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WO1999015610A1 - Utilisation de tensioactifs betainiques insatures comme epaississsants - Google Patents

Utilisation de tensioactifs betainiques insatures comme epaississsants Download PDF

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Publication number
WO1999015610A1
WO1999015610A1 PCT/EP1998/005875 EP9805875W WO9915610A1 WO 1999015610 A1 WO1999015610 A1 WO 1999015610A1 EP 9805875 W EP9805875 W EP 9805875W WO 9915610 A1 WO9915610 A1 WO 9915610A1
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WIPO (PCT)
Prior art keywords
acid
carbon atoms
use according
fatty
surfactants
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP1998/005875
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German (de)
English (en)
Inventor
Joaquin Bigorra
Rafael Pi Subirana
Esther Prat Queralt
Nuria Bonastre Gilabert
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
BASF Personal Care and Nutrition GmbH
Original Assignee
Henkel AG and Co KGaA
Cognis Deutschland GmbH and Co KG
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Filing date
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Application filed by Henkel AG and Co KGaA, Cognis Deutschland GmbH and Co KG filed Critical Henkel AG and Co KGaA
Publication of WO1999015610A1 publication Critical patent/WO1999015610A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/90—Betaines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
    • C11D17/003—Colloidal solutions, e.g. gels; Thixotropic solutions or pastes
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/16—Sulfonic acids or sulfuric acid esters; Salts thereof derived from divalent or polyvalent alcohols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29—Sulfates of polyoxyalkylene ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/662—Carbohydrates or derivatives

Definitions

  • the invention relates to the use of unsaturated betaine surfactants as thickeners for aqueous surfactant solutions.
  • Aqueous surfactant solutions or aqueous surfactant-containing preparations such as, for example, hair shampoos or hand dishwashing detergents, often have an insufficiently low viscosity. It is immediately clear that an agent which has a flow behavior such as water is difficult to dose and therefore there is a risk for the consumer that he always uses more than desired.
  • thickeners are added to such preparations, which are often synthetic polymeric compounds, such as, for example, poly (meth) acrylates, polyvinyl compounds, polycarboxylates, modified natural products, such as, for example, Carboxymethyl celluloses and cellulose ethers or natural products, e.g.
  • the object of the invention was therefore to provide substances which reliably thicken the widest possible spectrum of aqueous surfactant solutions and at the same time themselves have surface-active properties.
  • the invention relates to the use of unsaturated betaine surfactants as thickeners for aqueous surfactant solutions.
  • betaine surfactants which contain a mono- or polyunsaturated hydrocarbon or acyra radical are excellent thickeners for aqueous solutions of anionic, nonionic, cationic and / or amphoteric or zwitterionic surfactants.
  • Betaines are known surfactants which are predominantly produced by carboxyalkylation, preferably carboxymethylation, of aminic compounds.
  • the starting materials are preferably condensed with halocarboxylic acids or their salts, in particular with sodium chloroacetate, one mol of salt being formed per mole of betaine.
  • unsaturated carboxylic acids such as acrylic acid is also possible.
  • betaines and "real" amphoteric surfactants reference is made to the contribution by U.PIoog in Seifen- ⁇ le-Fette-Wwachs, 108, 373 (1982). Further overviews on this topic can be found for example by A. O'Lennick et al. in HAPPI, Nov.
  • betaines suitable as thickeners are the carboxyalkylation products of secondary and in particular tertiary unsaturated amines which follow the formula (I)
  • R 1 for a hydrocarbon radical having 6 to 22 carbon atoms and 1, 2 or 3 double bonds
  • R 2 for hydrogen or alkyl radicals with 1 to 4 carbon atoms
  • R 3 for alkyl radicals with 1 to 4 carbon atoms
  • n for numbers from 1 to 6
  • X represents an alkali and / or alkaline earth metal or ammonium.
  • Typical examples are the carboxymethylation products of oleylmethylamine, oleyldimethylamine, elaidylmethylamine, elaidyldimethylamine, petroselinylmethylamine, petroselinyldimethylamine, ünolylmethylamine, linolyldimethylamine, linolenylmethylamine, linoienyldimethylamine and erucyldimethylamine, as well as erucyldimethylamine.
  • Also suitable as thickeners are carboxyalkylation products of unsaturated amido amines which follow the formula (II)
  • R 4 CO represents an aliphatic acyl radical having 6 to 22 carbon atoms and 1, 2 or 3 double bonds
  • m represents numbers from 1 to 3 and R 2 , R 3 , n and X have the meanings given above.
  • Typical examples are reaction products of unsaturated fatty acids with 16 to 22 carbon atoms, namely palmoleic acid, stearic acid, oleic acid, elaidic acid, petroselinic acid, linoleic acid, linolenic acid, gadoleic acid and erucic acid as well as their technical mixtures, which predominantly, ie to more than 50% by weight, these fatty acids contain, with N, N-dimethylaminoethylamine, N, N-dimethylaminopropylamine, N, N-diethylaminoethylamine and NN-diethylaminopropylamine, which are condensed with sodium chloroacetate.
  • R 5 is a hydrocarbon radical having 15 to 21 carbon atoms and 1, 2 or 3 double bonds
  • R 6 is a hydroxyl group
  • an OCOR 5 or NHCOR 5 radical and m is 2 or 3.
  • These substances are also known substances which, for example, by cyclizing condensation of 1 or 2 moles of unsaturated fatty acid, namely palmoleic acid, stearic acid, oleic acid, elaidic acid, petroselinic acid, linoleic acid, linolenic acid, gadoleic acid and erucic acid and their technical mixtures these fatty acids predominantly, ie contain more than 50% by weight, can be obtained with polyvalent amines such as aminoethylethanolamine (AEEA) or diethylenetriamine.
  • AEEA aminoethylethanolamine
  • the corresponding carboxyalkylation products are mixtures of different open-chain betaines.
  • Typical examples are condensation products of the above-mentioned fatty acids with AEEA, preferably imidazolines based on oleic acid, which are subsequently betainized with sodium chloroacetate.
  • the betaine surfactants are usually used in amounts of 0.1 to 5, preferably 0.5 to 4 and in particular 1 to 2% by weight, based on the solids content of the aqueous surfactant solutions.
  • a particular advantage of the invention is that a large number of different surfactant solutions can be reliably thickened with the addition of the unsaturated betaines.
  • the use of the unsaturated surfactants increases the proportion of surfactant in the formulation, which is advantageous with regard to the detergent properties.
  • Typical examples of surfactants whose aqueous solutions can be thickened by adding the unsaturated betaines are anionic surfactants, such as soaps, alkylbenzenesulfonates, alkanesulfonates, olefin sulfonates, alkyl ether sulfonates, glycerol ether sulfonates, ⁇ -methyl ester sulfonates, sulfo fatty acids, alkyl sulfates, fatty alcohol ether Glycerol ether, Hydroxymischethersulfate, monoglyceride (ether) sulfates, fatty acid amide (ether) sulfates, mono- and dialkyl sulfosuccinates, mono- and di- alkyl sulfosuccinamates, sulfotriglycerides, amide soaps, ether carboxylic acids and salts thereof, fatty acid isethionates, fatty acid
  • anionic surfactants contain polyglycol ether chains, they can have a conventional, but preferably a narrow, homolog distribution.
  • Typical examples of nonionic surfactants are fatty alcohol polyglycol ethers, alkylphenol polyglycol ethers, fatty acid polyglycol esters, fatty acid amide polyglycol ethers, fatty amine polyglycol ethers, alkoxylated triglycerides, mixed ethers or mixed formals, optionally partially oxidized aik (en) yloligoglycosides, particularly nucylglycolic acid amide, and glucorogluconic acid amide, and glucoronic acid amide, and glucorosulfonic acid derivatives Wheat-based products), polyesters, esters, sugar esters, sorbitan esters, polysorbates and amine oxides.
  • nonionic surfactants contain polyglycol ether chains, they can have a conventional, but preferably a narrow, homolog distribution.
  • Typical examples of cationic surfactants are quaternary ammonium compounds and ester quats, in particular quaternized fatty acid trialkanolamine ester salts.
  • Typical examples of amphoteric or zwitterionic surfactants are saturated alkyl betaines, alkyl amido betaines, aminopropionates, aminoglycinates, imidazolinium betaines and sulfobetaines. The surfactants mentioned are exclusively known compounds.
  • J.Falbe ed.
  • Surfactants in Consumer Products Springer Verlag, Berlin, 1987, pp. 54-124
  • J.Falbe ed.
  • Catalysts, Surfactants and Mineral Oil Additives Thieme Verlag, Stuttgart, 1978, p. 123-217.
  • Aqueous solutions of alkyl ether sulfates, monoglyceride (ether) sulfates, alk (en) yl oligoglycosides and saturated betaines are preferably thickened.
  • the solids concentration in the solutions can be 5 to 60, preferably 10 to 50 and in particular 20 to 40% by weight.
  • the surfactant solutions to be thickened may contain other auxiliaries and additives, in particular those customary for cosmetic applications, such as, for example, oil bodies, emulsifiers, superfatting agents, pearlescent waxes, stabilizers, consistency enhancers, additional thickening agents, cationic polymers, silicone compounds, biogenic active ingredients, antidandruff agents, film formers, preservatives , Hydrotropes, solubiiizers, UV light protection filters, insect repellents, self-tanners, perfume oils, dyes and the like.
  • auxiliaries and additives such as, for example, oil bodies, emulsifiers, superfatting agents, pearlescent waxes, stabilizers, consistency enhancers, additional thickening agents, cationic polymers, silicone compounds, biogenic active ingredients, antidandruff agents, film formers, preservatives , Hydrotropes, solubiiizers, UV light protection filters, insect repellents, self-tanners, perfume oils, dyes and the
  • Suitable emulsifiers are nonionic surfactants from at least one of the following groups:
  • alkyl mono- and oligoglycosides with 8 to 22 carbon atoms in the alkyl radical and their ethoxylated analogs
  • polyol and especially polyglycerol esters such as e.g. Polyglycerol polyricinoleate, polyglycerol poly-12-hydroxystearate or polyglycerol dimerate. Mixtures of compounds from several of these classes of substances are also suitable;
  • partial esters based on linear, branched, unsaturated or saturated C6 / 22 fatty acids, ricinoleic acid and 12-hydroxystearic acid and glycerol, polyglycerol, pentaerythritol, dipentaerythritol, sugar alcohols (eg sorbitol), alkyl glucosides (eg methyl glucoside, butylgiucoside - glucoside) and polyglucosides (eg cellulose);
  • the adducts of ethylene oxide and / or of propylene oxide with fatty alcohols, fatty acids, alkylphenols, glycerol mono- and diesters and sorbitan mono- and diesters of fatty acids or with castor oil are known, commercially available products. These are mixtures of homologs, the middle of which Degree of alkoxylation corresponds to the ratio of the amounts of ethylene oxide and / or propylene oxide and substrate with which the addition reaction is carried out.
  • Ci2 / i8 fatty acid monoesters and diesters of adducts of ethylene oxide with glycerol are known from DE-PS 20 24 051 as refatting agents for cosmetic preparations.
  • C8 / i8 alkyl mono- and oligoglycosides their preparation and their use are known from the prior art. They are produced in particular by reacting glucose or oligosaccharides with primary alcohols with 8 to 18 carbon atoms.
  • glycoside residue both monoglycosides in which a cyclic sugar residue is glycosidically bonded to the fatty alcohol and oligomeric glycosides with a degree of oligomerization of up to preferably about 8 are suitable.
  • the degree of oligomerization is a statistical mean value which is based on a homogeneous distribution customary for such technical products.
  • Zwitterionic surfactants can also be used as emulsifiers.
  • Zwitterionic surfactants are surface-active compounds that contain at least one quaternary ammonium group and at least one carboxylate and one sulfonate group in the molecule.
  • Particularly suitable zwitterionic surfactants are the so-called betaines, such as the N-alkyl-N, N-dimethylammonium glycinate, for example coconut alkyldimethylammonium glycinate, N-acylamino propyl-N, N-dimethylammonium glycinate, for example coconut acylaminopropyldimethylammonium glycinate, and 2-alkyl-3-carboxyl -3-hydroxyethylimidazolines each having 8 to 18 carbon atoms in the alkyl or acyl group and the cocoacylaminoethylhydroxyethylcarboxymethylglycinate.
  • fatty acid amide derivative known under the CTFA name Cocamidopropyl Betaine is particularly preferred.
  • Suitable emulsifiers are ampholytic surfactants.
  • Ampholytic surfactants are surface-active compounds which, in addition to a C ⁇ -alkyl or -acyl group, contain at least one free amino group and at least one -COOH or -SO3H group in the molecule and are capable of forming internal salts.
  • ampholytic surfactants are N-alkylglycines, N-alkylpropionic acids, N-alkylaminobutyric acids, N-alkyliminodipropionic acids, N-hydroxyethyl-N-alkylamidopropylglycines, N-alkyltaurines, N-alkylsarcosines, 2-alkylaminopropionic acids and alkylaminoacetic acids, each with about 8 to 18 carbon atoms in the alkyl group.
  • Particularly preferred ampholytic surfactants are N-cocoalkylaminopropionate, cocoacylaminoethylaminopropionate and Ci2 / i8-acylsarcosine.
  • quaternary emulsifiers are also suitable, those of the ester quat type, preferably methyl-quaternized difatty acid triethanolamine ester salts, being particularly preferred.
  • Substances such as, for example, lanolin and lecithin and polyethoxylated or acylated lanolin and lecithin derivatives, polyol fatty acid esters, monoglycerides and fatty acid alkanolamides can be used as superfatting agents, the latter simultaneously serving as foam stabilizers.
  • Pearlescent waxes are: alkylene glycol esters, especially ethylene glycol distearate; Fatty acid alkanolamides, especially coconut fatty acid diethanolamide; Partial glycerides, especially stearic acid monoglyceride; Esters of polyvalent, optionally hydroxy-substituted carboxylic acids with fatty alcohols having 6 to 22 carbon atoms, especially long-chain esters of tartaric acid; Fatty substances, such as, for example, fatty alcohols, fatty ketones, fatty aldehydes, fatty ethers and fatty carbonates, which have a total of at least 24 carbon atoms, especially lauron and distearyl ether; Fatty acids such as stearic acid, hydroxystearic acid or behenic acid, ring opening products of olefin epoxides with 12 to 22 carbon atoms with fatty alcohols with 12 to 22 carbon atoms and / or polyols with 2 to 15 carbon atoms
  • Suitable thickeners are, for example, polysaccharides, in particular xanthan gum, guar guar, agar agar, alginates and tyloses, carboxymethyl cellulose and hydroxyethyl cellulose, and also higher molecular weight polyethylene glycol mono- and diesters of fatty acids, polyacrylates, (for example Carbopole® from Goodrich or Synthaiene® from Sigma), polyacrylic amides, polyvinyl alcohol and polyvinyl pyrrolidone as well as electrolytes such as table salt and ammonium chloride.
  • polysaccharides in particular xanthan gum, guar guar, agar agar, alginates and tyloses, carboxymethyl cellulose and hydroxyethyl cellulose, and also higher molecular weight polyethylene glycol mono- and diesters of fatty acids, polyacrylates, (for example Carbopole® from Goodrich or Synthaiene® from Sigma), polyacrylic amide
  • Suitable cationic polymers are, for example, cationic cellulose derivatives, e.g. a quaternized hydroxyethyl cellulose available under the name Polymer JR 400® from Amerchol, cationic starch, copolymers of diallylammonium salts and acrylamides, quaternized vinylpyrroiidone / vinylimidazole polymers such as e.g.
  • Luviquat® condensation products of polyglycols and amines, quaternized collagen polypeptides, such as, for example, lauryldimonium hydroxypropyl hydrolyzed collagen (Lamequat®IJGrünau), quaternized wheat polypeptides, polyethyleneimine, cationic silicone polymers, e.g. Amidomethicones, copolymers of adipic acid and dimethylaminohydroxypropyldiethylenetriamine (Cartaretine® / Sandoz), copolymers of acrylic acid with dimethyldiallylammonium chloride (Merquat® 550 / Chemviron), polyaminopolyamides, e.g.
  • cationic chitin derivatives such as quaternized chitosan, optionally microcrystalline, condensation products of dihaloalkylene, such as e.g. Dibromobutane with bisdialkylamines, e.g. Bis-dimethylamino-1,3-propane, cationic guar gum, such as e.g. Jaguar® CBS, Jaguar® C-17, Jaguar® C-16 from Celanese, quaternized ammonium salt polymers such as e.g. Mirapol® A-15, Mirapol® AD-1, Mirapol® AZ-1 from Miranol.
  • dihaloalkylene such as e.g. Dibromobutane with bisdialkylamines, e.g. Bis-dimethylamino-1,3-propane
  • cationic guar gum such as e.g. Jaguar® CBS, Jaguar® C-17, Jaguar® C-16 from Celanese
  • quaternized ammonium salt polymers such as
  • Suitable silicone compounds are, for example, dimethylpolysiloxanes, methylphenylpolysiloxanes, cyclic silicones and amino, fatty acid, alcohol, polyether, epoxy, fluorine, glycoside and / or alkyl-modified silicone compounds, which can be both liquid and resinous at room temperature.
  • Typical examples of fats are glycerides, beeswax, camamauba wax, candelilla wax, montan wax, paraffin wax or microwaxes, if appropriate in combination with hydrophilic waxes, for example cetylstearyl alcohol or partial glycerides.
  • Metal salts of fatty acids such as magnesium, aluminum and / or zinc stearate can be used as stabilizers.
  • Biogenic active substances are, for example, tocopherol, tocopherol acetate, tocopherol palmitate, ascorbic acid, deoxyribonucleic acid, retinol, bisabolot, allantoin, phytantriol, panthenol, AHA acids, amino acids, ceramides, pseudoceramides, essential oils, plant extracts and vitamins.
  • Climbazole, octopirox and zinc pyrethione can be used as antidandruff agents.
  • Common film formers are, for example, chitosan, microcrystalline chitosan, quaternized chitosan, polyvinylpyrrolidone, vinylpyrrolidone-vinyl acetate copolymers, polymers of the acrylic acid series, quaternary cellulose derivatives, collagen, hyaluronic acid or their salts and similar compounds.
  • Montmorillonites, clay minerals, pemulene and alkyl-modified carbopol types can serve as swelling agents for aqueous phases.
  • UV light protection filters are organic substances which are able to absorb ultraviolet rays and the absorbed energy in the form of longer-wave radiation, e.g. To give off heat again.
  • UVB filters can be oil-soluble or water-soluble. As oil-soluble substances e.g. to call:
  • 4-aminobenzoic acid derivatives preferably 4- (dimethylamino) benzoic acid 2-ethylhexyl ester, 4-
  • esters of cinnamic acid preferably 2-ethylhexyl 4-methoxycinnamate, 2-ethylhexyl 4-methoxycinnamate, 2-ethylhexyl 2-cyano-3-phenylcinnamate (octocrylene);
  • esters of salicylic acid preferably 2-ethylhexyl salicylic acid, 4-isopropylbenzyl salicylic acid, omomenthyl salicylic acid;
  • benzophenone preferably 2-hydroxy-4-methoxybenzophenone, 2-hydroxy-4-methoxy-4'-methylbenzophenone, 2,2'-dihydroxy-4-methoxybenzophenone;
  • Esters of benzalmalonic acid preferably di-2-ethylhexyl 4-methoxybenzmalonate
  • Triazine derivatives e.g. 2,4,6-trianilino- (p-carbo-2'-ethyl-1'-hexyloxy) -1, 3,5-triazine and octyltriazone.
  • Propane-1,3-dione e.g. 1 - (4-tert-butylphenyl) -3- (4'methoxyphenyl) propane-1,3-dione;
  • Sulfonic acid derivatives of 3-benzylidene camphor e.g. 4- (2-oxo-3-bornylidene methyl) benzenesulfonic acid and 2-methyl-5- (2-oxo-3-bornylidene) sulfonic acid and their salts.
  • UV-A filters such as 1- (4'-tert-butylphenyl) -3- (4'-methoxyphenyl) propane-1, 3-dione or 1-phenyl-3-
  • UV-A filters 4'-isopropylphenyl) propane-1,3-dione.
  • the UV-A and UV-B filters can of course also be used in mixtures.
  • insoluble pigments namely finely dispersed metal oxides or salts, such as, for example, titanium dioxide, zinc oxide, iron oxide, aluminum oxide, cerium oxide, zirconium oxide, silicates (talc), barium sulfate and zinc stearate are also suitable for this purpose.
  • the particles should have an average diameter of less than 100 nm, preferably between 5 and 50 nm and in particular between 15 and 30 nm. They can have a spherical shape have, however, it is also possible to use those particles which have an ellipsoidal shape or shape which differs in some other way from the spherical shape.
  • secondary light stabilizers of the antioxidant type can also be used, which interrupt the photochemical reaction chain which is triggered when UV radiation penetrates the skin. Typical examples are superoxide dismutase, tocopherols (vitamin E) and ascorbic acid (vitamin C).
  • hydrotropes such as, for example, ethanol, isopropyl alcohol or polyols
  • Polyols that come into consideration here preferably have 2 to 15 carbon atoms and at least two hydroxyl groups. Typical examples are
  • Alkylene glycols such as, for example, ethylene glycol, diethylene glycol, propylene glycol, butylene glycol, hexylene glycol and polyethylene glycols with an average molecular weight of 100 to 1,000 daltons;
  • Methyl compounds such as in particular trimethylolethane, trimethylolpropane, trimethylolbutane, pentaerythritol and dipentaerythritol;
  • Lower alkyl glucosides in particular those with 1 to 8 carbons in the alkyl radical, such as methyl and butyl glucoside;
  • Sugar alcohols with 5 to 12 carbon atoms such as sorbitol or mannitol,
  • Aminosugars such as glucamine.
  • Suitable preservatives are, for example, phenoxyethanol, formaldehyde solution, parabens, pentanediol or sorbic acid.
  • N, N-diethyl-m-touluamide, 1, 2-pentanediol or Insect repellent 3535 are suitable as insect repellents, and dihydroxyacetone is suitable as a self-tanning agent.
  • Perfume oils include extracts from flowers (lavender, roses, jasmine, neroli), stems and leaves (geranium, patchouli, petitgrain), fruits (anise, coriander, caraway seeds, juniper), fruit peels (bergamot, lemon, oranges), roots (Macis, Angelica, Celery, Cardamom, Costus, Iris, Calmus), woods (sandal, guaiac, cedar, rosewood), herbs and grasses (tarragon, lemon grass, sage, thyme), needles and twigs (spruce , Fir, pine, mountain pine), resins and balsams (galbanum, elemi, benzoin, myrrh, olibanum, opoponax).
  • Animal raw materials such as musk, civet and castoreum are also suitable.
  • Ambroxan, eugenol, isoeugenol, citronellal, hydroxycitronellal, geraniol, citronellol, geranyl acetate, citral, ionone and methylionone are suitable as synthetic or semi-synthetic perfume oils.
  • the dyes which can be used are those substances which are suitable and approved for cosmetic purposes, as compiled, for example, in the publication "Cosmetic Dyes" by the Dye Commission of the German Research Foundation, Verlag Chemie, Weinheim, 1984, pp. 81-106. These dyes are usually used in concentrations of 0.001 to 0.1% by weight, based on the mixture as a whole.
  • the total proportion of auxiliaries and additives can be 1 to 50, preferably 5 to 40,% by weight, based on the composition.
  • the agents can be produced by customary cold or hot processes; the phase inversion temperature method is preferably used.

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Abstract

L'invention concerne l'utilisation de tensioactifs bétaïniques insaturés comme épaississants pour des solutions tensioactives aqueuses, notamment pour des solutions d'alkyléthersulfates, (éther)sulfates monoglycériques, alc(én)yloligoglucosides et bétaïnes saturées. Un avantage particulier de l'invention réside dans le fait que l'utilisation des tensioactifs bétaïniques à la place des épaississants polymères disponibles dans le commerce permet de réduire pour un rendement constant la teneur en tensioactifs des préparations.
PCT/EP1998/005875 1997-09-25 1998-09-16 Utilisation de tensioactifs betainiques insatures comme epaississsants Ceased WO1999015610A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19742285A DE19742285C1 (de) 1997-09-25 1997-09-25 Verwendung von ungesättigten Betaintensiden als Verdickungsmittel
DE19742285.3 1997-09-25

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WO1999015610A1 true WO1999015610A1 (fr) 1999-04-01

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Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1197206A1 (fr) * 2000-08-29 2002-04-17 Cognis Deutschland GmbH Utilisation des esters de betaine comme agents epaississants
FR2850567A1 (fr) * 2003-02-03 2004-08-06 Oreal Composition cosmetique comprenant un amide cationique hydrogelifiant et un tensioactif
FR2850565A1 (fr) * 2003-02-03 2004-08-06 Oreal Composition cosmetique comprenant un amide hydrogelifiant et un polymere benefique
WO2004068998A3 (fr) * 2003-02-03 2004-09-16 Oreal Composition cosmetique comprenant un amide cationique hydrogelifiant et un tensioactif
WO2004068996A3 (fr) * 2003-02-03 2004-10-28 Oreal Composition cosmetique comprenant un amide ionique hydrogelifiant et un polymère benefique pour la chevelure
US20100069269A1 (en) * 2007-03-08 2010-03-18 Evelyne Prat Use of betaines as foaming agents and foam drainage reducing agents
EP2365053A1 (fr) * 2010-03-12 2011-09-14 The Procter & Gamble Company Compositions liquides de détergent comprenant des gélifiants amido à pH réglable et procédés de fabrication
US8841235B2 (en) 2010-08-10 2014-09-23 Rhodia Operations Agricultural pesticide compositions
US9045720B2 (en) 2004-12-30 2015-06-02 Rhodia Chimie Herbicidal composition comprising an aminophosphate or aminophosphonate salt, a betaine and an amine oxide
US9107405B2 (en) 2005-11-14 2015-08-18 Rhodia Operations Agricultural adjuvant compostions, pesticide compositions, and methods for using such compositions
CN105693613A (zh) * 2014-11-24 2016-06-22 天津博克尼科技发展有限公司 一种羟乙基油酸咪唑啉甜菜碱碘络合物的制造方法
CN111088123A (zh) * 2019-12-25 2020-05-01 广州立白企业集团有限公司 浓缩型液体洗涤剂组合物及其制备方法
WO2024149654A1 (fr) 2023-01-11 2024-07-18 Basf Se Utilisation d'amidopropyl bétaïnes d'acides gras insaturés comme épaississants
WO2024149652A1 (fr) 2023-01-11 2024-07-18 Basf Se Mélanges d'amidopropyl bétaïnes dérivés de mélanges d'acides gras comprenant des acides gras insaturés et des alkyl(én)yl (poly)glycosides

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EP0260205A2 (fr) * 1986-09-08 1988-03-16 Cotelle S.A. Composition de nettoyage d'installations sanitaires
GB2245281A (en) * 1990-05-29 1992-01-02 Kao Corp Less irritative detergent composition
WO1994024248A1 (fr) * 1993-04-20 1994-10-27 Henkel Corporation Composition liquide conferant un aspect nacre
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Cited By (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1197206A1 (fr) * 2000-08-29 2002-04-17 Cognis Deutschland GmbH Utilisation des esters de betaine comme agents epaississants
FR2850567A1 (fr) * 2003-02-03 2004-08-06 Oreal Composition cosmetique comprenant un amide cationique hydrogelifiant et un tensioactif
FR2850565A1 (fr) * 2003-02-03 2004-08-06 Oreal Composition cosmetique comprenant un amide hydrogelifiant et un polymere benefique
WO2004068998A3 (fr) * 2003-02-03 2004-09-16 Oreal Composition cosmetique comprenant un amide cationique hydrogelifiant et un tensioactif
WO2004068996A3 (fr) * 2003-02-03 2004-10-28 Oreal Composition cosmetique comprenant un amide ionique hydrogelifiant et un polymère benefique pour la chevelure
US9045720B2 (en) 2004-12-30 2015-06-02 Rhodia Chimie Herbicidal composition comprising an aminophosphate or aminophosphonate salt, a betaine and an amine oxide
US9107405B2 (en) 2005-11-14 2015-08-18 Rhodia Operations Agricultural adjuvant compostions, pesticide compositions, and methods for using such compositions
US20100069269A1 (en) * 2007-03-08 2010-03-18 Evelyne Prat Use of betaines as foaming agents and foam drainage reducing agents
US8222197B2 (en) 2010-03-12 2012-07-17 The Procter & Gamble Company Liquid detergent compositions comprising pH tuneable amido-gellants, and processes for making
WO2011112910A1 (fr) * 2010-03-12 2011-09-15 The Procter & Gamble Company Compositions détersives liquides comprenant des gélifiants d'amidon à ph réglable, et leurs méthodes de fabrication
WO2011112912A1 (fr) * 2010-03-12 2011-09-15 The Procter & Gamble Company Gélifiant d'amidon à ph réglable utilisable dans des compositions de produit de consommation
US8236748B2 (en) 2010-03-12 2012-08-07 The Procter & Gamble Company pH tuneable amido-gellant for use in consumer product compositions
EP2365052A1 (fr) * 2010-03-12 2011-09-14 The Procter & Gamble Company Compositions liquides de détergent comprenant des gélifiants amido à pH réglable et procédés de fabrication
EP2365053A1 (fr) * 2010-03-12 2011-09-14 The Procter & Gamble Company Compositions liquides de détergent comprenant des gélifiants amido à pH réglable et procédés de fabrication
US8841235B2 (en) 2010-08-10 2014-09-23 Rhodia Operations Agricultural pesticide compositions
CN105693613A (zh) * 2014-11-24 2016-06-22 天津博克尼科技发展有限公司 一种羟乙基油酸咪唑啉甜菜碱碘络合物的制造方法
CN111088123A (zh) * 2019-12-25 2020-05-01 广州立白企业集团有限公司 浓缩型液体洗涤剂组合物及其制备方法
CN111088123B (zh) * 2019-12-25 2021-06-25 广州立白企业集团有限公司 浓缩型液体洗涤剂组合物及其制备方法
WO2024149654A1 (fr) 2023-01-11 2024-07-18 Basf Se Utilisation d'amidopropyl bétaïnes d'acides gras insaturés comme épaississants
WO2024149652A1 (fr) 2023-01-11 2024-07-18 Basf Se Mélanges d'amidopropyl bétaïnes dérivés de mélanges d'acides gras comprenant des acides gras insaturés et des alkyl(én)yl (poly)glycosides

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