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WO1999025188A2 - Composition pesticide - Google Patents

Composition pesticide Download PDF

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Publication number
WO1999025188A2
WO1999025188A2 PCT/EP1998/007244 EP9807244W WO9925188A2 WO 1999025188 A2 WO1999025188 A2 WO 1999025188A2 EP 9807244 W EP9807244 W EP 9807244W WO 9925188 A2 WO9925188 A2 WO 9925188A2
Authority
WO
WIPO (PCT)
Prior art keywords
composition
abamectin
xxxiv
propagation material
london
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP1998/007244
Other languages
English (en)
Other versions
WO1999025188A3 (fr
Inventor
Christopher Thomas Ball
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Novartis Pharma GmbH Austria
Novartis AG
Original Assignee
Novartis Erfindungen Verwaltungs GmbH
Novartis AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from CH264697A external-priority patent/CH692594A5/de
Application filed by Novartis Erfindungen Verwaltungs GmbH, Novartis AG filed Critical Novartis Erfindungen Verwaltungs GmbH
Priority to AU19617/99A priority Critical patent/AU1961799A/en
Publication of WO1999025188A2 publication Critical patent/WO1999025188A2/fr
Publication of WO1999025188A3 publication Critical patent/WO1999025188A3/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N29/00—Biocides, pest repellants or attractants, or plant growth regulators containing halogenated hydrocarbons
    • A01N29/04—Halogen directly attached to a carbocyclic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/24—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms
    • A01N43/26—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings
    • A01N43/28—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings with two hetero atoms in positions 1,3
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/24—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms
    • A01N43/32—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms six-membered rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/66—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms
    • A01N43/68—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms with two or three nitrogen atoms directly attached to ring carbon atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/707—1,2,3- or 1,2,4-triazines; Hydrogenated 1,2,3- or 1,2,4-triazines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/12—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/24—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing the groups, or; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/30—Derivatives containing the group >N—CO—N aryl or >N—CS—N—aryl
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/34—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the groups, e.g. biuret; Thio analogues thereof; Urea-aldehyde condensation products
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N49/00—Biocides, pest repellants or attractants, or plant growth regulators, containing compounds containing the group, wherein m+n>=1, both X together may also mean —Y— or a direct carbon-to-carbon bond, and the carbon atoms marked with an asterisk are not part of any ring system other than that which may be formed by the atoms X, the carbon atoms in square brackets being part of any acyclic or cyclic structure, or the group, wherein A means a carbon atom or Y, n>=0, and not more than one of these carbon atoms being a member of the same ring system, e.g. juvenile insect hormones or mimics thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
    • A01N57/12—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing acyclic or cycloaliphatic radicals
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
    • A01N57/14—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing aromatic radicals
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
    • A01N57/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing heterocyclic radicals
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/26—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-nitrogen bonds
    • A01N57/28—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-nitrogen bonds containing acyclic or cycloaliphatic radicals
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N63/00—Biocides, pest repellants or attractants, or plant growth regulators containing microorganisms, viruses, microbial fungi, animals or substances produced by, or obtained from, microorganisms, viruses, microbial fungi or animals, e.g. enzymes or fermentates
    • A01N63/20—Bacteria; Substances produced thereby or obtained therefrom
    • A01N63/22—Bacillus
    • A01N63/23—B. thuringiensis

Definitions

  • the present invention relates to a composition which comprises a pesticidaliy active compound combination, a method for controlling pests with this composition, a process for the preparation of the composition, its use and plant propagation material treated with it, and the use of abamectin and the compounds of the formulae (I) to (XXXIV) below for the preparation of the composition.
  • the invention accordingly relates to a composition for controlling insects or representatives of the order Acarina, which comprises a combination of variable amounts of abamectin (A), and one or more of the following compounds:
  • (XXXIV) a product which can be isolated from a Bacillus thuringiensis strain; in each case in free form or in salt form, and at least one auxiliary.
  • Compounds (I) to (XXXIV) which contain at least one basic centre can form, for example, acid addition salts. These are formed, for example, with strong inorganic acids such as mineral acids, for example perchloric acid, sulfuric acid, nitric acid, nitrous acid, a phosphoric acid or a hydrogen halide acid, with strong organic carboxylic acids, such as d-C 4 alkanecarboxylic acids which are unsubstituted or substituted, for example by halo- gen, for example acetic acid, such as dicarboxylic acids which are saturated or unsaturated, for example oxalic, malonic, succinic, maleic, fumaric or phthalic acid, such as hydroxy- carboxylic acids, for example ascorbic, lactic, malic, tartaric or citric acid, or such as benzoic acid, or with organic sulfonic acids, such as CrC alkane- or arylsulfonic acids which are unsubstitute
  • Suitable salts with bases are, for example, metal salts, such as alkali metal or alkaline earth metal salts, for example sodium, potassium or magnesium salts, or salts with ammonia or an organic amine, such as morphoiine, piperidine, pyrrolidine, a mono-, di- or tri-lower alkylamine, for example ethyl-, diethyl-, triethyl- or dimethyl-propyl-amine, or a mono-, di- or trihydroxy-lower alkylamine, for example mono-, di- or triethanolamine. If appropriate, corresponding inner salts can furthermore be formed.
  • metal salts such as alkali metal or alkaline earth metal salts, for example sodium, potassium or magnesium salts
  • salts with ammonia or an organic amine such as morphoiine, piperidine, pyrrolidine, a mono-, di- or tri-lower alkylamine, for example ethyl-, diethyl-,
  • Agrochemically advantageous salts are preferred in the context of the invention.
  • the compounds (I) to (XXXIV) in free form are to be understood as including the corresponding salts, and the salts are to be understood as including the free compounds (I) to (XXXIV).
  • the free form is in general preferred.
  • Thiocyclam is preferred as hydrogen oxalate salt.
  • compositions which comprise abamectin and the compounds (I) to (XXXIV) in free form are preferred in the context of the present invention.
  • compositions which, in addition to abamectin, comprises only one further pesticidally active compound (I) to (XXXIV). Furthermore, preference is given to compositions which, in addition to abamectin, contain azamethiphos, or fenoxycarb, or cypermethrin high-cis, or profenofos, or lufenuron, or pymetrozine.
  • compositions which contain a compound which can be isolated from a Bacillus thuringiensis strain are particularly preferred.
  • insecticidally active compounds or the strains from which they can be isolated are particularly preferred:
  • SAN 4151 San 2391, SAN 4011, H7 (B401), H14, EG2348 (Condor OF®), EG2349 (Boligard®), EG2371 (Cutlass®), EG2424 (Foil®, Jackpot®); H3a,3b (Javelin®, Steward®, Thuricide®, Vault®); CGA237218 (M200, Able®), H14, GC91 (Agree®, Turex®), DSM3435, known from US-P-4 996 156; DSM3440, known from US-P-4 996 156; HD541 , HD571 and very particularly H7 (B401 ), H14, H3a,3b, CGA237218 (M200), H14, GC91 , DSM3435;
  • the active compound combination according to the invention preferably comprises the active compound (A) and one of the active compounds (I) to (XXXIV) in a mixing ratio of 100:1 to 1 :6000, in particular 1 :50 bis 50:1 , in particular in a ratio between 1 :20 and 20:1 , in particular between 10:1 and 1 :10, especially between 5:1 and 1 :5, particularly preferably between 2:1 and 1 :2, and also preferably between 4:1 and 2:1 , especially in the ratio 1 :1 , or 5:1 , or 5:2, or 5:3, or 5:4, or 4:1 , or 4:2, or 4:3, or 3:1 , or 3:2, or 2:1 , or 1 :5, or 2:5, or 3:5, or 4:5, or 1 :4, or 2:4, or 3:4, or 1 :3, or 2:3, or 1 :2, or, 1 :600, or 1 :300, or 1 :150, or 1 :35, or 2:35, or 4:35, or 1 :
  • the rates of application of abamectin and of the individual compounds (I) to (XXXIV) are lowered for a comparably good action.
  • the combined mixture also still has a high degree of pest control where the two individual substances have become completely ineffective in the range of lower rates of application. This allows on the one hand a considerable extension of the spectrum of pests which can be controlled, and on the other hand an increase in application reliability.
  • compositions according to the invention also additionally have further surprising advantages which can likewise be described as synergistic in a broader sense: thus, for example, it is possible to control pests which cannot be controlled or sufficiently effectively controlled with abamectin or (I) to (XXXIV), and the compositions according to the invention are better tolerated by plants, i.e. they have, for example, reduced phytotoxicity, than abamectin or (I) to (XXXIV).
  • insects can furthermore be controlled in their various stages of development, which is not always the case with abamectin or the individual compounds (I) to (XXXIV), since these compounds can be used, for example, only as adulticides or only as larvicides against quite specific larval stages.
  • abamectin with certain compounds (I) to (XXXIV) have more favourable properties during grinding, mixing, storage and also spraying.
  • compositions according to the invention are useful preventively and/or curatively in the field of pest control, while being tolerated by warmblooded animals, fish and plants, and have a very favourable biocidal spectrum.
  • the compositions according to the invention are active against all or individual stages of development of normally sensitive and also resistant animal pests, such as insects and representatives of the order Acarina.
  • the insecticidal and/or acaricidal action of the compositions according to the invention can manifest itself here directly, i.e.
  • the good action corresponding to a rate of destruction (mortality) of at least 50 to 60%.
  • the abovementioned animal pests include, for example, those which are mentioned in the European Patent Application EP-A-736 252.
  • the pests mentioned in EP-A-736 252 are therefore expressly incorporated into the subject matter of the present invention by reference.
  • active compound mixtures according to the invention in particular pests of the type mentioned which occur on plants, especially useful plants and ornamentals in agriculture, in horticulture and in forestry, or on parts such as fruit, blossom, foliage, stems, tubers, or roots, of such plants can be controlled, i.e. checked or destroyed; in some cases even parts of plants which grow later are still protected from these pests.
  • the pesticidal mixture according to the invention can advantageously be employed for pest control in cereals, such as maize or sorghum; in fruit, for example pome, stone and soft fruit, such as apples, pears, plums, peaches, almonds, cherries or berries, for example strawberries, raspberries and blackberries; in leguminous plants, such as beans, lentils, peas or soya; in oil-bearing crops, such as oilseed rape, mustard, poppy, olive, sunflower, coconut, castor, cacao or groundnuts; in cucurbits, such as pumpkins, cucumbers or melons; in fibre plants, such as cotton, flax, hemp or jute; in citrus fruits, such as oranges, lemons, grapefruits or mandarins; in vegetables, such as spinach, lettuce, asparagus, cabbage varieties, carrots, onions, tomatoes, potatoes or capsicum; in lauraceous plants, such as avocado, cinnamonium or camphor; or in tobacco, nuts, coffee, aubergines, sugar cane, tea, pepper
  • the pesticides according to the invention are emulsifiable concentrates, suspension concentrates, directly sprayable or dilutable solutions, spreadable pastes, dilute emulsions, sprayable powders, soluble powders, dispersible powders, wettable powders, dusts, granules or encapsulations in polymeric substances which comprise abamectin and one of the other active compounds (I) to (XXXIV) according to the invention.
  • the active compounds are employed in these compositions in a pure form, the solid active compounds, for example, being employed in a specific particle size, or, preferably, together with - at least - one of the auxiliaries conventionally used in the art of formulation, such as extenders, for example solvents or solid carriers, or such as surface-active compounds (surfactants).
  • auxiliaries conventionally used in the art of formulation, such as extenders, for example solvents or solid carriers, or such as surface-active compounds (surfactants).
  • Suitable solvents are, for example: non-hydrogenated or partly hydrogenated aromatic hydrocarbons, preferably fractions C 8 to C1 2 of alkylbenzenes, such as xylene mixtures, alkylated naphthalenes or tetrahydronaphthalene, aliphatic or cycloaliphatic hydrocarbons, such as paraffins or cyclohexane, alcohols, such as ethanol, propanol or butanol, glycols and ethers and esters thereof, such as propyiene glycol, dipropylene glycol ether, ethylene glycol or ethylene glycol monomethyl or -ethyl ether, ketones, such as cyclohexanone, isophorone or diacetone alcohol, strongly polar solvents, such as N-methylpyrrolid-2-one, dimethyl sulfoxide or N,N-dimethylformamide, water, non-epoxidized or epoxidized plant oils, such as non-ep
  • Suitable formulation auxiliaries are, for example, solid carriers, solvents, stabilizers, slow release auxiliaries, dyes and, if appropriate, surface-active substances (surfactants).
  • Suitable carriers and auxiliaries here are all substances customarily used for crop protection compositions, in particular for molluscicides.
  • Suitable auxiliaries, such as solvents, solid carriers, surface-active compounds, nonionic surfactants, cationic surfactants, anionic surfactants and further auxiliaries for the compositions used according to the invention are, for example, the same as described in EP-A-736 252.
  • compositions generally comprise 0.1 to 99%, in particular 0.1 to 95%, of a mixture of the active compound (A) with one of the active compounds (I) to (XXXIV), and 1 to 99.9%, in particular 5 to 99.9%, of - at least - one solid or liquid auxiliary, where generally 0 to 25%, in particular 0.1 to 20%, of the compositions can be surfactants (% is in each case per cent by weight). While concentrated compositions are more preferably commercial goods, the end user generally uses dilute compositions which have considerably lower active compound concentrations. Preferred compositions contain, in particular, the same ingredients in the same amounts as given in EP-A-736'252.
  • compositions according to the invention can also comprise other solid or liquid auxiliaries such as stabilizers, for example non-epoxidized or epoxidized plant oils (for example epoxidized coconut oil, rapeseed oil or soya oil), defoamers, for example silicone oil, preservatives, viscosity regulators, binders and/or tackifiers, as well as fertilizers or other active compounds for achieving specific effects, for example bactericides, fungicides, nematicides, molluscicides or herbicides.
  • auxiliaries such as stabilizers, for example non-epoxidized or epoxidized plant oils (for example epoxidized coconut oil, rapeseed oil or soya oil), defoamers, for example silicone oil, preservatives, viscosity regulators, binders and/or tackifiers, as well as fertilizers or other active compounds for achieving specific effects, for example bactericides, fungicides, n
  • compositions according to the invention are prepared in a known manner, in the absence of auxiliaries, for example by grinding, sieving and/or pressing a solid active compound or active compound mixture, for example to a particular particle size, and in the presence of at least one auxiliary, for example by intimate mixing and/or grinding the active compound or active compound mixture with the auxiliary or auxilaries.
  • the invention therefore also relates to a process for the preparation of the compositions.
  • Mixtures of abamectin with one or more of the compounds (I) to (XXXIV) are preferably employed with the auxiliaries conventionally used in the art of formulation, and are therefore processed, for example, to emulsifiable concentrates, directly sprayable or dilutable solu- tions, dilute emulsions, wettable powders, soluble powders, dusts and granules, and also to encapsulations in, for example, polymeric substances, in a known manner.
  • the methods of application, such as spraying, atomizing, dusting, wetting, scattering or pouring are chosen, as is the nature of the composition, according to the aims to be achieved and the given circumstances.
  • the invention furthermore relates to the methods of application of the compositions, i.e. the methods of controlling pests of the type mentioned, such as spraying, atomizing, dusting, spreading, dressing, scattering or pouring, to be chosen according to the aims to be achieved and the given circumstances, and the use of the compositions for controlling pests of the type mentioned.
  • Typical rates of concentration here are between 0.1 and 1000 ppm, preferably between 0.1 and 500 ppm, of active compound.
  • the rate of application can vary within wide limits and depends on the nature of the soil, the nature of the application, (leaf application; seed dressing; application in the seed furrow), the crop plant, the pest to be controlled, the particular climatic circumstances which prevail and other factors determined by the nature of the application, the time of application and the target crop.
  • the rates of application per hectare are in general 1 to 2000 g of active compound per hectare, in particular 10 to 1000 g/ha, preferably 20 to 600 g/ha.
  • a preferred method of application in the field of crop protection is application to the foliage of the plants (foliar application), where the frequency of application and rate of application can be chosen according to the risk of infestation by the particular pest.
  • the active compounds can also enter the plants via the root system (systemic action) by impregnating the locus of the plants with a liquid composition or introducing the active compounds in solid form into the locus of the plants, for example into the soil, for example in the form of granules (soil application). In paddy rice crops, such granules can be metered onto the flooded rice field.
  • compositions according to the invention are also suitable for the protection of plant propagation material, for example seeds, such as fruit, tubers, or grain, or plant seedlings, against animal pests.
  • the propagation material can be treated with the composition before being brought out; for example seed can be dressed before sowing.
  • the active compounds according to the invention can also be applied to the seed grains (coating) either by impregnating the grains in a liquid composition or coating them with a solid composition.
  • the composition can also be applied to the site where the propagation material is brought out, during broadcasting, for example into the seed furrow during sowing.
  • the invention furthermore relates to these treatment methods for plant propagation material and the plant propagation material treated in this way.
  • Example F1 Emulsion concentrates a) b) c)
  • Tributylphenol polyethylene glycol ether (30 mol of EO) 12% 4%
  • EO is the degree of ethoxylation of castor oil or tributylphenol.
  • Emulsions of any desired concentration can be prepared from such concentrates by dilution with water.
  • Example F2 Solutions a) b) c) d)
  • Epoxidized coconut oil 1 % 5%
  • the solutions are suitable for use in the form of tiny drops.
  • Example F3 Granules a) b) c) d)
  • Attapulgite 90% 18% The active compounds are dissolved together in methylene chloride, the solution is sprayed onto the carrier and the solvent is then evaporated off in vacuo.
  • a synergistic effect is present whenever the action Ae of the combination of an active ingredient of formula (A) with one of the compounds (I) to (XXXIV) is greater than the sum of the actionss of the active ingredients applied individually:
  • the expected pesticidal action Ae for a given combination of two pesticides can be calculated as follows (q.v. COLBY, S.R., "Calculating synergistic and antagonistic response of herbicide combinations", Weeds 15, pages 20-22, 1967):
  • Y percent mortality after treatment with compound (I) to (XXXIV) at a rate of application of q kg / ha versus untreated controls.
  • Ae expected pesticidal action (percent mortality versus the untreated controls) after treatment with Abamectin and a compound (I) to (XXXIV) at a rate of application of p + q kg / ha.
  • Example B1 Action against Bemisia tabaci
  • Dwarf bean plants are placed in gauze cages and populated with adults of Bemisia tabaci. After oviposition has taken place, all the adults are removed. 10 days later, the plants with the nymphs on them are sprayed with an aqueous suspension spray liquor comprising 50 ppm of the active compound mixture. After a further 14 days, the percentage hatching of the eggs is evaluated in comparison with untreated control batches.
  • Example B2 Action against Spodoptera littoralis caterpillars
  • Young soya plants are sprayed with an aqueous emulsion spray liquor which comprises 400 ppm of the active compound mixture. After the spray coating has dried on, the soya plants are populated with 10 caterpillars of the third stage of Spodoptera littoralis and placed in a plastic container. Evaluation takes place 3 days later. The percentage reduction in the population and the percentage reduction in feeding damage (% action) are determined from comparison of the number of dead caterpillars and of the feeding damage on the treated plants with those on the untreated plants.
  • Example B3 Ovicidal action on Lobesia botrana
  • Lobesia botrana eggs deposited on filter paper are immersed for a short time in an acetone- aqueous test solution comprising 400 ppm of the active compound mixture to be tested. After the test solution has dried, the eggs are incubated in Petri dishes. After 6 days, the percentage hatching of the eggs is evaluated in comparison with untreated control batches (% reduction in hatching).
  • Example B4 Ovicidal action on Heliothis virescens
  • Heliothis virescens eggs deposited on filter paper are immersed for a short time in an acetone-aqueous test solution comprising 400 ppm of the active compound mixture to be tested. After the test solution has dried, the eggs are incubated in Petri dishes. After 6 days, the percentage hatching of the eggs is evaluated in comparison with untreated control batches (% reduction in hatching).
  • Example B5 Action against Plutella xylostella caterpillars
  • Young cabbage plants are sprayed with an aqueous emulsion spray liquor which comprises 440 ppm of the active compound. After the spray coating has dried on, the cabbage plants are populated with 10 caterpillars of the third stage of Plutella xylostella and placed in a plastic container. Evaluation takes place 3 days later. The percentage reduction in the population and the percentage reduction in eating damage (% action) are determined from comparison of the number of dead caterpillars and of the eating damage on the treated plants with those on the untreated plants.

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Zoology (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Dentistry (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Environmental Sciences (AREA)
  • Plant Pathology (AREA)
  • Biotechnology (AREA)
  • Microbiology (AREA)
  • Virology (AREA)
  • Insects & Arthropods (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

L'invention concerne une composition destinée à éliminer les insectes ou des représentants de l'ordre des acariens, comprenant une combinaison de quantités variables d'abamectine (A) et d'un ou plusieurs des composés ci-après: azamétiphos; chlorfenvinphos; cyperméthrine; cyperméthrine à degré élevé cis; cyromazine; diafenthiuron; diazinon; dichlorvos;dicrotophos; dicyclanil; fenoxycarb; fluazuron; furathiocarb; isazofos; iodfenphos; kinoprène; lufenuron; méthacriphos; méthidathion; monocrotophos; phosphanidon; profenofos; diofenolan; pyrométrozine; bromopropylate; méthoprène; disulfuton; quinalphos; tau-fluvalinate; thiocyclame; thiometon; propetamphos; formothion, diènochlore ou un produit pouvant être isolé d'une souche de Bacillus thuringiensis; et au moins un produit auxiliaire. L'invention concerne également un procédé d'élimination des insectes, un procédé de préparation de la composition précitée, son utilisation et le matériau de propagation végétal traité avec celle-ci, ainsi que l'utilisation d'abamectine pour la préparation de ladite composition.
PCT/EP1998/007244 1997-11-14 1998-11-12 Composition pesticide Ceased WO1999025188A2 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU19617/99A AU1961799A (en) 1997-11-14 1998-11-12 Pesticidal composition

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
CH263597 1997-11-14
CH2635/97 1997-11-14
CH2646/97 1997-11-17
CH264697A CH692594A5 (de) 1997-11-17 1997-11-17 Pestizides Mittel.

Publications (2)

Publication Number Publication Date
WO1999025188A2 true WO1999025188A2 (fr) 1999-05-27
WO1999025188A3 WO1999025188A3 (fr) 1999-08-26

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Application Number Title Priority Date Filing Date
PCT/EP1998/007244 Ceased WO1999025188A2 (fr) 1997-11-14 1998-11-12 Composition pesticide

Country Status (6)

Country Link
AR (1) AR017608A1 (fr)
AU (1) AU1961799A (fr)
CO (1) CO5040011A1 (fr)
EG (1) EG21586A (fr)
MA (1) MA24699A1 (fr)
WO (1) WO1999025188A2 (fr)

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004026033A1 (fr) * 2002-09-20 2004-04-01 Artpharm Pty Ltd Pesticides pour les plantes et leurs utilisations
AU2005100403B4 (en) * 2005-05-13 2005-09-01 Jurox Pty Ltd Parasiticide Composition
AU2007202548B1 (en) * 2007-06-01 2007-11-01 Zoetis Services Llc Pesticide Composition
CN100397989C (zh) * 2005-11-21 2008-07-02 河北威远生物化工股份有限公司 含有阿维菌素的杀虫水乳剂
CN100399900C (zh) * 2006-09-19 2008-07-09 东莞市农业科学研究中心 一种含阿维菌素和丁醚脲的农药组合物及其应用
WO2010020510A3 (fr) * 2008-08-18 2011-01-27 Syngenta Participations Ag Associations insecticides
EP2258194A3 (fr) * 2004-11-04 2011-03-02 Makhteshim Chemical Works Limited Compositions pesticides
CN102805089A (zh) * 2012-08-28 2012-12-05 广西田园生化股份有限公司 一种含丁氟螨酯和甲氨基阿维菌素的杀虫杀螨组合物
CN103875688A (zh) * 2014-03-19 2014-06-25 黄业新 一种含吡蚜酮和阿维菌素的农药组合物
CN103918676A (zh) * 2014-04-16 2014-07-16 罗晓丹 一种杀虫组合物
US9730453B2 (en) 2008-12-31 2017-08-15 Makhteshim Chemical Works Ltd. Method for controlling insects in plants
CN108651486A (zh) * 2018-04-28 2018-10-16 江西省农业科学院植物保护研究所 一种灭螺治螟高效药剂
WO2019005700A1 (fr) * 2017-06-26 2019-01-03 Merial, Inc. Compositions de granulés parasiticides à double action, leurs procédés et utilisations

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5953404A (ja) * 1982-09-21 1984-03-28 Sankyo Co Ltd 殺ダニ剤
EP0242502A3 (fr) * 1986-01-25 1987-12-09 Hoechst Aktiengesellschaft Compositions pesticides
GB2220856A (en) * 1988-07-18 1990-01-24 Merck & Co Inc Novel synergistic agricultural insecticidal and acaricidal combinations containing avermectin derivatives
EP0736252A3 (fr) * 1995-04-05 1997-05-02 Ciba Geigy Ag Compositions synergiques avec diafenthiuron

Cited By (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004026033A1 (fr) * 2002-09-20 2004-04-01 Artpharm Pty Ltd Pesticides pour les plantes et leurs utilisations
EP2258194A3 (fr) * 2004-11-04 2011-03-02 Makhteshim Chemical Works Limited Compositions pesticides
AU2005100403B4 (en) * 2005-05-13 2005-09-01 Jurox Pty Ltd Parasiticide Composition
CN100397989C (zh) * 2005-11-21 2008-07-02 河北威远生物化工股份有限公司 含有阿维菌素的杀虫水乳剂
CN100399900C (zh) * 2006-09-19 2008-07-09 东莞市农业科学研究中心 一种含阿维菌素和丁醚脲的农药组合物及其应用
AU2007202548B1 (en) * 2007-06-01 2007-11-01 Zoetis Services Llc Pesticide Composition
CN102164491B (zh) * 2008-08-18 2013-11-06 先正达参股股份有限公司 包含阿维菌素和丁氟螨酯的杀虫组合
EA017524B1 (ru) * 2008-08-18 2013-01-30 Зингента Партисипейшнс Аг Инсектицидные комбинации
WO2010020510A3 (fr) * 2008-08-18 2011-01-27 Syngenta Participations Ag Associations insecticides
US8598130B2 (en) 2008-08-18 2013-12-03 Syngenta Crop Protection Llc Insecticidal combinations
CN102164491A (zh) * 2008-08-18 2011-08-24 先正达参股股份有限公司 包含阿维菌素和丁氟螨酯的杀虫组合
US9730453B2 (en) 2008-12-31 2017-08-15 Makhteshim Chemical Works Ltd. Method for controlling insects in plants
CN102805089A (zh) * 2012-08-28 2012-12-05 广西田园生化股份有限公司 一种含丁氟螨酯和甲氨基阿维菌素的杀虫杀螨组合物
CN103875688A (zh) * 2014-03-19 2014-06-25 黄业新 一种含吡蚜酮和阿维菌素的农药组合物
CN103875688B (zh) * 2014-03-19 2015-10-14 顾祥茂 一种含吡蚜酮和阿维菌素的农药组合物
CN103918676A (zh) * 2014-04-16 2014-07-16 罗晓丹 一种杀虫组合物
WO2019005700A1 (fr) * 2017-06-26 2019-01-03 Merial, Inc. Compositions de granulés parasiticides à double action, leurs procédés et utilisations
US11147273B2 (en) 2017-06-26 2021-10-19 Boehringer Ingelheim Animal Health USA Inc. Dual active parasiticidal granule compositions, methods and uses thereof
AU2018292285B2 (en) * 2017-06-26 2023-05-25 Boehringer Ingelheim Animal Health USA Inc. Dual active parasiticidal granule compositions, methods and uses thereof
CN108651486A (zh) * 2018-04-28 2018-10-16 江西省农业科学院植物保护研究所 一种灭螺治螟高效药剂

Also Published As

Publication number Publication date
AU1961799A (en) 1999-06-07
AR017608A1 (es) 2001-09-12
WO1999025188A3 (fr) 1999-08-26
EG21586A (en) 2001-12-31
CO5040011A1 (es) 2001-05-29
MA24699A1 (fr) 1999-07-01

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