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WO1998005295A1 - Mousse d'oxygene pour traitement capillaire d'oxydation - Google Patents

Mousse d'oxygene pour traitement capillaire d'oxydation Download PDF

Info

Publication number
WO1998005295A1
WO1998005295A1 PCT/EP1997/003677 EP9703677W WO9805295A1 WO 1998005295 A1 WO1998005295 A1 WO 1998005295A1 EP 9703677 W EP9703677 W EP 9703677W WO 9805295 A1 WO9805295 A1 WO 9805295A1
Authority
WO
WIPO (PCT)
Prior art keywords
hair
oxygen
foam
oxidative
foam according
Prior art date
Application number
PCT/EP1997/003677
Other languages
German (de)
English (en)
Inventor
Dieter Hoch
Bodo Hildebrandt
Franz Steigerwald
Original Assignee
Wella Aktiengesellschaft
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wella Aktiengesellschaft filed Critical Wella Aktiengesellschaft
Priority to EP97932805A priority Critical patent/EP0857053A1/fr
Priority to BR9706808A priority patent/BR9706808A/pt
Publication of WO1998005295A1 publication Critical patent/WO1998005295A1/fr

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/04—Preparations for permanent waving or straightening the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/046—Aerosols; Foams
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/22—Peroxides; Oxygen; Ozone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/10—Preparations for permanently dyeing the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
    • A61K2800/22—Gas releasing

Definitions

  • the invention relates to an oxygen foam for oxidative hair treatment, which is produced by foaming a surfactant solution with pure oxygen.
  • oxidative processes are of crucial importance in the production of perms or in certain hair coloring processes.
  • the hair is first treated with a hair styling agent that reduces keratin.
  • sulfur compounds having a reducing action are generally used, which belong either to the group of sulfites, hydrogen sulfites or to the group of mercaptocarboxylic acids. These substances are able to reduce the keratin of human hair and thereby enable the hair to be deformed.
  • the hair keratin is reduced, then the hair is rinsed with water and finally fixed with oxidizing agents, preferably bromates or hydrogen peroxide.
  • oxidizing agents preferably bromates or hydrogen peroxide.
  • the previously split disulfide bridges of hair keratin are reconnected in the new form given to the hair. The hair is then rinsed with water.
  • Oxidation processes are also of central importance in the production of hair colors.
  • Oxidation hair colors are an important part of a hair treatment serving cosmetic product range. They consist of two components that are mixed shortly before use and then applied to the hair to be dyed.
  • the first component the dye carrier mass, contains the dyeing substances. It can be in the form of a liquid, gel or an emulsion.
  • As a second component an aqueous, cream-like or powdery product has always been used in which a suitable oxidizing agent is contained.
  • the most suitable oxidizing agents in hair coloring are hydrogen peroxide or its addition compounds with urea, melanin or sodium borate. Hydrogen peroxide has a strong oxidation effect and is unstable in aqueous solutions, so that alternative oxidation methods are sought. It has therefore already been proposed to use oxygen or ozone for oxidative hair treatment.
  • DE-AS 1 034 329 describes a process in which the hairs, which are initially moistened with an alkaline thioglycolate solution, are fixed after their shaping by a gaseous oxidizing agent, for example oxygen.
  • a gaseous oxidizing agent for example oxygen.
  • the gaseous oxidizing agent required for the fixation is taken from a cartridge which is attached in a hood under which the fixation takes place.
  • DE-AS 1 045204 describes a process for bleaching, dyeing and waving the human head hair, in which ozone is mixed with dry warm air immediately after its formation and then acts on the hair.
  • a rigid drying hood with built-in radiator and fan is used, which on the suction side of the fan in the upper part of the hood is a known, with silent discharge working ozone generator and between this and the Fan has a preferably annular heater.
  • an oxygen foam for oxidative hair treatment which is produced by foaming a surfactant solution with pure oxygen and has a service life which is sufficient for the continuous release of the bound oxygen from the slowly breaking foam during the entire treatment time.
  • a suitable oxygen foam is produced from an aqueous solution containing 1-10 percent by weight of surfactants by introducing pure oxygen and, depending on the amount of surfactant used, has a Standing time between 5 and 60 minutes. The surfactant solution is foamed with the oxygen until a stiff foam is formed, which can be applied to the hair like a hood.
  • a suitable method for producing the oxygen foam according to the invention is that the oxygen, as a compressed gas, is removed from a pressure vessel and blown into the surfactant solution in finely divided form. It is advisable to introduce the oxygen from the pressure vessel via a throttle valve through a porous sintered material or another sieve structure into the surfactant solution.
  • the oxygen foam according to the invention can also be removed as a ready-to-use aerosol from a pressure container in which the surfactant solution and the oxygen are contained as a compressed gas.
  • Suitable pressure containers are made of metal, glass or plastic and have a foam spray head as a valve, which seals the container and allows an immediately applicable oxygen foam to swell out when actuated, which is then applied directly to the hair like a hood.
  • the anionic surfactants used to produce the oxygen foam are alkylbenzenesulfonates, alkanesulfonates,
  • Fatty alcohol ethoxylates, fatty amine ethoxylates, fatty acid ethoxylates and other ethoxylates customary as surface-active substances are used.
  • Cationic surfactants such as alkylammonium compounds or amphoteric surfactants are also available
  • Adding a small amount of a foam stabilizer to the above-mentioned surfactants can further increase the stability of the oxygen foam according to the invention be increased and adjusted so that a continuous release of oxygen from the foam is ensured over the entire desired period.
  • the suitable foam stabilizers belong to the group of fatty acid alkanolamides.
  • an oxygen foam is generated which breaks slowly during the intended exposure time and continuously releases oxygen under very mild conditions.
  • oxygen constantly escapes through the thin foam membranes and can thus act on the scalp hair without the additional use of a special hood.
  • the foam according to the invention is so strong that it cannot run off the head.
  • surfactant solution For a single hair treatment, 50 to 100 g of surfactant solution are generally foamed with pure oxygen. This results in 2 to 2.5 1 foam, the service life of which depends on the specified surfactant concentration and any addition of a foam stabilizer. Immediately after application, the foam begins to break slowly, releasing the oxygen to the hair. Depending on the setting of the desired service life, the foam will practically completely collapse again after 10 to 60 minutes.
  • the oxygen foam according to the invention can advantageously be used for the permanent shaping of hair.
  • the hair after it has been wound up in the desired shape, is treated with a shaping agent known per se, rinsed with water and then covered in a hood-like manner for oxidative aftertreatment with the oxygen foam according to the invention, which is then applied to the hair for 5-30 minutes acts.
  • the oxygen foam can be applied to the hair a second time and a further treatment for another 5 - 30 minutes. Then the foam is rinsed well with water and the hair is dried.
  • the treatment with the oxygen foam according to the invention allows the permanent wave to be fixed in a manner which corresponds to the previously customary fixing with hydrogen peroxide or other oxidizing agents.
  • the desired dye is produced by the reaction of certain developers with coupler substances in the presence of an oxidizing agent which was previously mainly hydrogen peroxide.
  • an oxidizing agent which was previously mainly hydrogen peroxide.
  • 1,4-Diaminobenzene, 2, 5-diaminotoluene, 2,5-diaminophenylethanol, 4-aminophenol and 4-amino-3-methylphenol, 4-amino-2-aminomethylphenol, tetra-aminopyrimidine, 4- N, N '-bis (2-hydroxyethyl) amino-aniline and substituted 4,5-diaminopyrazoles are used.
  • Typical coupler substances are resorcinol, 4-chlororesorcinol, sesamol, 2-methylresorcinol, 3-aminophenol, 4- (2 '-hydroxyethyl) amino-1, 2-methylene-dioxy-benzene and 2-amino-4- (2' -hydroxyethylamino ) -anisole.
  • 1-naphthol, 4,6-dichlororesorcinol, 2,4-diamino-5-fluorotoluene, 4-amino-5-fluoro-2-hydroxytoluene, 4-amino-2-hydroxy-5-methoxytoluene also come as coupler substances.
  • 5-amino-2-methylphenol 2, 4-diamino-phenoxyethanol, 4-amino-2-hydroxyphenoxyethanol, 3-amino-2-methylphenol, 4-hydroxy-l, 2-methylenedioxybenzene, 4-amino-l, 2-methylenedioxybenzene, 2,4-diamino-phenetol, 2, 4-diamino-5-methylphenetol, 4-hydroxyindole and 3, 5-diamino-2, 6-dimeth-oxypyridine.
  • self-coupling color precursors and dyes directly on the hair can also be included.
  • the developer and coupler substances are used in the hair dye either as such or in the form of their physiologically acceptable salts with inorganic or organic acids such as chlorides, sulfates, phosphates, acetates, lactates or citrates.
  • the coupler substances are generally used in an approximately equimolar amount, based on the developer substances used.
  • the pH of the Colorant is preferably in the range of 6.0-11.5. The pH is adjusted in the alkaline range, especially with ammonia, monethanolamine, triethanolamine, sodium hydroxide or potassium hydroxide and in the acidic range with phosphoric acid, acetic acid, citric acid or tartaric acid. Further details on the composition of oxidation colorants are disclosed in DE-PS 40 05 008.
  • Colorant and the foam rinsed out and then dried the hair. It may also be advantageous to mix the color carrier mass with the oxygen foam immediately before use and then to apply the mass to the hair in an amount of 60 to 200 g.
  • This process achieves a uniform hair coloration, which corresponds to the results of the oxidative hair dyeing processes that have been customary to date. However, it has the advantage of being able to do without aggressive oxidizing agents and the complex equipment that was previously required for the use of gaseous oxidizing agents.
  • a cosmetic combination preparation for permanent shaping of hair then contains moderately as component I a keratin-reducing preparation suitable for producing a perm and as component II an aqueous solution of a surfactant from which the oxygen foam according to the invention is produced immediately before the treatment.
  • a cosmetic combination preparation that is to be used for the oxidative coloring of hair contains as component I a color carrier composition consisting of a developer substance-coupler substance combination in the form of a liquid, a gel or an emulsion in an amount sufficient for hair coloring and as component II one aqueous solution of a surfactant provided for the production of the oxygen foam.
  • reaction accelerators for the air oxidation of the permanent wave solution the dye carrier or the surfactant solution can advantageously be added.
  • Amino naphthols, organic and inorganic iron compounds, cobalt or platinum compounds and ferments suitable for oxygen transfer in amounts of 0.1-1.0% by weight have already been used for this.
  • Example 1 Combination preparation for permanent shaping of hair
  • Component II Aqueous solution of a surfactant
  • Example 2 Combination preparation for oxidative hair coloring
  • Component I ink carrier
  • Component II Aqueous solution of a surfactant
  • Example 3 Process for producing a perm
  • the hair is first washed and then terry. After winding on hair curlers, about 60 g of permanent wave solution from Example 1 (component I) is applied and left to act on the hair for 20 minutes. Then it is rinsed out with water, excess moisture is dabbed off and a solid foam produced by blowing oxygen gas into the surfactant solution of Example 1 (component II) is applied to the hair and all the wraps evenly. After an exposure time of 5 to 10 minutes, it is unwound and the oxygen foam is applied again to the unwound hair. After a further exposure time of 5 to 10 minutes, the hair is rinsed out thoroughly. The desired perm was created.
  • the dye carrier component I from Example 2
  • an oxygen foam which has been prepared by blowing pure oxygen into 50 g of surfactant solution (component II from Example 2) before use
  • the mixture is applied to medium-brown human hair and leave it on for 20 minutes at room temperature.
  • the hair dye mixture is then rinsed out with water and the hair is dried.
  • the hair treated in this way is evenly dark brown in color from the roots to the ends of the hair.
  • the oxidative hair dye used darkens only slightly after mixing the two components, smells only slightly of ammonia and is well tolerated by the skin.
  • Example 5 Process for hair coloring with subsequent oxidative hair treatment
  • the dye carrier component I from Example 2
  • an oxygen foam which has been produced by blowing pure oxygen in 50 g of surfactant solution (component II of Example 2), is additionally applied to the hair like a hood and mixed intensively with the dye carrier. If necessary, the ink carrier composition can also be washed out before the oxygen foam is used. After a further exposure time of 20 minutes, the remainders of the dye carrier and the oxygen foam are rinsed out with water and the hair is dried. The hair treated in this way is evenly dark brown in color from the roots to the tips.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Chemical & Material Sciences (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Dispersion Chemistry (AREA)
  • Emergency Medicine (AREA)
  • Inorganic Chemistry (AREA)
  • Cosmetics (AREA)
  • Brushes (AREA)

Abstract

L'invention concerne une mousse d'oxygène pour un traitement capillaire d'oxydation, produite par moussage d'une solution de tensioactif avec de l'oxygène pur, et présentant un temps de maintien tel que l'oxygène lié continue à se dégager de la mousse qui se désagrège lentement, pendant la totalité de la durée du traitement.
PCT/EP1997/003677 1996-08-07 1997-07-11 Mousse d'oxygene pour traitement capillaire d'oxydation WO1998005295A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
EP97932805A EP0857053A1 (fr) 1996-08-07 1997-07-11 Mousse d'oxygene pour traitement capillaire d'oxydation
BR9706808A BR9706808A (pt) 1996-08-07 1997-07-11 Espuma de exigénio para o tratamento oxidativo do cabelo

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19631806.8 1996-08-07
DE1996131806 DE19631806A1 (de) 1996-08-07 1996-08-07 Sauerstoffschaum zur oxidativen Haarbehandlung

Publications (1)

Publication Number Publication Date
WO1998005295A1 true WO1998005295A1 (fr) 1998-02-12

Family

ID=7801979

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP1997/003677 WO1998005295A1 (fr) 1996-08-07 1997-07-11 Mousse d'oxygene pour traitement capillaire d'oxydation

Country Status (4)

Country Link
EP (1) EP0857053A1 (fr)
BR (2) BR9706808A (fr)
DE (1) DE19631806A1 (fr)
WO (1) WO1998005295A1 (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999039702A3 (fr) * 1997-10-31 1999-10-14 Childrens Medical Center Regulation de la taille et de la croissance d'un tissu normal vascularise
IT201800007261A1 (it) * 2018-07-17 2020-01-17 Metodo per la cosmesi dei capelli che impiega ossigeno gassoso

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2623860A1 (de) * 1976-05-28 1977-12-01 Alfred Peters Dauerwelle und fixierung
DE3315780A1 (de) * 1983-04-30 1984-10-31 Michael 7709 Weiterdingen Jendro Verfahren und gemisch zum reinigen von flaechenelementen
DE3732030A1 (de) * 1987-03-06 1988-09-15 Mtm Obermaier Gmbh & Co Kg Verfahren zur fluessigkeitsbehandlung von materialien
JPH03215207A (ja) * 1990-01-18 1991-09-20 Daikin Ind Ltd パーマネント装置
JPH03247311A (ja) * 1990-02-23 1991-11-05 Daikin Ind Ltd 理美容用泡立器
DE19514630A1 (de) * 1995-04-20 1996-10-24 Hartmann Haarkosmetik Gmbh Frisurenstabilität bzw. Frisurenkonstanz und Haargeschmeidigkeit bewirkendes Haarwaschmittel

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2623860A1 (de) * 1976-05-28 1977-12-01 Alfred Peters Dauerwelle und fixierung
DE3315780A1 (de) * 1983-04-30 1984-10-31 Michael 7709 Weiterdingen Jendro Verfahren und gemisch zum reinigen von flaechenelementen
DE3732030A1 (de) * 1987-03-06 1988-09-15 Mtm Obermaier Gmbh & Co Kg Verfahren zur fluessigkeitsbehandlung von materialien
JPH03215207A (ja) * 1990-01-18 1991-09-20 Daikin Ind Ltd パーマネント装置
JPH03247311A (ja) * 1990-02-23 1991-11-05 Daikin Ind Ltd 理美容用泡立器
DE19514630A1 (de) * 1995-04-20 1996-10-24 Hartmann Haarkosmetik Gmbh Frisurenstabilität bzw. Frisurenkonstanz und Haargeschmeidigkeit bewirkendes Haarwaschmittel

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
PATENT ABSTRACTS OF JAPAN vol. 015, no. 488 (C - 0893) 11 December 1991 (1991-12-11) *
PATENT ABSTRACTS OF JAPAN vol. 016, no. 040 (C - 0906) 31 January 1992 (1992-01-31) *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999039702A3 (fr) * 1997-10-31 1999-10-14 Childrens Medical Center Regulation de la taille et de la croissance d'un tissu normal vascularise
IT201800007261A1 (it) * 2018-07-17 2020-01-17 Metodo per la cosmesi dei capelli che impiega ossigeno gassoso
EP3597272A1 (fr) * 2018-07-17 2020-01-22 Tricomef S.R.L. Procédé cosmétique pour les cheveux en utilisant l'oxygène gaseux

Also Published As

Publication number Publication date
BR9706860A (pt) 2000-05-02
EP0857053A1 (fr) 1998-08-12
BR9706808A (pt) 1999-07-20
DE19631806A1 (de) 1998-02-12

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