among them, about 420 kg of waste is used as building materials. About 190 kg of garbage is used as raw material for organic compound fertilizer.

Claims

1 . 将垃圾处理成建材原料及有机复合肥原料的方法, 其特征在于: 包括提供 小于整砖体积的待处理垃圾, 将这样的垃圾置于密闭装置中, 在 120~220'C温度和 3-15个大气压力下保持 1一 5小时, 然后减压至 0.5—4大气压力将密闭装置内的垃 圾向外喷出, 对喷出后自然形成分类的可制作建材原料类物和可制作有机复合肥类 物分别进行干燥、 磁分、 粉碎、 收集。 1. A method for processing garbage into building material raw materials and organic compound fertilizer raw materials, characterized by comprising: providing less than the entire brick volume of waste to be treated, placing such waste in a closed device, at a temperature of 120 ~ 220'C and 3 Hold at -15 atmospheric pressure for 1 to 5 hours, and then decompress to 0.5-4 atmospheric pressure to eject the garbage in the closed device to the outside. After spraying, it can naturally form classified building materials and organic materials that can be produced Compound fertilizers are dried, magnetically separated, crushed, and collected. 2. 根据权利要求 1所述的将垃圾处理成建材原料及有机复合肥原料的方法, 其特征在于: 干燥所达到的湿度为 10%— 20%。  2. The method for processing garbage into raw materials for building materials and raw materials for organic compound fertilizers according to claim 1, characterized in that the humidity reached by drying is 10% -20%. 3. 根据权利要求 1 所述的将垃圾处理成建材原料及有机复合肥原料的方法, 其特 征在于: 对做建材原料的垃圾粉碎粒度为 80— 200目, 对做有机复合肥原料的垃圾 粉碎粒度为不小于 100目。  3. The method for processing garbage into building material raw materials and organic compound fertilizer raw materials according to claim 1, characterized in that: the particle size of the waste used as the building material raw material is 80-200 mesh, and the waste used as the organic compound fertilizer raw material is crushed. The particle size is not less than 100 mesh.
PCT/CN2000/000015 1999-01-22 2000-01-24 A process for transforming waste into building material and raw material of organic compositions fertiliser Ceased WO2000043137A1 (en)

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