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WO1999048872A3 - Method for separating an azepine derivative from a mixture containing an amine and an azepine derivative - Google Patents

Method for separating an azepine derivative from a mixture containing an amine and an azepine derivative Download PDF

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Publication number
WO1999048872A3
WO1999048872A3 PCT/EP1999/001786 EP9901786W WO9948872A3 WO 1999048872 A3 WO1999048872 A3 WO 1999048872A3 EP 9901786 W EP9901786 W EP 9901786W WO 9948872 A3 WO9948872 A3 WO 9948872A3
Authority
WO
WIPO (PCT)
Prior art keywords
azepine derivative
amine
separating
mixture containing
azepine
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP1999/001786
Other languages
German (de)
French (fr)
Other versions
WO1999048872A2 (en
Inventor
Alwin Rehfinger
Hermann Luyken
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Priority to KR1020007010357A priority Critical patent/KR20010042021A/en
Priority to US09/623,699 priority patent/US6300497B1/en
Priority to AU34146/99A priority patent/AU3414699A/en
Priority to JP2000537855A priority patent/JP2002507602A/en
Priority to CA002323617A priority patent/CA2323617A1/en
Priority to EP99915652A priority patent/EP1064266A2/en
Priority to BR9908972-6A priority patent/BR9908972A/en
Publication of WO1999048872A2 publication Critical patent/WO1999048872A2/en
Publication of WO1999048872A3 publication Critical patent/WO1999048872A3/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D223/00—Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom
    • C07D223/02—Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom not condensed with other rings
    • C07D223/06—Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom not condensed with other rings with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D223/12—Nitrogen atoms not forming part of a nitro radical
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/44—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of carboxylic acids or esters thereof in presence of ammonia or amines, or by reduction of nitriles, carboxylic acid amides, imines or imino-ethers
    • C07C209/48—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of carboxylic acids or esters thereof in presence of ammonia or amines, or by reduction of nitriles, carboxylic acid amides, imines or imino-ethers by reduction of nitriles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/82—Purification; Separation; Stabilisation; Use of additives
    • C07C209/86—Separation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/32—Separation; Purification; Stabilisation; Use of additives
    • C07C253/34—Separation; Purification

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Other In-Based Heterocyclic Compounds (AREA)
  • Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)
  • Polyamides (AREA)

Abstract

The invention relates to a method for separating by distillation all or part of an azepine derivative (III) selected from the group consisting of amino hexylidenimine, tetrahydroazepine, hexylhexahydroazepine and amino hexylhexahydroazepine, from a mixture (II) containing an azepine derivative (III) and an amine (I). The invention is characterized in that the distillation is carried out at an overhead temperature of between 160 and 250 °C.
PCT/EP1999/001786 1998-03-20 1999-03-18 Method for separating an azepine derivative from a mixture containing an amine and an azepine derivative Ceased WO1999048872A2 (en)

Priority Applications (7)

Application Number Priority Date Filing Date Title
KR1020007010357A KR20010042021A (en) 1998-03-20 1999-03-18 Method for Separating an Azepine Derivative from a Mixture Containing an Amine and an Azepine Derivative
US09/623,699 US6300497B1 (en) 1998-03-20 1999-03-18 Method for separating an azepine derivative from a mixture containing an amine and an azepine derivative
AU34146/99A AU3414699A (en) 1998-03-20 1999-03-18 Method for separating an azepine derivative from a mixture containing an amine and an azepine derivative
JP2000537855A JP2002507602A (en) 1998-03-20 1999-03-18 Method for removing azepine derivative from mixture containing amine and azepine derivative
CA002323617A CA2323617A1 (en) 1998-03-20 1999-03-18 Method for separating an azepine derivative from a mixture containing an amine and an azepine derivative
EP99915652A EP1064266A2 (en) 1998-03-20 1999-03-18 Method for separating an azepine derivative from a mixture containing an amine and an azepine derivative
BR9908972-6A BR9908972A (en) 1998-03-20 1999-03-18 Process for distillation removal of part or all of an azepine derivative

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19812427.9 1998-03-20
DE19812427A DE19812427A1 (en) 1998-03-20 1998-03-20 Separation of azepine derivative for purification of amine, especially polyamide precursor

Publications (2)

Publication Number Publication Date
WO1999048872A2 WO1999048872A2 (en) 1999-09-30
WO1999048872A3 true WO1999048872A3 (en) 1999-12-02

Family

ID=7861784

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP1999/001786 Ceased WO1999048872A2 (en) 1998-03-20 1999-03-18 Method for separating an azepine derivative from a mixture containing an amine and an azepine derivative

Country Status (13)

Country Link
US (1) US6300497B1 (en)
EP (1) EP1064266A2 (en)
JP (1) JP2002507602A (en)
KR (1) KR20010042021A (en)
CN (1) CN1306514A (en)
AR (1) AR015246A1 (en)
AU (1) AU3414699A (en)
BR (1) BR9908972A (en)
CA (1) CA2323617A1 (en)
DE (1) DE19812427A1 (en)
ID (1) ID25865A (en)
TW (1) TW474921B (en)
WO (1) WO1999048872A2 (en)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10009384A1 (en) * 2000-02-29 2001-08-30 Basf Ag Process for reducing the content of an unsaturated imine in a mixture containing an imine and an amine
DE10010825A1 (en) * 2000-03-08 2001-09-13 Basf Ag Separation of azepine derivative from amine, especially for purifying 6-aminocapronitrile or hexamethylenediamine, comprises distillation at low temperature
US20020116644A1 (en) * 2001-01-30 2002-08-22 Galea Secured Networks Inc. Adapter card for wirespeed security treatment of communications traffic
US6887352B2 (en) * 2003-03-07 2005-05-03 Invista North America S.A.R.L. Distillative method for separating hexamethylenediamine from a mixture comprising hexamethylenediamine, 6-aminocapronitrile and tetrahydroazepine
US7060819B2 (en) * 2003-09-15 2006-06-13 Invista North America S.A.R.L. Process for producing hexamethylenediamine and aminocapronitrile from adiponitrile, wherein the hexamethylenediamine contains less than 100 ppm tetrahydroazepine
US7094528B2 (en) * 2004-06-30 2006-08-22 Kimberly-Clark Worldwide, Inc. Magnetic enzyme detection techniques
US7208632B2 (en) 2004-09-10 2007-04-24 Invista North America S.A R.L. Separation of 6-aminocapronitrile and hexamethylenediamine from a mixture comprising hexamethylenediamine, 6-aminocapronitrile and tetrahydroazepine
US7468119B2 (en) 2004-09-10 2008-12-23 Invista North America S.A.R.L. Separation of 6-aminocapronitrile and hexamethylenediamine from a mixture comprising hexamethylenediamine, 6-aminocapronitrile and tetrahydroazepine
FR2902425B1 (en) * 2006-06-20 2008-07-18 Rhodia Recherches & Tech PROCESS FOR PRODUCING PRIMARY DIAMINS
FR2922207B1 (en) * 2007-10-11 2009-12-04 Rhodia Operations PROCESS FOR PURIFYING HEXAMETHYLENE DIAMINE
HUE027861T2 (en) * 2007-11-14 2016-11-28 Covestro Deutschland Ag Preparation of light-colored isocyanates
CN104292112B (en) * 2014-10-16 2016-08-24 重庆紫光化工股份有限公司 A kind of isophorone diamine product separation method

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1993014064A1 (en) * 1992-01-06 1993-07-22 E.I. Du Pont De Nemours And Company Removal of tetrahydroazepine (tha) from 6-aminocapronitrile by reaction with reactive methylene compounds
WO1993016984A1 (en) * 1992-02-27 1993-09-02 E.I. Du Pont De Nemours And Company Purification of 6-aminocapronitrile
WO1996020931A1 (en) * 1995-01-05 1996-07-11 Basf Aktiengesellschaft Method of simultaneously preparing caprolactam and hexamethylene diamine
WO1998034900A1 (en) * 1997-02-07 1998-08-13 Basf Aktiengesellschaft Method for separating an imine from a mixture containing an amine and an imine

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2208598A (en) 1938-09-24 1940-07-23 Du Pont Aliphatic amino-nitriles and process of producing them
DE848654C (en) 1950-08-19 1952-09-08 Basf Ag Process for the preparation of partial hydrogenation products of adipic dinitrile
US2762835A (en) 1953-03-12 1956-09-11 Celanese Corp Preparation of amino nitriles
GB893709A (en) 1959-04-15 1962-04-11 Chemstrand Corp Method for the purification of hexamethylenediamine
US3193472A (en) 1963-01-07 1965-07-06 Monsanto Co Process for the purification of hexamethylenediamine
GB1238351A (en) 1968-01-17 1971-07-07
CA915707A (en) 1969-07-11 1972-11-28 J. Kershaw Bernard Hydrogenation of adiponitrile
US4601859A (en) 1984-05-04 1986-07-22 Allied Corporation Selective hydrogenation of aliphatic dinitriles to omega-aminonitriles in ammonia with supported, finely dispersed rhodium-containing catalyst
US5151543A (en) 1991-05-31 1992-09-29 E. I. Du Pont De Nemours And Company Selective low pressure hydrogenation of a dinitrile to an aminonitrile
DE4235466A1 (en) 1992-10-21 1994-04-28 Bayer Ag Prepn. of (cyclo)aliphatic amino:nitrile cpds. by catalytic redn. of di-nitrile - using iron sponge catalyst obtd. in redn. of iron ore and reduced in hydrogen, opt. after oxidn.
DE19548289A1 (en) 1995-12-22 1997-06-26 Basf Ag Process for the simultaneous production of caprolactam and hexamethylenediamine

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1993014064A1 (en) * 1992-01-06 1993-07-22 E.I. Du Pont De Nemours And Company Removal of tetrahydroazepine (tha) from 6-aminocapronitrile by reaction with reactive methylene compounds
WO1993016984A1 (en) * 1992-02-27 1993-09-02 E.I. Du Pont De Nemours And Company Purification of 6-aminocapronitrile
WO1996020931A1 (en) * 1995-01-05 1996-07-11 Basf Aktiengesellschaft Method of simultaneously preparing caprolactam and hexamethylene diamine
WO1998034900A1 (en) * 1997-02-07 1998-08-13 Basf Aktiengesellschaft Method for separating an imine from a mixture containing an amine and an imine

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
CHEMICAL ABSTRACTS, vol. 76, no. 5, 31 January 1972, Columbus, Ohio, US; abstract no. 24676, XP002117446 *
D.M. POPOV ET AL., OTKRYTIYA, IZOBRET., PROM. OBRAZTSY, TOVARNYE ZNAKI, vol. 48, no. 30, 1971, pages 237 *

Also Published As

Publication number Publication date
BR9908972A (en) 2000-12-05
US6300497B1 (en) 2001-10-09
ID25865A (en) 2000-11-09
DE19812427A1 (en) 1999-09-23
AR015246A1 (en) 2001-04-18
CA2323617A1 (en) 1999-09-30
AU3414699A (en) 1999-10-18
CN1306514A (en) 2001-08-01
KR20010042021A (en) 2001-05-25
TW474921B (en) 2002-02-01
WO1999048872A2 (en) 1999-09-30
JP2002507602A (en) 2002-03-12
EP1064266A2 (en) 2001-01-03

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