WO1998007891A1 - Method of manufacturing sintered ore and sintering machine therefor - Google Patents
Method of manufacturing sintered ore and sintering machine therefor Download PDFInfo
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- WO1998007891A1 WO1998007891A1 PCT/JP1997/002843 JP9702843W WO9807891A1 WO 1998007891 A1 WO1998007891 A1 WO 1998007891A1 JP 9702843 W JP9702843 W JP 9702843W WO 9807891 A1 WO9807891 A1 WO 9807891A1
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- WIPO (PCT)
- Prior art keywords
- raw material
- sintering
- packed bed
- material packed
- pressure
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B1/00—Preliminary treatment of ores or scrap
- C22B1/14—Agglomerating; Briquetting; Binding; Granulating
- C22B1/16—Sintering; Agglomerating
- C22B1/20—Sintering; Agglomerating in sintering machines with movable grates
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B1/00—Preliminary treatment of ores or scrap
- C22B1/14—Agglomerating; Briquetting; Binding; Granulating
- C22B1/16—Sintering; Agglomerating
- C22B1/20—Sintering; Agglomerating in sintering machines with movable grates
- C22B1/205—Sintering; Agglomerating in sintering machines with movable grates regulation of the sintering process
Definitions
- the present invention relates to a method and a sintering machine for producing a sintered ore, which is a raw material of a blast furnace production method, and more particularly to a method for transferring a combustion molten zone from the upper side to the lower side of a sintering pallet.
- the supply rate of the oxygen-containing gas is increased, the differential pressure is increased, the traveling speed of the combustion melting zone is extremely accelerated, the production rate is increased, and the product is increased.
- the present invention relates to a method for producing a sinter which improves quality and yield and a sintering machine therefor.
- Dwight toroid type sintering machines are widely used. This is done by adding a solvent such as limestone or silica stone, a fuel such as coke breeze, and water to the raw ore powder, mixing and granulating the mixture, and filling the mixture on a sintered pallet arranged in the shape of a villa.
- the sintering pallet is sequentially moved horizontally to ignite the surface of the packed bed in the ignition furnace, and then sucked from below to burn the fuel such as coke in the blended raw material
- the generated heat melts and solidifies the raw material ore, gradually moving the combustion zone from the surface layer to the lower layer and sintering it.
- the sintering time is about 20 to 40 minutes.
- the Dwight Toroids type sintering machine is a continuous type and is suitable for mass production because it is widely used. is there.
- Current Dowai toroid type sintering machine is increased in size, width 5 m X rather force is up to things like the length 1 00 m, the production rate is 34 ⁇ 43 t Z d Z m 2 approximately.
- the global resource situation there is a remarkable shortage of supply of lump ore, which is a raw material for the blast furnace manufacturing method, and the price of lump ore is increasing accordingly. Use is required.
- silica stone and serpentine, limestone, and coke breeze and anthracite added as fuel are added as auxiliary materials. It is better to reduce the amount, such as coke oven gas and pulverized coal, which is the fuel for ignition.
- the first half of the upper part of the strand is provided with the first half of the negative pressure
- the second half of the upper part of the strand is provided with the second half of the pressure
- By circulating the exhaust gas in the second half by the pressure in the first half and the negative pressure in the first half it is possible to reduce the amount of exhaust gas, reduce power costs and prevent a drop in productivity.
- the part to be sintered in the second half of the atmosphere is covered with a positive pressure hood, and the second half is sintered. The purpose is to remove the blower following the wind box and reduce the amount of exhaust gas by means of exhaust gas circulation equipment that minimizes equipment costs. No attempt was made to increase it to increase productivity.
- the sintering completion point in this method is in the early stage of the latter half of the hood, and on the strand in the remaining range of the latter half. I can only imagine that they are doing cooling in the country. Therefore, the sintering completion point is not as close as possible to the mining section, and the entire strand is not used to maximize the production rate.
- the purpose is to prevent pressurized air from flowing out into the atmosphere, and there is no mention of actively increasing the transfer speed of the sintering zone in the raw material packed bed to improve productivity.
- the suction flow rate at this location must be higher than the suction flow rate of the conventional method of sucking air. For this reason, the shortage of the high-temperature holding time in the baking of the upper layer of the raw material layer, which has been a problem in the past, is promoted, and the yield and quality of the upper layer of the raw material layer are deteriorated, so that the total productivity is greatly increased. It didn't make it.
- Japanese Patent Application Laid-Open No. 61-243131 discloses that “the upper surface of a sintered ore on an endless pallet is used in order to eliminate the need for a large hermetic housing required for the pressure sintering method. A cost can be reduced by providing a hood in the hood, forcing air into the hood, and creating a negative pressure in the wind box below the endless pallet. " However, the purpose is to reduce the total power of the conventional exhaust fan power combined with the push-in and exhaust fan power, and to increase the transfer speed of the combustion zone in the packed bed to increase productivity. No attempt was made to improve the quality of the project.
- the push-in fan and the exhaust fan are used.
- the current sintering machine exhausts the entire volume of the high-temperature air that has expanded in volume, while the room temperature air is pushed in and blown to reduce the total power, thereby improving productivity. It does not positively increase the transition speed of the combustion zone in the required raw material bed.
- Japanese Patent Publication No. 5-55574 discloses that “a plurality of wind boxes are divided in the longitudinal direction of the pallet, and the sintering raw material charged and laminated on the pallet is divided into a plurality of wind box groups.
- the suction negative pressure decreases in the early stage of the sintering reaction compared to the suction negative pressure in the normal operation, and increases in the middle period up to the end of the firing reaction.
- the yield, drop strength (SI) and RDI of the upper part of the sintering bed can be improved, and in addition, the exhaust power can be reduced.
- the sensible heat of the sinter can be recovered efficiently.
- the sinter in the upper part of the sintering bed has already improved the RDI and SI compared to the sinter in the lower part, and in order to further improve the quality of the entire sinter, 'It is more important to improve the sinter in the lower layer. Even if the yield in the upper part of the sintering bed can be improved, the quality of the sinter ore can be reduced, and the power consumption can be reduced somewhat, the balance of the air intake volume at the beginning, middle and late stages of sintering can be improved to save energy. Also There were also adverse effects such as lower yield in the middle part and lower SI in the lower part.
- the production rate of the sintering machine largely depends on the transition speed when the combustion zone in the raw material packed bed gradually transitions from the surface layer to the lower layer.
- the problem in improving the sintering production rate is that the sintering machine is in the process of firing from the upper layer to the lower layer of the raw material bed in the strand from the ignition section to the mining section. That is, the transition speed of the combustion melting zone is slow. Therefore, if the transition speed of the combustion melting zone is the same as before, increasing the layer thickness of the packed bed and the moving speed of the sintering pallet will increase the length of the sintering machine required to complete sintering. As the sintering time increases, the production rate does not increase.
- the transition speed of the combustion zone is too high, the amount of heat required for sintering cannot be secured due to insufficient coke combustion, which may lead to deterioration in yield and quality. Therefore, it is important to secure the heat required for the sintering reaction and to increase the transition speed of the combustion melting zone in order to greatly increase the production rate of the sintering machine. Furthermore, in the raw material bed, since the ventilation resistance of the combustion zone is large, if the thickness of the combustion zone in the height direction of the raw material bed is minimized, the air permeability is improved and coke combustion is performed. By increasing the speed, the transition speed of the combustion melting zone can be increased. Thus, controlling the cooling rate of the cooling zone above the combustion zone and the transition speed of the combustion zone in a well-balanced manner is also important for greatly improving the production rate of the sintering machine.
- the present invention is to reduce the thickness of the raw material packed layer and the moving speed of the sintered pallet. It is an object of the present invention to provide a method for producing a sintered ore, a method for producing a low SiO 2 sintered ore, and a sintering machine used for these methods, which can greatly increase the productivity of the sintering machine by increasing it.
- the gist of the present invention that achieves the above objects is as follows.
- a blended raw material containing raw material ore, a solvent and a fuel is charged on a sintering machine pallet to form a raw material packed bed, which is then ignited on the surface of the raw packed bed and lit from above.
- the mass flow rate of the oxygen-containing gas to be supplied to the raw material packed bed is determined when the upper layer of the raw material packed bed is sufficiently fired.
- the sintering is performed by changing the mass flow rate of the oxygen-containing gas supplied in the range of sintering the upper layer to 1.0 to 2.6 times, and sintering. Concentration production method.
- a pressurized hood for pressurizing an oxygen-containing gas is provided on the raw material packed bed on the sintered pallet, and the pressure in the pressurized hood is increased to 100 to 3000 mmAci with respect to the atmospheric pressure.
- a pressurized hood for supplying oxygen-containing gas under pressure within the range of 5 to 95% of the pressure is provided, and the inside of the pressurized hood is pressurized to 100 to 3000 dragon Aq against atmospheric pressure.
- the sinter production method according to any one of (1) to (3).
- a pressurized hood for pressurizing and supplying an oxygen-containing gas within a range of 5 to 95% of the width of the pallet is provided on the raw material packed layer on the sintered pallet.
- the sintering exhaust gas is circulated through a pressurized hood provided on the raw material packed layer and pressurized to supply an oxygen-containing gas, wherein (12) to (14).
- the sintering machine according to 1.
- FIG. 1 is a view showing an embodiment of a sintering machine according to Examples la and 3a of the present invention.
- FIG. 2 is a view showing an embodiment of a sintering machine according to Embodiment 1b of the present invention.
- FIG. 3 is a diagram showing an embodiment of a sintering machine according to Examples lc to le and 3b of the present invention.
- FIG. 4 is a diagram showing an embodiment of a sintering machine according to Examples 2a to 2d and 3c of the present invention.
- FIG. 5 is a view showing another embodiment of the sintering machine of the present invention.
- FIG. 6 is a view showing a sealing mechanism of a pressurized hood of the sintering machine according to the present invention.
- FIG. 7 is a view showing a plate-shaped thin cake supporting stand of the sintering machine according to the present invention. is there.
- FIG. 8 (a) is an explanatory diagram showing the transition of the combustion melting zone in the pallet according to the present invention.
- FIG. 8 (b) is a sectional view taken along the line AA ′ of the combustion melting zone in the pallet according to the present invention.
- FIG. 8 (c) is an explanatory diagram showing the transition of the combustion melting zone at the time of cooling on the strand according to the present invention.
- FIG. 8 (a) is an explanatory view showing one example of a raw material packed bed sintering process of the present invention.
- I is the initial raw material zone
- ⁇ is the wet (condensed water) zone
- m is the dry zone
- w is the combustion zone
- V is the melting zone
- VI is the sintering zone.
- FIG. 8 (b) is a sectional view taken along the line AA ′ in the center of FIG. 8 (a).
- point B indicates a position closest to the ignition furnace where an initial combustion melting zone is formed in the present invention and the supply amount of the oxygen-containing gas in the raw material packed bed is changed and increased
- point C is the combustion completion point. Is shown. In normal operation, operation is performed so that the sintering completion point is constant in order to use the entire strand efficiently and stably produce. When the production volume is important, the sintering completion point should be as close as possible to the mining side, and when yield and quality are to be emphasized, allowance for one or two wind boxes should be provided.
- the sintering completion point should be kept close to the ignition furnace side to keep the sintering constant.
- the operation where the sintering completion point C 'is changed to the middle part of the strand Is performed when cooling on a strand, for example, as shown in Fig. 8 (c), the operation where the sintering completion point C 'is changed to the middle part of the strand Is performed.
- the supply amount of the oxygen-containing gas may be changed based on the layer thickness or the position in the strand length direction based on the present invention disclosed below.
- an example is shown in which the sintering completion point is located at a position where the strand length is 95% from the ignition portion.
- the blowing or suction pressure is shown as the pressure with respect to the atmospheric pressure.
- the range of 30% or less of the strand length from the ignited part is almost equivalent to the firing area of the upper 20% of the raw material packed bed, and the yield and quality of the upper layer of the raw material packed bed are generally lower and middle. Inferior to. This is because the coke combustion rate, which gives the calorific value necessary for the calcination reaction, is not sufficient because it is just after ignition. In addition, it is due to the heat dissipated from the surface. Therefore, it is necessary to secure the amount of heat required for the sintering reaction.
- the range of 30% or less of the strand length from the ignition portion, which is the firing area in the upper layer of the raw material packed layer is less than the conventional range.
- the high temperature holding time of the upper part of the raw material packed bed can be secured, so that the yield and quality of the upper part of the raw material packed bed can be secured.
- the calorific value of the part may be increased.
- the suction negative pressure at the site it is preferable to lower the suction negative pressure at the site, to enhance the coke segregation at the upper part of the raw material packed layer, or to add a please to the surface layer.
- heat can be applied from the outside of the raw material packed layer. For example, hot air can be sucked into the portion, or induction heating by microwave or the like can be performed.
- the range of 30 to 95% of the strand length from the ignition part corresponds to the firing area in the lower part of the raw material packed bed.
- the sintered zone in the upper part of the raw material packed bed has low air resistance.
- the thickness of the combustion-melting zone having a high airflow resistance increases, so that the airflow resistance increases.
- the air permeability deteriorates and the calorific value becomes excessive.
- the mass flow rate of the oxygen-containing gas is forcibly supplied from above to the combustion zone with a large pressure loss in the range from the middle to the lower part (within the range of 30 to 95% of the strand length from the ignition part).
- the coke combustion rate in the middle to lower layers is increased, and the combustion melting zone is increased.
- the cooling speed of the cooling zone above the combustion melting zone is increased by increasing the cooling speed, and the calorie required for sintering is secured, and the thickness of the combustion melting zone is reduced and the air permeability is improved. in this way It is important to control the calorific value and air permeability depending on the temperature of the combustion melting zone and the thickness in the height direction of the raw material packed bed in order to improve the sintering production rate.
- the mass flow rate represents the mass of gas flowing per unit time, and the unit is expressed in kgZ s or the like.
- the generally used flow rate is a volume flow rate, which indicates the volume of gas flowing per unit time, and the unit is expressed in m 3 Z s or the like.
- the volume flow varies with temperature and pressure according to the equation of state of the gas.
- the oxygen-containing gas in the present invention includes not only the atmosphere but also the exhaust gas discharged from the sintering machine and the exhaust gas from other processes, etc., as well as the mixed gas of the atmosphere and the exhaust gas and the oxygen-enriched gas. It also contains gas, and gas with an oxygen concentration of 12 to 40 vol% is preferred.
- the mass flow rate of the oxygen-containing gas supplied to the raw material storage layer within the range of 30 to 95% of the length of the strand from the ignition part is set to the range of the raw material charge in the range of the strand excluding the above range.
- the reason why the mass flow rate of the oxygen-containing gas supplied to the ⁇ layer is adjusted to 1.01 to 2.6 times is that when the mass flow rate is less than 1.01 times, the transition speed of the combustion melting zone hardly changes. If it is more than 6 times, the gas flow velocity will increase too much and the combustion melting zone will be supercooled, or the raw material packed bed will be compacted due to the increase in the differential pressure above and below the raw material packed bed, and the gas permeability will be impaired.
- the mass flow rate of the oxygen-containing gas sucked into the raw material packed bed within the range of 50 to 85% of the length of the strand from the ignition part is adjusted to the range of the raw material filled in the range of the strand excluding the above range. It is particularly preferable to adjust the mass flow rate of the oxygen-containing gas supplied to the bed to 1.1 to 1.8 times from the viewpoint of improving the productivity of sinter.
- the length of the strand from the ignition part must be 30 to 95%.
- Thickness direction of raw material packed bed within the range Is preferably 1.1 to 5.0 times the pressure difference in the thickness direction of the raw material packed bed in the range of the strand excluding the above range.
- the ventilation resistance is about 1.5 to 5 times larger than that of the other range.
- the differential pressure is less than 1.1 times, the effect of promoting the transition speed of the combustion and melting zone by increasing the air flow rate is small, and if the differential pressure exceeds 5.0 times, the gas flow velocity becomes too large, and Since the speed is greatly increased, it becomes impossible to secure a high-temperature holding time, and the raw material packed layer is undesirably densified and the air permeability is deteriorated. Further, it is particularly preferable to increase the pressure difference to 1.2 to 2.0 times from the viewpoint of improving productivity. It is preferable that the gas supply is gradually increased from the ignition section to the ore removal section to make the transition speed of the combustion melting zone and the cooling speed close.
- the cooling rate will be faster than the coke burning rate for a short period of time, and some parts will not be able to maintain a sufficient amount of calcining heat. This is because the quality of the sinter is deteriorated.
- the mass flow rate is increased by increasing the differential pressure of the raw material bed within the range of 30 to 95% of the strand length from the ignition part, the production rate of sinter As well as improving the yield, it is possible to obtain products with excellent yield and quality. If the pressure difference is increased and the gas supply is increased, the amount of exhaust gas discharged from this part also increases in tandem with this. However, since the firing reaction is active and the oxygen consumption efficiency is high, the oxygen consumption efficiency may be reduced.
- the unit of airflow can be reduced by minimizing the supply of excess gas in the upper part and in the vicinity of the mining part.
- the present inventors avoid the deterioration of air permeability caused by the consolidation of the raw material packed bed by increasing the mass flow rate of the oxygen-containing gas by combining the downward suction of the raw material packed bed and the pressurization from above. Then, the mass flow rate of the oxygen-containing gas to be supplied to the raw material packed bed within the range of 30 to 95% of the length of the strand from the ignition section is reduced to the range of the raw material in the range of the strand excluding the above range.
- a pressurized hood is provided to cover the raw material packed bed loaded on the sintering pallet, the inside of the hood is pressurized, and oxygen-containing gas is blown from above to the raw material packed bed.
- the air is sucked and exhausted from the wind box just below the pallet, and the pressure difference between the upper part of the raw material packed bed and the lower part of the raw material packed bed is controlled. Let the gas flow.
- the static pressure in the raw material packed bed is higher than the static pressure in the raw material packed bed formed by suctioning the raw material packed bed from below at atmospheric pressure. Can be increased.
- the present invention can increase the mass flow rate to be supplied into the raw material packed bed compared to the conventional method.
- Gas density can be made higher than before.
- the supply amount of the oxygen-containing gas into the raw material packed bed increases, the coke burning rate in the raw material packed bed increases, the calorific value of the combustion zone increases, and the transition speed increases.
- the cooling zone transition speed increases. If the static pressure in the raw material packed bed increases, the heat transfer rate between the gas and the solid also increases, which can promote the transition of the combustion melting zone and the cooling of the cooling zone.
- gas can be supplied to the combustion melting zone where a reaction has occurred by forming a uniform gas flow through the sintered zone having low airflow resistance.
- gas when gas is supplied by suction from below, gas is subjected to relatively high ventilation resistance in the wet zone with relatively high ventilation resistance and the combustion and melting zone in which the calcination reaction is occurring. Flow, forming an uneven gas flow This is a state in which the reaction efficiency between the body and the solid tends to deteriorate. Therefore, the gas flow pushed in from above forms a more uniform gas flow than the gas flow sucked from below, so that the oxygen consumption efficiency is improved and the unit air volume required for sinter production can be reduced. .
- the pressure hood provided above the raw material packed bed must be 100 to 3000 mm.
- the suction negative pressure of the wind box just below the pallet is set in the range of 12000 to 1 mmAq, due to the setting of the differential pressure pattern above and below the raw material packed bed. If the pressure is less than 2000 mmAq, the static pressure level in the raw material bed will not be much higher than in the conventional method even if the upper part of the raw material bed is pressurized. The increase in heat transfer rate due to an increase in gas density is small. If it exceeds 1 nunAq, the exhaust gas cannot be sucked.
- the upper and lower sides of the raw material packed bed within the range of 30 to 95% of the strand length from the ignition part It is preferable that the pressure difference be between 1,000 and 3000 mmAq, which depends on the layer thickness and the pallet speed.
- the pressure difference between the upper and lower parts of the raw material bed is less than 1 000 Aq
- the pressure difference in the raw material bed is smaller than in the conventional method, and the gas flow rate is lower than the effect of increasing the static pressure. This is because the adverse effects increase.
- the strand length is within the range of 30 to 95% from the ignition section.
- the mass flow rate of the oxygen-containing gas sucked into the raw material bed in the above-mentioned range is 1.01 to 1.01 with respect to the mass flow rate of the oxygen-containing gas supplied to the raw material bed in the range of the strand excluding the above range. 2.
- the pressure difference in the layer thickness direction of the raw material packed bed is increased by a factor of 6 with respect to the pressure difference in the layer thickness direction of the raw material packed bed in the strand range excluding the above range. It can be easily adjusted by a factor of 0.
- the transition speed of the combustion zone cannot be increased from the current level.
- the area with a strand length of 30% or less from the ignition part is blown from the upper part of the raw material packed bed with 100 to 100 mmAq under pressure and directly below the pallet.
- the negative suction pressure for suction and exhaust from the wind box force is set to 11,000 to 11 mmAq, and the differential pressure between the upper and lower parts of the raw material bed is adjusted to 300 to 2,000 nnnAq to obtain the differential pressure of the conventional downward suction. If the pressure difference is the same or a small pressure difference, the high-temperature holding time can be secured or increased, and the calorific value required for firing can be obtained. At this time, the oxygen supply rate of the upper layer of the raw material packed bed is increased, so that the same effect of improving coke combustibility as oxygen enrichment can be obtained, and the yield and quality of the upper layer of the raw material packed bed can be improved. You can do more.
- the pressurized feed is moved from the ignition section to the It is preferable to set the length within a range of 30 to 95% in terms of simplification of equipment. Furthermore, if the pressurized hood is divided into a plurality of pieces in the length direction of the strand, the mass flow rate can be changed stepwise from the igniting section to the mining section.
- the transition speed of the combustion melting zone is high because the vicinity of the side wall within 5% in the pallet width direction from the pallet side wall of the raw material packed layer has less airflow resistance than the center part. For this reason, if a pressure hood is provided within the range of 5 to 95% of the width of the raw material packed bed and gas is supplied so that the transition speed of the combustion melting zone becomes uniform in the width direction, the combustion melting zone The effect of increasing the transition speed is even greater.
- the pressure hood is installed above the moving sintering pallet. It is preferable to provide a seal mechanism at the lower end of the pressure hood to avoid air leakage. As shown in FIG. 6, the sealing mechanism is such that the sheet 24 provided at the lower end of the hood is pressed against the upper surface of the raw material-filled layer 7 by the internal pressure of the pressurizing hood 19 to seal, A structure in which the pallet is slid on the raw material packed layer 7 as it moves is preferable. In addition, a structure having several stages of sealing mechanisms 23, a structure in which air is blown from the outside of the pressure hood 19 between the pressure hood 19 and the raw material packed layer 7, a side wall of the pallet 6, and the like are provided. It is also possible to provide a sealing mechanism by utilizing it, and it is not limited to these examples.
- the oxygen concentration should be between 12 and 21 in the pressurized hood in the range of 30-95% of the strand length from the igniter, and particularly preferably in the range of 60-80% of the strand length.
- Supplying a gas adjusted to less than vol% promotes the generation of magnetite that improves RD1 and suppresses the oxidation of nitrogen in coke to NOx, improving RDI and reducing NOx. It is effective in controlling the occurrence You.
- part of the exhaust gas from the sintering machine can be recycled.
- the capacity of the blower for exhaust gas circulation is designed by taking into account the suction negative pressure, the air flow, and the size of the equipment so that the air flow from the upper part of the raw material packed bed can be sent to the exhaust gas treatment equipment.
- the oxygen concentration is preferably 12 vol% or more and less than 21 vol%. In particular, when the oxygen concentration is less than 18 vol%, the effects of improving RDI and suppressing NOx generation become more remarkable.
- the optimal number of plate-shaped sinter cake support stands 21 depends on the size of the pallet 6, for example, a 4 m wide and 2 m long pallet. At the conclusion, it is 2 to 10 sheets and the height is preferably 200 to 400. The more the number of sinter cake support stands, the more the sinter cake support effect can be exhibited. However, if the number of sheets exceeds 10, the volume occupied by the sinter cake support stand will increase, and conversely, the adverse effect on the production rate will begin to appear, and the production rate will begin to decline. If the sinter cake is supported by the sinter cake support stand, breathability is improved.
- the amount of CO generated increases due to the increased coke combustion rate, and the reaction to reduce the generated NO with CO gas becomes more active, thereby suppressing the generation of NOx. .
- the present invention is of particularly useful for the production of low Si0 2 sinter containing Si0 2 3.9 ⁇ 4.9mass% is, Si0 2 is a call want underlying limestone blending ratio becomes below 4.9Mass% and a CaO Si0 2 of the influence of the reduction of slag main component begin to remarkable deterioration of the production rate and RD1, because can not improve the production rate and RD! exacerbated also by the present invention and is less than 3.9mass%.
- the mass flow rate of the oxygen-containing gas sucked into the raw material packed bed within the range of 30 to 95% of the length of the strand from the ignition section in the strand from the ignition section to the mining section can be increased up to 2.6 times the mass flow rate of the oxygen-containing gas sucked into the raw material packed bed in the range of the strand excluding the above range, so that the conventional layer thickness of 400 to 600 mm can be obtained.
- the moving speed of the sintering pallet can be increased 2.0 times or more compared to the conventional method.
- the thickness of the material-filled bed can be as large as 600 to 1500 mm, which is more than twice the conventional thickness, thereby increasing the production rate of the sintering machine up to 2.0 times the conventional sintering production rate. It has the tremendous effect of improving the production rate as well as improving the product yield and quality, and reducing the basic unit of exhaust gas flow rate.
- the production rate can be kept constant, and the product yield and sinter quality can be improved, and the exhaust gas flow rate can be reduced.
- a sintering machine used in the method for producing a sintered ore of the present invention a plurality of wind boxes at the lower part of a sintering strand are connected in parallel to a suction duct, and In addition to the conventional structure with a blower, a blower is added, and suction is performed from any point within the range of 30 to 95% of the suction duct length from the ignition section to the mining section, and the suction duct is used.
- the mass flow rate of the oxygen-containing gas supplied to the raw material packed bed within the range of 30 to 95% of the length of the strand from the ignition part is reduced by the range of the strand excluding the above range.
- 1.0 to 2.6 times the mass flow rate of the oxygen-containing gas to be sucked into the raw material bed, and the pressure difference in the thickness direction of the raw material bed except for the above range It can be adjusted to 1.1 to 5.0 times the pressure difference in the thickness direction of the raw material packed bed in the range of the command.
- the suction duct is divided into a range of 30 to 95% of the length of the strand from the ignition part and the remaining range, and the structure in which the blowers are installed independently is the mass flow rate and the differential pressure. It is preferable in terms of adjusting the position.
- three blowers may be provided for the front, middle and rear stages of the strand, the front and rear stages do not need to change the differential pressure, so the front and rear stages are connected to each other, and the strand length is 30 It is preferable to use two aircraft for the middle stage within the range of ⁇ 95% and for the other range.
- a hood is provided on the raw material bed to be pressurized, and the inside of the hood is pressurized and the pressure in the hood and the pressure in the window box below It is preferable to measure Further, it is desirable to provide a seal structure between the hood and the raw material packed bed and between the hood or the hood and the pallet.
- FIGS. 1 to 3 are views showing an embodiment of the sintering machine of the present invention.
- the sintering blended raw material 1 is continuously supplied from the surge hopper 2 to the pallet 6 via the drum feeder 3 and the raw material charging device 5, and is layered on the pallet 6 as a raw material filling layer 7. It is laminated.
- the sprocket 4 on the raw material supply side is rotated to move the pallet 6 at a predetermined speed, and at the same time, a plurality of wind boxes 8 and a main box provided below the pallet 6 are provided. 9, Intake by the blower 11 through the exhaust gas dust collector 10 and exhaust from the chimney 12.
- a sub duct 13 is connected to a part of the main duct 9, and the sub duct 13 is taken in by a blower 15 through an exhaust gas dust collector 14, and the exhaust gas is returned to the main duct 9. Exhaust gas taken in by the probe 15 can also be discharged from the chimney 12. Further, it is desirable that the main body 9 be provided with a damper 16 for adjusting the negative pressure in the duct.
- the ignition furnace 27 ignites the upper surface of the raw material packed bed 7 and controls the speed so that the raw material packed bed 7 on the pallet 6 completes the sintering reaction over the whole bed while reaching the mining section. Continuous operation is performed. Exhaust gas can be circulated to the pressurized hood 19 by the blower 18 from the front of the chimney 12, and air can be mixed at the same time. When pressurizing the inside of the pressurized hood 19, a seal mechanism 23 as shown in FIG. 6 is provided between the surface layer portion of the raw material packed bed and the lower end of the hood. Maintain internal pressure.
- the length in the pallet traveling direction and the length in the pallet width direction can be set freely. Further, in this apparatus, the thickness of the raw material-filled layer 7 can be 600 to 1500 mm, which makes it possible to make the raw material-filled layer 7 thicker than before.
- Blending raw materials, without particular for the manufacture of a low Si0 2 sinter one conventional As a general formulation, various iron ore and limestone, quicklime, serpentinite, miscellaneous raw materials such as scale, return ores, Si0 2 is 5.8Mass% in sinter coke breeze, A 1 2 0 3 was adjusted to 1.8 mass%, and the basicity was adjusted to 1.7. The return ratio was set at 15% based on the total of 100 new materials, and the coke ratio was set at 4.2% based on the total of 100 new materials. The same formulation was used for both the comparative example and the example.
- Example 1a the layer thickness was 550 hidden, the length of the strand from the ignition section was 30%, and the length from the strand length of 95% to the mining section was 1500 mmAq.
- the air was sucked downward at a pressure of 2500 mmAq between 30 and 95%, and the upper part of the raw material packed bed was opened to the atmosphere.
- the mass flow ratio was 1.26 and the differential pressure in the layer thickness direction was 2500 Aq in the other range within the range of the strand length of 30 to 95%.
- Example 1b the layer thickness was 550 mm, the area from the ignition section to the mining section was suctioned downward at -1000 mmAq, and the pressurized hood on the upper portion of the raw material packed bed having a strand length of 30 to 95% was drawn. The inside was pressurized to 1500 mmAq. In this case, the mass flow ratio was 1.27 and the differential pressure in the layer thickness direction was 2500 mmAq in the range of the strand length of 50 to 95% with respect to the other range.
- Example 1c the layer thickness was 550 mm, the length from the ignition section was 30% of the strand length, and the section from the 95% strand length to the mining section was suctioned downward at -500 mmAq.
- the pressure hood is further continued and the pressure in the pressure hood is increased to 500 Aq.
- the pressure in the pressure hood was increased to 2000 mniAq.
- the mass flow ratio is 1.77 and the pressure difference in the layer thickness direction is 3000 when the strand length is within the range of 30 to 95%. Aq.
- Example 1d the layer thickness was 550 nim, the area from the ignition section to the mining section was suctioned downward at a rate of 1000 mniAq, and a pallet width direction of 50 to 90% strand length 1 () to 90% Exhaust gas before the chimney was circulated in the pressure hood provided in the range, and the oxygen concentration was adjusted to 18 vol% and pressurized to 1500 mmAq.
- the mass flow rate ratio was 1.27 and the differential pressure in the thickness direction was 2500 dragon Aq in the range of 50 to 90% of the strand length.
- Example 1e four layers of plate-shaped skeleton supporters were installed evenly in the pallet width direction in parallel on the pallet with a layer thickness of 550 mm, and the distance from the ignition part to the mining part was -1000. Suction was performed using Aq, and the inside of a pressure hood provided in the range of 10 to 90% in the pallet width direction with a strand length of 5 () to 90% was pressurized to 1500 mmAq. In this case, the mass flow ratio was 1.27 and the differential pressure in the thickness direction was 2500 face Aq in the range of 50 to 90% of the strand length.
- Example 1f the layer thickness was 800 ⁇ , and other settings were the same as in Example 1e.
- the mass flow ratio was 1.27 and the differential pressure in the layer thickness direction was 2500 mmAq in the range of the strand length of 50 to 90% with respect to the other range.
- the same compounding material as in the example was sintered by the conventional method in which the atmosphere was sucked from the ignition section to the mining section at a constant layer thickness of 550 and a negative pressure of 1500 minAq. did.
- Table 1 shows the production rates, product yields, RD1, and NOx emissions per unit of the sintered ore obtained in Comparative Example 1 and Examples 1a to 1f.
- the basic unit of NOx emission is represented by the product of the exhaust gas flow rate and the NOx concentration in the exhaust gas.
- the production rate was significantly improved as compared with the comparative example.
- the product yield tends to decrease, but in the present invention, the product yield is improved.
- the RD1, J1S-RKJIS standard (final reduction rate) and the basic unit of NOx emission were also improved, and excellent operational and environmental effects were achieved.
- FIGS. 4 and 5 show another embodiment of the sintering machine of the present invention.
- the difference from the embodiment shown in FIGS. 1 and 3 is that the main duct 9 is completely removed. It is divided into independent blowers 11 and 15.
- a blower 29 can be provided. When setting a plurality of pressure patterns in the direction of the strand length, a plurality of blowers may be provided in this manner.
- the blending raw materials were the same as in Example 1, and the operation was adjusted for the pallet speed so that the sintering completion point was in the mining part.
- Example 2a the layer thickness was 550 ⁇ , the length from the ignition part to the strand length of 50% was 1 lOOmmAq, and the distance from the ignition part to the strand length of 80% to the tailing part was 1500mmAq, and was lower at 1500mmAq. Suction is performed to open the upper part of the raw material packed bed to the atmosphere, and the lower part of the strand length of 50 to 80% is suctioned at -500 mmAq, and the pressure in the pressurized hood is set to 2000 mmAq. Pressed. In this case, if the strand length is within the range of 50 to 80%, the mass flow rate is The ratio was 1.52, and the differential pressure in the thickness direction was 2500 mmAq.
- Example 2b the layer thickness was 550 mm, the length from the ignition section to 50% of the strand length was suctioned downward at 1 500 mmAq, and a pressure hood was further provided in this range.
- the pressure in the pressurized hood was set to 500 mmAq, the pressure from the strand length of 80% to the mining part was reduced by 1000 Aq, and the pressure in the hood was set to 500 mmAq.
- Downward suction was performed at 1500 mmAq between strand lengths of 50-80%, and the pressure in the pressure hood was increased to 100 mmAq.
- the mass flow ratio was 1.56 and the pressure difference in the thickness direction was 2500 mm Aq in the range of 50 to 80% of the strand length.
- Example 2c the layer thickness was 800 mm, and other settings were the same as in Example 2a. In this case, the mass flow ratio was 1.52 and the differential pressure in the layer thickness direction was 2500 mmAq in the range of 50 to 80% of the strand length c.
- Example 2d the layer thickness was set to 800, and four plate-like sinter cake support stands were installed on the pallet evenly in the width direction of the pallet. Same as a. In this case, the mass flow ratio was 1.52 and the differential pressure in the layer thickness direction was 2500 mmAq in the range of the strand length of 50 to 80%, compared to the other range.
- Comparative Example 1 the same blended raw material as in Examples 2a to 2d was suctioned from the ignition section to the mining section at a layer thickness of 550 ⁇ and a negative pressure of 1500 Aq, and the inside of the blended raw material layer was baked at a negative pressure. Sintered by conventional methods.
- Table 2 shows the production rate, product yield, RDI, and NOx emission rate of the sintered ore obtained in Comparative Example 1 and Examples 2a to 2d.
- the production rates of Examples 2a to 2d were remarkably improved as compared with the comparative examples.
- the product yield tends to decrease, but in the present invention, the product yield is also improved.
- RD and JI The unit emissions of S-RI and NOx have also been improved, and excellent operational and environmental benefits have been achieved.
- Example 2d of the present invention has extremely excellent characteristics as the characteristics of the sintered ore that surpasses the values of the known technology.
- Example 3a a layer thickness of 550 mni, a stroke length of 60% from the ignition part, and a stroke length of 80% from the strand length to the mining part were suctioned downward at ⁇ 1500 mmAq.
- the air was suctioned by suctioning downward at 1,500 mm (1) between the strand lengths of 60-80%.
- the mass flow ratio was 1.26 and the pressure difference in the thickness direction was 2500 Aq.
- Example 3b the thickness of the layer was 550 mm, the initial firing period from the ignition portion to the strand length of 60%, and the final firing period from the strand length of 80% to the mining portion was-1500 mmAq.
- the mass flow ratio was 1.38 within the range of the strand length of 60 to 80% and the pressure difference in the thickness direction was 2500 mmAq.
- Example 3c the layer thickness was 550 mm, the strand length from the ignition section was 60%, and the strand length from 80% to the mining section was suctioned downward at -500 mmAq.
- a pressure hood is further provided in the pressure hood, the pressure in the pressure hood is set to 500 mmAq, and a pressure of 1500 mmAq is drawn downward between a strand length of 60 to 80% and pressurized.
- the pressure inside the hood at 100 mmAq, a part of the exhaust gas before the chimney was blown under pressure with the oxygen concentration adjusted to 16%.
- the mass flow ratio was 1.56 and the differential pressure in the thickness direction was 2500 mmAq in the range of the strand length of 60 to 80% with respect to the other range.
- Comparative Example 2 the same compounding raw material as in Examples 3a to 3c was used with a layer thickness of 550 ⁇ and a negative The atmosphere was sucked from the ignition section to the mining section at a constant pressure of 1500 imnAq, and the inside of the mixed material layer was sintered by a conventional method of sintering at a negative pressure.
- Table 3 shows the production rates, product yields, RD1 and NOx emission basic units of the sintered ore obtained in Comparative Example and Examples 3a to 3c.
- the production rate was significantly improved as compared with the comparative example.
- the product yield tends to decrease, but in the present invention, the product yield is also improved.
- Et al is, RDI, JIS-RI and NOx emissions per unit is also improved, as well as an excellent effect in operation plane and environmental, it could manufacture a low Si0 2 sinter.
- the setting of the negative pressure during sintering, the oxygen concentration of the suction gas, and the suction time are not limited to those in the above-described embodiment.
- Productivity orientation, RDI, J1S-RI improvement orientation, NOx emission reduction orientation, exhaust gas volume reduction Can be changed by pointing o
- the layer thickness of the compounding material packed bed which had been difficult conventionally can be increased greatly, and the pallet moving speed can be increased, and the production rate of the sintering machine can be greatly improved.
- the product yield and RD for JIS-RI are improved, and the amount of exhaust gas is reduced.
- the present invention simultaneously provides an incompatible improvement effect, and the effect is extremely large.
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Abstract
Description
明 細 書 焼結鉱の製造方法およびその焼結機 技術分野 Description Sinter production method and sintering machine
本発明は高炉製造法の原料である焼結鉱を製造する方法及び焼結 機に関し、 特に焼結層のパレッ ト上方から下方に向かって燃焼溶融 帯を移行させる際に、 所定の厚み方向の焼結層を得た後に、 酸素含 有ガスの供給量を増大して、 差圧を増加させて前記燃焼溶融帯の移 行速度を極端に加速し、 生産率を増大するとと もに成品の品質およ び歩留りを向上する焼結鉱の製造方法およびその焼結機に関する。 従来の技術 The present invention relates to a method and a sintering machine for producing a sintered ore, which is a raw material of a blast furnace production method, and more particularly to a method for transferring a combustion molten zone from the upper side to the lower side of a sintering pallet. After obtaining the sintered layer, the supply rate of the oxygen-containing gas is increased, the differential pressure is increased, the traveling speed of the combustion melting zone is extremely accelerated, the production rate is increased, and the product is increased. The present invention relates to a method for producing a sinter which improves quality and yield and a sintering machine therefor. Conventional technology
鉄鉱石の焼結に関しては、 ドワイ トロイ ド式焼結機が広く用いら れている。 これは、 原料粉鉱石に石灰石ゃ珪石等の溶剤と粉コーク ス等の燃料と水とを加えて混合、 造粒した配合原料を、 キヤタ ビラ 状に配列した焼結パレッ ト上に充塡して原料充塡層を形成し、 焼結 パレツ トを順次水平移動して、 点火炉内で充塡層の表面に点火した 後、 下方から吸引して、 配合原料内のコークス等の燃料を燃焼させ 、 発生した熱で原料粉鉱石を溶融、 凝固し、 燃焼帯を漸次表層部か ら下層部に移行させて焼結するもので、 焼結時間は 20〜40分程度で あ O For sintering iron ore, Dwight toroid type sintering machines are widely used. This is done by adding a solvent such as limestone or silica stone, a fuel such as coke breeze, and water to the raw ore powder, mixing and granulating the mixture, and filling the mixture on a sintered pallet arranged in the shape of a villa. The sintering pallet is sequentially moved horizontally to ignite the surface of the packed bed in the ignition furnace, and then sucked from below to burn the fuel such as coke in the blended raw material The generated heat melts and solidifies the raw material ore, gradually moving the combustion zone from the surface layer to the lower layer and sintering it.The sintering time is about 20 to 40 minutes.
グリ一ナヮルド式焼結機等のような他の回分式焼結機に比べて、 ドワイ トロイ ド式焼結機は連続式であり、 大量生産に適しているの が広く用いられている理由である。 現在の ドワイ トロイ ド式焼結機 は大型化しており、 幅 5 m X長さ 1 00 mといったものまである力く、 生産率は 34 ~ 43 t Z d Z m 2 程度である。 こ こで、 世界的な資源事情を鑑みると、 高炉製造法の原料となる 塊鉱石の供給量不足が顕著となつており、 これに伴い塊鉱石の価格 も増大する一方なので、 粉鉱石の多量使用が求められている。 ただ し、 焼結鉱の生産量を増大するために、 焼結機を増設したり、 ある いは焼結機を更に大型化すると多額の設備投資が必要になるばかり でなく、 排出される排ガス量が増加し環境上も好ま しく ない等の問 題が起こる。 このため、 焼結機の生産性向上が強く求められている 。 ただし、 焼結鉱の製造は、 高炉製造法から要求される成品焼結鉱 の品質を維持して生産率を最大とすると共に、 燃料原単位と点火燃 料原単位は最小と し、 NOx 排出を極力抑制するような操業が求めら れる。 従って、 実際の操業では、 焼結鉱の品質を維持する範囲内で 、 副原料と して添加している珪石ゃ蛇紋岩、 石灰石、 燃料と して添 加している粉コークスゃ無煙炭などの量、 点火時の燃料であるコー クス炉ガスゃ微粉炭などの量は少なくする方が良い。 Compared to other batch type sintering machines such as a green type sintering machine, the Dwight Toroids type sintering machine is a continuous type and is suitable for mass production because it is widely used. is there. Current Dowai toroid type sintering machine is increased in size, width 5 m X rather force is up to things like the length 1 00 m, the production rate is 34 ~ 43 t Z d Z m 2 approximately. Considering the global resource situation, there is a remarkable shortage of supply of lump ore, which is a raw material for the blast furnace manufacturing method, and the price of lump ore is increasing accordingly. Use is required. However, increasing the number of sintering machines or increasing the size of sintering machines in order to increase the production of sinter ore requires not only large capital investment but also exhaust gas emissions. Problems such as the increase in volume and the unfavorable environment occur. For this reason, there is a strong demand for improved productivity of sintering machines. However, in the production of sintered ore, the production rate is maximized while maintaining the quality of the product sintered ore required by the blast furnace production method, the unit fuel consumption and the unit ignition fuel are minimized, and NOx emissions are reduced. It is required to operate the plant as much as possible. Therefore, in the actual operation, as long as the quality of the sinter is maintained, silica stone and serpentine, limestone, and coke breeze and anthracite added as fuel are added as auxiliary materials. It is better to reduce the amount, such as coke oven gas and pulverized coal, which is the fuel for ignition.
ところが、 いたずらに焼結原料への副原料や燃料の配合割合、 点 火燃料の量を下げても良い結果が得られるものではなく 、 それらを 大幅に低下させると焼結鉱の冷間強度や RD I (還元粉化率) を悪化 させたり、 返鉱が多く なつて、 むしろ燃料原単位や点火燃料原単位 の悪化を引き起こ し、 さ らに NOx 転換率が悪化して NOx 排出量は逆 に増加することになる。 また、 焼結鉱の S i 02を 5. Omas s %以下に低 下させると、 RD 1が大きく悪化することもよく知られている。 However, good results cannot be obtained by unnecessarily reducing the mixing ratio of the auxiliary material and the fuel to the sintering raw material and the amount of the ignition fuel. Deterioration of RDI (reduced pulverization rate) and return of minerals increased, which in turn led to deterioration of fuel consumption and ignition fuel consumption. Furthermore, NOx conversion rate worsened and NOx emissions decreased. Conversely, it will increase. Also, the S i 0 2 sinter 5. when the Omas s% or less in the low made, is also well known that the RD 1 is deteriorated greatly.
特公昭 55- 19299号公報には、 「ス トラン ド上部の前半部に負圧の 前半フー ド部を設け、 ス トラ ン ド上部の後半部に加圧の後半フー ド 部を設けて、 後半部の加圧力と前半部の負圧力により後半部の排ガ スを循環すれば、 排ガス量を減らすとともに、 電力費の低減、 生産 性の低下を防止できる」 ことが開示されている。 しかし、 この方法 は後半部の大気で焼結させる部分を正圧用フ一 ドで被い、 後半部の ウィ ン ドボッ クスに続く ブロア一を除去し、 設備費を極力抑えた排 ガス循環設備により排ガス量を低減させるのが目的であり、 原料充 塡層内の燃焼溶融帯の移行速度を積極的に増大させ生産性の向上を 図ることなどは何ら言及されていないものであった。 さ らに、 開示 された排ガス組成や、 排ガス特性、 図面などから、 この方法におけ る焼結完了点は後半フ— ド部の初期であり、 後半部の残りの範囲で ス トラ ン ド上でのクーリ ングを行つていると しか考えられない。 従 つて、 焼成完了点を極力排鉱部に近づけてス トラ ン ド全体を使って 生産率を最大とするものではない。 In Japanese Patent Publication No. 55-19299, "The first half of the upper part of the strand is provided with the first half of the negative pressure, the second half of the upper part of the strand is provided with the second half of the pressure, By circulating the exhaust gas in the second half by the pressure in the first half and the negative pressure in the first half, it is possible to reduce the amount of exhaust gas, reduce power costs and prevent a drop in productivity. " However, in this method, the part to be sintered in the second half of the atmosphere is covered with a positive pressure hood, and the second half is sintered. The purpose is to remove the blower following the wind box and reduce the amount of exhaust gas by means of exhaust gas circulation equipment that minimizes equipment costs. No attempt was made to increase it to increase productivity. Furthermore, based on the disclosed exhaust gas composition, exhaust gas characteristics, drawings, etc., the sintering completion point in this method is in the early stage of the latter half of the hood, and on the strand in the remaining range of the latter half. I can only imagine that they are doing cooling in the country. Therefore, the sintering completion point is not as close as possible to the mining section, and the entire strand is not used to maximize the production rate.
特公昭 56 - 1 9556号公報には、 「加圧焼結ゾーンを形成する正圧フ 一ドを設けるとともに、 該正圧フ一 ドの給排鉱側端部に吸引により 負圧ゾーンを形成する負圧フー ドを設ければ、 設備全体を覆う気密 ハウジングを要せずに加圧焼結法により生産性及び操業コス トを改 善できる」 ことが開示されている。 しかし、 この方法は従来の加圧 焼結法における問題点である、 焼結パレッ 卜の移動経路上でのハウ ジング内への原料供給始端部及びハウジング内からの焼結鉱の搬出 端部における加圧空気の大気中への流出を防止することが目的であ り、 原料充填層内の焼結帯の移行速度を積極的に増大させ生産性の 向上を図ることなどは何ら言及されていないものであった。 また、 給鉱側端部に吸引による負圧ゾーンを形成するためには、 この部位 の吸引流速を従来の大気を吸引する方法の吸引流速より も大き く し なければならない。 このために、 従来から問題であった原料層上層 部の焼成における高温保持時間の不足を助長してしまい、 原料層上 層部の歩留り、 品質を悪化させるので、 トータルの生産性を大き く 増大させるものではなかった。 In Japanese Patent Publication No. 56-19956, "A positive pressure hood for forming a pressure sintering zone is provided, and a negative pressure zone is formed by suction at an end of the supply and discharge side of the positive pressure hood. If a negative pressure hood is provided, productivity and operating costs can be improved by the pressure sintering method without requiring an airtight housing that covers the entire equipment. " However, this method is a problem in the conventional pressure sintering method, in which the starting point of raw material supply into the housing on the moving path of the sintering pallet and the end of sintering ore discharging from the housing are performed. The purpose is to prevent pressurized air from flowing out into the atmosphere, and there is no mention of actively increasing the transfer speed of the sintering zone in the raw material packed bed to improve productivity. Was something. In addition, in order to form a negative pressure zone by suction at the end of the feeder side, the suction flow rate at this location must be higher than the suction flow rate of the conventional method of sucking air. For this reason, the shortage of the high-temperature holding time in the baking of the upper layer of the raw material layer, which has been a problem in the past, is promoted, and the yield and quality of the upper layer of the raw material layer are deteriorated, so that the total productivity is greatly increased. It didn't make it.
特開昭 6 1— 243 131号公報には、 「加圧焼結法に必要な大型の気密 ハウジングを不用とするために、 無端状パレツ ト上の焼結鉱の上面 にフー ドを設け、 フー ド内に空気を押し込み、 無端状パレッ ト下の 風箱内を負圧にすればコス 卜の低減を図ることができる」 ことが開 示されている。 しかし、 従来の排気フ ァ ンの電力に対して、 押し込 みと排気フ ァ ンを合わせた トータル電力の削減が目的であり、 原料 充塡層内の燃焼帯の移行速度を増大させ生産性の向上を図ることな どは何ら言及されていないものであった。 つまり、 点火部から排鉱 部までのス トラン ド全体において、 プロセスに必要な空気圧である 原料充塡層上部と下部の差圧を一定条件とするために押し込みフ ァ ンと排気フ ァ ンをバラ ンスさせて、 現行の焼結機が体積膨張した高 温空気を全量排気しているのに対し、 室温空気を押し込み送風する ことで トータル電力の低減を図るものであって、 生産性向上に必要 な原料充塡層内の燃焼帯の移行速度を積極的に増大させるものでは ない。 Japanese Patent Application Laid-Open No. 61-243131 discloses that “the upper surface of a sintered ore on an endless pallet is used in order to eliminate the need for a large hermetic housing required for the pressure sintering method. A cost can be reduced by providing a hood in the hood, forcing air into the hood, and creating a negative pressure in the wind box below the endless pallet. " However, the purpose is to reduce the total power of the conventional exhaust fan power combined with the push-in and exhaust fan power, and to increase the transfer speed of the combustion zone in the packed bed to increase productivity. No attempt was made to improve the quality of the project. In other words, in order to maintain a constant pressure difference between the upper and lower parts of the raw material bed, which is the air pressure required for the process, in the entire strand from the ignition part to the exhaust part, the push-in fan and the exhaust fan are used. By balancing, the current sintering machine exhausts the entire volume of the high-temperature air that has expanded in volume, while the room temperature air is pushed in and blown to reduce the total power, thereby improving productivity. It does not positively increase the transition speed of the combustion zone in the required raw material bed.
特公平 5 - 55574 号公報には、 「パレッ ト長手方向に複数の風箱 を区分して、 該区分された複数の風箱群単位に該パレツ ト上に装入 積層された焼結原料の焼結反応に対応して、 吸引負圧を焼結反応の 初期においては通常操業の吸引負圧に比較して減少し、 焼成反応終 了点に到る中期においては増加し、 該焼成反応終了点付近からの終 期においては減少するように制御すれば、 焼結べッ ド上層部の歩留 り、 落下強度 (S I ) 、 RD Iが向上し、 それに加えて排風電力を削減 することと焼結鉱顕熱を効率的に回収することができる」 ことが開 示されている。 しかし、 焼結べッ ド上層部の焼結鉱は、 下層部の焼 結鉱より RD I及び S Iはすでに改善されており、 焼結鉱全体の品質を より改善するには、 焼結べッ ド中 ' 下層部の焼結鉱を改善すること の方が重要である。 また、 焼結べッ ド上層部の歩留り改善と焼結鉱 の品質改善、 電力原単位低減が多少できても、 焼成の初期と中期と 後期の大気吸引する風量のバラ ンスを改善し省エネルギーを図るも のであり、 中層部での歩留り低下、 下層部で S I 低下が見られるな どの悪影響もあった。 Japanese Patent Publication No. 5-55574 discloses that “a plurality of wind boxes are divided in the longitudinal direction of the pallet, and the sintering raw material charged and laminated on the pallet is divided into a plurality of wind box groups. In response to the sintering reaction, the suction negative pressure decreases in the early stage of the sintering reaction compared to the suction negative pressure in the normal operation, and increases in the middle period up to the end of the firing reaction. By controlling so as to decrease at the final stage from the vicinity of the point, the yield, drop strength (SI) and RDI of the upper part of the sintering bed can be improved, and in addition, the exhaust power can be reduced. The sensible heat of the sinter can be recovered efficiently. " However, the sinter in the upper part of the sintering bed has already improved the RDI and SI compared to the sinter in the lower part, and in order to further improve the quality of the entire sinter, 'It is more important to improve the sinter in the lower layer. Even if the yield in the upper part of the sintering bed can be improved, the quality of the sinter ore can be reduced, and the power consumption can be reduced somewhat, the balance of the air intake volume at the beginning, middle and late stages of sintering can be improved to save energy. Also There were also adverse effects such as lower yield in the middle part and lower SI in the lower part.
また、 焼結鉱の顕熱回収エネルギーを増大するためには、 焼成終 期の成品焼結鉱の温度を増大させる必要があり、 原料充塡層内の赤 熱帯( 燃焼溶融帯) の高さ方向の幅を増大させなければならない。 このため、 該赤熱帯の通気抵抗は非常に大き く なり、 生産率を大き く支配する赤熱帯の移行速度を増すことが出来ず、 焼成終期の生産 率を逆に悪化させるなどの悪影響を及ぼし、 トータルと しての生産 率の大幅な向上は期待できないものであった。 In order to increase the sensible heat recovery energy of the sinter, it is necessary to increase the temperature of the product sinter at the end of sintering, and the height of the red tropical zone (combustion melting zone) The width in the direction must be increased. For this reason, the ventilation resistance of the red tropics becomes extremely large, and the transition speed of the red tropics, which largely controls the production rate, cannot be increased, which adversely affects the production rate at the end of firing. However, a significant increase in the total production rate could not be expected.
さ らに、 焼成反応の中期において生産率を確保するために吸引負 圧を増加するとあるが、 開示されている説明図によると、 排ガス風 量は中期において焼成前期に近いところは、 負圧を従来法より増し ているにも関わらす小さ く なっているなど、 トータルの生産率を大 き く増大させるものではないと考えられる。 発明の開示 Furthermore, in order to secure the production rate in the middle stage of the firing reaction, the suction negative pressure is increased.According to the disclosed explanatory diagram, the exhaust gas flow rate in the middle It is thought that this does not significantly increase the total production rate, as it is smaller than the conventional method. Disclosure of the invention
前記従来の技術は、 いずれも設備面の経済性、 操業コス トを改善 しょう とするものである。 従って、 いずれも配合原料を焼結パレッ ト上に層厚 400〜 600mni程度に充填し、 点火炉にて配合原料中の燃 料に着火する現状の操業条件を前提にしている。 All of the above-mentioned conventional technologies are intended to improve the economical efficiency of equipment and the operating cost. Therefore, in all cases, it is assumed that the mixed raw material is filled on the sintering pallet to a thickness of about 400 to 600 mni, and that the fuel in the raw material is ignited in the ignition furnace under the current operating conditions.
焼結機の生産率は、 原料充填層内の燃焼溶融帯が表層部から漸次 下層部に移行するときの移行速度に大き く依存する。 焼結の生産率 を向上する上で問題となるのは、 焼結機は点火部から排鉱部までの ス トラ ン ド内で原料充塡層の上層から下層までを焼成する過程にお いて、 燃焼溶融帯の移行速度が遅いという ことである。 従って、 燃 焼溶融帯の移行速度が従来と同じであれば、 充塡層の層厚や焼結パ レツ トの移動速度を増加させると、 焼結完了に必要な焼結機の長さ 及び焼結時間が増加するので、 生産率は向上しない。 The production rate of the sintering machine largely depends on the transition speed when the combustion zone in the raw material packed bed gradually transitions from the surface layer to the lower layer. The problem in improving the sintering production rate is that the sintering machine is in the process of firing from the upper layer to the lower layer of the raw material bed in the strand from the ignition section to the mining section. That is, the transition speed of the combustion melting zone is slow. Therefore, if the transition speed of the combustion melting zone is the same as before, increasing the layer thickness of the packed bed and the moving speed of the sintering pallet will increase the length of the sintering machine required to complete sintering. As the sintering time increases, the production rate does not increase.
また、 燃焼溶融帯の移行速度を大き く し過ぎると、 コークスの燃 焼不足を引き起すこ となどから焼成に必要な熱量を確保できないの で、 歩留りや品質の悪化を招く原因になる。 従って、 焼成反応に必 要な熱量を確保するとともに、 燃焼溶融帯の移行速度を大き くする ことが、 焼結機の生産率を大幅に向上させるために重要である。 さ らに、 原料充塡層の中では、 燃焼溶融帯の通気抵抗が大きいので、 燃焼溶融帯の原料充塡層高さ方向の厚みを必要最小限にすれば、 通 気性を向上しコークス燃焼速度を上げて燃焼溶融帯の移行速度を増 大させることができる。 このように燃焼溶融帯の上にある冷却帯の 冷却速度と燃焼溶融帯の移行速度をバラ ンス良く制御することも、 焼結機の生産率を大幅に向上させるために重要である。 On the other hand, if the transition speed of the combustion zone is too high, the amount of heat required for sintering cannot be secured due to insufficient coke combustion, which may lead to deterioration in yield and quality. Therefore, it is important to secure the heat required for the sintering reaction and to increase the transition speed of the combustion melting zone in order to greatly increase the production rate of the sintering machine. Furthermore, in the raw material bed, since the ventilation resistance of the combustion zone is large, if the thickness of the combustion zone in the height direction of the raw material bed is minimized, the air permeability is improved and coke combustion is performed. By increasing the speed, the transition speed of the combustion melting zone can be increased. Thus, controlling the cooling rate of the cooling zone above the combustion zone and the transition speed of the combustion zone in a well-balanced manner is also important for greatly improving the production rate of the sintering machine.
一般的に、 燃焼溶融帯の移行速度を増加させるためには、 ブロア 一の負圧を増大して吸引流速を増加させ、 原料充塡層への酸素の供 給量を増加させることが考えられる。 Generally, in order to increase the transition speed of the combustion melting zone, it is considered to increase the suction flow rate by increasing the negative pressure of the blower to increase the supply amount of oxygen to the raw material packed bed. .
しかし、 原料充填層上層部の歩留り、 焼結鉱の品質低下を防止す るには原料充塡層上層部の高温保持時間を保つ必要があり、 原料充 塡層上層部の焼成エリア、 すなわち焼結ス トラ ン ドの前段での燃焼 溶融帯の移行速度は現状より増加できない。 また、 ブロア一の負圧 の増大により、 重力と送風圧力が重畳して原料充塡層が圧縮されて 通気が阻害されるこ と、 さ らに排風量及び漏風量の増大を招く 問題 などがあり、 ブロア一の負圧を大き く増大させることは行われてい ない。 However, in order to prevent the yield of the upper layer of the raw material packed layer and the deterioration of the quality of the sintered ore, it is necessary to maintain the high temperature holding time of the upper layer of the raw material packed layer. The transition speed of the combustion and melting zone before the consolidation strand cannot be increased from the current level. In addition, due to the increase in the negative pressure of the blower, gravity and blowing pressure are superimposed, compressing the raw material packed bed and obstructing ventilation, and further increasing the amount of exhaust air and leakage. There is no significant increase in the negative pressure of the blower.
一方、 高炉の高微粉炭比操業時のスラグ量低減のために、 低 S i 02 焼結鉱の製造が求められているが、 このときに顕在化する生産率や R D Iの悪化、 N 0 X排出量の増加などの問題が解決されないでいた。 そこで本発明は、 原料充塡層の層厚や焼結パレッ 卜の移動速度を 増加させて焼結機の生産性を大幅に向上できる焼結鉱の製造方法、 低 S i 0 2焼結鉱の製造方法、 及びこれらに使用する焼結機を提供する ことを目的とする。 Meanwhile, in order to reduce the slag of the high pulverized coal ratio during operation of the blast furnace, but the production of low S i 0 2 sintered ore is sought, deterioration of production rate and RDI that manifested in this case, N 0 Problems such as an increase in X emissions were not solved. Therefore, the present invention is to reduce the thickness of the raw material packed layer and the moving speed of the sintered pallet. It is an object of the present invention to provide a method for producing a sintered ore, a method for producing a low SiO 2 sintered ore, and a sintering machine used for these methods, which can greatly increase the productivity of the sintering machine by increasing it.
上記の目的を達成する本発明の要旨は、 下記の通りである。 The gist of the present invention that achieves the above objects is as follows.
( 1 ) 原料粉鉱石と溶剤と燃料とを含む配合原料を焼結機のパレ ッ ト上に装入して原料充塡層を形成した後、 原料充塡層表層に点火 したして上方から下方に焼結反応させることによって焼結鉱を製造 する方法において、 原料充塡層上層部を十分に焼成した時点で、 原 料充填層に供給する酸素含有ガスの質量流量を、 該原料充塡層上層 部を焼成する範囲において供給する酸素含有ガスの質量流量の 1. 0 1 〜 2. 6倍に変更して焼結することを特徴とする成品歩留りおよび品 質の優れた成品を得る焼結鉱製造方法。 (1) A blended raw material containing raw material ore, a solvent and a fuel is charged on a sintering machine pallet to form a raw material packed bed, which is then ignited on the surface of the raw packed bed and lit from above. In the method of producing a sintered ore by performing a sintering reaction downward, the mass flow rate of the oxygen-containing gas to be supplied to the raw material packed bed is determined when the upper layer of the raw material packed bed is sufficiently fired. The sintering is performed by changing the mass flow rate of the oxygen-containing gas supplied in the range of sintering the upper layer to 1.0 to 2.6 times, and sintering. Concentration production method.
( 2 ) 原料粉鉱石と溶剤と燃料とを含む配合原料を焼結機のパレ ッ ト上に装入して原料充填層を形成した後、 原料充塡層表層に点火 して上方から下方に燃焼溶融帯を移行させながら連続的に焼結鉱を 製造する方法において、 燃焼溶融帯の形成範囲の先端が原料充填層 の表層から原料充填層高さの 2 0 %の位置より下方に達した時点で 、 原料充塡層に供給する酸素含有ガスの質量流量を、 該原料充塡層 を焼成する範囲において供給する酸素含有ガスの質量流量の 1 . 0 1〜 2. 6倍に変更して焼結することを特徴とする成品歩留りおよび品質 の優れた成品を得る焼結鉱製造方法。 (2) The raw material ore, the solvent, and the blended raw material containing the fuel are charged on the sintering pallet to form a raw material packed bed, and then the raw material packed bed surface is ignited and ignited from above to below. In the method of continuously producing sintered ore while shifting the combustion melting zone, the leading end of the formation range of the combustion melting zone reached below the position of 20% of the height of the raw material packed bed from the surface layer of the raw material packed bed At this point, the mass flow rate of the oxygen-containing gas supplied to the raw material packed bed was changed to 1.01 to 2.6 times the mass flow rate of the oxygen-containing gas supplied in the range where the raw material packed bed was fired. A sinter ore production method for obtaining a product having excellent product yield and quality characterized by sintering.
( 3 ) 前記焼結パレッ ト上の原料充塡層の上に酸素含有ガスを加 圧供給する加圧フー ドを設け、 該加圧フー ド内を大気圧に対して 1 00〜3000mmAciに加圧するとともに、 原料充填層の下方から大気圧に 対して一 2000 1 mmAqで吸引することを特徴とする ( 1 ) または (3) A pressurized hood for pressurizing an oxygen-containing gas is provided on the raw material packed bed on the sintered pallet, and the pressure in the pressurized hood is increased to 100 to 3000 mmAci with respect to the atmospheric pressure. (1) or suction from the lower part of the raw material packed bed at a pressure of 20001 mmAq with respect to atmospheric pressure.
( 2 ) に記載の焼結鉱製造方法。 The method for producing a sintered ore according to (2).
( 4 ) 前記焼結パレッ ト上の原料充塡層の上で、 パレツ ト幅方向 の 5〜95%の範囲内に酸素含有ガスを加圧供給する加圧フ 一 ドを設 け、 該加圧フー ド内を大気圧に対して 100〜3000龍 Aqに加圧するこ とを特徴とする ( 1 ) から ( 3 ) のいずれかに記載の焼結鉱製造方 法。 (4) On the raw material packed bed on the sintered pallet, in the pallet width direction A pressurized hood for supplying oxygen-containing gas under pressure within the range of 5 to 95% of the pressure is provided, and the inside of the pressurized hood is pressurized to 100 to 3000 dragon Aq against atmospheric pressure. The sinter production method according to any one of (1) to (3).
( 5 ) 前記原料充塡層の上方から下方のうち、 燃焼溶融帯の形成 範囲の先端が原料充填層の表眉から原料充塡層高さの 2 0 %の位置 より下方に達した以降の範囲の原料充塡層の上に、 酸素含有ガスを 加圧供袷する加圧フー ドを設け、 該加圧フー ド内を大気圧に対して 100〜3000mmAqに加圧することを特徴とする ( 3 ) または ( 4 ) に 記載の焼結鉱製造方法。 (5) From the top to the bottom of the raw material packed bed, after the tip of the formation range of the combustion melting zone reaches below the position of 20% of the raw material packed bed height from the surface of the raw material packed bed. A pressure hood for pressurizing and supplying an oxygen-containing gas is provided on the raw material packed layer in the range, and the inside of the pressure hood is pressurized to 100 to 3000 mmAq with respect to the atmospheric pressure. 3) or the method for producing a sintered ore according to (4).
( 6 ) 前記原料充填層の上に設けた酸素含有ガスを加圧供給する 加圧フー ドに焼結排ガスを循環させることを特徴とする ( 3 ) から ( 5 ) のいずれかに記載の焼結鉱製造方法。 (6) The firing method according to any one of (3) to (5), wherein the sintering exhaust gas is circulated through a pressurized hood that pressurizes and supplies an oxygen-containing gas provided on the raw material packed bed. Concentration production method.
( 7 ) 前記焼結パレツ 卜のグレー ト上にパレッ ト進行方向にほぼ 平行に板状のシ ンターケーキ支持スタン ドを複数枚設けた ドワイ ト ロイ ド式焼結機を用いて焼結することを特徴とする ( 1 ) から ( 6 ) のいずれかに記載の焼結鉱製造方法。 (7) Sintering is performed using a Dwight toroid type sintering machine provided with a plurality of plate-shaped sinter cake supporting stands on the grate of the sintering pallet substantially parallel to the pallet traveling direction. The method for producing a sintered ore according to any one of (1) to (6), characterized in that:
( 8 ) 化学成分として 3.9〜 4.9mass%の Si02を含む焼結鉱を製 造することを特徴とする ( 1 ) から ( 7 ) のいずれかに記載の焼結 鉱製造方法。 (8) sinter process according to any one of to manufacture sintered ore containing 3.9~ 4.9mass% of Si0 2 as chemical components from and wherein (1) (7).
( 9 ) 前記原料充塡層の層厚を 600〜1500画とすることを特徴と する ( 1 ) から ( 8 ) のいずれかに記載の焼結鉱製造方法。 (9) The method for producing a sintered ore according to any one of (1) to (8), wherein the thickness of the material-filled layer is set to 600 to 1500 pixels.
( 1 0 ) 焼結ス トラ ン ド下部の複数のウィ ン ドボッ クスを吸引ダ ク 卜に並列に接続し、 該吸引ダク 卜にメ イ ンブロア一を設けた下方 吸引式の焼結機において、 点火部から排鉱部までの吸引ダク ト長さ の 30%から焼結完了点の範囲内のダク 卜から吸引し、 かつ該吸引ダ ク トに排出するブロア一をさ らに設けたことを特徴とする焼結機。 ( 1 1 ) 焼結ス トラ ン ド下部の複数のゥィ ン ドボッ クスを並列に 接続した吸引ダク トを、 点火部から排鉱部までのス トラ ン ド長さ 30 %から焼結完了点の範囲内と残りの範囲に分割し、 各々独立してブ ロアーを設けたこ とを特徴とする焼結機。 (10) In a downward suction type sintering machine in which a plurality of wind boxes at the lower part of the sintering stand are connected in parallel to a suction duct, and a main blower is provided in the suction duct, It is necessary to additionally provide a blower that sucks from the duct within the range of 30% of the suction duct length from the ignition part to the mining part and the sintering completion point, and discharges it to the suction duct. Characterized sintering machine. (11) The suction duct, which is composed of a plurality of lead boxes connected in parallel at the lower part of the sintering strand, is connected to the sintering completion point at a strand length of 30% from the ignition section to the mining section. The sintering machine is characterized in that the sintering machine is divided into an area within the range and a remaining area, and each of them is provided with an independent blower.
( 1 2 ) 前記焼結パレッ 卜の原料充塡層の上に酸素含有ガスを加 圧供給する加圧フー ドを設けたこ とを特徴とする (10) または (11 ) に記載の焼結機。 (12) The sintering machine according to (10) or (11), wherein a pressurized hood for supplying an oxygen-containing gas under pressure is provided on the raw material packed bed of the sintering pallet. .
( 1 3 ) 前記原料充塡層の上方から下方のうち、 燃焼溶融帯の形 成範囲の先端が原料充塡層の表層から原料充塡層高さの 2 0 %の位 置より下方に達した以降の範囲の原料充塡層の上に、 酸素含有ガス を加圧供給する加圧フー ドを設けたこ とを特徴とする (10) または (11) に記載の焼結機。 (13) From the top to the bottom of the raw material packed bed, the leading end of the formation range of the combustion melting zone reaches below the position of 20% of the height of the raw material packed bed from the surface layer of the raw material packed bed. The sintering machine according to (10) or (11), wherein a pressurized hood for pressurizing and supplying an oxygen-containing gas is provided on the raw material packed bed in the range after the above.
( 1 4 ) 前記焼結パレ ッ ト上の原料充塡層の上で、 パレ ッ ト幅方 向の 5〜95%の範囲内に酸素含有ガスを加圧供給する加圧フー ドを 設けたこ とを特徵とする (12) または (13) に記載の焼結機。 (14) A pressurized hood for pressurizing and supplying an oxygen-containing gas within a range of 5 to 95% of the width of the pallet is provided on the raw material packed layer on the sintered pallet. And the sintering machine according to (12) or (13).
( 1 5 ) 前記原料充填層の上に設けた酸素含有ガスを加圧供給す る加圧フー ドに焼結排ガスを循環させるこ とを特徴とする (12) か ら (14) のいずれかに記載の焼結機。 (15) The sintering exhaust gas is circulated through a pressurized hood provided on the raw material packed layer and pressurized to supply an oxygen-containing gas, wherein (12) to (14). The sintering machine according to 1.
( 1 6 ) 前記酸素含有ガスを加圧供給するフー ドの下端部にシー ル機構を設けたこ とを特徴とする (12) から (15) のいずれかに記 載の焼結機。 (16) The sintering machine according to any one of (12) to (15), wherein a seal mechanism is provided at a lower end of the hood for supplying the oxygen-containing gas under pressure.
( 1 7 ) 下方吸引式焼結機の構造が、 焼結パレッ 卜のグレー ト上 のパレッ ト進行方向にほぼ平行に板状のシ ンターケーキ支持スタ ン ドを複数枚設けたことを特徴とする (10) から (16) のいずれかに 記載の焼結機。 図面の簡単な説明 第 1 図は本発明の実施例 l a、 3 aに係る焼結機の実施態様を示 す図である。 (17) The structure of the downward suction type sintering machine is characterized in that a plurality of plate-shaped sinter cake support stands are provided almost parallel to the pallet traveling direction on the sintering pallet. The sintering machine according to any one of (10) to (16). BRIEF DESCRIPTION OF THE FIGURES FIG. 1 is a view showing an embodiment of a sintering machine according to Examples la and 3a of the present invention.
第 2図は本発明の実施例 1 bに係る焼結機の実施態様を示す図で ある。 FIG. 2 is a view showing an embodiment of a sintering machine according to Embodiment 1b of the present invention.
第 3図は本発明の実施例 l c〜 l e、 3 bに係る焼結機の実施態 様を示す図である。 FIG. 3 is a diagram showing an embodiment of a sintering machine according to Examples lc to le and 3b of the present invention.
第 4図は本発明の実施例 2 a〜 2 d、 3 c に係る焼結機の実施態 様を示す図である。 FIG. 4 is a diagram showing an embodiment of a sintering machine according to Examples 2a to 2d and 3c of the present invention.
第 5図は本発明の焼結機の他の実施態様を示す図である。 FIG. 5 is a view showing another embodiment of the sintering machine of the present invention.
第 6図は本発明に係る焼結機の加圧フー ドのシール機構を示す図 第 7図は本発明に係る焼結機の板状のシ ン夕一ケーキ支持スタ ン ドを示す図である。 FIG. 6 is a view showing a sealing mechanism of a pressurized hood of the sintering machine according to the present invention. FIG. 7 is a view showing a plate-shaped thin cake supporting stand of the sintering machine according to the present invention. is there.
第 8 ( a ) 図は、 本発明に係るパレッ 卜における燃焼溶融帯の推 移を示す説明図である。 第 8 ( b ) 図は、 本発明に係るパレッ 卜に おける燃焼溶融帯の、 A— A ' 断面図である。 第 8 ( c ) 図は、 本 発明に係るス トラン ド上でのクーリ ング時の燃焼溶融帯の推移を示 す説明図である。 発明を実施するための最良の形態 FIG. 8 (a) is an explanatory diagram showing the transition of the combustion melting zone in the pallet according to the present invention. FIG. 8 (b) is a sectional view taken along the line AA ′ of the combustion melting zone in the pallet according to the present invention. FIG. 8 (c) is an explanatory diagram showing the transition of the combustion melting zone at the time of cooling on the strand according to the present invention. BEST MODE FOR CARRYING OUT THE INVENTION
一般に焼結鉱は、 原料粉鉱石と溶剤と燃料とを含む配合原料を ド ワイ トロイ ド式焼結機のパレッ ト上に装入して原料充塡層を形成し 、 点火部で点火した後、 酸素含有ガスを下方から吸引 しながら排鉱 部へと移動させ製造している。 従って、 焼成は原料充填層の上方か ら下方へと行われるが、 ス ト ラ ン ド長さ方向と対比して表現でき、 かつ理解し易いため、 以下ではス トラ ン ド長さを用いて本発明を説 明する。 第 8 ( a ) 図は、 本発明の原料充塡層焼結過程の一例を示す説明 図である。 この図で、 I は初期原料帯、 Πは湿潤 (水分凝縮) 帯、 mは乾燥帯、 wは燃焼帯、 Vは溶融帯および VIは焼結帯である。 第Generally, sinter ore is prepared by charging a blended raw material containing raw ore powder, a solvent and a fuel on a pallet of a Dwight toroid type sintering machine to form a raw material packed layer, and then igniting in an ignition section. In addition, the oxygen-containing gas is sucked from below and moved to the mining section to produce. Therefore, sintering is performed from the upper side to the lower side of the raw material packed layer. However, since it can be expressed in comparison with the strand length direction and is easy to understand, the following description uses the strand length. The present invention will be described. FIG. 8 (a) is an explanatory view showing one example of a raw material packed bed sintering process of the present invention. In this figure, I is the initial raw material zone, Π is the wet (condensed water) zone, m is the dry zone, w is the combustion zone, V is the melting zone, and VI is the sintering zone. No.
8 ( b ) 図は、 第 8 ( a ) 図の中央部分での A— A ' 断面図である 。 また、 点 Bは、 本発明における初期に燃焼溶融帯を形成し、 原料 充填層での酸素含有ガスの供給量を変更し増大させる最も点火炉に 近い位置を示し、 また点 Cは燃焼完了点を示す。 通常の操業では、 ス トラ ン ド全体を効率良く使って安定的に生産するために、 焼結完 了点が一定となるように操業する。 生産量を重視する場合は、 焼結 完了点を極力排鉱側に近づける操業と し、 また、 歩留りや品質を重 視する場合には、 ウィ ン ドボッ クスの一つあるいは二つ分の余裕を もつて焼結完了点を点火炉側に近付づけて一定となるように操業す る。 ただし、 ス トラ ン ド上でク一リ ングを行う場合には、 例えば第 8 ( c ) 図に示すように、 焼結完了点 C ' をス ト ラ ン ドの中間部に まで変更した操業が行われる。 この場合には、 以下に開示する本発 明をもとに層厚、 またはス トラ ン ド長さ方向の位置でもって酸素含 有ガスの供給量の変更をすれば良い。 さ らに、 以下の説明において 焼結完了点は、 点火部からス ト ラ ン ド長さ 9 5 %の位置となる例を 示した。 なお、 送風あるいは吸引圧力は大気圧に対する圧力で示し ている。 FIG. 8 (b) is a sectional view taken along the line AA ′ in the center of FIG. 8 (a). In addition, point B indicates a position closest to the ignition furnace where an initial combustion melting zone is formed in the present invention and the supply amount of the oxygen-containing gas in the raw material packed bed is changed and increased, and point C is the combustion completion point. Is shown. In normal operation, operation is performed so that the sintering completion point is constant in order to use the entire strand efficiently and stably produce. When the production volume is important, the sintering completion point should be as close as possible to the mining side, and when yield and quality are to be emphasized, allowance for one or two wind boxes should be provided. The sintering completion point should be kept close to the ignition furnace side to keep the sintering constant. However, when cooling on a strand, for example, as shown in Fig. 8 (c), the operation where the sintering completion point C 'is changed to the middle part of the strand Is performed. In this case, the supply amount of the oxygen-containing gas may be changed based on the layer thickness or the position in the strand length direction based on the present invention disclosed below. Further, in the following description, an example is shown in which the sintering completion point is located at a position where the strand length is 95% from the ignition portion. The blowing or suction pressure is shown as the pressure with respect to the atmospheric pressure.
点火部からス ト ラ ン ド長さ 30 %以下の範囲は原料充塡層の上層部 2 0 %の焼成エリアにほぼ相当し、 原料充塡層上層部の歩留りや品 質は一般に中下層部に比べて劣っている。 これは焼成反応に必要な 熱量を与えるコークス燃焼速度等が、 点火直後であるため不十分と なっているからである。 さ らに、 表面からの放散熱があること等の 原因による。 従って、 焼結反応に必要な熱量を確保する必要がある ために、 原料充塡層の上層部の焼成過程で燃焼溶融帯の移行速度を 増加させることは、 歩留りや品質悪化などの理由から好ま しく ない 従って、 本発明では原料充填層の上層部の焼成エリ アである点火 部からス トラ ン ド長さ 30 %以下の範囲は、 従来と同じ吸引負圧にす れば、 原料充填層の上層部の高温保持時間を確保することができる ので、 原枓充塡層の上層部の歩留りや品質を確保することができる 原料充塡層の上部の歩留りや品質を積極的に向上させるには、 該 部位の焼成熱量を増大させれば良い。 このためには、 該部位の吸引 負圧を低く したり、 原料充填層上部のコークス偏析を強化したり、 あるいは表層部にプリーズを添加すること等が好ま しい。 また、 原 料充填層の外部から熱量を加えることもでき、 例えば、 熱風を該部 位に吸引させたり、 マイク ロ波等による誘導加熱を行う ことができ 。 The range of 30% or less of the strand length from the ignited part is almost equivalent to the firing area of the upper 20% of the raw material packed bed, and the yield and quality of the upper layer of the raw material packed bed are generally lower and middle. Inferior to. This is because the coke combustion rate, which gives the calorific value necessary for the calcination reaction, is not sufficient because it is just after ignition. In addition, it is due to the heat dissipated from the surface. Therefore, it is necessary to secure the amount of heat required for the sintering reaction. Increasing the amount is not preferable for reasons such as yield and quality deterioration.Therefore, in the present invention, the range of 30% or less of the strand length from the ignition portion, which is the firing area in the upper layer of the raw material packed layer, is less than the conventional range. With the same suction negative pressure as above, the high temperature holding time of the upper part of the raw material packed bed can be secured, so that the yield and quality of the upper part of the raw material packed bed can be secured. In order to positively improve the yield and the quality of the upper part, the calorific value of the part may be increased. For this purpose, it is preferable to lower the suction negative pressure at the site, to enhance the coke segregation at the upper part of the raw material packed layer, or to add a please to the surface layer. In addition, heat can be applied from the outside of the raw material packed layer. For example, hot air can be sucked into the portion, or induction heating by microwave or the like can be performed.
点火部からのス 卜ラ ン ド長さ 30〜95 %の範囲は、 原料充塡層の中 • 下層部の焼成エリアにあたり、 原料充塡層の上層部の焼結帯は通 気抵抗が小さいのに対し、 原料充塡層の中層から下層部は通気抵抗 の大きい燃焼溶融帯の厚みが大きくなるため通気抵抗が大き く なる 。 特に、 ス トラ ン ド長さ 50〜95 %では、 通気性が悪化するとともに 、 焼成熱量も過剰になっている。 この中層から下層部 (点火部から ス トラ ン ド長さ 30〜95 %内の範囲) の範囲内の圧損の大きい燃焼溶 融帯へ上方から強制的に供給して、 酸素含有ガスの質量流量を前記 範囲を除く ス トラン ド範囲の原料充塡層に供給する酸素含有ガスの 1 . 01〜 2. 6倍に増加させれば、 中層から下層部のコークス燃焼速度 を増加させて燃焼溶融帯の移行速度を増加させ、 かつ燃焼溶融帯上 の冷却帯の冷却速度も増加させ、 焼成に必要な熱量を確保すると共 に、 燃焼溶融帯の厚みが減少して、 通気性が向上する。 このように 、 燃焼溶融帯の温度、 及び原料充塡層高さ方向の厚みに依存する焼 成熱量と通気性の制御が焼結の生産率を向上する上で重要である。 本発明で質量流量とは、 単位時間当たり に流れるガスの質量を表 すものであり、 その単位は kgZ s などで表現される。 また、 一般に 使用されている流量とは体積流量を示し、 単位時間当たりに流れる ガスの体積を表すものであり、 その単位は m 3 Z s などで表現され る。 質量流量が同じであれば、 体積流量は気体の状態方程式に従い 温度や圧力によって変化する。 The range of 30 to 95% of the strand length from the ignition part corresponds to the firing area in the lower part of the raw material packed bed. The sintered zone in the upper part of the raw material packed bed has low air resistance. On the other hand, in the middle to lower layers of the raw material-filled layer, the thickness of the combustion-melting zone having a high airflow resistance increases, so that the airflow resistance increases. In particular, at a strand length of 50 to 95%, the air permeability deteriorates and the calorific value becomes excessive. The mass flow rate of the oxygen-containing gas is forcibly supplied from above to the combustion zone with a large pressure loss in the range from the middle to the lower part (within the range of 30 to 95% of the strand length from the ignition part). Is increased to 1.0 to 2.6 times the oxygen-containing gas supplied to the raw material bed in the range of the strand excluding the above range, the coke combustion rate in the middle to lower layers is increased, and the combustion melting zone is increased. In addition, the cooling speed of the cooling zone above the combustion melting zone is increased by increasing the cooling speed, and the calorie required for sintering is secured, and the thickness of the combustion melting zone is reduced and the air permeability is improved. in this way It is important to control the calorific value and air permeability depending on the temperature of the combustion melting zone and the thickness in the height direction of the raw material packed bed in order to improve the sintering production rate. In the present invention, the mass flow rate represents the mass of gas flowing per unit time, and the unit is expressed in kgZ s or the like. The generally used flow rate is a volume flow rate, which indicates the volume of gas flowing per unit time, and the unit is expressed in m 3 Z s or the like. For the same mass flow, the volume flow varies with temperature and pressure according to the equation of state of the gas.
また、 本発明における酸素含有ガスとは、 大気はもちろんのこ と 、 焼結機から排出される排ガスや、 他のプロセスからの排ガスなど も含むと共に、 大気と排ガスの混合ガス、 酸素富化したガスも含む もので、 酸素濃度が 12 ~ 40vo l %のガスが好ま しい。 Further, the oxygen-containing gas in the present invention includes not only the atmosphere but also the exhaust gas discharged from the sintering machine and the exhaust gas from other processes, etc., as well as the mixed gas of the atmosphere and the exhaust gas and the oxygen-enriched gas. It also contains gas, and gas with an oxygen concentration of 12 to 40 vol% is preferred.
ここで、 点火部からのス トラ ン ド長さ 30〜95 %の範囲内の原料充 塡層に供給する酸素含有ガスの質量流量を、 前記範囲を除く ス ト ラ ン ドの範囲の原料充塡層に供給する酸素含有ガスの質量流量に対し て 1. 01〜 2. 6倍に調節するのは、 質量流量が 1. 01倍未満では燃焼溶 融帯の移行速度がほとんど変化せず、 2. 6倍超ではガス流速が増加 しすぎて燃焼溶融帯が過冷却され、 または原料充填層上下の差圧の 増加により原料充塡層が圧密され通気性が阻害されるためである。 さ らに、 点火部からのス トラ ン ド長さ 50〜85 %の範囲内の原料充填 層に吸引する酸素含有ガスの質量流量を、 前記範囲を除く ス ト ラ ン ドの範囲の原料充塡層に供給する酸素含有ガスの質量流量に対して 1. 1〜 1. 8 倍に調節することが、 焼結鉱の生産性向上の点で特に 好ま しい。 Here, the mass flow rate of the oxygen-containing gas supplied to the raw material storage layer within the range of 30 to 95% of the length of the strand from the ignition part is set to the range of the raw material charge in the range of the strand excluding the above range. The reason why the mass flow rate of the oxygen-containing gas supplied to the 塡 layer is adjusted to 1.01 to 2.6 times is that when the mass flow rate is less than 1.01 times, the transition speed of the combustion melting zone hardly changes. If it is more than 6 times, the gas flow velocity will increase too much and the combustion melting zone will be supercooled, or the raw material packed bed will be compacted due to the increase in the differential pressure above and below the raw material packed bed, and the gas permeability will be impaired. In addition, the mass flow rate of the oxygen-containing gas sucked into the raw material packed bed within the range of 50 to 85% of the length of the strand from the ignition part is adjusted to the range of the raw material filled in the range of the strand excluding the above range. It is particularly preferable to adjust the mass flow rate of the oxygen-containing gas supplied to the bed to 1.1 to 1.8 times from the viewpoint of improving the productivity of sinter.
また、 酸素含有ガスと して大気を吸引 して燃焼溶融帯の移行速度 を增加させる場合には、 上記規定の質量流量とするため、 点火部か らス トラ ン ド長さ 30〜95 %の範囲内における原料充塡層の層厚方向 の差圧を前記範囲を除く ス トラ ン ド範囲の原料充填層の層厚方向の 差圧に対して 1. 1〜 5. 0倍とすることが好ま しい。 こ こでス ト ラ ン ド長さ 30〜95 %の範囲内は、 それ以外の範囲に比較して通気抵抗が 1. 5〜 5 倍程度大きい。 したがって、 前記差圧が 1 . 1倍未満では通 風量増加による燃焼溶融帯の移行速度の促進の効果が少な く 、 差圧 が 5. 0倍を越えるとガス流速が大き く なりすぎて、 冷却速度が大き く増すために高温保持時間が確保できな く なり、 原料充塡層が圧密 化して通気性が悪化するため好ま し く ない。 さ らに差圧を 1 . 2〜 2 . 0倍とするこ とが生産性向上の点で特に好ま しい。 なお、 ガスの供 給量は点火部側から排鉱部側へ除々 に増加させ、 燃焼溶融帯の移行 速度と冷却速度を近づけるのが好ま しい。 急激に供給量を増加させ ると、 短時間ではあるが、 コ一クス燃焼速度より も冷却速度の方が 大き く なり、 十分な焼成熱量が保てなく なる部位が発生し、 該部位 の歩留り、 焼結鉱の品質の悪化を招いてしま うからである。 When the air is sucked into the atmosphere as an oxygen-containing gas to increase the transition speed of the combustion and melting zone, in order to achieve the above-mentioned mass flow rate, the length of the strand from the ignition part must be 30 to 95%. Thickness direction of raw material packed bed within the range Is preferably 1.1 to 5.0 times the pressure difference in the thickness direction of the raw material packed bed in the range of the strand excluding the above range. Here, in the range of the strand length of 30 to 95%, the ventilation resistance is about 1.5 to 5 times larger than that of the other range. Therefore, if the differential pressure is less than 1.1 times, the effect of promoting the transition speed of the combustion and melting zone by increasing the air flow rate is small, and if the differential pressure exceeds 5.0 times, the gas flow velocity becomes too large, and Since the speed is greatly increased, it becomes impossible to secure a high-temperature holding time, and the raw material packed layer is undesirably densified and the air permeability is deteriorated. Further, it is particularly preferable to increase the pressure difference to 1.2 to 2.0 times from the viewpoint of improving productivity. It is preferable that the gas supply is gradually increased from the ignition section to the ore removal section to make the transition speed of the combustion melting zone and the cooling speed close. If the supply rate is rapidly increased, the cooling rate will be faster than the coke burning rate for a short period of time, and some parts will not be able to maintain a sufficient amount of calcining heat. This is because the quality of the sinter is deteriorated.
以上のように、 点火部からのス トラ ン ド長さ 30 ~ 95 %の範囲内の 原料充塡層の差圧を増加して質量流量を増加させれば焼結鉱の生産 率を大幅に向上するとと もに、 歩留りおよび品質の優れた成品を得 ることができる。 差圧を増しガスの供給量を増加すると、 これに連 れられて該部位の排ガス排出量も増大するが、 焼成反応が活発で酸 素消費効率が高い部位なので、 酸素消費効率を低下させるこ となく As described above, if the mass flow rate is increased by increasing the differential pressure of the raw material bed within the range of 30 to 95% of the strand length from the ignition part, the production rate of sinter As well as improving the yield, it is possible to obtain products with excellent yield and quality. If the pressure difference is increased and the gas supply is increased, the amount of exhaust gas discharged from this part also increases in tandem with this. However, since the firing reaction is active and the oxygen consumption efficiency is high, the oxygen consumption efficiency may be reduced. Just
、 さ らに上層部分及び排鉱部近傍の過剰なガスの供給量を極力抑え るこ となどから、 風量原単位を削減できる。 In addition, the unit of airflow can be reduced by minimizing the supply of excess gas in the upper part and in the vicinity of the mining part.
本発明者等は、 原料充塡層の下方吸引と上方からの加圧を組み合 わせて酸素含有ガスの質量流量を増加させれば原料充塡層の圧密化 に起因する通気性悪化を回避して、 点火部からス ト ラ ン ド長さ 30〜 95 %の範囲内における原料充塡層に供給する酸素含有ガスの質量流 量を、 前記範囲を除く ス ト ラ ン ドの範囲の原料充填層に供給する酸 素含有ガスの質量流量に対して 1. 01〜 2. 6倍に し、 さ らに好ま し く は原料充塡層の層厚方向の差圧を前記範囲を除く ス トラ ン ド範囲の 原料充塡層の層厚方向の差圧に対して 1. 1〜 5. 0倍に調節すれば、 燃焼溶融帯の移行速度を増大できると と もに、 成品歩留りおよび品 質を向上できるこ とを見出 した。 The present inventors avoid the deterioration of air permeability caused by the consolidation of the raw material packed bed by increasing the mass flow rate of the oxygen-containing gas by combining the downward suction of the raw material packed bed and the pressurization from above. Then, the mass flow rate of the oxygen-containing gas to be supplied to the raw material packed bed within the range of 30 to 95% of the length of the strand from the ignition section is reduced to the range of the raw material in the range of the strand excluding the above range. Acid supplied to packed bed 1.01 to 2.6 times the mass flow rate of the element-containing gas, and more preferably, the differential pressure in the thickness direction of the raw material packed bed in the range of the strand excluding the above range By adjusting the pressure difference in the thickness direction of the packed bed to 1.1 to 5.0 times, the transfer speed of the combustion zone can be increased, and the product yield and quality can be improved. Was found.
焼結パレッ 卜上に装入した原料充塡層の上を覆う加圧フー ドを設 け、 フー ド内を加圧して、 上方から原料充塡層に酸素含有ガスを加 圧送風する と と もに、 パレツ ト直下にあるウィ ン ドボッ ク スから吸 引排気し、 原料充塡層上方と原料充塡層下方との間の差圧を制御し て、 原料充塡層の上方から下方にガスを流す。 このよ う にして、 従 来は原料充填層の上が大気圧で下方から吸引 して形成している原料 充塡層内の静圧に対して、 本発明では原料充塡層内の静圧を増加で きる。 従来の大気を吸引する方法と原料充塡層上下の差圧が同じで あれば、 本発明では原料充塡層内に供給する質量流量を従来より も 増加させることができ、 原料充塡層内のガス密度を従来より も大き く できる。 その結果、 原料充塡層内への酸素含有ガスの供給量が増 加して、 原料充填層中のコークス燃焼速度が大き く なり、 燃焼溶融 帯の焼成熱量を増大すると と もに、 移行速度を増加させ、 冷却帯の 移行速度も促進できる。 原料充塡層内の静圧が増せば気体 固体間 の伝熱速度も増加し、 燃焼溶融帯の移行及び冷却帯の冷却を促進で きる。 A pressurized hood is provided to cover the raw material packed bed loaded on the sintering pallet, the inside of the hood is pressurized, and oxygen-containing gas is blown from above to the raw material packed bed. In particular, the air is sucked and exhausted from the wind box just below the pallet, and the pressure difference between the upper part of the raw material packed bed and the lower part of the raw material packed bed is controlled. Let the gas flow. Thus, in the present invention, the static pressure in the raw material packed bed is higher than the static pressure in the raw material packed bed formed by suctioning the raw material packed bed from below at atmospheric pressure. Can be increased. If the pressure difference between the upper and lower portions of the raw material packed bed is the same as that of the conventional method of sucking the atmosphere, the present invention can increase the mass flow rate to be supplied into the raw material packed bed compared to the conventional method. Gas density can be made higher than before. As a result, the supply amount of the oxygen-containing gas into the raw material packed bed increases, the coke burning rate in the raw material packed bed increases, the calorific value of the combustion zone increases, and the transition speed increases. To increase the cooling zone transition speed. If the static pressure in the raw material packed bed increases, the heat transfer rate between the gas and the solid also increases, which can promote the transition of the combustion melting zone and the cooling of the cooling zone.
また、 上方からの押し込み送風では、 通気抵抗の小さい焼結帯を 通し、 均一なガス流れを形成して反応の起きている燃焼溶融帯へガ スを供給することができる。 一方、 下方からの吸引によるガスの供 給では、 通気抵抗の比較的大きい湿潤帯、 及び焼成反応の起きてい る燃焼溶融帯の大きい通気抵抗を受けるので、 ガスが通気抵抗の小 さいところを優先的に流れるため、 不均一なガス流れを形成し、 気 体—固体間の反応効率が悪化し易い状態である。 従って、 上方から 押し込むガス流れの方が下方からの吸引によるガス流れに対して均 一なガス流れを形成するので、 酸素消費効率が向上し、 焼結鉱製造 に必要な風量原単位を低減できる。 In addition, in the case of forced air blowing from above, gas can be supplied to the combustion melting zone where a reaction has occurred by forming a uniform gas flow through the sintered zone having low airflow resistance. On the other hand, when gas is supplied by suction from below, gas is subjected to relatively high ventilation resistance in the wet zone with relatively high ventilation resistance and the combustion and melting zone in which the calcination reaction is occurring. Flow, forming an uneven gas flow This is a state in which the reaction efficiency between the body and the solid tends to deteriorate. Therefore, the gas flow pushed in from above forms a more uniform gas flow than the gas flow sucked from below, so that the oxygen consumption efficiency is improved and the unit air volume required for sinter production can be reduced. .
さ らに、 ス トラ ン ド長さ 30〜95 %の範囲内の原料充塡層の差圧を 増せば、 差圧増大による質量流量の増加による効果と、 静圧レベル 増大による効果が加わり、 その生産性向上効果は非常に大き く なる のである。 In addition, increasing the pressure difference of the raw material bed within the range of 30 to 95% of the strand length will have the effect of increasing the mass flow rate by increasing the pressure difference and the effect of increasing the static pressure level. The productivity improvement effect will be very large.
原料充塡層内の質量流量及び静圧レベルを従来方法より増加させ るためには、 原料充塡層上方に設けた加圧フー ド内を 1 00〜 3000 mm In order to increase the mass flow rate and the static pressure level in the raw material packed bed compared to the conventional method, the pressure hood provided above the raw material packed bed must be 100 to 3000 mm.
A qの範囲で加圧し、 原料充塡層の下方から— 2000 1 mmA qでガス を供給する。 原料充塡層上方の圧力が 1 00匪 A q未満であれば、 従来 の操業に比べてあま り生産性に変化がな く 、 原料充塡層上方の圧力 が 3000mmAq超となると、 原料充塡層上下の差圧が大き く なりすぎて 、 重力と送風圧力が重畳して原料充塡層を圧縮する力が大き く なり 、 原料充塡層が圧密化して通気性が悪化するため好ま し く ない。 さ らに、 加圧力を大き く するほど、 フー ドとフー ドと接する対象物と の間からの漏風が増し、 シールが困難になるこ とや、 大がかりな設 備を必要とするなどの問題が起きる。 パレ ツ 卜直下にあるウィ ン ド ボッ クスの吸引負圧は、 原料充填層の上下の差圧パターンの設定な どによる力く、 一 2000〜一 1 mmAqの範囲にする。 一 2000mmA q未満であ れば、 原料充¾層上方を加圧しても、 原料充塡層内の静圧レベルが 従来法よりあま り大き く ならないので、 酸素供給速度増によるコー クス燃焼速度の増加やガス密度増による伝熱速度の増加は少ない。 一 1 nunAq超であれば、 排ガスを吸引するこ とができないからである 点火部からス トラ ン ド長さ 30〜 95 %の範囲内の原料充填層の上下 の差圧は、 層厚ゃパレツ 卜速度に依存するカ^ 1 000〜 3000mmAqにす るのが好ま しい。 原料充塡層上下の差圧が 1 000腿 Aq未満では、 原料 充塡層内の差圧が従来法より も小さ く 、 静圧を増すこ とによる効果 より も、 ガス流速が低下することによる悪影響が大き く なるからで ある。 原料充塡層内の差圧を 3000mmAq超にするこ とは、 重力と送風 圧力が重畳して原料充塡層を圧縮するので、 原料充塡層が圧密化し て通気性が悪化するため好ま し く ない。 Pressurize in the range of Aq, and supply gas at -2000 1 mmAq from below the raw material packed bed. If the pressure above the raw material bed is less than 100 Aq, the productivity will not change much compared to the conventional operation. If the pressure above the raw material bed exceeds 3000 mmAq, the raw material will be charged. This is preferable because the pressure difference between the top and bottom of the layer becomes too large, and the force of compressing the raw material bed increases due to the superposition of gravity and the blowing pressure, and the raw material packed layer becomes more compact and the air permeability deteriorates. Absent. In addition, as the pressure is increased, air leakage from the hood to the object in contact with the hood increases, making sealing difficult and requiring large-scale equipment. Happens. The suction negative pressure of the wind box just below the pallet is set in the range of 12000 to 1 mmAq, due to the setting of the differential pressure pattern above and below the raw material packed bed. If the pressure is less than 2000 mmAq, the static pressure level in the raw material bed will not be much higher than in the conventional method even if the upper part of the raw material bed is pressurized. The increase in heat transfer rate due to an increase in gas density is small. If it exceeds 1 nunAq, the exhaust gas cannot be sucked.The upper and lower sides of the raw material packed bed within the range of 30 to 95% of the strand length from the ignition part It is preferable that the pressure difference be between 1,000 and 3000 mmAq, which depends on the layer thickness and the pallet speed. When the pressure difference between the upper and lower parts of the raw material bed is less than 1 000 Aq, the pressure difference in the raw material bed is smaller than in the conventional method, and the gas flow rate is lower than the effect of increasing the static pressure. This is because the adverse effects increase. It is preferable to make the pressure difference in the raw material bed more than 3000 mmAq because the gravity and the blast pressure are superimposed to compress the raw material bed, so that the raw material bed becomes denser and the air permeability deteriorates. Not good.
点火部から排鉱部までの全範囲にス トラ ン ド長さ方向に複数に分 割して加圧フー ドを設けることにより、 点火部からス トラ ン ド長さ 30〜95 %の範囲内における原料充塡層に吸引する酸素含有ガスの質 量流量を、 前記範囲を除く ス ト ラ ン ドの範囲の原料充塡層に供給す る酸素含有ガスの質量流量に対して 1. 01〜 2. 6倍に、 さ らに原料充 塡層の層厚方向の差圧を前記範囲を除く ス 卜ラ ン ド範囲の原料充填 層の層厚方向の差圧に対して l . i〜 5. 0倍に容易に調節できる。 前述したように、 点火部からのス ト ラ ン ド長さ 30 %の範囲は、 原 料層上層部の歩留り、 焼結鉱の品質低下を防止するために高温保持 時間を保つ必要があり、 上層部の焼成においては燃焼帯の移行速度 を現状より増加できない。 従来の 400〜 600mmの層厚の場合、 点火 部からのス トラ ン ド長さ 30 %以下の範囲は原料充塡層上方から 1 00 〜 l O OOmmAqで加圧送風し、 パレッ ト直下にあるウィ ン ドボッ ク ス力、 ら吸引排気する吸引負圧は一 1 000〜一 1 mmAqにし、 原料充塡層の上 下の差圧を 300〜2000nnnAqに調節して、 従来の下方吸引の差圧と同 じ差圧または小さい差圧とすれば、 高温保持時間を確保または増加 し、 焼成に必要な熱量を得ることができる。 このとき、 原料充塡層 上層の酸素供給速度が増加するため、 酸素富化と同じよ うなコーク ス燃焼性の向上効果も得ることができ、 原料充塡層上層の歩留及び 品質の向上をさ らに図るこ とができる。 ただし、 ス トラ ン ド長さ 30〜95 %の範囲内の原料充填層以外は通 常の下方吸引で生産率を大き く する効果が比較的小さいため、 加圧 フ一 ドを点火部からス トラ ン ド長さ 30〜 95 %の範囲内に設ける こ と が設備の簡素化の点で好ま しい。 さ らに、 加圧フー ドをス トラ ン ド 長さ方向に複数に分割して設ければ、 点火部側から排鉱部側へ質量 流量を段階的に変化させるこ と もできる。 By providing a pressurized hood that is divided into multiple parts in the length direction of the strand in the entire range from the ignition section to the mining section, the strand length is within the range of 30 to 95% from the ignition section. The mass flow rate of the oxygen-containing gas sucked into the raw material bed in the above-mentioned range is 1.01 to 1.01 with respect to the mass flow rate of the oxygen-containing gas supplied to the raw material bed in the range of the strand excluding the above range. 2. The pressure difference in the layer thickness direction of the raw material packed bed is increased by a factor of 6 with respect to the pressure difference in the layer thickness direction of the raw material packed bed in the strand range excluding the above range. It can be easily adjusted by a factor of 0. As described above, in the range of the strand length of 30% from the ignition part, it is necessary to maintain the high-temperature holding time in order to prevent the yield of the upper part of the raw material layer and the deterioration of sinter quality. In the firing of the upper layer, the transition speed of the combustion zone cannot be increased from the current level. In the case of the conventional layer thickness of 400 to 600 mm, the area with a strand length of 30% or less from the ignition part is blown from the upper part of the raw material packed bed with 100 to 100 mmAq under pressure and directly below the pallet. The negative suction pressure for suction and exhaust from the wind box force is set to 11,000 to 11 mmAq, and the differential pressure between the upper and lower parts of the raw material bed is adjusted to 300 to 2,000 nnnAq to obtain the differential pressure of the conventional downward suction. If the pressure difference is the same or a small pressure difference, the high-temperature holding time can be secured or increased, and the calorific value required for firing can be obtained. At this time, the oxygen supply rate of the upper layer of the raw material packed bed is increased, so that the same effect of improving coke combustibility as oxygen enrichment can be obtained, and the yield and quality of the upper layer of the raw material packed bed can be improved. You can do more. However, since the effect of increasing the production rate by the normal downward suction is relatively small except for the raw material packed bed with a strand length within the range of 30 to 95%, the pressurized feed is moved from the ignition section to the It is preferable to set the length within a range of 30 to 95% in terms of simplification of equipment. Furthermore, if the pressurized hood is divided into a plurality of pieces in the length direction of the strand, the mass flow rate can be changed stepwise from the igniting section to the mining section.
さ らに、 原料充塡層のパレッ 卜側壁からパレ ツ 卜幅方向に 5 %以 内の側壁近傍は中心部に比較して通気抵抗が大き く ないため、 燃焼 溶融帯の移行速度が大きい。 このため、 原料充填層の幅方向の 5 〜 95 %の範囲内に加圧フー ドを設け、 燃焼溶融帯の移行速度が幅方向 に均一になるよう にガスを供給すれば、 燃焼溶融帯の移行速度を増 加する効果がさ らに大き く なる。 Furthermore, the transition speed of the combustion melting zone is high because the vicinity of the side wall within 5% in the pallet width direction from the pallet side wall of the raw material packed layer has less airflow resistance than the center part. For this reason, if a pressure hood is provided within the range of 5 to 95% of the width of the raw material packed bed and gas is supplied so that the transition speed of the combustion melting zone becomes uniform in the width direction, the combustion melting zone The effect of increasing the transition speed is even greater.
加圧フ一 ドは移動する焼結パレッ 卜の上方に設置するカ^ 漏風を 避けるため加圧フー ドの下端にシール機構を設けるこ とが好ま しい 。 シール機構と しては、 第 6図に例示するように、 加圧フー ド 19の 内圧により フー ド下端部に設けたシー ト 24を原料充塡層 7 の上面に 押しつけるこ とにより シールし、 パレッ トの移動と共に原料充塡層 7 上を摺動させる構造が好ま しい。 また、 数段のシール機構 23を設 けた構造、 加圧フー ド 19と原料充塡層 7 との間に加圧フー ド 19の外 側からエアーブローする構造、 パレツ ト 6 の側壁部などを利用 して シール機構を設けるこ となどもでき、 これらの例に限られたもので はない。 The pressure hood is installed above the moving sintering pallet. It is preferable to provide a seal mechanism at the lower end of the pressure hood to avoid air leakage. As shown in FIG. 6, the sealing mechanism is such that the sheet 24 provided at the lower end of the hood is pressed against the upper surface of the raw material-filled layer 7 by the internal pressure of the pressurizing hood 19 to seal, A structure in which the pallet is slid on the raw material packed layer 7 as it moves is preferable. In addition, a structure having several stages of sealing mechanisms 23, a structure in which air is blown from the outside of the pressure hood 19 between the pressure hood 19 and the raw material packed layer 7, a side wall of the pallet 6, and the like are provided. It is also possible to provide a sealing mechanism by utilizing it, and it is not limited to these examples.
点火部からのス トラ ン ド長さ 30〜95 %の範囲内、 特に好ま し く は ス トラ ン ド長さ 60〜 80 %までの範囲の加圧フー ド内に、 酸素濃度を 12〜 21 vo l %未満に調整したガスを供給して焼成すると RD 1の向上 に良いマグネタイ トの生成が促進され、 コーク ス中窒素の NOx への 酸化も抑制するこ とができ、 RD I改善と NOx発生の抑制に有効であ る。 加圧フー ド内の酸素濃度を 12〜 21vol%未満に調整するには、 焼結機の排ガスの一部を循環利用できる。 この場合、 原料充塡層上 方からガスを供給した風量を排ガス処理設備に送れるよう に吸引負 圧と風量、 設備の大きさなどを加味して排ガス循環用のブロア一の 能力を設計する。 The oxygen concentration should be between 12 and 21 in the pressurized hood in the range of 30-95% of the strand length from the igniter, and particularly preferably in the range of 60-80% of the strand length. Supplying a gas adjusted to less than vol% promotes the generation of magnetite that improves RD1 and suppresses the oxidation of nitrogen in coke to NOx, improving RDI and reducing NOx. It is effective in controlling the occurrence You. To adjust the oxygen concentration in the pressurized hood to less than 12 to 21 vol%, part of the exhaust gas from the sintering machine can be recycled. In this case, the capacity of the blower for exhaust gas circulation is designed by taking into account the suction negative pressure, the air flow, and the size of the equipment so that the air flow from the upper part of the raw material packed bed can be sent to the exhaust gas treatment equipment.
酸素濃度が 21vol%未満では、 マグネタイ トの生成が促進される ことにより RD!が改善され、 酸素濃度が低いこ とによりコ一ク ス中 窒素の NOxへの酸化が抑制されるが、 12vol%未満になる と生産性 低下の悪影響が顕著になるため、 酸素濃度は 12vol%以上 21vol% 未満が好ま しい。 特に、 酸素濃度を 18vol%未満にすると、 RDI改 善と NOx発生の抑制の効果はより顕著になる。 When the oxygen concentration is less than 21 vol%, RD! Is improved by promoting the generation of magnetite, and when the oxygen concentration is low, the oxidation of nitrogen in the coke to NOx is suppressed. If it is less than 10%, the adverse effect of the decrease in productivity becomes remarkable. Therefore, the oxygen concentration is preferably 12 vol% or more and less than 21 vol%. In particular, when the oxygen concentration is less than 18 vol%, the effects of improving RDI and suppressing NOx generation become more remarkable.
特開平 4 一 168234号公報に記載されている、 パレ ツ ト進行方向と 平行に幅方向に板状のシンターケーキ支持スタ ン ドを複数枚設置し た焼結機を用いて焼成中にシ ンタ一ケーキを支持するこ とにより、 原料充塡層の下層部にシ ンターケーキの荷重が加わらな く なり、 原 料充塡層の下層部の通気性を改善して、 生産率が大き く 向上する。 さ らに、 シ ンターケーキの荷重が軽減されただけ、 原料充塡層上下 の差圧を増すことができ、 生産率をさ らに向上できる。 シ ンターケ ーキ支持スタ ン ドの一例を第 7図に示す。 板状のシ ンターケーキ支 持スタ ン ド 21の最適設置枚数はパレツ ト 6 の大きさによる力 例え ば幅 4 m、 長さ 2 mのパレ ツ 卜で、 原料充填層厚 500~ 600mmの焼 結機では、 2〜10枚であり、 高さは 200〜 400關とするのが好ま し い。 シ ンタ一ケーキ支持スタ ン ドの枚数が多いほどシ ンタ一ケーキ に対して十分な支持効果が発揮できる。 しかし、 10枚を超えると シ ンターケーキ支持スタ ン ドの占める体積が増え、 逆に生産率に対す る悪影響が顕在化し始め、 生産率の低下が見られるよう になる。 シ ンターケーキ支持スタ ン ドでシ ンタ一ケーキを支持すると通気性が さ らに向上し、 コークス燃焼速度が大き く なるために CO発生量が増 加し、 その結果生成した NOを COガスで還元する反応が活発になるた めに、 NOxの発生も抑制される。 このよう に、 本発明においてシン タ一ケーキ支持スタ ン ドを複数枚設置するこ とにより、 両立が困難 であった NOx発生抑制と、 生産率向上、 成品歩留向上、 焼結鉱品質 向上とを同時に実現できる。 During sintering using a sintering machine described in JP-A-4-1168234, in which a plurality of plate-shaped sinter cake supporting stands are installed in the width direction parallel to the pallet traveling direction, the sintering is performed. By supporting one cake, the load of the sinter cake is not applied to the lower part of the raw material bed, and the air permeability of the lower part of the raw material bed is improved, and the production rate is greatly improved. I do. Furthermore, as the load on the sinter cake is reduced, the pressure difference between the upper and lower layers of the raw material bed can be increased, and the production rate can be further improved. Fig. 7 shows an example of the Sinter Cake support stand. The optimal number of plate-shaped sinter cake support stands 21 depends on the size of the pallet 6, for example, a 4 m wide and 2 m long pallet. At the conclusion, it is 2 to 10 sheets and the height is preferably 200 to 400. The more the number of sinter cake support stands, the more the sinter cake support effect can be exhibited. However, if the number of sheets exceeds 10, the volume occupied by the sinter cake support stand will increase, and conversely, the adverse effect on the production rate will begin to appear, and the production rate will begin to decline. If the sinter cake is supported by the sinter cake support stand, breathability is improved. Furthermore, the amount of CO generated increases due to the increased coke combustion rate, and the reaction to reduce the generated NO with CO gas becomes more active, thereby suppressing the generation of NOx. . As described above, by installing a plurality of sinter cake support stands in the present invention, it is possible to suppress the generation of NOx, which was difficult to achieve at the same time, to improve the production rate, improve the product yield, and improve the sinter quality. Can be realized simultaneously.
本発明が Si02を 3.9〜 4.9mass%含む低 Si02焼結鉱の製造に特に 有効であるのは、 Si02が 4.9mass%以下になる と石灰石配合比が下 がるこ とや CaOと Si02のスラグ主成分の減少の影響で生産率や RD1 の悪化が顕著になり始め、 3.9mass%未満になる と本発明によって も生産率や RD!の悪化を改善できないからである。 The present invention is of particularly useful for the production of low Si0 2 sinter containing Si0 2 3.9~ 4.9mass% is, Si0 2 is a call want underlying limestone blending ratio becomes below 4.9Mass% and a CaO Si0 2 of the influence of the reduction of slag main component begin to remarkable deterioration of the production rate and RD1, because can not improve the production rate and RD! exacerbated also by the present invention and is less than 3.9mass%.
本発明により、 点火部から排鉱部までのス トラ ン ドのうち、 点火 部からのス トラ ン ド長さ 30〜95%の範囲内の原料充塡層に吸引する 酸素含有ガスの質量流量を、 前記範囲を除く ス ト ラ ン ドの範囲の原 料充填層に吸引する酸素含有ガスの質量流量に対して 2.6倍まで増 加させることができるため、 従来の 400〜 600mmの層厚での焼結操 業では焼結パレッ 卜の移動速度を従来の 2.0倍以上に増加させる こ とができる。 さ らに、 原料充填層の層厚を 600〜 1500mmと従来の 2 倍以上とするこ とさえ可能で、 これにより焼結機の生産率を従来の 焼結生産率に対して最大 2.0倍にまで向上するこ とが可能で、 絶大 な生産率向上効果を発揮すると と もに、 成品歩留りおよび品質の向 上、 排ガス風量原単位の削減効果を発揮する。 また、 生産率を一定 に保ち、 成品歩留りや焼結鉱品質の向上、 排ガス風量原単位の削減 を図るこ と もできる。 According to the present invention, the mass flow rate of the oxygen-containing gas sucked into the raw material packed bed within the range of 30 to 95% of the length of the strand from the ignition section in the strand from the ignition section to the mining section Can be increased up to 2.6 times the mass flow rate of the oxygen-containing gas sucked into the raw material packed bed in the range of the strand excluding the above range, so that the conventional layer thickness of 400 to 600 mm can be obtained. In the sintering operation, the moving speed of the sintering pallet can be increased 2.0 times or more compared to the conventional method. In addition, the thickness of the material-filled bed can be as large as 600 to 1500 mm, which is more than twice the conventional thickness, thereby increasing the production rate of the sintering machine up to 2.0 times the conventional sintering production rate. It has the tremendous effect of improving the production rate as well as improving the product yield and quality, and reducing the basic unit of exhaust gas flow rate. In addition, the production rate can be kept constant, and the product yield and sinter quality can be improved, and the exhaust gas flow rate can be reduced.
また、 原料充塡層下方から吸引する吸引負圧を小さ く するほど、 パレ ツ 卜 とウィ ン ドボッ クスとの間の摺動部からの外気の流入を減 少させることができる。 従って、 焼成に有効な風量が増加し漏風が 低減するので、 さ らに生産性も向上し風量原単位も低減できる。 本発明の焼結鉱製造方法に用いる焼結機と しては、 焼結ス ト ラ ン ド下部の複数のウィ ン ドボッ クスを吸引ダク トに並列に接続し、 該 吸引ダク トにメ ィ ンブロア一を設けた従来の構造にさ らにブロア一 を加え、 点火部から排鉱部までの吸引ダク ト長の 30〜95 %の範囲内 の任意の箇所から吸引 し、 かつ該吸引ダク 卜に排出するこ とにより 、 点火部からス ト ラ ン ド長さ 30〜 95 %の範囲内における原料充填層 に供給する酸素含有ガスの質量流量を、 前記範囲を除く ス ト ラ ン ド の範囲の原料充塡層に吸引する酸素含有ガスの質量流量に対して 1 . 0 1〜 2. 6倍にし、 さ らに原料充塡層の層厚方向の差圧を前記範囲を 除く ス ト ラ ン ド範囲の原料充塡層の層厚方向の差圧に対して 1. 1〜 5. 0倍に調節することができる。 Further, as the suction negative pressure sucked from below the raw material packed bed is reduced, the inflow of outside air from the sliding portion between the pallet and the wind box can be reduced. Therefore, the effective air volume for firing increases, and Because of the reduction, productivity can be further improved and the unit air volume can be reduced. As a sintering machine used in the method for producing a sintered ore of the present invention, a plurality of wind boxes at the lower part of a sintering strand are connected in parallel to a suction duct, and In addition to the conventional structure with a blower, a blower is added, and suction is performed from any point within the range of 30 to 95% of the suction duct length from the ignition section to the mining section, and the suction duct is used. The mass flow rate of the oxygen-containing gas supplied to the raw material packed bed within the range of 30 to 95% of the length of the strand from the ignition part is reduced by the range of the strand excluding the above range. 1.0 to 2.6 times the mass flow rate of the oxygen-containing gas to be sucked into the raw material bed, and the pressure difference in the thickness direction of the raw material bed except for the above range It can be adjusted to 1.1 to 5.0 times the pressure difference in the thickness direction of the raw material packed bed in the range of the command.
さ らに、 前記吸引ダク トを点火部からス トラ ン ド長さ 30〜95 %の 範囲内と残りの範囲に分割し、 各々独立してブロア一を設置した構 造が質量流量、 差圧の調節の点で好ま しい。 ブロア一はス トラ ン ド の前段、 中段、 後段用と 3機設けても良いが、 前段と後段は差圧を 変える必要がないため前段と後段を連結し、 ス ト ラ ン ド長さ 30〜95 %の範囲内の中段用とそれ以外の範囲用の 2機とするこ とが好ま し い。 Furthermore, the suction duct is divided into a range of 30 to 95% of the length of the strand from the ignition part and the remaining range, and the structure in which the blowers are installed independently is the mass flow rate and the differential pressure. It is preferable in terms of adjusting the position. Although three blowers may be provided for the front, middle and rear stages of the strand, the front and rear stages do not need to change the differential pressure, so the front and rear stages are connected to each other, and the strand length is 30 It is preferable to use two aircraft for the middle stage within the range of ~ 95% and for the other range.
上方からの加圧を組み合わせる場合には、 加圧する原料充塡層の 上にフー ドを設け、 フー ド内を加圧してフ一 ド内の圧力と下方にあ るウィ ン ドボッ クス内の圧力を計測するのが好ま しい。 さ らに、 フ ー ドと原料充塡層との間、 およびノまたはフー ドとパレツ ト との間 でシール構造を設けることが望ま しい。 実施例 When combined with pressurization from above, a hood is provided on the raw material bed to be pressurized, and the inside of the hood is pressurized and the pressure in the hood and the pressure in the window box below It is preferable to measure Further, it is desirable to provide a seal structure between the hood and the raw material packed bed and between the hood or the hood and the pallet. Example
本発明を実施例 1 , 2, 3 により詳細に説明する。 焼結面積 500m 2 で焼結パレッ ト幅 5 mの実機焼結機をそれぞれ 一部改造して、 1 水準 7 日間ずつの操業を行った。 The present invention will be described in more detail with reference to Examples 1, 2, and 3. Sintering area 500 meters 2 in the sintering pallet width 5 m actual sintering machine was modified part respectively, were run of one level for 7 days.
実施例 1 Example 1
第 1 図から第 3図は本発明の焼結機の実施例を示す図である。 焼 結配合原料 1 はサージホッパー 2 から ドラムフ ィ ーダー 3 、 原料装 入装置 5 を介してパレツ ト 6上に連続的に供給され、 パレ ツ 卜 6上 に原料充塡層 7 と して層状に積層される。 この間、 原料給鉱側のス プロケッ ト 4 を回転させてパレツ 卜 6 を所定の速度で移動させると 共に、 パレ ッ ト 6 の下側に複数個設けたウィ ン ドボッ クス 8 、 メ イ ンダク ト 9 、 排ガス集塵機 10を経てブロア一 11により吸気し、 煙突 12より排ガスを排出する。 さ らに、 メ イ ンダク ト 9 の一部にはサブ ダク ト 13が連設されており、 排ガス集塵機 14を経てブロア一 15によ り吸気し、 排ガスをメ イ ンダク ト 9 に戻す。 プロァ一 15により吸気 した排ガスは、 煙突 12より排出すること もできる。 また、 メ イ ンダ ク ト 9 には、 ダク ト内の負圧を調節するダンバ一16などを設けるこ とが望ま しい。 1 to 3 are views showing an embodiment of the sintering machine of the present invention. The sintering blended raw material 1 is continuously supplied from the surge hopper 2 to the pallet 6 via the drum feeder 3 and the raw material charging device 5, and is layered on the pallet 6 as a raw material filling layer 7. It is laminated. During this time, the sprocket 4 on the raw material supply side is rotated to move the pallet 6 at a predetermined speed, and at the same time, a plurality of wind boxes 8 and a main box provided below the pallet 6 are provided. 9, Intake by the blower 11 through the exhaust gas dust collector 10 and exhaust from the chimney 12. Further, a sub duct 13 is connected to a part of the main duct 9, and the sub duct 13 is taken in by a blower 15 through an exhaust gas dust collector 14, and the exhaust gas is returned to the main duct 9. Exhaust gas taken in by the probe 15 can also be discharged from the chimney 12. Further, it is desirable that the main body 9 be provided with a damper 16 for adjusting the negative pressure in the duct.
点火炉 27により原料充塡層 7 の上面に点火して、 パレツ ト 6上の 原料充塡層 7が排鉱部に達する間に全層にわたつて焼結反応を完了 させるよう に速度制御された連続運転が実施される。 煙突 12の前か らブロア一 18により、 排ガスを加圧フー ド 19に循環でき、 同時に空 気を混合することができる。 この加圧フー ド 19内を加圧する場合に は、 第 6 図に示すようなシ一ル機構 23を原料充塡層表層部とフ一ド の下端部との間に設けるこ とによりフー ド内圧を保つ。 パレツ ト進 行方向の長さ、 及びパレ ッ ト幅方向の長さを自由に設定できる。 さ らに、 この装置では、 原料充塡層 7 の層厚を 600~ 1500ΙΜΙと従来よ り厚く 充壙するこ と もできるようになつている。 The ignition furnace 27 ignites the upper surface of the raw material packed bed 7 and controls the speed so that the raw material packed bed 7 on the pallet 6 completes the sintering reaction over the whole bed while reaching the mining section. Continuous operation is performed. Exhaust gas can be circulated to the pressurized hood 19 by the blower 18 from the front of the chimney 12, and air can be mixed at the same time. When pressurizing the inside of the pressurized hood 19, a seal mechanism 23 as shown in FIG. 6 is provided between the surface layer portion of the raw material packed bed and the lower end of the hood. Maintain internal pressure. The length in the pallet traveling direction and the length in the pallet width direction can be set freely. Further, in this apparatus, the thickness of the raw material-filled layer 7 can be 600 to 1500 mm, which makes it possible to make the raw material-filled layer 7 thicker than before.
配合原料は、 低 Si02焼結鉱の製造を特に目的とせずに、 従来の一 般的な配合と して、 種々の鉄鉱石及び石灰石、 生石灰、 蛇紋岩、 ス ケール等の雑原料、 返鉱、 粉コークスを焼結鉱中の Si02が 5.8mass %, A 1203が 1.8mass%になるように調整し、 塩基度は 1.7になる ように配合した。 返鉱配合率は新原料の合計 100に対して 15%—定 、 コークス配合率は新原料の合計 100に対して 4.2%—定と した。 比較例、 実施例ともに同じ配合と した。 Blending raw materials, without particular for the manufacture of a low Si0 2 sinter, one conventional As a general formulation, various iron ore and limestone, quicklime, serpentinite, miscellaneous raw materials such as scale, return ores, Si0 2 is 5.8Mass% in sinter coke breeze, A 1 2 0 3 Was adjusted to 1.8 mass%, and the basicity was adjusted to 1.7. The return ratio was set at 15% based on the total of 100 new materials, and the coke ratio was set at 4.2% based on the total of 100 new materials. The same formulation was used for both the comparative example and the example.
配合原料に返鉱、 粉コークスを配合した後に水を添加して ミ キサ 一で混合、 造粒して焼結機に装入した。 操業は、 焼結完了点が排鉱 部の直前になるようにパレ ツ トスピー ドを調整した。 After returning ore and fine coke to the raw materials, water was added, mixed with a mixer, granulated, and charged into a sintering machine. In the operation, the pallet speed was adjusted so that the sintering completion point was immediately before the mining section.
実施例 1 aでは、 層厚を 550隱、 点火部からス トラ ン ド長さ 30% 、 及びス トラ ン ド長さ 95%から排鉱部までを一 1500mmAqと し、 ス ト ラ ン ド長さ 30〜95%の間を— 2500mmAqで下方吸引 し、 原料充塡層上 部は大気開放した。 この場合、 ス ト ラ ン ド長さ 30〜95%の範囲内で はそれ以外の範囲に対して、 質量流量比は 1.26で、 層厚方向の差圧 は 2500 Aqであつた。 In Example 1a, the layer thickness was 550 hidden, the length of the strand from the ignition section was 30%, and the length from the strand length of 95% to the mining section was 1500 mmAq. The air was sucked downward at a pressure of 2500 mmAq between 30 and 95%, and the upper part of the raw material packed bed was opened to the atmosphere. In this case, the mass flow ratio was 1.26 and the differential pressure in the layer thickness direction was 2500 Aq in the other range within the range of the strand length of 30 to 95%.
実施例 1 bでは、 層厚を 550mm、 点火部から排鉱部までを— 1000 mmAqで下方吸引 し、 ス トラ ン ド長さ 30〜 95%の間の原料充塡層上部 の加圧フー ド内を 1500mmAqに加圧した。 この場合、 ス トラ ン ド長さ 50〜95%の範囲内ではそれ以外の範囲に対して、 質量流量比は 1.27 で、 層厚方向の差圧は 2500mmAqであった。 In Example 1b, the layer thickness was 550 mm, the area from the ignition section to the mining section was suctioned downward at -1000 mmAq, and the pressurized hood on the upper portion of the raw material packed bed having a strand length of 30 to 95% was drawn. The inside was pressurized to 1500 mmAq. In this case, the mass flow ratio was 1.27 and the differential pressure in the layer thickness direction was 2500 mmAq in the range of the strand length of 50 to 95% with respect to the other range.
実施例 1 cでは、 層厚を 550mm、 点火部からス ト ラ ン ド長さ 30% 、 及びス ト ラ ン ド長さ 95%から排鉱部までを - 500mmAq で下方吸引 するとと もに、 該範囲にも加圧フー ドをさ らに続けて加圧フー ド内 の圧力を 500關 Aqと して加圧し、 ス トラ ン ド長さ 30〜 95%の間を一 lOOOimnAqで下方吸引すると と もに加圧フ一 ド内の圧力を 2000mniAqに 加圧した。 この場合、 ス トラ ン ド長さ 30〜95%の範囲内ではそれ以 外の範囲に対して、 質量流量比は 1.77で、 層厚方向の差圧は 3000難 Aqであった。 In Example 1c, the layer thickness was 550 mm, the length from the ignition section was 30% of the strand length, and the section from the 95% strand length to the mining section was suctioned downward at -500 mmAq. In this range, the pressure hood is further continued and the pressure in the pressure hood is increased to 500 Aq. At the same time, the pressure in the pressure hood was increased to 2000 mniAq. In this case, the mass flow ratio is 1.77 and the pressure difference in the layer thickness direction is 3000 when the strand length is within the range of 30 to 95%. Aq.
実施例 1 dでは、 層厚を 550nim、 点火部から排鉱部までを一 1000 mniAqで下方吸引 し、 ス ト ラ ン ド長さ 50〜90%のパレ ッ ト幅方向 1()〜 90%の範囲に設けた加圧フー ド内に煙突前の排ガスを循環して、 酸 素濃度を 18vol%に調節し、 1500mmAqに加圧した。 この場合、 ス ト ラ ン ド長さ 50〜90%の範囲内ではそれ以外の範囲に対して、 質量流 量比は 1.27で、 層厚方向の差圧は 2500龍 Aqであつた。 In Example 1d, the layer thickness was 550 nim, the area from the ignition section to the mining section was suctioned downward at a rate of 1000 mniAq, and a pallet width direction of 50 to 90% strand length 1 () to 90% Exhaust gas before the chimney was circulated in the pressure hood provided in the range, and the oxygen concentration was adjusted to 18 vol% and pressurized to 1500 mmAq. In this case, the mass flow rate ratio was 1.27 and the differential pressure in the thickness direction was 2500 dragon Aq in the range of 50 to 90% of the strand length.
実施例 1 eでは、 層厚を 550mm、 パレツ 卜 に板状のシ ンターケ一 キ支持スタ ン トをパレツ ト幅方向に均等に 4枚平行に設置し、 点火 部から排鉱部までを— 1000誦 Aqで下方吸引 し、 ス ト ラ ン ド長さ 5()〜 90%のパレ ッ ト幅方向 10〜 90%の範囲に設けた加圧フー ド内を 1500 mmAqに加圧した。 この場合、 ス トラ ン ド長さ 50〜 90%の範囲内では それ以外の範囲に対して、 質量流量比は 1.27で、 層厚方向の差圧は 2500顏 Aqであった。 In Example 1e, four layers of plate-shaped skeleton supporters were installed evenly in the pallet width direction in parallel on the pallet with a layer thickness of 550 mm, and the distance from the ignition part to the mining part was -1000. Suction was performed using Aq, and the inside of a pressure hood provided in the range of 10 to 90% in the pallet width direction with a strand length of 5 () to 90% was pressurized to 1500 mmAq. In this case, the mass flow ratio was 1.27 and the differential pressure in the thickness direction was 2500 face Aq in the range of 50 to 90% of the strand length.
実施例 1 f では、 層厚を 800ππη、 これ以外の設定は実施例 1 e と 同じにした。 この場合、 ス トラ ン ド長さ 50〜90%の範囲内ではそれ 以外の範囲に対して、 質量流量比は 1.27で、 層厚方向の差圧は 2500 mmAqであった。 In Example 1f, the layer thickness was 800ππη, and other settings were the same as in Example 1e. In this case, the mass flow ratio was 1.27 and the differential pressure in the layer thickness direction was 2500 mmAq in the range of the strand length of 50 to 90% with respect to the other range.
比較例は、 実施例と同じ配合原料を層厚 550 、 負圧 1500minAq— 定で点火部から排鉱部まで大気を吸引して、 配合原料層内は負圧で 焼結する従来法で焼結した。 In the comparative example, the same compounding material as in the example was sintered by the conventional method in which the atmosphere was sucked from the ignition section to the mining section at a constant layer thickness of 550 and a negative pressure of 1500 minAq. did.
第 1 表に比較例 1 と実施例 1 a 〜 1 f で得られた焼結鉱の生産率 、 成品歩留り、 RD1、 NOx排出量原単位を示す。 こ こで、 NOx排出 量原単位とは、 排ガス風量と排ガス中 NOx濃度との積で表される。 第 1 表から分かるように、 実施例 1 a 〜 1 f では比較例に対して生 産率が著しく 向上した。 また、 従来は生産率が向上すると成品歩留 りが低下する傾向があつたが、 本発明では成品歩留り も向上した。 さ らに、 RD1、 J1S- RKJIS規格による最終還元率) と NOx排出量原 単位も改善され、 操業面及び環境面において優れた効果を発揮でき た。 Table 1 shows the production rates, product yields, RD1, and NOx emissions per unit of the sintered ore obtained in Comparative Example 1 and Examples 1a to 1f. Here, the basic unit of NOx emission is represented by the product of the exhaust gas flow rate and the NOx concentration in the exhaust gas. As can be seen from Table 1, in Examples 1a to 1f, the production rate was significantly improved as compared with the comparative example. Further, conventionally, when the production rate is improved, the product yield tends to decrease, but in the present invention, the product yield is improved. In addition, the RD1, J1S-RKJIS standard (final reduction rate) and the basic unit of NOx emission were also improved, and excellent operational and environmental effects were achieved.
第 1 表 Table 1
実施例 2 Example 2
第 4図および第 5 図は本発明の焼結機の他の実施例を示す図で、 第 1 図および第 3図に示した実施例との相違点は、 メ イ ンダク 卜 9 を完全に分割して、 独立したブロア一 11, 15を設けている点である 。 さ らに、 ブロア一 2 9 を設けるこ と もできる。 ス トラ ン ド長さ方 向に圧力パター ンを複数設定する場合は、 このよ う にブロアーを複 数設ければ良い。 FIGS. 4 and 5 show another embodiment of the sintering machine of the present invention. The difference from the embodiment shown in FIGS. 1 and 3 is that the main duct 9 is completely removed. It is divided into independent blowers 11 and 15. In addition, a blower 29 can be provided. When setting a plurality of pressure patterns in the direction of the strand length, a plurality of blowers may be provided in this manner.
配合原料は実施例 1 と同じであり、 操業は、 焼結完了点が排鉱部 になるようにパレツ トスピー ドを調整した。 The blending raw materials were the same as in Example 1, and the operation was adjusted for the pallet speed so that the sintering completion point was in the mining part.
実施例 2 aでは、 層厚を 550ππη、 点火部からス トラ ン ド長さ 50% までを一 lOOOmmAqと し、 点火部からス トラ ン ド長さ 80%から排鉱部 までを一 1500mmAqで下方吸引 して原料充塡層上方は大気開放と し、 ス ト ラ ン ド長さ 50〜80%の間を— 500mmAq で下方吸引すると と もに 加圧フー ド内の圧力を 2000mmAqと して加圧した。 この場合、 ス トラ ン ド長さ 50〜80%の範囲内ではそれ以外の範囲に対して、 質量流量 比は 1.52で、 層厚方向の差圧は 2500mmAqであつた。 In Example 2a, the layer thickness was 550ππη, the length from the ignition part to the strand length of 50% was 1 lOOmmAq, and the distance from the ignition part to the strand length of 80% to the tailing part was 1500mmAq, and was lower at 1500mmAq. Suction is performed to open the upper part of the raw material packed bed to the atmosphere, and the lower part of the strand length of 50 to 80% is suctioned at -500 mmAq, and the pressure in the pressurized hood is set to 2000 mmAq. Pressed. In this case, if the strand length is within the range of 50 to 80%, the mass flow rate is The ratio was 1.52, and the differential pressure in the thickness direction was 2500 mmAq.
実施例 2 bでは、 層厚を 550mm、 点火部からス ト ラ ン ド長さ 50% までを一 500mmAq で下方吸引すると と もに、 該範囲にも加圧フー ド をさ らに設けて、 加圧フー ド内の圧力を 500mmAqと し、 ス ト ラ ン ド 長さ 80%から排鉱部までを一 1000關 Aqで下方吸引刷る と と もにフ一 ド内の圧力を 500mmAq と し、 ス トラ ン ド長さ 50〜 80%の間を一 1500 mmAqで下方吸引するとと もに加圧フー ド内の圧力を lOOOmmAqと して 加圧した。 この場合、 ス トラ ン ド長さ 50〜80%の範囲内ではそれ以 外の範囲に対して、 質量流量比は 1.56で、 層厚方向の差圧は 2500mm Aqであった。 In Example 2b, the layer thickness was 550 mm, the length from the ignition section to 50% of the strand length was suctioned downward at 1 500 mmAq, and a pressure hood was further provided in this range. The pressure in the pressurized hood was set to 500 mmAq, the pressure from the strand length of 80% to the mining part was reduced by 1000 Aq, and the pressure in the hood was set to 500 mmAq. Downward suction was performed at 1500 mmAq between strand lengths of 50-80%, and the pressure in the pressure hood was increased to 100 mmAq. In this case, the mass flow ratio was 1.56 and the pressure difference in the thickness direction was 2500 mm Aq in the range of 50 to 80% of the strand length.
実施例 2 cでは、 層厚を 800mmと し、 これ以外の設定は実施例 2 a と同じに した。 この場合、 ス トラ ン ド長さ 50~80%の範囲内では それ以外の範囲に対して、 質量流量比は 1.52で、 層厚方向の差圧は 2500mmAqであつた c In Example 2c, the layer thickness was 800 mm, and other settings were the same as in Example 2a. In this case, the mass flow ratio was 1.52 and the differential pressure in the layer thickness direction was 2500 mmAq in the range of 50 to 80% of the strand length c.
実施例 2 dでは、 層厚を 800議と し、 パレツ トに板状の シ ンター ケーキ支持スタ ン ドをパレツ ト幅方向に均等に 4枚平行に設置し、 これ以外の設定は実施例 2 a と同じにした。 この場合、 ス ト ラ ン ド 長さ 50〜 80%の範囲内ではそれ以外の範囲に対して、 質量流量比は 1.52で、 層厚方向の差圧は 2500mmAqであった。 In Example 2d, the layer thickness was set to 800, and four plate-like sinter cake support stands were installed on the pallet evenly in the width direction of the pallet. Same as a. In this case, the mass flow ratio was 1.52 and the differential pressure in the layer thickness direction was 2500 mmAq in the range of the strand length of 50 to 80%, compared to the other range.
比較例 1 は、 実施例 2a〜2dと同じ配合原料を層厚 550ππη、 負圧 15 00關 Aq—定で点火部から排鉱部まで大気を吸引 して、 配合原料層内 は負圧で焼結する従来法で焼結した。 In Comparative Example 1, the same blended raw material as in Examples 2a to 2d was suctioned from the ignition section to the mining section at a layer thickness of 550ππη and a negative pressure of 1500 Aq, and the inside of the blended raw material layer was baked at a negative pressure. Sintered by conventional methods.
第 2表に比較例 1 と実施例 2 a〜 2 dで得られた焼結鉱の生産率 、 成品歩留り、 RDI、 NOx排出量原単位を示す。 第 2表から分かる ように、 実施例 2 a〜 2 dでは比較例に対して生産率が著し く 向上 した。 また、 従来は生産率が向上すると成品歩留りが低下する傾向 があったが、 本発明では成品歩留り も向上した。 さ らに、 RDし JI S - R Iと NOx排出量原単位も改善され、 操業面及び環境面において優 れた効果を発揮できた。 Table 2 shows the production rate, product yield, RDI, and NOx emission rate of the sintered ore obtained in Comparative Example 1 and Examples 2a to 2d. As can be seen from Table 2, the production rates of Examples 2a to 2d were remarkably improved as compared with the comparative examples. Further, conventionally, when the production rate is improved, the product yield tends to decrease, but in the present invention, the product yield is also improved. In addition, RD and JI The unit emissions of S-RI and NOx have also been improved, and excellent operational and environmental benefits have been achieved.
なお、 前記公知技術の特公平 5 - 55574 号公報との比較を合わせ て第 2表の続きと して下記表に示す。 この表より、 本発明の実施例 2 dでは、 焼結鉱の特性と して本公知技術の値を凌駕する、 極めて良 好な特性を有することがわかる。 The following table is a continuation of Table 2 together with a comparison with the above-mentioned known technique in Japanese Patent Publication No. 5-55574. From this table, it can be seen that Example 2d of the present invention has extremely excellent characteristics as the characteristics of the sintered ore that surpasses the values of the known technology.
第 2表 Table 2
(第 2表つづき) (Continued from Table 2)
実施例 3 Example 3
実施例 1 および実施例 2 と同様の焼結機を用いた。 配合原料は低 S i 0 2焼結鉱の製造を目的と して、 種々の鉄鉱石及び石灰石、 生石灰 、 蛇紋岩、 スケール等の雑原料、 返鉱、 粉コークスを焼結鉱中の Si 02が 4.6mass%、 Al 203が 1.85mass%になるよう に調整し、 塩基度 は 1.9になるように配合した。 返鉱配合率は新原料の合計 100に対 して 15%—定、 コークス配合率は新原料の合計 100に対して 3.5% 一定と した。 比較例、 実施例と もに同 じ配合と した。 The same sintering machine as in Examples 1 and 2 was used. Blending raw materials intended for the manufacture of low S i 0 2 sinter, various iron ore and limestone, quicklime , Serpentine, miscellaneous raw materials such as scale, return ores, Si 0 2 is 4.6Mass% in sinter coke breeze, Al 2 0 3 was adjusted to be 1.85Mass%, basicity becomes 1.9 Was blended as follows. The ratio of returned ore is fixed at 15% based on the total of 100 new materials, and the ratio of coke is fixed at 3.5% with respect to the total of 100 new materials. The same formulation was used for both the comparative example and the example.
実施例 3 aでは、 層厚を 550mni、 点火部からス 卜ラ ン ド長さ 60% 、 及びス ト ラ ン ド長さ 80%から排鉱部までを— 1500mmAqで下方吸引 し、 ス ト ラ ン ド長さ 60〜80%の間を一 2500ΙΜΙΑ(1で下方吸引 して大気 を吸引 した。 この場合、 ス トラ ン ド長さ 60〜80%の範囲内ではそれ 以外の範囲に対して、 質量流量比は 1.26で、 層厚方向の差圧は 2500 關 Aqであった。 In Example 3a, a layer thickness of 550 mni, a stroke length of 60% from the ignition part, and a stroke length of 80% from the strand length to the mining part were suctioned downward at −1500 mmAq. The air was suctioned by suctioning downward at 1,500 mm (1) between the strand lengths of 60-80%. In this case, if the strand length was within the range of 60-80%, The mass flow ratio was 1.26 and the pressure difference in the thickness direction was 2500 Aq.
実施例 3 bでは、 層厚を 550mm、 点火部からス ト ラ ン ド長さ 60% までの焼成初期、 及びス トラ ン ド長さ 80%から排鉱部までの焼成終 期を— 1500mmAqで下方吸引 し、 その範囲の排ガスの一部をス トラ ン ド長さ 60〜80%の間のパレツ ト上部に、 空気を混合して酸素濃度 1 6vol%と して循環して— 2500mmAqで下方吸引 した。 この場合、 ス ト ラ ン ド長さ 60〜 80%の範囲内ではそれ以外の範囲に対して質量流量 比は 1.38で、 層厚方向の差圧は 2500mmAqであつた。 In Example 3b, the thickness of the layer was 550 mm, the initial firing period from the ignition portion to the strand length of 60%, and the final firing period from the strand length of 80% to the mining portion was-1500 mmAq. Aspirate downward, and part of the exhaust gas in that range is mixed with air and circulated to the upper part of the pallet with a strand length of 60 to 80% to an oxygen concentration of 16 vol%, and circulated downward at 2500 mmAq. Aspirated. In this case, the mass flow ratio was 1.38 within the range of the strand length of 60 to 80% and the pressure difference in the thickness direction was 2500 mmAq.
実施例 3 cでは、 層厚を 550mm、 点火部からス トラ ン ド長さ 60% 、 及びス トラ ン ド長さ 80%から排鉱部までを— 500mmAq で下方吸引 するとと もに、 該範囲に加圧フー ドをさ らに設けて、 加圧フー ド内 の圧力を 500mmAqと し、 ス ト ラ ン ド長さ 60〜 80%の間を一 1500mmAq で下方吸引する と と もに加圧フ一 ド内の圧力を lOOOmmAqと して煙突 前の排ガスの一部を酸素濃度を 16%に調節して加圧送風した。 この 場合、 ス トラ ン ド長さ 60〜80%の範囲内ではそれ以外の範囲に対し て質量流量比は 1.56で、 層厚方向の差圧は 2500mmAqであつた。 In Example 3c, the layer thickness was 550 mm, the strand length from the ignition section was 60%, and the strand length from 80% to the mining section was suctioned downward at -500 mmAq. A pressure hood is further provided in the pressure hood, the pressure in the pressure hood is set to 500 mmAq, and a pressure of 1500 mmAq is drawn downward between a strand length of 60 to 80% and pressurized. With the pressure inside the hood at 100 mmAq, a part of the exhaust gas before the chimney was blown under pressure with the oxygen concentration adjusted to 16%. In this case, the mass flow ratio was 1.56 and the differential pressure in the thickness direction was 2500 mmAq in the range of the strand length of 60 to 80% with respect to the other range.
比較例 2 は、 実施例 3 a〜 3 c と同じ配合原料を層厚 550ιππι、 負 圧 1500imnAq—定で点火部から排鉱部まで大気を吸引 して、 配合原料 層内は負圧で焼結する従来法で焼結した。 In Comparative Example 2, the same compounding raw material as in Examples 3a to 3c was used with a layer thickness of 550ιππι and a negative The atmosphere was sucked from the ignition section to the mining section at a constant pressure of 1500 imnAq, and the inside of the mixed material layer was sintered by a conventional method of sintering at a negative pressure.
第 3表に比較例と実施例 3 a - 3 cで得られた焼結鉱の生産率、 成品歩留り、 RD1、 NOx排出量原単位を示す。 第 3表から分かるよ うに、 実施例 3 a〜 3 cでは比較例に対して生産率が著し く 向上し た。 また、 従来は生産率が向上すると成品歩留りが低下する傾向が あつたが、 本発明では成品歩留り も向上した。 さ らに、 RDI、 JIS- RIと NOx排出量原単位も改善され、 操業面及び環境面において優れ た効果を発揮するとともに、 低 Si02焼結鉱の製造ができた。 Table 3 shows the production rates, product yields, RD1 and NOx emission basic units of the sintered ore obtained in Comparative Example and Examples 3a to 3c. As can be seen from Table 3, in Examples 3a to 3c, the production rate was significantly improved as compared with the comparative example. Further, conventionally, when the production rate is improved, the product yield tends to decrease, but in the present invention, the product yield is also improved. Et al is, RDI, JIS-RI and NOx emissions per unit is also improved, as well as an excellent effect in operation plane and environmental, it could manufacture a low Si0 2 sinter.
第 3表 Table 3
なお、 焼結時の負圧の設定や吸引ガスの酸素濃度と吸引時間は上 記実施例に限るものではなく、 生産性指向や RDI、 J1S- RI改善指向 、 NOx排出抑制指向、 排ガス量抑制指向で変化させることができる o The setting of the negative pressure during sintering, the oxygen concentration of the suction gas, and the suction time are not limited to those in the above-described embodiment.Productivity orientation, RDI, J1S-RI improvement orientation, NOx emission reduction orientation, exhaust gas volume reduction Can be changed by pointing o
本発明によれば、 従来困難であった大幅な配合原料充塡層の層厚 の増加ゃパレツ 卜移動速度の増加が可能となり、 焼結機の生産率を 大幅に向上させることができる。 さ らに、 成品歩留りや RDし JIS- RIが改善され、 排ガス量が低減される。 このよう に本発明は両立し 難い改善効果を同時にもたら しており、 その効果は非常に大きい。 ADVANTAGE OF THE INVENTION According to this invention, the layer thickness of the compounding material packed bed which had been difficult conventionally can be increased greatly, and the pallet moving speed can be increased, and the production rate of the sintering machine can be greatly improved. In addition, the product yield and RD for JIS-RI are improved, and the amount of exhaust gas is reduced. As described above, the present invention simultaneously provides an incompatible improvement effect, and the effect is extremely large.
Claims
Priority Applications (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE69716231T DE69716231T2 (en) | 1996-08-16 | 1997-08-15 | METHOD AND DEVICE FOR SINTERING MINERALS |
| JP51056998A JP3930570B2 (en) | 1996-08-16 | 1997-08-15 | Method for producing sintered ore and sintering machine therefor |
| BR9706625-7A BR9706625A (en) | 1996-08-16 | 1997-08-15 | Sintered ore production method and sintering machine for the same |
| AU38653/97A AU697445B2 (en) | 1996-08-16 | 1997-08-15 | Method of producing sintered ore and sintering machine therefor |
| EP97935796A EP0861908B1 (en) | 1996-08-16 | 1997-08-15 | Method of manufacturing sintered ore and sintering machine therefor |
| KR1019980702769A KR100257441B1 (en) | 1996-08-16 | 1998-04-16 | Method of manufacturing sintered ore and sintering machine therefor |
Applications Claiming Priority (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8/233696 | 1996-08-16 | ||
| JP23369696 | 1996-08-16 | ||
| JP27858696 | 1996-10-01 | ||
| JP8/278586 | 1996-10-01 | ||
| JP18026597 | 1997-06-23 | ||
| JP9/180265 | 1997-06-23 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO1998007891A1 true WO1998007891A1 (en) | 1998-02-26 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/JP1997/002843 Ceased WO1998007891A1 (en) | 1996-08-16 | 1997-08-15 | Method of manufacturing sintered ore and sintering machine therefor |
Country Status (8)
| Country | Link |
|---|---|
| EP (1) | EP0861908B1 (en) |
| JP (1) | JP3930570B2 (en) |
| KR (1) | KR100257441B1 (en) |
| CN (1) | CN1062913C (en) |
| AU (1) | AU697445B2 (en) |
| BR (1) | BR9706625A (en) |
| DE (1) | DE69716231T2 (en) |
| WO (1) | WO1998007891A1 (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009523912A (en) * | 2006-01-19 | 2009-06-25 | シーメンス・ファオアーイー・メタルズ・テクノロジーズ・ゲーエムベーハー・ウント・コ | Process for sintering in sintering equipment |
| JP2011252203A (en) * | 2010-06-02 | 2011-12-15 | Nippon Steel Corp | Method for manufacturing sintered ore, method for designing sinter cake supporting stand, and method for determining layer thickness of raw material filling-up layer |
| WO2014080450A1 (en) | 2012-11-20 | 2014-05-30 | Jfeスチール株式会社 | Oxygen-gas fuel supply device for sintering machine |
| CN113215390A (en) * | 2020-12-24 | 2021-08-06 | 北京高能时代环境技术股份有限公司 | Copper-containing sludge sintering method |
| US11104643B2 (en) | 2017-06-19 | 2021-08-31 | Unitika Ltd. | Bismaleimide modified product and method for producing the same |
| JPWO2021172254A1 (en) * | 2020-02-27 | 2021-09-02 |
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|---|---|---|---|---|
| AU2006309650B8 (en) * | 2005-10-31 | 2010-12-16 | Jfe Steel Corporation | Method for producing sintered ore and sintering machine |
| JP4590001B2 (en) * | 2008-02-27 | 2010-12-01 | 新日本製鐵株式会社 | Method for producing sintered ore and sintering machine |
| CN101881559B (en) * | 2010-07-22 | 2011-11-16 | 张健 | Novel energy-saving sintering machine |
| CN103033064B (en) * | 2012-12-28 | 2015-03-11 | 北京世纪源博科技股份有限公司 | Device for recovering waste heat of sintering flue gas |
| CN103033063B (en) * | 2012-12-28 | 2016-05-18 | 北京世纪源博科技股份有限公司 | Sinter fume exhaust heat recovering method |
| CN115143792B (en) * | 2022-07-22 | 2025-06-24 | 山东钢铁股份有限公司 | Sintering machine and method for improving sintering yield |
| JPWO2024117144A1 (en) * | 2022-11-29 | 2024-06-06 |
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- 1997-08-15 JP JP51056998A patent/JP3930570B2/en not_active Expired - Lifetime
- 1997-08-15 WO PCT/JP1997/002843 patent/WO1998007891A1/en not_active Ceased
- 1997-08-15 BR BR9706625-7A patent/BR9706625A/en not_active Application Discontinuation
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- 1997-08-15 EP EP97935796A patent/EP0861908B1/en not_active Expired - Lifetime
- 1997-08-15 AU AU38653/97A patent/AU697445B2/en not_active Expired
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| JPH0273924A (en) * | 1988-09-09 | 1990-03-13 | Nippon Steel Corp | Oxygen-enriching operation in sintering machine |
| JPH0543951A (en) * | 1991-08-13 | 1993-02-23 | Nippon Steel Corp | Method for operating sintering machine |
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009523912A (en) * | 2006-01-19 | 2009-06-25 | シーメンス・ファオアーイー・メタルズ・テクノロジーズ・ゲーエムベーハー・ウント・コ | Process for sintering in sintering equipment |
| JP2011252203A (en) * | 2010-06-02 | 2011-12-15 | Nippon Steel Corp | Method for manufacturing sintered ore, method for designing sinter cake supporting stand, and method for determining layer thickness of raw material filling-up layer |
| WO2014080450A1 (en) | 2012-11-20 | 2014-05-30 | Jfeスチール株式会社 | Oxygen-gas fuel supply device for sintering machine |
| US11104643B2 (en) | 2017-06-19 | 2021-08-31 | Unitika Ltd. | Bismaleimide modified product and method for producing the same |
| JPWO2021172254A1 (en) * | 2020-02-27 | 2021-09-02 | ||
| WO2021172254A1 (en) * | 2020-02-27 | 2021-09-02 | Jfeスチール株式会社 | Method for producing sintered ore |
| EP4112756A4 (en) * | 2020-02-27 | 2023-01-11 | JFE Steel Corporation | Method for producing sintered ore |
| US12404566B2 (en) | 2020-02-27 | 2025-09-02 | Jfe Steel Corporation | Method for producing sintered ore |
| CN113215390A (en) * | 2020-12-24 | 2021-08-06 | 北京高能时代环境技术股份有限公司 | Copper-containing sludge sintering method |
| CN113215390B (en) * | 2020-12-24 | 2022-07-22 | 北京高能时代环境技术股份有限公司 | Copper-containing sludge sintering method |
Also Published As
| Publication number | Publication date |
|---|---|
| AU697445B2 (en) | 1998-10-08 |
| DE69716231T2 (en) | 2003-08-14 |
| KR100257441B1 (en) | 2000-05-15 |
| BR9706625A (en) | 1999-11-23 |
| EP0861908A1 (en) | 1998-09-02 |
| CN1062913C (en) | 2001-03-07 |
| AU3865397A (en) | 1998-03-06 |
| JP3930570B2 (en) | 2007-06-13 |
| CN1198779A (en) | 1998-11-11 |
| DE69716231D1 (en) | 2002-11-14 |
| EP0861908A4 (en) | 1998-10-07 |
| EP0861908B1 (en) | 2002-10-09 |
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