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WO1998045648A1 - Procede et dispositif pour eliminer, en respectant l'environnement, des matieres toxiques se presentant de preference en futs volumineux - Google Patents

Procede et dispositif pour eliminer, en respectant l'environnement, des matieres toxiques se presentant de preference en futs volumineux Download PDF

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Publication number
WO1998045648A1
WO1998045648A1 PCT/DE1998/000980 DE9800980W WO9845648A1 WO 1998045648 A1 WO1998045648 A1 WO 1998045648A1 DE 9800980 W DE9800980 W DE 9800980W WO 9845648 A1 WO9845648 A1 WO 9845648A1
Authority
WO
WIPO (PCT)
Prior art keywords
reaction chamber
reaction
packing
chamber
water
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/DE1998/000980
Other languages
German (de)
English (en)
Inventor
Heinrich Hampel
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
HAMPEL ROMAN
Original Assignee
HAMPEL ROMAN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by HAMPEL ROMAN filed Critical HAMPEL ROMAN
Priority to AU80100/98A priority Critical patent/AU8010098A/en
Publication of WO1998045648A1 publication Critical patent/WO1998045648A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F42—AMMUNITION; BLASTING
    • F42B—EXPLOSIVE CHARGES, e.g. FOR BLASTING, FIREWORKS, AMMUNITION
    • F42B33/00—Manufacture of ammunition; Dismantling of ammunition; Apparatus therefor
    • F42B33/06—Dismantling fuzes, cartridges, projectiles, missiles, rockets or bombs
    • F42B33/067—Dismantling fuzes, cartridges, projectiles, missiles, rockets or bombs by combustion
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00—Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/08—Incineration of waste; Incinerator constructions; Details, accessories or control therefor having supplementary heating
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00—Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/08—Incineration of waste; Incinerator constructions; Details, accessories or control therefor having supplementary heating
    • F23G5/14—Incineration of waste; Incinerator constructions; Details, accessories or control therefor having supplementary heating including secondary combustion
    • F23G5/16—Incineration of waste; Incinerator constructions; Details, accessories or control therefor having supplementary heating including secondary combustion in a separate combustion chamber
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23M—CASINGS, LININGS, WALLS OR DOORS SPECIALLY ADAPTED FOR COMBUSTION CHAMBERS, e.g. FIREBRIDGES; DEVICES FOR DEFLECTING AIR, FLAMES OR COMBUSTION PRODUCTS IN COMBUSTION CHAMBERS; SAFETY ARRANGEMENTS SPECIALLY ADAPTED FOR COMBUSTION APPARATUS; DETAILS OF COMBUSTION CHAMBERS, NOT OTHERWISE PROVIDED FOR
    • F23M20/00—Details of combustion chambers, not otherwise provided for, e.g. means for storing heat from flames
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2203/00—Furnace arrangements
    • F23G2203/70—Modular furnace
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2205/00—Waste feed arrangements
    • F23G2205/18—Waste feed arrangements using airlock systems
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2206/00—Waste heat recuperation
    • F23G2206/10—Waste heat recuperation reintroducing the heat in the same process, e.g. for predrying
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2900/00—Special features of, or arrangements for incinerators
    • F23G2900/54401—Feeding waste in containers, bags or barrels
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23L—SUPPLYING AIR OR NON-COMBUSTIBLE LIQUIDS OR GASES TO COMBUSTION APPARATUS IN GENERAL ; VALVES OR DAMPERS SPECIALLY ADAPTED FOR CONTROLLING AIR SUPPLY OR DRAUGHT IN COMBUSTION APPARATUS; INDUCING DRAUGHT IN COMBUSTION APPARATUS; TOPS FOR CHIMNEYS OR VENTILATING SHAFTS; TERMINALS FOR FLUES
    • F23L2900/00—Special arrangements for supplying or treating air or oxidant for combustion; Injecting inert gas, water or steam into the combustion chamber
    • F23L2900/07001—Injecting synthetic air, i.e. a combustion supporting mixture made of pure oxygen and an inert gas, e.g. nitrogen or recycled fumes
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23L—SUPPLYING AIR OR NON-COMBUSTIBLE LIQUIDS OR GASES TO COMBUSTION APPARATUS IN GENERAL ; VALVES OR DAMPERS SPECIALLY ADAPTED FOR CONTROLLING AIR SUPPLY OR DRAUGHT IN COMBUSTION APPARATUS; INDUCING DRAUGHT IN COMBUSTION APPARATUS; TOPS FOR CHIMNEYS OR VENTILATING SHAFTS; TERMINALS FOR FLUES
    • F23L2900/00—Special arrangements for supplying or treating air or oxidant for combustion; Injecting inert gas, water or steam into the combustion chamber
    • F23L2900/07008—Injection of water into the combustion chamber
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00—Combustion technologies with mitigation potential
    • Y02E20/32—Direct CO2 mitigation
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00—Combustion technologies with mitigation potential
    • Y02E20/34—Indirect CO2mitigation, i.e. by acting on non CO2directly related matters of the process, e.g. pre-heating or heat recovery

Definitions

  • the invention relates to a method and a device for the environmentally friendly disposal of toxins, which are preferably present in large containers, by means of a reaction process (3 in a closed reaction chamber, where the toxins are deflagrated, explosively converted, burned or pyrolyzed, in which the Gaseous reaction products resulting from the reaction process are passed through the heat-storing packing and sucked out of the reaction chamber.
  • Such substances are often present in large containers (20ö-I-benaiter). In some cases, the substances are solid or adhere to containers, making it difficult to remove them from the containers. They must therefore be disposed of together with their containers if possible.
  • the process is still disadvantageous in that the combustion gases derived from the reaction chamber and cooled in an aftertreatment have to be heated up again strongly during a recirculation.
  • additional burners are arranged in the reaction chamber. With the Exhaust gases from the burners in turn increase the total amount of combustion gases, which must then also be passed through the afterburning system.
  • the use of heat-storing fillers is advantageous for such thermal reaction processes.
  • the solutions disclosed in the latter documents are unsuitable for the disposal of the toxins under consideration here, or they also have the disadvantage of the high amount of exhaust gas that arises.
  • the invention has for its object to provide a method that works energetically effective, in which the amount of exhaust gas can be kept low and in which the pollutants are largely eliminated before passing through the post-combustion chamber.
  • a facility suitable for carrying out the process is also to be specified.
  • the object is achieved by a method with the following method steps:
  • reaction gases are filtered, washed out and / or cooled - and then the reaction process before the repeated passage through the packing at least in part, depending on the thermal and / or chemical conditions prevailing in the reaction chamber, heated or cooled and / or with air, Enriched with oxygen or fuel, fed again,
  • the process according to the invention can preferably be carried out in such a way that the temperature of the packing is additionally controlled by introducing water into the reaction chamber.
  • the average temperature of the packing is preferably kept between 200 ° and 800 ° C. In this temperature range, nitrogen oxides can hardly be generated, which would otherwise have to be disposed of in further process steps.
  • a further process step provides that the packing is preheated to a predetermined temperature at the start of operation of the reaction chamber, so that a predetermined temperature prevails in the reaction chamber at the start of a process.
  • reaction gases are expediently passed over at least one surge tank.
  • the temperature in the reaction chamber and thus the temperature of the packing will rise or fall.
  • the partially cleaned reaction gases are therefore either cooled (down to 30 ° C) or returned to the reaction chamber in the hot state (200 ° C to 900 ° C), thus producing a constant temperature within the reaction chamber.
  • the interaction of hot and cold recirculation gas flows is also possible.
  • the process can preferably be carried out in such a way that oxygen is added to the gaseous reaction products fed back into the reaction chamber.
  • oxygen is added to the gaseous reaction products fed back into the reaction chamber.
  • the proportion of oxygen in the total amount of the gases returned to the reaction chamber can be up to 80% (volume percent).
  • the process can also be carried out in such a way that fuel is added to the gaseous reaction products fed back into the reaction chamber when the reaction chamber a reductive atmosphere should always be created.
  • fuel is added to the gaseous reaction products fed back into the reaction chamber when the reaction chamber a reductive atmosphere should always be created.
  • undesirable nitrogen oxides can be reduced to nitrogen and water.
  • no oxygen or air is introduced into the recycle gas stream.
  • the toxins are the reaction chamber z. B. supplied via an entrance lock together with their containers or via a feed line.
  • the method also provides that the water obtained in the reaction process is cleaned and returned to the process, e.g. B. the reaction chamber or a spray dryer, or a wastewater disposal.
  • a spontaneous pressure increase in the reaction chamber or in a pressure compensation tank is compensated with special regulators and slowly passed on to the other parts of the plant.
  • the condensation of water vapor and other components limits the pressure increase.
  • the process enables toxic substances to be disposed of in small, but efficient, waste disposal plants, whereby hazardous goods can be disposed of up to several tons per hour and yet far fewer emissions are released into the environment than in conventional large-scale incineration plants.
  • a device for carrying out the method is, as is known, equipped with a closed reaction chamber which stores the toxins in an inlet lock or can be fed via a feed line. It is partly filled with heat-storing fillers, has a gas outlet arranged in the flow of the gaseous reaction products behind the fillers and a gas inlet and an inlet for the addition of chemicals.
  • An exhaust pipe system is connected to a chimney via an afterburning and exhaust treatment system
  • the reaction chamber has a closable outlet opening for the removal of packing and
  • gas outlet and gas inlet are connected to one another by a system of exhaust gas pipelines, optionally via a surge tank, quench, washer, filter, spray cooler, electric heater, dryer, air, oxygen supply and heater.
  • a system of exhaust gas pipelines optionally via a surge tank, quench, washer, filter, spray cooler, electric heater, dryer, air, oxygen supply and heater.
  • the device can be designed according to the invention so that the reaction chamber is followed by an annealing chamber for annealing the packing, which annealing chamber can be connected to the exhaust pipe system in order to provide the necessary energy for annealing the packing by the reaction gases.
  • the reaction chamber can be preceded by a closed emptying room which contains facilities for opening and emptying toxic containers.
  • the device for emptying the toxic substance can also be connected to the exhaust pipe system, so that the reaction gas is used as a pressure medium for emptying.
  • the containers can be compressed with the recirculation gas and annealed in the annealing chamber.
  • thick-walled steel tube segments can serve as filler.
  • the reaction chamber preferably has a water inlet which is expediently connected to a water pipeline system which in turn is connected to a water purification system for the condensate obtained after the reaction process.
  • a water purification system for the condensate obtained after the reaction process.
  • water can optionally be sprayed in via the water inlet.
  • halogenated hydrocarbons and inorganic halogenated compounds are present, they are afterburned at 1200 ° C and passed on to a quench. For other inhalants, they are immediately cooled in a quench.
  • the invention will be explained in more detail below using an exemplary embodiment.
  • the accompanying drawing shows the sequence of the method according to the invention based on a schematic diagram of a combustion and pyrolysis plant with exhaust gas recirculation.
  • the core of the system is an explosion-resistant reactor 1, which is normally loaded with a disposal container 3 via an entrance lock 2.
  • the reaction chamber 4 of the reactor 1 is largely filled with packing elements 5.
  • the filler 5 are thick-walled steel pipe segments in the present embodiment. They can be conveyed by operating a locking device 6 into an annealing chamber 7 arranged downstream of the reaction chamber 4, in order to anneal them there after a given operating time and to sort them into a sorting space 8 for reuse or for scrapping.
  • the reaction chamber 4 is closed in a pressure-tight manner. If necessary, 4 negative pressure can be maintained in the reaction chamber.
  • a disposal goods container 3 which is passed through the entrance lock 2 falls onto the surface of the packing 5 and will burst due to the impact or after some time due to the temperature.
  • the upper packing 5 have a temperature of 500-800 'C. They are preheated before the reactor 1 is started up.
  • the pressure in the reaction chamber 4 can rise sharply.
  • the combustion gases pass through the packing 5 and are fed to a surge tank 12 via a gas outlet 11, via a pressure regulator 13 and a heat exchanger 14 Combustion gases in the simplest case back to a cold exhaust gas collector 15 and thus back into the reaction chamber 4.
  • a prerequisite is that the combustion process in the reaction chamber 4 is exothermic.
  • the combustion gases can be heated by means of a burner 16 and fed to a hot gas collector 19 via a mixer 17 and a further pressure expansion tank 18.
  • the combustion gases can also be passed through a spray dryer 20, a fabric filter 21 and a condenser 22.
  • the cleaned combustion gases in turn reach the cold gas collector 15 via a compressor 23.
  • the burner 16 also serves to heat the packing 5 with hot air before starting the reactor 1.
  • sulfur dioxide (SO2) and hydrochloric acid (HC1) are precipitated in the spray dryer 20. Salts and sludges can be retained with the fabric filter 21.
  • the condensate water accumulating in the condenser 22 is pumped off by means of a pump 24 and either led to the spray dryer 20 or to a water purification system 25, in order then to be stored in a pure water tank 26. It can be sprayed in the reaction chamber 4 in the case of extremely exothermic processes during the combustion of the waste material for energy dissipation.
  • the second surge tank 18 has the task of temporarily storing hot Rezi rkulationsgas because z. B. a larger amount of steam may be generated at the start of a reaction. If a normal pressure has been established after some time, the gas passes through the pressure compensation tank 18, which is opened by a pressure relief valve only at the appropriate pressure.
  • a part of the recirculating gas stream is branched off and into the afterburning chamber 27 or under intermediate circuit of a quench 28 and an exhaust gas purification system 29 passed into a chimney 30.
  • the afterburning system 27 works with a burner 31, which is supplied by a propane gas system from a propane gas tank 32.
  • the propane gas container 32 also supplies the propane gas for the burners 33 in the annealing chamber 7 and the burner 16 for heating the recirculating gas stream.
  • the recirculating combustion gases can be supplied with oxygen via an oxygen system 34.
  • the use of pure oxygen has the advantage over the use of air that the recirculating gas quantity is considerably reduced.
  • the amount of oxygen in the cold recirculation gas stream can be up to 80%.
  • a low oxygen rate can be set, whereas in extremely endothermic reactions and a small recirculation exhaust gas stream (e.g. when disposing of aqueous salt solutions) one high oxygen rate can be chosen.
  • the amount of oxygen can be up to 30% and in typical endothermic reactions up to 50% to promote the combustion process.
  • the reactor 1 can also periodically chemicals, z.
  • potassium hydroxide solution (Ca (OH) 2) and Kai ziumsulfi t (CaS) are supplied.
  • the substances have the task of creating an alkaline atmosphere in reactor 1 and chlorine, fluorine and heavy metal bind particles. A large part of these substances is already deposited as salt and ash on the packing 5, which at the same time calm the gas flow and form a large surface for combustion and pyrolysis, and is separated during the periodic removal of the packing 5 from the reactor 1 in a cleaning process and then disposed of as special waste.
  • the emptying device 39 is located in a special emptying space 41, from which the empty containers 38 reach another space with a press 42 and are pressed there, if necessary.
  • the pressed residues can then be annealed or burned in the annealing chamber 7.

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Environmental & Geological Engineering (AREA)
  • Analytical Chemistry (AREA)
  • Biomedical Technology (AREA)
  • Health & Medical Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Combustion & Propulsion (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Processing Of Solid Wastes (AREA)
  • Treating Waste Gases (AREA)
  • Incineration Of Waste (AREA)

Abstract

Selon le procédé présenté, les gaz de réaction sont filtrés, lavés et/ou refroidis, puis au moins une partie de ces gaz, avant leur nouveau passage à travers les corps de remplissage, est réchauffée ou refroidie, et/ou enrichie d'air, d'oxygène ou de combustible, selon les conditions thermiques et/ou physiques régnant dans la chambre de réaction, puis est de nouveau acheminée vers le processus de réaction. La partie restante des produits de réaction gazeux est détournée du circuit, analysée, subit une postcombustion en fonction du résultat de l'analyse, puis rejetée dans l'atmosphère, une fois lavée et refroidie. La température moyenne des corps de remplissage est régulée par le chauffage et/ou le refroidissement des produits de réaction gazeux acheminés de nouveau à la chambre de réaction. Le procédé selon l'invention est particulièrement adapté aux petites installations d'élimination performantes.
PCT/DE1998/000980 1997-04-09 1998-04-07 Procede et dispositif pour eliminer, en respectant l'environnement, des matieres toxiques se presentant de preference en futs volumineux Ceased WO1998045648A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU80100/98A AU8010098A (en) 1997-04-09 1998-04-07 Method and device for the environmentally friendly disposal of toxicants prefer ably in large drums

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19714740.2 1997-04-09
DE19714740A DE19714740C1 (de) 1997-04-09 1997-04-09 Verfahren und Einrichtung zur umweltschonenenden Entsorgung von vorzugsweise in großen Gebinden vorliegenden Giftstoffen

Publications (1)

Publication Number Publication Date
WO1998045648A1 true WO1998045648A1 (fr) 1998-10-15

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/DE1998/000980 Ceased WO1998045648A1 (fr) 1997-04-09 1998-04-07 Procede et dispositif pour eliminer, en respectant l'environnement, des matieres toxiques se presentant de preference en futs volumineux

Country Status (3)

Country Link
AU (1) AU8010098A (fr)
DE (1) DE19714740C1 (fr)
WO (1) WO1998045648A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2016515915A (ja) * 2013-02-14 2016-06-02 アレヴァ・エンセ ガラス繊維容器および廃棄物焼却方法

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1141167C (zh) * 1998-05-29 2004-03-10 森托塞姆投资两合公司 工业废气净化方法
ATE279252T1 (de) 1999-03-12 2004-10-15 Eisenmann Kg Maschbau Verfahren zur entsorgung gefährlicher oder hochenergetischer materialien sowie vorrichtung zur durchführung dieses verfahrens

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3918718A1 (de) * 1989-06-08 1990-12-13 Nukem Gmbh Vorrichtung zur thermischen behandlung von organischen und anorganischen stoffen
US5495063A (en) * 1992-06-29 1996-02-27 Buck Werke Gmbh & Co. Process for environmentally safe destruction of pyrotechnic material
DE19606945C1 (de) * 1996-02-23 1997-07-24 Christoph Hampel Spreng-, Verbrennungs- und Pyrolyseeinrichtung zur umweltfreundlichen Entsorgung von Gefahrengut

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3028193C2 (de) * 1980-07-25 1984-11-22 Nukem Gmbh, 6450 Hanau Verfahren und Vorrichtung zur pyrolytischen Zersetzung von Halogene und/oder Phosphor enthaltenden organischen Substanzen
DE3819699C1 (en) * 1988-06-09 1989-08-24 Artur Richard 6000 Frankfurt De Greul Process for pyrolysing plastics, components of organic hazardous waste and the like in modified sand coker, and equipment for carrying out the process
IL113593A0 (en) * 1994-05-06 1995-08-31 Thermatrix Inc Method and apparatus for thermal desorption soil remediation

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3918718A1 (de) * 1989-06-08 1990-12-13 Nukem Gmbh Vorrichtung zur thermischen behandlung von organischen und anorganischen stoffen
US5495063A (en) * 1992-06-29 1996-02-27 Buck Werke Gmbh & Co. Process for environmentally safe destruction of pyrotechnic material
DE19606945C1 (de) * 1996-02-23 1997-07-24 Christoph Hampel Spreng-, Verbrennungs- und Pyrolyseeinrichtung zur umweltfreundlichen Entsorgung von Gefahrengut

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2016515915A (ja) * 2013-02-14 2016-06-02 アレヴァ・エンセ ガラス繊維容器および廃棄物焼却方法

Also Published As

Publication number Publication date
DE19714740C1 (de) 1998-12-17
AU8010098A (en) 1998-10-30

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