[go: up one dir, main page]

WO1999035926A1 - Materiau etanche a l'eau et a effet de barriere thermique - Google Patents

Materiau etanche a l'eau et a effet de barriere thermique Download PDF

Info

Publication number
WO1999035926A1
WO1999035926A1 PCT/US1998/010138 US9810138W WO9935926A1 WO 1999035926 A1 WO1999035926 A1 WO 1999035926A1 US 9810138 W US9810138 W US 9810138W WO 9935926 A1 WO9935926 A1 WO 9935926A1
Authority
WO
WIPO (PCT)
Prior art keywords
fabric
textile assembly
water
garment
textile
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US1998/010138
Other languages
English (en)
Inventor
Craig D. Lack
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Gore Enterprise Holdings Inc
Original Assignee
Gore Enterprise Holdings Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Gore Enterprise Holdings Inc filed Critical Gore Enterprise Holdings Inc
Priority to AU73908/98A priority Critical patent/AU7390898A/en
Publication of WO1999035926A1 publication Critical patent/WO1999035926A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A41—WEARING APPAREL
    • A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D31/00—Materials specially adapted for outerwear
    • A41D31/04—Materials specially adapted for outerwear characterised by special function or use
    • A41D31/08—Heat resistant; Fire retardant
    • A41D31/085—Heat resistant; Fire retardant using layered materials

Definitions

  • This invention relates to a flexible, pliant, liquid water resistant composite material, particularly useful in garments.
  • Conventional firefighter turnout garments typically are comprised of three layers.
  • One layer is an outer shell typically made from a PBI/Kevlar blend or Nomex in the form of woven cloths.
  • a shell is a protective textile covering. The outer shell primarily provides protection from mechanical and direct flame threats.
  • a second layer is a liquid barrier which provides protection from water and other fluids. State-of-the-art moisture barriers provide liquid water penetration resistance while remaining permeable to water-vapor. Permeable to water vapor is sometimes termed "breathable". These "breathable" moisture barriers provide heat stress reduction to the wearer.
  • Two commercially available liquid water resistant, moisture barriers are GORE- TEXTM moisture barrier and CROSSTECHTM moisture barrier both available from W. L. Gore and Associates.
  • liquid water resistant, water-vapor- permeable composites of a microporous expanded polytetrafluoroethylene membrane coated with a water-vapor permeable continuous polymer that imparts oleophobicity to the construction.
  • This construction is laminated to a fabric.
  • a third layer is used for insulation, e.g. thick, lofty, quilted, single layer or multi-layer, non-woven/woven fabric designed to provide thermal insulation can be employed.
  • This invention is a fabric composite construction which provides the performance of both a moisture barrier layer and thermal insulation, but it is less encumbering than most art constructions, is liquid water and liquid penetration resistant, thermally protective, and preferably may be water-vapor- permeable. Accordingly, it finds use in firefighter turnout garments, high temperature resistant gloves, and the like.
  • the invention comprises a textile assembly comprising
  • the spacer material is a thermally stable polymer material and includes open-cell, closed-cell, and syntactic foams. Preferably the spacer material has continuous voids through it.
  • the textile of this invention can be used to produce apparel items such as gloves, footwear, coats, and jackets as well as non-garment items such as surgical back-table covers where resilient, thermal insulation may be required.
  • textile assembly is meant any construction having a fabric therein.
  • shell is meant a protective fabric.
  • fabric any cloth or a material resembling a cloth.(e.g. woven, nonwoven, knit, etc) useful in garments
  • spacer material is meant a material that keeps apart other materials which the spacer is between.
  • voids is meant gaseous spaces in the spacer material.
  • Figure 1 is a schematic of a garment lay-up consisting of syntactic silicone foam bumps (or raised dots) adhered to a waterproof, moisture vapor permeable fabric that is located adjacent a shell fabric.
  • Figure 2 is a schematic of a garment lay-up consisting of silicone foam lines adhered to a waterproof, moisture vapor permeable fabric that is adjacent a shell fabric.
  • Figure 3 is a schematic of a garment lay-up consisting of silicone foam bumps adhered to a waterproof, moisture vapor permeable fabric that is located adjacent a shell fabric.
  • Figure 4 is a schematic of a garment lay-up consisting of silicone foam bumps adhered to a textile that is located adjacent a waterproof, moisture vapor permeable fabric and a shell fabric.
  • This invention is a flexible, composite construction that functions as both a liquid and thermal barrier material.
  • Components include a liquid penetration resistant fabric. barrier.
  • the thermal barrier portion is provided by a spacer material that separates the shell fabric from layer b of the textile assembly.
  • the spacer material may be an open-celled polymer foam, closed-celled foam, or a syntactic foam,.
  • Water-resistant materials which resist liquid water penetration are well known to persons skilled in the art of making rainwear.
  • the degree of water-resistance required in a so-called waterproof garment depends upon the severity of the external conditions to which it is subjected.
  • a suitable test of water-resistant (Suter test) is described herein.
  • An acceptable practical indication of water-resistance is one in which there is no evidence of water being forced through a sample by a pressure of 1.4 pounds per square inch (0.1 kg/cm 2 ), or more typically 2.0 pounds per square inch (0.14kg/cm 2 ). This also gives a measure of hydrophobicity in respect of porous materials.
  • a water-vapor-permeable material is that evaporated perspiration from the wearer's body is allowed to escape from within the garment by passage through the material, thus preventing build-up of liquid water within the garment and consequent clammy feeling.
  • the material should generally have a water-vapor-permeability of at least 1 ,000, preferably greater than 1500 and more preferably greater than 3000 g/m 2 /day. However, values in excess of 100,000 g/m 2 /day are possible with certain substrates.
  • the water-vapor- permeability of the material will usually be somewhat lower than this (e.g. 5,000 to 12,000 g/m 2 /day or up to 30,000 g/m 2 for certain substrates) but generally speaking its water-vapor-permeability may also be within the ranges outlined above.
  • a suitable water-resistant water-vapor-permeable flexible membrane for use herein is disclosed in US Patent No. 3,953,566 which discloses a porous expanded polytetrafluoroethylene (PTFE) material.
  • the expanded porous PTFE has a micro-structure characterized by nodes interconnected by fibrils. If desired, the water-resistance may be enhanced by coating the expanded PTFE with a hydrophobic and/or oleophobic coating material.
  • the water-resistant water-vapor-permeable membrane might also be a microporous material such as a high molecular weight microporous polyethylene or polypropylene, microporous polyurethanes or polyesters, or a hydrophilic monolithic polymer such as a polyurethane.
  • a microporous material such as a high molecular weight microporous polyethylene or polypropylene, microporous polyurethanes or polyesters, or a hydrophilic monolithic polymer such as a polyurethane.
  • the water-resistant water-vapor-permeable membrane may include a coating of a water-resistant water-vapor-permeable hydrophilic film of the type disclosed in US Patent No. 4,194,041 , the membrane and hydrophilic film together forming a composite.
  • Such hydrophilic films are generally also oleophobic.
  • the flexible membrane may be formed of porous expanded PTFE as described in US Patent No. 3,953,566, and the coated membrane may be formed as described in USP4, 194,041.
  • the carrier fabric and the shell can be one of a number of known fabrics such as a woven, non-woven or knitted fabric of a material such as nylon, polyester, or flame resistant cotton.
  • the carrier fabric may be comprised of either filament yarns, or staple yarns, or a combination of staple and filament yarns in either woven, nonwoven, or knit form.
  • the carrier fabric of layer b is present to provide strength and support to the liquid water repellent material.
  • layer b being, in addition, a water-vapor-permeable material is that evaporated perspiration from the wearer's body is allowed to escape from within the garment by passage through the material, thus preventing build-up of liquid water within the garment and consequent clammy feeling.
  • the shell fabric constitutes the outer surface of a garment formed and provides the required visual or aesthetic appearance and the necessary mechanical or physical properties. It can be a fabric as defined above.
  • An inventive feature of the invention is the presence of the spacer material which maintains a space between the shell fabric and layer b.
  • the air-space provides an insulating function, thus eliminating need for a thick lofty, quilted material.
  • the spacer material is preferably comprised of polymeric raised dots or ridges.
  • the spacer material can be adhered directly to either one or both surfaces of layer b. Or it may also be adhered to other layers such as the shell fabric, the carrier fabric, or an inner liner fabric.
  • the layers can be combined in any number of arrangements such as but not limited to those described in the specific examples.
  • the spacer material may be in the form of discrete raised dots or bumps, raised ridges or lines, broken dashed ridges, or a grid pattern.
  • the pattern of this polymeric spacer material should be chosen to provide the optimal balance of final product performance desired.
  • it is a foamed material.
  • Materials suitable for the foamed spacer include but are not limited to open-cell foams, closed-cell foams, and syntactic foams of various thermally stable polymers.
  • Suitable polymers include but are not limited to silicone polymers, melamine polymers, polyamide polymers, fluoropolymers, neoprene polymers, polyurethane polymers, and co-polymers of these and other suitably thermally stable polymers.
  • Reactive, gas liberating, silicone foams are available from companies such as General Electric Silicones.
  • foams can be produced by "blowing" of conventional materials. Syntactic foams can be produced by the inclusion of microballoons into a non-foam forming polymer.
  • the polymeric spacer is a cured foamed silicone composition.
  • silicones are available and employed as liquid curable organopolysiloxane compositions made foamable by admixing a foaming or blowing agent.
  • the curable silicone composition is liquid, preferably a viscose liquid, which facilitates application to substrates. It ordinarily comprises a liquid diorganosiloxane having functional groups, such as, for example, where R is hydrocarbon of 1 - 2.0 carbons, preferably methyl, combined with an organosilicone compound having functional groups for cross-linking sites, e.g.,
  • R is hydrocarbon of 1 - 20 carbons, preferably methyl and X is a hydrolizable group such as alkoxy groups such as methoxy, ethoxy and propoxy groups, acyloxy groups such as acetoxy group, oxime groups, aminoxy groups, isopropenoxy group and the like.
  • Another organopolysiloxane is one having at least two vinyl groups bonded to the silicon atoms in a molecule combined with an organohydrogenpolysiloxane having at least three hydrogen atoms directly bonded to the silicon atoms in a molecule together with a catalyst for the addition reaction of hydrosilation.
  • the condensation catalyst used in the first type is exemplified by tin compounds such as dibutyltin dilaurate, dioctyltin dilaurate, dioctyltin diacetate, tin octylate and the like, carboxylic acid salts of iron, zinc, lead and the like metals, platinum compound such as chloroplatinic acid and amine compounds according to the types of the condensation reaction , for the second type it may be platinum or a platinum compound such as platinum black, chloroplatinic acid and the like.
  • tin compounds such as dibutyltin dilaurate, dioctyltin dilaurate, dioctyltin diacetate, tin octylate and the like
  • carboxylic acid salts of iron, zinc, lead and the like metals platinum compound such as chloroplatinic acid and amine compounds according to the types of the condensation reaction
  • platinum compound such as chloroplatinic acid and
  • the foaming or blowing agents suitable for use include those widely used in the plastics or synthetic rubber industries such as thermally decomposable organic blowing agents and the microcapsule type blowing agents which may be microcapsules encapsulating an organic liquid having a low boiling point with a synthetic resin film having resistance against solvents.
  • thermally decomposable organic blowing agents include several organic compounds decomposable by heating producing gaseous decomposition products such as azobisisobutyronitrile, dinitroso-pentamethylene tetramine, azobisformamide and the like.
  • the blowing agents of the microcapsule type include the microcapsules of a hydrocarbon or halogenated hydrocarbon solvent as well as either and alcoholic solvents having a low boiling point such as isobutane, n-hexane, diethylether, methyl alcohol, methylene chloride, tricholoroethane and the like encapsulated in a polyvinylidene chloride resin film.
  • alcoholic solvents having a low boiling point such as isobutane, n-hexane, diethylether, methyl alcohol, methylene chloride, tricholoroethane and the like encapsulated in a polyvinylidene chloride resin film.
  • the foamable silicone-containing composition used in the present invention is obtained by blending from 1 to 200 parts by weight or, preferably, from 10 to 100 parts by weight of the above mentioned blowing agent with 100 parts by weight of the curable silicone composition mainly composed of the above described liquid diorganopolysiloxane.
  • the blowing agent may be blended with the curable silicone composition either in advance to form a ready-mixed mixture or directly before application. It is optional that the composition be diluted with an organic solvent to have a viscosity or consistency suitable for application to cloths.
  • the composition may contain other conventional additives such as an inorganic filler, coloring agent, e.g. pigment, and the like.
  • Treatment of fabric or substrate with the spacer material can be performed by intermittant coating of the fabric material or a substrate with the spacer material by knife coating, embossed roller coating, or the like followed by preliminary drying and then heat treatment so that the spacer material can be cured with simultaneous foaming to give a discontinuous coating on the fabric or substrate.
  • element 3 of Figure 1 depicts the layer b
  • Element 2 depicts the raised dots or "bumps", and element 1 represent the shell fabric. As can be seen, the presence of the "bumps” keeps the shell fabric 1 spaced apart from layer b, thus creating an air space that provides the insulating effect.
  • shell fabric 4 is separated from layer b (6) by spacer ridges 5.
  • shell fabric 7 is separated from layer b (9) by raised spacer dots 8 and a woven liner 10 is depicted as adjacent to layer b.
  • spacer dots or bumps 13 are depicted as being attached to fabric 14. As seen, the dots 13 separate fabric 14 from layer b (12) which is protected by shell fabric 11.
  • the dots will have a diameter of between about 0.05 to 0.5 inches, preferably 0.1 to 0.24 inches; a height of between about 0.02 to
  • the spacer will be about 0.05 to 0.3 inches in width and run the distance of the substrate. Other dimensions and the like will be the same as described above.
  • the spacer can also be in the form of raised grid 2 or rectangles of about the same general dimensions as described above. It will be understood that whether dots or rods or rectangular shaped, the spacer material may be ordered and spaced in rows or circles, or can be randomly spaced, so long as an air space is maintained as described further above.
  • the textile assembly of the invention can be used in wearing apparel, such as garments including hats, gloves, jackets, sweaters, cold-weather wear, fire fighting garments, etc.
  • the assembly material can be seamed together for use in garments and the seams of the water resistant water-vapor-permeable material sealed by seam sealing tape, as is known in the apparel field.
  • Total heat loss reported in watts/m 2 , is used to compare the heat transfer qualities of fabric samples. With its evaporative components, total heat loss was a useful criteria for comparing the water-vapor permeability of the samples reported herein. The higher the total heat loss value, the greater the water-vapor permeability and in firefighting garments, the greater the heat stress reduction capability. It is preferred that the total heat loss is at least 150 watts/m 2 .
  • Handle-o-meter model #211-5 A 20 mm apparatus gap and a 1000 gram beam loading were used. The lower the value; the less force required to bend the test specimen i.e. the better the hand. Because fabric orientation may effect hand and because orientation can vary in the garment assembly process, measurements on test lay-ups were made in the warp and fill directions of knit and the lower of the two values reported.
  • Thermal protective performance measurements were made using the Thermal Protective Performance (TPP) test method described in the 1971 NFPA, 1997 edition document. The higher the value, the better the thermal protective performance.
  • TPP Thermal Protective Performance
  • the heights of the foam entities as well as the thickness of the fabric lay- ups were measured with a standard pedestal mounted micrometer. A one inch diameter foot was attached to the micrometer such that the micrometer probe rested evenly on the test specimen.
  • the test results on a conventional firefighting garment lay-up are included in the result tables.
  • the conventional lay-up chosen was a polybenzamidazole (PBI)/Kevlar® blended woven shell fabric (available from Southern Mills, Inc.) that was 7.5 oz./yard 2 , a CROSSTECH® moisture barrier (available from W.L.Gore and Associates, Inc.), and a 7.5oz./yd 2 Aralite® quilted Nomex® thermal liner (available from Southern Mills, Inc.).
  • the CROSSTECH moisture barrier used comprised a porous, stretched polytetrafluoroethylene coated over its surface and partially impregnated with a water-vapor-permeable polyurethane, and adhered to a backing fabric.
  • one embodiment utilized a syntactic foam (2) in combination with a moisture vapor permeable, liquid resistant barrier (3).
  • One means of preparing a syntactic foam was to mix expandable microspheres such as Expancel DU-090 from Expancel Company in a two part, thermosetting, heat activated silicone such as Sylgard 577 from Dow Corning. Ten parts by weight of Sylgard 577 Part A was mixed with one part by weight with the Sylgard 577 Part B. Then, three percent by weight of the expandable microspheres were mixed into the silicone mixture. The resulting material was then loaded into a 50 ml syringe.
  • the syringe was then used to deposit approximately 0.125 inch diameter droplets of this material onto the textile side of a CROSSTECH® moisture barrier, i.e. Nomex® SLE-89TM spunlaced textile laminate (available from W.L.Gore and Associates, Inc.) so as to create a pattern where the droplets were approximately 0.5 inch apart .
  • This composite material was then placed in a preheated convection oven for 3 minutes at 180°C during which time the microballoons inflated while the silicone binder cured.
  • the expandable microspheres effectively created a pattern of syntactic silicone foam bumps which were durably adhered to the moisture barrier substrate material.
  • the percent surface coverage was varied by changing the pattern with which the resin mix was deposited onto the substrate.
  • the foam bumps were approximately 0.09 inches high and covered approximately 16% of the fabric surface.
  • a second embodiment was a coated ePTFE membrane laminated on one side to a Nomex® woven face fabric (6) available from W.L. Gore & Associates, Inc., with a foam ridges (5) adhered to the reverse side.
  • RTF7000 reactive silicone foam from General Electric was used.
  • One hundred parts by weight of the RTF700 resin were weighed into a suitable mixing container.
  • 7 parts by weight of the 7110 curing and blowing agent were weighed into a separate container.
  • the 7110 was mixed into the RTF7000 resin. This mixture was quickly loaded into a 50 ml syringe and the syringe then used to deposit parallel lines of the reacting foam mixture onto the substrate material.
  • the foam lines were approximately 0.2 inches wide and spaced approximately 0.6 inches apart.
  • the preferred samples were prepared by placing the foam/fabric composite into a 150 C preheated oven for 5 minutes. Parallel ridges of approximately 0.16 inch high silicone foam resulted which covered approximately 30% of the substrate surface area.
  • other patterns could also be used such as dots, bumps, grids, dashed lines, or any other suitable pattern.
  • Example 3 As shown in Figure 3, a third embodiment utilized silicone foam in the form of bumps (8) adhered to the textile side of the Nomex SLE-89TM spunlaced / CROSSTECH® moisture barrier material (9). Similar to Example 2, RTF7000 reactive silicone foam was used in this example. The RTF7000 foam was mixed as described in Example 2. However in order to produce a regular pattern of bumps, the mixed foam precursor material was forced (using a doctor blade device) through the openings of a template material which was located on top of the Nomex SLE-89TM spunlaced / CROSSTECH® substrate. The hole size and spacing of the template as well as the template thickness were selected to produce the desired foam bump size and placement.
  • foam bumps that are approximately 0.2 inch in diameter were made.
  • foam bumps were used in a regular pattern in which each was located approximately 0.3 inches from the neighboring bumps. Thus, approximately 20% of the resulting substrate surface was effectively covered by the foam bumps.
  • the size, shape, and pattern (including amount of surface covered) must be optimized.
  • Performance tests were conducted on a typical garment lay-up of this invention.
  • a PBI/Kevlar® woven shell fabric (7) (such as that sold by Southern Mills) was placed adjacent to one side of the above described construction and a woven Nomex® fabric liner (10) on the other.
  • tests results were compared to a typical firefighter garment lay-up comprised of a 7.5 oz/yd2 woven shell fabric next to a CROSSTECH® moisture barrier laminate next to a 7.5 oz/yd2 quilted thermal liner.
  • the results of this comparison given in Table 3, show dramatically improved water-vapor- permeability and improved hand of this invention compared to the conventional lay-up.
  • a fourth embodiment utilized a silicone foam in the form of bumps (13) adhered to a textile (14).
  • This composite textile layer was then located adjacent to the waterproof layer CROSSTECH® water-vapor- permeable barrier (12) on the side opposite the Nomex side to yield the desired effect.
  • the foam chemistry, pattern, and application method used in this example was substantially the same as that described in Example 3.
  • this technique was used to create a regular pattern of silicone foam bumps on a woven Nomex® textile.
  • the silicone foam bumps were approximately 0.1 inch high and approximately 0.2 inch in diameter.
  • foam bumps were used in a regular pattern in which each was located approximately 0.3 inches from the neighboring bumps. Performance tests were conducted on a typical garment lay-up.
  • PBI/Kevlar® woven shell fabric (11) was placed adjacent to one side of the above described invention and a waterproof CROSSTECH® moisture barrier on the other side.
  • all tests results were compared to a typical firefighter garment lay-up comprised of a 7.5 ozl ⁇ l woven shell fabric next to a CROSSTECH® moisture barrier laminate next to a 7.5 oz/yd2 quilted thermal liner.
  • the results of this comparison, given in Table 4 show improved hand of this invention compared to the conventional lay-up.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Laminated Bodies (AREA)

Abstract

Cette invention se rapporte à une structure textile offrant une protection contre la chaleur ou le froid, lorsqu'elle est utilisée dans des vêtements. Cette protection est formée par un espace d'air contenu dans la structure. Cet espace d'air est formé par un matériau d'espacement placé dans la structure et empêchant les deux faces adjacentes de la structure de s'accoler l'une à l'autre.
PCT/US1998/010138 1998-01-14 1998-05-18 Materiau etanche a l'eau et a effet de barriere thermique Ceased WO1999035926A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU73908/98A AU7390898A (en) 1998-01-14 1998-05-18 Waterproof and thermal barrier material

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US713698A 1998-01-14 1998-01-14
US09/007,136 1998-01-14

Publications (1)

Publication Number Publication Date
WO1999035926A1 true WO1999035926A1 (fr) 1999-07-22

Family

ID=21724430

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1998/010138 Ceased WO1999035926A1 (fr) 1998-01-14 1998-05-18 Materiau etanche a l'eau et a effet de barriere thermique

Country Status (2)

Country Link
AU (1) AU7390898A (fr)
WO (1) WO1999035926A1 (fr)

Cited By (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002001977A1 (fr) * 2000-06-29 2002-01-10 W.L. Gore & Associates (Uk) Ltd. Assemblage de vetement
EP1413213A1 (fr) * 2002-10-23 2004-04-28 Proline Textile Textile composite anti-feu impermeable comprenant un reseau de fils en relief
FR2846202A1 (fr) * 2002-10-23 2004-04-30 Proline Textile Textile composite anti-feu impermeable comprenant un reseau de fibres floquees
WO2007003147A1 (fr) * 2005-07-04 2007-01-11 Lion Apparel Deutschland Gmbh Vetement de protection comprenant une membrane isolante destinee en particulier a l'utilisation dans le cadre de la lutte contre les incendies
WO2009055046A1 (fr) * 2007-10-24 2009-04-30 Gore Enterprise Holdings, Inc. Matériaux de protection thermique
US7977261B2 (en) * 2006-08-11 2011-07-12 The United States Of America As Represented By The Secretary Of The Army Thermal barrier fabric
US8383528B2 (en) 2007-10-24 2013-02-26 W. L. Gore & Associates, Inc. Burn protective materials
ITBO20110638A1 (it) * 2011-11-08 2013-05-09 Angelo Fabrizio Bianchi Capo d'abbigliamento traspirante
EP2614734A1 (fr) * 2012-01-10 2013-07-17 Manufactures Industrials de Tortella, SA Tissu naturel étirable étanche ignifuge et revêtement/protecteur de matelas ou oreiller utilisant ledit tissu
USRE44851E1 (en) 1999-07-13 2014-04-22 Stirling Mouldings Limited Flexible material
CN104013146A (zh) * 2014-06-24 2014-09-03 公安部上海消防研究所 消防员灭火防护服隔热层材料
CN104191750A (zh) * 2014-09-10 2014-12-10 公安部天津消防研究所 一种带有防水透湿膜的灭火防护服外层复合织物及其工艺
USRE45402E1 (en) 1999-07-13 2015-03-03 Stirling Mouldings Limited Flexible material
US9149084B2 (en) 2009-06-23 2015-10-06 Nike, Inc. Apparel incorporating a protective element and method for making
US20150366281A1 (en) * 2013-01-30 2015-12-24 Miller D. Stephen Resilient prominence fabric and articles made therefrom
US9386812B2 (en) 2011-07-25 2016-07-12 Nike, Inc. Articles of apparel incorporating cushioning elements
US9398779B2 (en) 2011-02-25 2016-07-26 Nike, Inc. Articles of apparel incorporating cushioning elements and methods of manufacturing the articles of apparel
US9505203B2 (en) 2010-11-30 2016-11-29 Nike, Inc. Method of manufacturing dye-sublimation printed elements
US9675122B2 (en) 2009-06-23 2017-06-13 Nike, Inc. Apparel incorporating a protective element
EP2186428B2 (fr) † 2008-11-13 2018-01-17 Otmar Schneider Montage de tissu pour vêtement de protection
US10034498B2 (en) 2011-07-25 2018-07-31 Nike, Inc. Articles of apparel incorporating cushioning elements
US10264834B2 (en) * 2016-03-25 2019-04-23 Nike, Inc. Foam nodes for creating stand off on apparel items
US20190126585A1 (en) * 2016-04-21 2019-05-02 O&M Halyard, Inc, Multi-Layered Structure and Articles Formed Therefrom Having Improved Splash Resistance by Increased Interlayer Spacing
US10364527B2 (en) 2007-10-24 2019-07-30 W. L. Gore & Associates, Inc. Burn protective materials
US10390573B2 (en) 2008-08-01 2019-08-27 Nike, Inc. Apparel with selectively attachable and detachable elements
US10499694B2 (en) 2008-08-01 2019-12-10 Nike, Inc. Apparel with selectively attachable and detachable elements
US10959476B2 (en) 2011-07-25 2021-03-30 Nike, Inc. Articles of apparel incorporating cushioning elements
US11192327B2 (en) * 2017-07-03 2021-12-07 Axel Nickel Voluminous meltblown nonwoven fabric with improved stackability and storability
CN114103294A (zh) * 2021-10-29 2022-03-01 上海郎哲实业有限公司 一种高强力透气耐磨棉涤交织面料
WO2023075732A3 (fr) * 2021-10-25 2023-07-20 Kordsa Teknik Tekstil A.S. Matériau isolant polyvalent et son procédé de production

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1213415A (fr) * 1955-12-16 1960-03-31 équipement universel de protection
US4136222A (en) * 1977-04-18 1979-01-23 Minnesota Mining And Manufacturing Company Thermally insulating sheet material
US5098770A (en) * 1988-10-14 1992-03-24 Lainiere De Picardie Composite fireproof and waterproof textile and clothing and seat comprising such a textile
EP0501080A1 (fr) * 1991-02-25 1992-09-02 LAINIERE DE PICARDIE: Société anonyme Doublure composite anti-feu de vêtement
US5430896A (en) * 1993-08-02 1995-07-11 Bisley; Bill D. Water resistant sock
WO1997043917A1 (fr) * 1996-05-21 1997-11-27 Lion Apparel, Inc. Doublure de vetement thermique a billes calorifuges

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1213415A (fr) * 1955-12-16 1960-03-31 équipement universel de protection
US4136222A (en) * 1977-04-18 1979-01-23 Minnesota Mining And Manufacturing Company Thermally insulating sheet material
US5098770A (en) * 1988-10-14 1992-03-24 Lainiere De Picardie Composite fireproof and waterproof textile and clothing and seat comprising such a textile
EP0501080A1 (fr) * 1991-02-25 1992-09-02 LAINIERE DE PICARDIE: Société anonyme Doublure composite anti-feu de vêtement
US5430896A (en) * 1993-08-02 1995-07-11 Bisley; Bill D. Water resistant sock
WO1997043917A1 (fr) * 1996-05-21 1997-11-27 Lion Apparel, Inc. Doublure de vetement thermique a billes calorifuges

Cited By (49)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
USRE45402E1 (en) 1999-07-13 2015-03-03 Stirling Mouldings Limited Flexible material
USRE44851E1 (en) 1999-07-13 2014-04-22 Stirling Mouldings Limited Flexible material
AU2001274269B2 (en) * 2000-06-29 2004-10-28 W.L. Gore & Associates (Uk) Ltd. Garment assembly
WO2002001977A1 (fr) * 2000-06-29 2002-01-10 W.L. Gore & Associates (Uk) Ltd. Assemblage de vetement
EP1413213A1 (fr) * 2002-10-23 2004-04-28 Proline Textile Textile composite anti-feu impermeable comprenant un reseau de fils en relief
FR2846200A1 (fr) * 2002-10-23 2004-04-30 Proline Textile Textile composite anti-feu impermeable comprenant un reseau de fils en relief
FR2846202A1 (fr) * 2002-10-23 2004-04-30 Proline Textile Textile composite anti-feu impermeable comprenant un reseau de fibres floquees
WO2007003147A1 (fr) * 2005-07-04 2007-01-11 Lion Apparel Deutschland Gmbh Vetement de protection comprenant une membrane isolante destinee en particulier a l'utilisation dans le cadre de la lutte contre les incendies
US7977261B2 (en) * 2006-08-11 2011-07-12 The United States Of America As Represented By The Secretary Of The Army Thermal barrier fabric
WO2009055046A1 (fr) * 2007-10-24 2009-04-30 Gore Enterprise Holdings, Inc. Matériaux de protection thermique
US8383528B2 (en) 2007-10-24 2013-02-26 W. L. Gore & Associates, Inc. Burn protective materials
US10364527B2 (en) 2007-10-24 2019-07-30 W. L. Gore & Associates, Inc. Burn protective materials
EP3434476A1 (fr) * 2007-10-24 2019-01-30 W.L. Gore & Associates, Inc Matériaux de protection thermique
US8722145B2 (en) 2007-10-24 2014-05-13 W. L. Gore & Associates, Inc. Thermally protective materials
US8734905B2 (en) 2007-10-24 2014-05-27 W. L. Gore & Associates, Inc. Thermally protective materials
US8753461B2 (en) 2007-10-24 2014-06-17 W. L. Gore & Associates, Inc. Burn protective materials
US10390573B2 (en) 2008-08-01 2019-08-27 Nike, Inc. Apparel with selectively attachable and detachable elements
US11284652B2 (en) 2008-08-01 2022-03-29 Nike, Inc. Apparel with selectively attachable and detachable elements
US11246358B2 (en) 2008-08-01 2022-02-15 Nike, Inc. Apparel with selectively attachable and detachable elements
US11311061B2 (en) 2008-08-01 2022-04-26 Nike, Inc. Apparel with selectively attachable and detachable elements
US11950644B2 (en) 2008-08-01 2024-04-09 Nike, Inc. Apparel with selectively attachable and detachable elements
US10499694B2 (en) 2008-08-01 2019-12-10 Nike, Inc. Apparel with selectively attachable and detachable elements
EP2186428B2 (fr) † 2008-11-13 2018-01-17 Otmar Schneider Montage de tissu pour vêtement de protection
US9149084B2 (en) 2009-06-23 2015-10-06 Nike, Inc. Apparel incorporating a protective element and method for making
US10194707B2 (en) 2009-06-23 2019-02-05 Nike, Inc. Apparel incorporating a protective element
US9675122B2 (en) 2009-06-23 2017-06-13 Nike, Inc. Apparel incorporating a protective element
US9505203B2 (en) 2010-11-30 2016-11-29 Nike, Inc. Method of manufacturing dye-sublimation printed elements
US9398779B2 (en) 2011-02-25 2016-07-26 Nike, Inc. Articles of apparel incorporating cushioning elements and methods of manufacturing the articles of apparel
US9756884B2 (en) 2011-02-25 2017-09-12 Nike, Inc. Articles of apparel incorporating cushioning elements and methods of manufacturing the articles of apparel
US10034498B2 (en) 2011-07-25 2018-07-31 Nike, Inc. Articles of apparel incorporating cushioning elements
US10959476B2 (en) 2011-07-25 2021-03-30 Nike, Inc. Articles of apparel incorporating cushioning elements
US9386812B2 (en) 2011-07-25 2016-07-12 Nike, Inc. Articles of apparel incorporating cushioning elements
ITBO20110638A1 (it) * 2011-11-08 2013-05-09 Angelo Fabrizio Bianchi Capo d'abbigliamento traspirante
WO2013104975A1 (fr) 2012-01-10 2013-07-18 Manufactures Industrials De Tortella, Sa Tissu composite extensible, étanche, ignifuge, élément de protection pour oreiller ou matelas utilisant ce tissu et utilisation dudit tissu comme écran de protection
EP2614734A1 (fr) * 2012-01-10 2013-07-17 Manufactures Industrials de Tortella, SA Tissu naturel étirable étanche ignifuge et revêtement/protecteur de matelas ou oreiller utilisant ledit tissu
US9642471B2 (en) 2012-01-10 2017-05-09 Manufactures Industrials De Tortella, Sa Flame-retardant waterproof stretchable composite fabric, pillow or mattress protector using said fabric and use of said fabric as a protective screen
US9668530B2 (en) * 2013-01-30 2017-06-06 Stephen D. Miller Resilient prominence fabric and articles made therefrom
US20150366281A1 (en) * 2013-01-30 2015-12-24 Miller D. Stephen Resilient prominence fabric and articles made therefrom
CN104013146A (zh) * 2014-06-24 2014-09-03 公安部上海消防研究所 消防员灭火防护服隔热层材料
CN104191750A (zh) * 2014-09-10 2014-12-10 公安部天津消防研究所 一种带有防水透湿膜的灭火防护服外层复合织物及其工艺
US10765158B2 (en) 2016-03-25 2020-09-08 Nike, Inc. Foam nodes for creating stand off on apparel items
US20190191800A1 (en) * 2016-03-25 2019-06-27 Nike, Inc. Foam nodes for creating stand off on apparel items
US10264834B2 (en) * 2016-03-25 2019-04-23 Nike, Inc. Foam nodes for creating stand off on apparel items
US20190126585A1 (en) * 2016-04-21 2019-05-02 O&M Halyard, Inc, Multi-Layered Structure and Articles Formed Therefrom Having Improved Splash Resistance by Increased Interlayer Spacing
US10744739B2 (en) * 2016-04-21 2020-08-18 O&M Halyard, Inc. Multi-layered structure and articles formed therefrom having improved splash resistance by increased interlayer spacing
US11192327B2 (en) * 2017-07-03 2021-12-07 Axel Nickel Voluminous meltblown nonwoven fabric with improved stackability and storability
WO2023075732A3 (fr) * 2021-10-25 2023-07-20 Kordsa Teknik Tekstil A.S. Matériau isolant polyvalent et son procédé de production
CN114103294A (zh) * 2021-10-29 2022-03-01 上海郎哲实业有限公司 一种高强力透气耐磨棉涤交织面料
CN114103294B (zh) * 2021-10-29 2023-07-21 深圳市娜尔思时装有限公司 一种高强力透气耐磨棉涤交织面料

Also Published As

Publication number Publication date
AU7390898A (en) 1999-08-02

Similar Documents

Publication Publication Date Title
WO1999035926A1 (fr) Materiau etanche a l'eau et a effet de barriere thermique
CA2703189C (fr) Materiaux de protection contre les brulures
EP2424396B1 (fr) Matériaux de protection contre les brûlures
US8734905B2 (en) Thermally protective materials
HK1047021A1 (en) Thermally protective liner
KR102644780B1 (ko) 아크 플래시 보호재
KR20220151199A (ko) 아크 플래시 보호재
US11105039B2 (en) Burn protective materials
WO2022233972A1 (fr) Matériaux ignifuges étirables
JPWO2020115543A5 (fr)
JP2025531106A (ja) アークフラッシュ防護材料
HK1145948B (en) Burn protective materials comprising expandable graphite
HK1191523A (en) Burn protective materials comprising expandable graphite
HK1167580A (en) Burn protective materials
HK1167580B (en) Burn protective materials
HK1191523B (en) Burn protective materials comprising expandable graphite
HK1191612B (en) Thermally protective materials

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A1

Designated state(s): AL AM AT AU AZ BA BB BG BR BY CA CH CN CU CZ DE DK EE ES FI GB GE GH HU IL IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MD MG MK MN MW MX NO NZ PL PT RO RU SD SE SG SI SK SL TJ TM TR TT UA UG UZ VN YU ZW

AL Designated countries for regional patents

Kind code of ref document: A1

Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LU MC NL PT SE

DFPE Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101)
121 Ep: the epo has been informed by wipo that ep was designated in this application
NENP Non-entry into the national phase

Ref country code: CA

Ref country code: KR

REG Reference to national code

Ref country code: DE

Ref legal event code: 8642

122 Ep: pct application non-entry in european phase