WO1997032715A1 - Method and device for manufacturing resin-coated metal plates - Google Patents
Method and device for manufacturing resin-coated metal plates Download PDFInfo
- Publication number
- WO1997032715A1 WO1997032715A1 PCT/JP1996/001369 JP9601369W WO9732715A1 WO 1997032715 A1 WO1997032715 A1 WO 1997032715A1 JP 9601369 W JP9601369 W JP 9601369W WO 9732715 A1 WO9732715 A1 WO 9732715A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- resin
- metal plate
- film
- resin film
- solidified
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/14—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
- B32B37/15—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer being manufactured and immediately laminated before reaching its stable state, e.g. in which a layer is extruded and laminated while in semi-molten state
- B32B37/153—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer being manufactured and immediately laminated before reaching its stable state, e.g. in which a layer is extruded and laminated while in semi-molten state at least one layer is extruded and immediately laminated while in semi-molten state
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B41/00—Arrangements for controlling or monitoring lamination processes; Safety arrangements
- B32B2041/06—Starting the lamination machine or method
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2309/00—Parameters for the laminating or treatment process; Apparatus details
- B32B2309/08—Dimensions, e.g. volume
Definitions
- TECHNICAL FIELD The present invention relates to a method of manufacturing a solidified resin film and a metal plate of the formed film without waste of the metal plate and the resin and in the same process.
- TECHNICAL FIELD The present invention relates to a method and an apparatus for manufacturing a resin-coated metal plate which is capable of stably laminating a resin sheet and has excellent economic efficiency. Background art
- Japanese Patent Application Laid-Open No. H2-24-2737 describes a method in which a thermoplastic resin melted from a T-die is flowed down onto a pre-heated metal plate, and pressed with a nipple roll to form a resin.
- a manufacturing method for obtaining a coated metal plate has been proposed.
- Japanese Patent Application Laid-Open No. Hei 4-291442 discloses that the molten thermoplastic resin extruded from the T-die has an unusually thick film at both ends in the width direction, so that the molten thermoplastic resin wider than the steel sheet By coating the resin on the steel sheet and providing a solid thermoplastic resin wider than the molten thermoplastic resin on the opposite side of the coated surface, adhesion of the molten thermoplastic resin to the pressing roll on the steel sheet winding side can be prevented. And a method for obtaining a double-sided resin-coated steel sheet having a uniform film thickness distribution is proposed.
- Japanese Patent Application Laid-Open No. Hei 6-350024 discloses that the resin before coating is stretched not only in the length direction but also in the width direction, that is, by biaxially stretching.
- a method for producing a resin-coated metal plate capable of preventing the film thickness from fluctuating in the width direction of the film has been proposed, this method is certainly an effective method, but it requires a great deal of cost for biaxial stretching equipment. What is required is that the resin composition that can be biaxially stretched is practically limited, and the thickness of the resin during transverse stretching is reduced in order to reduce the thickness of the film at the end of the film with the aim of suppressing resin loss.
- the film If the film is made thinner or the grip is narrower, the film will be more likely to break, and even if biaxial stretching can be performed, the film thickness distribution will not be stable from the start of film formation and it will take some time, and even during instability Loss of resin due to lamination on metal plate Not only that, but also metal loss, and depending on the situation and production lot, it is not necessarily an economical manufacturing method, and there is a need for improvement. Also, even if the film is not stretched, the target film thickness and film thickness distribution may take a little longer than the biaxial stretching even if the film is not stretched.
- the present invention has been made in view of such a problem, and provides a method and an apparatus capable of economically producing a resin-coated metal plate at a high yield without wasting the metal plate and the resin. It is. Disclosure of the invention
- the thickness of a solidified resin film formed by passing a molten resin flowing down from a T-die through a film-forming cooling roll to form a film is reduced.
- the solidified resin film is wound around a solidified resin film winding device until it is confirmed that the thickness is within the thickness range, and after confirming that the thickness of the solidified resin film is within the target thickness range, the metal plate is formed.
- the solidified resin film is continuously rewound from a rewind reel, and the solidified resin film is pressure-bonded to the surface of the heated metal plate by a laminating roll. It is characterized by continuous lamination.
- a film cutting device is provided between the solidified resin film winding device and the laminating roll, and almost synchronously with the case where the solidified resin film is pressed on the surface of the heated metal plate with the laminating hole, If the cut resin film is cut at an appropriate position where the cut film is not wound around a roll or other device, lamination can be performed more easily.
- the solidified resin film obtained by the above means may be laminated on only one side of the metal plate, and the solidified resin film forming and winding device described above is provided on both sides of the metal plate.
- the solidified resin film may be laminated on both sides of the metal plate by any suitable means.
- the resin composition or the coating composition of the solidified resin films to be laminated on both sides may be different from each other, or may be the same, and should be determined according to the required characteristics.
- the solidified resin film formed by passing the molten resin flowing down from the T-die through a film forming cooling roll was rewound on the other side from a pre-made resin film rewinding roll.
- a ready-made resin film may be pressed simultaneously using a pair of laminating rolls provided via a metal plate, and the resin film may be laminated on both sides. Further, for the purpose of improving the film strength and the film forming speed, after the molten resin flowing down from the T die is passed through a film forming cooling roll, the solidified resin film formed is uniaxially stretched.
- Examples of the apparatus for manufacturing such a resin-coated metal sheet include a metal sheet rewinding apparatus for continuously rewinding a metal sheet, a heating apparatus for heating the metal sheet, and an extruder for flowing molten resin from a T-die.
- the solidified resin film after the solidified resin film falls within a target thickness range.
- a pair of laminating rolls installed via a metal plate for pressing the heated resin plate onto the heated metal plate; a cooling device for cooling the resin-coated metal plate on which the solidified resin film is continuously laminated; A resin-coated metal plate winding device for continuously winding the resin-coated metal plate.
- the laminating rolls are usually used as a pair as described above. However, when laminating is performed separately on each side, the above-described pair is used when another resin layer is laminated on the laminated resin layer. Lamination may be performed using two or more of the lamination ports as required.
- the film formation and lamination of the solidified resin film are all performed in the same process, and an extruder, a T die, a film forming cooling roll, A resin coating device consisting of a solidified resin film winding device and a pair of laminating rolls installed via a metal plate is installed not only on one side of the metal plate but also on each side of the metal plate. Installation is required. However, it is not always necessary to separately install the pair of laminating rolls for both sides, and the solidified resin films on both sides may be simultaneously laminated by one pair of laminating ports.
- lamination of a solidified resin film formed by passing a molten resin flowing down from a T-die to one side of a metal plate through a film forming cooling hole and lamination of an already-made resin film on the other side are performed in the same process.
- one side of the metal plate is the extruder, T die, film forming cooling roll, solidified resin film winding device, and a pair of laminating rolls installed via the metal plate. It is necessary to install at least a ready-made resin film rewinding device for rewinding a ready-made resin film on the other side. If necessary, another pair of laminating rolls may be provided via a metal plate if necessary on the other side, but it is not always necessary to provide them as described above.
- the above-described solidified resin film rewinding device and the already-made resin film rewinding device have not only a function of rewinding a film but also a function of controlling a film tension when laminating a metal plate. .
- the solidified resin film is put into a pair of laminations. It is possible to cut the film on the non-laminated side, that is, the film between the laminating roll and the solidified resin film, at a desired position that does not wind around various rolls or other devices almost in synchronism with the pressing by the mineral roll. preferable.
- FIG. 1 is an explanatory view showing an example of a manufacturing apparatus used to carry out the method for manufacturing a resin metal plate according to the present invention.
- FIG. 2 is an explanatory diagram showing an example of a uniaxial stretching apparatus that can be suitably used in the manufacturing method.
- the extruder, the T die, and the film forming The trimming of both ends as necessary until the thickness of the solidified resin film formed using the cooling roll reaches the target thickness,
- the film is wound on a solidified resin film winding device.
- both ends were trimmed, and after confirming that the thickness of the solidified resin film had reached a target thickness, the film was continuously unwound from a metal plate unwinder and heated.
- the solidified resin film is pressed against the metal plate with a laminating roll and continuously laminated to obtain a resin-coated metal plate.
- a film cutting device is provided between the solidified resin film winding device and the laminator roll, and almost synchronously with lamination of the solidified resin film to the metal plate, Cut the solidified resin film at an appropriate position so that the cut solidified resin film does not wrap around rolls or other equipment or adhere to the resin-coated metal plate.
- the solidified resin film formed by using an extruder, a T die, and a film forming cooling roll is formed on both sides of the metal plate, and each of the solidified resin films is formed. Laminated on both sides of the heated metal plate to obtain a resin-coated metal plate with double-sided resin coating.
- the resin coating on one side of the double-sided resin-coated resin-coated metal plate is performed by a solidified resin film formed by using an extruder, a T-die, and a film forming cooling roll, Resin coating is performed with a ready-made resin film.
- the resin coating on at least one side of the metal plate is made of a solidified resin film formed by using an extruder, a T-die and a film forming cooling roll, and further uniaxially stretched. Do.
- Claims 7 to 12 are apparatuses for carrying out the manufacturing method of claims 1 to 6, respectively.
- the metal sheet is continuously unwound from a metal sheet rewinding apparatus and heated by a heating apparatus, while flowing down from a T-die using an extruder.
- the molten resin is turned into a solidified resin film by a film forming cooling roll, and is wound around a solidified resin film winding device until it is confirmed that the solidified resin film has a desired thickness.
- the solidified resin film is pressed on a heated metal plate by a laminating roll to continuously laminate the laminated metal plate.
- the apparatus is provided with equipment for winding the resin-coated metal plate cooled by the cooling device with a resin-coated metal plate winding device.
- the production apparatus after confirming that the thickness of the solidified resin film formed by the film-forming cooling roll in the same facility as in claim 7 has reached the target thickness, Almost synchronously with the pressing with the laminating roll, the solidified resin film is cut at an appropriate position between the solidified resin film and the laminating roll as described above, and the cut solidified resin film is wound around a roll or a device, The supply of the solidified resin film to the solidified resin film winding device is stopped so that the solidified resin film does not adhere to the resin-coated metal plate, and the solidified resin film is heated in the same manner as in claim 7. It is provided with equipment for continuously laminating a metal plate.
- the manufacturing apparatus wherein the metal coating is performed by a resin coating device disposed on one side of the metal plate and configured by an extruder, a T-die, a film forming cooling roll, a solidified resin film winding device, and a laminating roll.
- An apparatus for continuously laminating a solidified resin film on only one side of the plate in the same manner as in claim 7 or 8 is provided.
- the production apparatus according to claim 10 wherein the resin coating apparatus is arranged on both sides of the metal plate, and includes an extruder, a T die, a film forming cooling roll, a solidified resin film winding device, and a laminating roll.
- a facility for continuously laminating a solidified resin film on both sides of a heated metal plate in the same manner as in claim 7 or 8 is provided.
- the laminating roll may be a single pair of laminating rolls via a metal plate as described above.
- the molten resin that has flowed down from the T-die is formed into a solidified resin film by a film forming cooling roll on one side of a metal plate using an extruder, and the solidified resin film is formed.
- Laminating is performed in the same manner as in claim 7 or 8, and a facility for laminating a ready-made resin film is provided by providing a ready-made resin film rewinding device on the other side of the metal plate.
- the apparatus for manufacturing a resin-coated metal plate generally includes a metal plate transfer path, a solidified resin film film / transfer path disposed above (front) the metal plate transfer path, and a bottom (back). ) And a resin film transfer path and a resin film crimping device.
- the metal plate transfer path heats the metal plate rewind reel 11 as a metal plate rewinding device that continuously rewinds the metal plate 10 and the metal plate 10 that has been rewound.
- It comprises a cooling device 16 for cooling the resin-coated metal plate 15 continuously laminated, and a resin-coated metal plate winding device 17 for winding the cooled resin-coated metal plate 15.
- a cooling device 16 for cooling the resin-coated metal plate 15 continuously laminated
- a resin-coated metal plate winding device 17 for winding the cooled resin-coated metal plate 15.
- the cooling device 33 may be used together, or the cooling device 33 alone may be used.
- the solidified resin film forming / transfer path disposed above (in front of) the metal plate transfer path is an extruder that causes the molten resin to flow down from the T-die, and the molten resin flows down.
- the uniaxial stretching device 21 for stretching, the uniaxial stretching device 21, and the film transfer direction conversion rolls 22, 23 for changing the support and transfer direction of the resin film 13, and the solidified resin film 13 are disposed after the uniaxial stretching device 21.
- the upper (table) laminating roll 25 and the lower (rear) laminating roll 31 and the upper laminating roll 2 which are disposed between 22 and 23 and press the solidified resin film 13 against the surface of the metal plate 10 5 (Table) and the solidified resin film take-up device 24, and the solidified resin film cut with a film cutter 26 such as a knife cutter or a laser cutter for cutting the solidified resin film 13 It consists of a film cutting device equipped with pinch rolls 34, 35, 36, 37 to prevent it from wrapping around rolls or other devices or sticking to coated metal plates.
- the ready-made resin film transfer path arranged on the lower (back) side continuously rewinds the ready-made resin film 14 and turns it toward the lower (back) surface of the metal plate 10.
- It comprises a pre-made resin film rewinding device 27 for transferring, and film transfer direction changing rolls 28, 29 for changing the transfer direction of the resin film 14.
- the resin film crimping device is composed of a pair of laminating rolls, that is, a laminating roll 25 and a laminating roll 31. It has the function of simultaneously bonding the lower (back) ready-made resin film to the metal plate and continuously laminating it.
- the film transfer direction changing rolls 22 and 23 or 28 and 29 need not necessarily be pressed against each other via the film.
- the above-described manufacturing apparatus merely shows a basic example of the present invention, and further increases the number of film forming cooling rolls, transfer direction changing rolls, a pair of laminating rolls, and a film static eliminator. And equipment such as a corona discharge treatment device. In addition, pass line rolls for film and metal sheets should be installed as necessary.
- the temperature of the laminating roll as well as the temperature of the heated metal plate greatly affects the properties of the laminating resin-coated metal plate. It is preferable to provide a laminating roll surface temperature adjusting roll that makes the roll contact with the laminating roll and rotates in synchronization with the rotation of the laminating roll.
- the metal plate 10 is unwound from the metal plate rewind reel 11 and the metal plate 10 is heated, and the fusion temperature of the solidified resin film 13 and the ready-made resin film 14 is heated by the heating device 12 ⁇ ⁇ ⁇ ⁇ , + 15 Heat to 0.
- the fusing temperature refers to the lowest temperature at which the resin film does not peel off on a flat plate after being thermally fused by being pressed on a heating metal plate by a laminating roll.
- the melting onset temperature is one measure. If the metal plate 10 is heated to an excessively high temperature, the contacted resin is thermally decomposed, which is not preferable.
- a film forming cooling roll 19, 2 having a cooling and solidifying function in which the resin melted from the die 18 is rotated at a predetermined speed VI by an extruder (not shown).
- the solidified resin film 13 obtained by flowing down to 0 and cooling and solidifying is trimmed at both ends as necessary, and then is axially stretched by a uniaxial stretching device 21. It is stretched and wound on a solidified resin film winding device 24.
- the film forming cooling hole 20 is generally not particularly required when a thin resin film is formed regardless of whether the film is uniaxially stretched.
- the thickness of the wound solidified resin film 13 is good, and the film thickness is within a range that is the same as or slightly larger than the width of the metal plate 10 to be coated, or finally a width that can satisfy the product width. Confirm that the distribution is within the target soil thickness of 15% and within ⁇ 6.
- the ready-made resin film 14 is rewound from the ready-made resin film rewinding device 27.
- the solidified resin film 13 had a constant surface temperature.
- the upper (front) laminating roll 25 is lowered in the direction of the arrow as shown, and the lower (back) laminating roll 31 is raised in the direction of the arrow, so that the solidified resin film 13 and the ready-made resin film 14 are removed.
- the above-mentioned resin film fusing temperature ⁇ T, +15 When pressed against both surfaces of the metal plate 10 heated to +150, almost immediately, immediately, the solidified resin film winding device 24 and the upper (table) laminating roll Cut the resin film 13 between 25 as much as possible (Table).
- the ready-made resin film pressure supporting rolls 30 and 32 installed after the laminating roll 31 are devices for pressing and supporting the ready-made resin film before lamination, and are used when the ready-made resin film is pressed by the laminating roll. Almost synchronously, the pressure support rolls 30 and 32 have a function of opening and are preferably provided, but are not necessarily required depending on the situation.
- the metal plates on which the solidified resin film 13 and the already-prepared resin film 14 are simultaneously and continuously laminated are cooled by the cooling devices 33 and 16 so that the resin-coated metal plate 15 is wound around the resin-coated metal plate. It is equipped with equipment for winding and manufacturing with a take-up device.
- the laminator roll 25 Since the resin film 13 is laminated on the surface of the metal plate 10 heated to 31 and 31, the solidified resin film 13 which is not of the desired thickness is laminated to generate defective products. Can be prevented, and the yield of the resin-coated metal plate 15 can be increased.
- the solidified resin film 13 extruded from the T die 18 until the target thickness is reached is not yet coated on the metal plate, so that it can be recycled by re-melting, and as a result, Almost no loss of resin associated with film formation.
- FIG. 2 shows an embodiment of the configuration of a uniaxial stretching apparatus that can be suitably used in the above-described method of manufacturing a resin-coated metal sheet.
- the uniaxial stretching apparatus The preheating section for setting an appropriate stretching temperature, the stretching section for uniaxially stretching the preheated solidified resin film depending on the peripheral speed of the roll, and the annealing section for removing the distortion of the stretched solidified resin film are roughly divided into three parts.
- the solidified resin film 13 is set to a glass transition temperature Tg to Tg + 7o in the preheating section of the uniaxial stretching apparatus, and usually 1.5 to 6 times the original length before stretching in the stretching section. Uniaxially stretch to length.
- the film is heat-set at the annealing portion at a temperature usually higher than the stretching temperature and within a temperature range in which the appearance of the solidified resin film can be normally maintained.
- the uniaxial stretching ratio is determined in consideration of the stretching ratio and the ratio capable of favorably exhibiting the properties including the film thickness distribution and the surface appearance depending on the constituent resin composition of the solidified resin film.
- the laminating speed before winding is assumed to be VI to 1.2 XV.
- the laminating speed is V, X stretching ratio (K) to 1.2 XV, XK.
- a resin film 13 wider than the metal plate 10 to be coated is laminated on the metal plate 10 with a good film thickness distribution. Laminate and trim the resin film 13 after lamination. At this time, the portion within the thickness range of 15% of the target thickness soil and within ⁇ 6 m is laminated on the metal plate 10.
- the width of the solidified resin film 13 immediately before lamination on the metal plate 10 having the target film thickness distribution is equal to the width of the metal plate 10 if film trimming is not performed.
- the range is 100% to 130%.
- the type of resin used in the present invention is not particularly limited, except for uniaxial stretching, as long as it can be extruded into a film and can be thermally fused to a metal plate, and is selected according to required characteristics. Should.
- the stretching ratio is taken into consideration in the case of uniaxial stretching and in the case of biaxial stretching, the resin composition which can be widely applied is broadly limited, and there are few types of resins.
- the resin film configuration that can be used in the present invention include:
- 2Modified olefin resin such as maleic acid-modified polypropylene
- Multi-layer resin composed of two layers of polypropylene resin laminated on the upper layer.
- Polyethylene terephthalate resin or 3, ⁇ ⁇ ⁇ ⁇ or 5 is further added to the upper layer of A multi-layer resin consisting of a two-layer film composed of a laminated polyethylene terephthalate / isophthalate copolymer resin, ⁇
- a multi-layer resin consisting of a two-layer film composed of a laminated polyethylene terephthalate / isophthalate copolymer resin, ⁇
- the lowermost layer of the above 1 the blended resin composition of the above 3, 4 or 5, metal, etc.
- Examples include a multilayer resin having a three-layer coating structure in which a resin having a small addition amount is laminated.
- the resin coating may contain additives such as pigments, stabilizers, and antibacterial materials, if necessary, in each of the single layer or the multiple layers.
- examples of the metal plate used in the present invention include surface cleaning treatment such as surface alumite treatment, degreasing pickling, surface etching treatment, and surface immersion chromic acid treatment. And an aluminum plate which has been subjected to electrolytic chromic acid treatment, or a steel plate which has been subjected to plating treatment such as untreated, Sn, Ni, Zn, etc., and then subjected to immersion chromic acid treatment or electrolytic chromic acid treatment.
- the molten resin is extruded from a T-die, and pressed on the metal sheet until the thickness of the solidified resin film formed by the film forming cooling roll is stabilized.
- the solidified resin film was first laminated on the surface of the metal plate using a laminating roll. However, it is possible to prevent the occurrence of defective products by laminating the solidified resin film 13 that does not satisfy the target thickness, and to increase the yield of the resin-coated metal plate 15.
- the solidified resin film 13 extruded from the T die 18 until the target thickness is reached is not yet coated on the metal plate, so that it can be recycled by re-melting, and as a result, Can almost eliminate the loss of resin related to film formation.
- the formation of the solidified resin film and the lamination on one side of the metal plate can be performed in the same step, and the loss of the resin and the metal plate can be minimized.
- a single-side resin-coated metal plate can be economically manufactured.
- the formation of a solidified resin film for double-sided lamination of the metal plate and the lamination on both surfaces of the metal plate are performed in the same step, and the loss of the resin and the metal plate is minimized. Therefore, a double-sided resin-coated metal plate can be manufactured economically.
- the composition of the solidified resin film to be laminated on one side of the metal plate is constant, and the resin composition of the film to be laminated on the other side needs to be variously changed.
- a double-sided resin-coated metal plate that requires small lot handling due to specification changes can be manufactured easily and consequently economically.
- the manufacturing method according to claim 6 it is possible not only to carry out the film formation of the solidified resin film and the lamination on the surface of the metal plate in the same process, but also to minimize the loss of the resin and the metal plate. Since the solidified resin film is uniaxially stretched before lamination in the same step, the film strength is higher than when an unstretched solidified resin film is laminated on a metal plate, and the film tension is easily controlled. If the productivity is further improved, the film formation speed is also increased, so that the productivity is improved and a resin-coated metal plate having economical efficiency is easily manufactured.
- References 12 to 12 denote apparatuses for enabling the production method according to claims 1 to 6 to achieve the above-described effects. That is, claims 7, 8, 9, 10, 10, 11, and 12 enable the implementation of claims 1, 2, 3, 4, 5, and 6, respectively, and implement the above-described effects by implementing the claims. It is a manufacturing device for obtaining.
- the apparatus and the manufacturing method of the present invention can provide a resin-coated metal plate having high economic efficiency which cannot be achieved by the conventional technology, and the application effect is great.
Landscapes
- Laminated Bodies (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
Abstract
Description
明 細 書 樹脂被覆金属板の製造方法及び製造装置 技術分野 本発明は、 金属板及び樹脂の無駄を生じることなく、 かつ、 同一工程で固化樹 脂フィルムの製膜と製膜したフィルムの金属板へのラミネートを安定して出来る 経済性に優れた樹脂被覆金属板の製造方法及び装置に関する。 背景技術 TECHNICAL FIELD The present invention relates to a method of manufacturing a solidified resin film and a metal plate of the formed film without waste of the metal plate and the resin and in the same process. TECHNICAL FIELD The present invention relates to a method and an apparatus for manufacturing a resin-coated metal plate which is capable of stably laminating a resin sheet and has excellent economic efficiency. Background art
樹脂被覆金属板の製造方法として、 特開平 2— 2 4 1 7 3 7号公報に、 Tダイ より溶融した熱可塑性榭脂を予熱してある金属板に流下し、 ニップルロールで圧 接して樹脂被覆金属板を得る製造方法が提示されている。 As a method for producing a resin-coated metal plate, Japanese Patent Application Laid-Open No. H2-24-2737 describes a method in which a thermoplastic resin melted from a T-die is flowed down onto a pre-heated metal plate, and pressed with a nipple roll to form a resin. A manufacturing method for obtaining a coated metal plate has been proposed.
また、 特開平 4一 2 9 4 1 4 2号公報に、 Tダイより押し出された溶融した熱 可塑性樹脂の幅方向の両端部の膜厚が異常に厚いため、 鋼板より幅の広い溶融熱 可塑性樹脂を鋼板に被覆すると共に、 該被覆面の反対面に、 該溶融熱可塑性樹脂 よりもさらに幅の広い固体熱可塑性樹脂を設けることにより、 溶融熱可塑性樹脂 の鋼板巻き付け側圧着ロールへの付着がなく、 膜厚分布が均一な両面樹脂被覆鋼 板を得る製造方法が提示されている。 In addition, Japanese Patent Application Laid-Open No. Hei 4-291442 discloses that the molten thermoplastic resin extruded from the T-die has an unusually thick film at both ends in the width direction, so that the molten thermoplastic resin wider than the steel sheet By coating the resin on the steel sheet and providing a solid thermoplastic resin wider than the molten thermoplastic resin on the opposite side of the coated surface, adhesion of the molten thermoplastic resin to the pressing roll on the steel sheet winding side can be prevented. And a method for obtaining a double-sided resin-coated steel sheet having a uniform film thickness distribution is proposed.
さらに、 特開平 6— 3 0 5 0 2 4号公報に、 被覆前の榭脂を長さ方向に延伸す るだけでなく、 幅方向にも延伸する、 すなわち、 二軸延伸することにより、 フィ ルムの幅方向の膜厚変動を防止することができる樹脂被覆金属板の製造方法が提 示されているが、 該方法は確かに有効な方法ではあるが、 二軸延伸設備に多大の 費用を要すこと、 実用上二軸延伸可能な樹脂組成が限られること、 さらには樹脂 損失の抑制を目的とし、 フィルム端部の厚膜部を少なくするために横延伸時の樹 脂の厚さを薄くしたり、 つかみしろを狭くするとフィルム切断が起こりやすくな ることや、 例え二軸延伸出来ても膜厚分布は製膜開始時からは安定せずある程度 の時間がかかり、 不安定の間も金属板にラミネートを行っているため樹脂損失だ けでなく金属損失があり、 状況や生産ロットによっては必ずしも経済性を有した 製造方法とは言えず、 改善する必要に迫られてきている。 また、 二軸延伸しなく とも、 未延伸でも目的とする膜厚及び膜厚分布は二軸延伸より多少時間がかかる が、 安定するまでに二ップ間隔等の製膜条件を微調整することにより得られるこ とや、 また、 後述する本発明の樹脂製膜が安定するまで金属板にラミネートしな いでフィルム巻き取り機で巻き取り、 該巻取つたフィルムを再使用すれば不安定 製膜間の榭脂損失をほぼ解消できることが判ってきた。 従って、 少なくとも特開 平 6— 3 0 5 0 2 4号公報による方法は経済性の面からは最適な製造方法ではな いと言える。 Furthermore, Japanese Patent Application Laid-Open No. Hei 6-350024 discloses that the resin before coating is stretched not only in the length direction but also in the width direction, that is, by biaxially stretching. Although a method for producing a resin-coated metal plate capable of preventing the film thickness from fluctuating in the width direction of the film has been proposed, this method is certainly an effective method, but it requires a great deal of cost for biaxial stretching equipment. What is required is that the resin composition that can be biaxially stretched is practically limited, and the thickness of the resin during transverse stretching is reduced in order to reduce the thickness of the film at the end of the film with the aim of suppressing resin loss. If the film is made thinner or the grip is narrower, the film will be more likely to break, and even if biaxial stretching can be performed, the film thickness distribution will not be stable from the start of film formation and it will take some time, and even during instability Loss of resin due to lamination on metal plate Not only that, but also metal loss, and depending on the situation and production lot, it is not necessarily an economical manufacturing method, and there is a need for improvement. Also, even if the film is not stretched, the target film thickness and film thickness distribution may take a little longer than the biaxial stretching even if the film is not stretched. Until the resin film of the present invention described later is stabilized, the film is wound on a film winding machine without laminating on a metal plate, and if the wound film is reused, unstable film formation will occur. It has been found that the resin loss during the process can be almost completely eliminated. Therefore, it can be said that at least the method disclosed in Japanese Patent Application Laid-Open No. Hei 6-350024 is not an optimal production method from the viewpoint of economy.
上記した樹脂被覆金属板の製造方法は、 いずれも、 以下の解決すべき課題を有 していた。 即ち、 これらの製造方法のほとんどは、 いずれも Tダイより押し出し た樹脂は冷却ロールとニップルロールとの間で、 溶融状態の樹脂を金属板に被覆 するものであるが、 金属板に被覆された榭脂フィルムの膜厚が安定するまでには 一定の時間を要する。 従って、 膜厚が安定するまでに製造された樹脂被覆金厲板 は不良製品として使用できず、 その間の金属板及び樹脂は無駄になる。 さらに、 前記した二軸延伸してラミネートする場合は、 前記と同様に金属板及び樹脂の無 駄になることに加え、 適用可能な樹脂が大幅に限定され、 又製膜安定性に欠ける 等の問題があった。 All of the above-described methods for producing a resin-coated metal plate have the following problems to be solved. In other words, in most of these production methods, the resin extruded from the T-die coats the molten resin on the metal plate between the cooling roll and the nipple roll.一定 It takes a certain amount of time for the thickness of the resin film to stabilize. Therefore, the resin-coated metal plate manufactured until the film thickness becomes stable cannot be used as a defective product, and the metal plate and resin during that time are wasted. Further, in the case of laminating by biaxial stretching as described above, in addition to the waste of the metal plate and the resin as described above, applicable resins are greatly limited, and the film forming stability is lacking. There was a problem.
本発明は、 このような問題に鑑みなされたものであり、 金属板及び樹脂の無駄 を生じることなく樹脂被覆金属板を歩留りょく経済的に製造することができる方 法及び装置を提供するものである。 発明の開示 The present invention has been made in view of such a problem, and provides a method and an apparatus capable of economically producing a resin-coated metal plate at a high yield without wasting the metal plate and the resin. It is. Disclosure of the invention
本発明の樹脂被覆金属板の製造方法は、 Tダイから流下させた溶融樹脂をフィ ルム形成冷却ロールを通過させることによって製膜し、 固化した固化榭脂フィル ムの厚みが、 目的とする膜厚範囲内であることを確認するまで該固化樹脂フィル ムを固化樹脂フィルム卷取装置に巻き取り、 固化榭脂フィルムの厚みが目的とす る膜厚範囲内であることを確認後、 金属板巻戻しリールから連続的に巻戻し、 加 熱された金属板の表面に該固化樹脂フィルムをラミネートロールにより圧着し連 続的にラミネートすることを特徴とする。 In the method for producing a resin-coated metal plate of the present invention, the thickness of a solidified resin film formed by passing a molten resin flowing down from a T-die through a film-forming cooling roll to form a film is reduced. The solidified resin film is wound around a solidified resin film winding device until it is confirmed that the thickness is within the thickness range, and after confirming that the thickness of the solidified resin film is within the target thickness range, the metal plate is formed. The solidified resin film is continuously rewound from a rewind reel, and the solidified resin film is pressure-bonded to the surface of the heated metal plate by a laminating roll. It is characterized by continuous lamination.
さらに、 固化樹脂フィルム卷取装置と前記ラミネートロールとの間にフィルム 切断装置を設け、 加熱された金厲板の表面に該固化樹脂フィルムをラミネート口 ールで圧着した時とほぼ同期的に、 前記固化樹脂フィルムの切断を、 切断したフ イルムがロールや他の装置に巻き付かない適切な位置で行えばより容易にラミネ 一卜が可能となる。 Further, a film cutting device is provided between the solidified resin film winding device and the laminating roll, and almost synchronously with the case where the solidified resin film is pressed on the surface of the heated metal plate with the laminating hole, If the cut resin film is cut at an appropriate position where the cut film is not wound around a roll or other device, lamination can be performed more easily.
また、 前記手段によって得た固化樹脂フィルムを前記金属板の片面のみにラミ ネートしても良く、 前述した固化樹脂フィルム製膜及び巻取り装置を金厲板の両 側方に設け、 前記と同様な手段により金属板の両面に固化樹脂フィルムをラミネ ートしても良い。 また、 その際両面にラミネートする固化樹脂フィルムの樹脂組 成あるいは被膜構成は互いに異なっても良いし、 また同じでも良く要求特性に応 じて決定すべきである。 Further, the solidified resin film obtained by the above means may be laminated on only one side of the metal plate, and the solidified resin film forming and winding device described above is provided on both sides of the metal plate. The solidified resin film may be laminated on both sides of the metal plate by any suitable means. In this case, the resin composition or the coating composition of the solidified resin films to be laminated on both sides may be different from each other, or may be the same, and should be determined according to the required characteristics.
さらに金属板の片面に、 前記 Tダイから流下させた溶融樹脂をフィルム形成冷 却ロールを通過させることによって製膜した固化榭脂フィルムを他の面に、 既製 樹脂フィルム巻戻しロールから巻戻した既製の樹脂フィルムを金属板を介して設 置した一対のラミネートロールを用いて同時に圧着し、 両面に樹脂フィルムをラ ミネ一卜しても良い。 さらにフィルム強度や製膜速度の向上を目的として、 前記 Tダイから流下させた溶融榭脂をフィルム形成冷却ロールを通過させることによ つて製膜した固化樹脂フィルムを一軸延伸した後、 該榭脂フィルムをラミネート ロールで加熱された金属板に圧着し連続的にラミネー卜することも可能であり、 樹脂被覆金属板の生産性が増すことや長手方向のフィルム強度が増し、 ラミネー ト時のテンションコントロールが容易となりラミネート性が向上する観点から好 ましい方法の一つと言える。 Further, on one side of the metal plate, the solidified resin film formed by passing the molten resin flowing down from the T-die through a film forming cooling roll was rewound on the other side from a pre-made resin film rewinding roll. A ready-made resin film may be pressed simultaneously using a pair of laminating rolls provided via a metal plate, and the resin film may be laminated on both sides. Further, for the purpose of improving the film strength and the film forming speed, after the molten resin flowing down from the T die is passed through a film forming cooling roll, the solidified resin film formed is uniaxially stretched. It is also possible to continuously laminate the film by pressing the film on a heated metal plate with a laminating roll, increasing the productivity of the resin-coated metal plate and increasing the film strength in the longitudinal direction, and controlling the tension during lamination. It can be said that this is one of the preferable methods from the viewpoint that the lamination property is improved and the laminating property is improved.
そして、 このような樹脂被覆金属板の製造装置としては、 金属板を連続的に巻 戻す金属板巻戻し装置と、 前記金属板を加熱する加熱装置と、 溶融樹脂を Tダイ から流下させる押し出し機と、 Tダイから流下する溶融樹脂から固化樹脂フィル ムを製膜するフィルム形成冷却ロールと、 前記固化樹脂フィルムが目的とする膜 厚範囲内になるまで該固化樹脂フィルムを巻き取る固化樹脂フィルム巻取装置と、 前記固化樹脂フィルムが目的とする膜厚範囲内になった後、 該固化樹脂フィルム を前記加熱された金属板に圧着させる金属板を介して設置した一対のラミネート ロールと、 該固化樹脂フィルムを連続的にラミネ一卜された樹脂被覆金属板を冷 却する冷却装置と、 冷却された樹脂被覆金属板を連続的に卷き取る樹脂被覆金属 板巻取装置とを設置することを特徴とする。 また、 ラミネートロールは通常、 前 記した様に一対として使用されるが、 片面ずつ別々にラミネートする場合ゃラミ ネートした樹脂層の上にさらに別の樹脂層をラミネ一卜する場合には前記一対の ラミネート口一ルを必要に応じ二基以上用いてラミネートを行っても良い。 Examples of the apparatus for manufacturing such a resin-coated metal sheet include a metal sheet rewinding apparatus for continuously rewinding a metal sheet, a heating apparatus for heating the metal sheet, and an extruder for flowing molten resin from a T-die. A film forming cooling roll for forming a solidified resin film from the molten resin flowing down from the T-die; and a solidified resin film winding for winding the solidified resin film until the solidified resin film falls within a target film thickness range. The solidified resin film after the solidified resin film falls within a target thickness range. A pair of laminating rolls installed via a metal plate for pressing the heated resin plate onto the heated metal plate; a cooling device for cooling the resin-coated metal plate on which the solidified resin film is continuously laminated; A resin-coated metal plate winding device for continuously winding the resin-coated metal plate. The laminating rolls are usually used as a pair as described above. However, when laminating is performed separately on each side, the above-described pair is used when another resin layer is laminated on the laminated resin layer. Lamination may be performed using two or more of the lamination ports as required.
次に、 すべて固化樹脂フィルムの製膜とラミネートを同一工程で行い、 該固化 樹脂フィルムを金属板の両面にラミネートした金属板を得るには押し出し機と、 Tダイと、 フィルム形成冷却ロールと、 固化樹脂フィルム巻取装置と、 金属板を 介して設置した一対のラミネートロールとからなる榭脂被覆装置を、 金属板の片 側方のみに設置するだけでなく、 それぞれ前記金属板の両側方に設置することが 必要である。 但し、 前記一対のラミネートロールについては必ずしも両側方用と して別々に設置する必要はなく、 一対のラミネート口一ルー基により両側方の固 化樹脂フィルムを同時にラミネートして良い。 Next, the film formation and lamination of the solidified resin film are all performed in the same process, and an extruder, a T die, a film forming cooling roll, A resin coating device consisting of a solidified resin film winding device and a pair of laminating rolls installed via a metal plate is installed not only on one side of the metal plate but also on each side of the metal plate. Installation is required. However, it is not always necessary to separately install the pair of laminating rolls for both sides, and the solidified resin films on both sides may be simultaneously laminated by one pair of laminating ports.
また、 金属板の一側方に Tダイから流下させた溶融樹脂をフィルム形成冷却口 ールを通過させることによって製膜した固化樹脂フィルム、 他側方に既製の樹脂 フィルムのラミネートを同一工程で行うためには、 金属板の一側方は前記押し出 し機と、 Tダイと、 フィルム形成冷却ロールと、 固化榭脂フィルム巻取装置と、 金属板を介して設置した一対のラミネートロールとからなる榭脂被覆装置を、 他 側方は、 既製の榭脂フィルムを巻き戻すための既製樹脂フィルム巻戻し装置を少 なくとも設置することが必要である。 該他側方には必要があれば、 さらに金属板 を介して別の一対のラミネートロールも設置しても良いが、 前述と同様に必ずし も設置する必要はない。 なお、 前述した固化樹脂フィルム巻き戻し装置及び既製 樹脂フィルム巻き戻し装置は単にフィルムを巻き戻す機能だけでなく金属板にラ ミネ一卜する時のフィルムテンションコントロール機能を有していることが好ま しい。 In addition, lamination of a solidified resin film formed by passing a molten resin flowing down from a T-die to one side of a metal plate through a film forming cooling hole and lamination of an already-made resin film on the other side are performed in the same process. To perform, one side of the metal plate is the extruder, T die, film forming cooling roll, solidified resin film winding device, and a pair of laminating rolls installed via the metal plate. It is necessary to install at least a ready-made resin film rewinding device for rewinding a ready-made resin film on the other side. If necessary, another pair of laminating rolls may be provided via a metal plate if necessary on the other side, but it is not always necessary to provide them as described above. It is preferable that the above-described solidified resin film rewinding device and the already-made resin film rewinding device have not only a function of rewinding a film but also a function of controlling a film tension when laminating a metal plate. .
さらに、 前述した設置する装置の他にラミネートロールと固化樹脂フィルム巻 取装置との間にフィルム切断装置を設置すると前記固化樹脂フィルムを一対のラ ミネ一トロールによる圧着時とほぼ同期的に非ラミネート側のフィルム、 即ちラ ミネートロールと固化樹脂フィルム間のフィルムの切断を各種ロールや他の装置 に巻き付いたりしない望ましい位置で行うことが可能でより好ましい。 Further, when a film cutting device is installed between the laminating roll and the solidified resin film winding device in addition to the above-described device to be installed, the solidified resin film is put into a pair of laminations. It is possible to cut the film on the non-laminated side, that is, the film between the laminating roll and the solidified resin film, at a desired position that does not wind around various rolls or other devices almost in synchronism with the pressing by the mineral roll. preferable.
さらに前記フィルム形成冷却ロールとラミネートロールとの間に一軸延伸装置 を設置することも、 前記したように製膜速度が早くなり樹脂被覆金属板の生産性 が増すことや長手方向のフィルム強度が増し、 ラミネート時のテンションコント ロールが容易になりラミネート安定性が向上する観点から好ましい。 図面の簡単な説明 Further, installing a uniaxial stretching device between the film forming cooling roll and the laminating roll also increases the film forming speed, increases the productivity of the resin-coated metal plate, and increases the longitudinal film strength, as described above. It is preferable from the viewpoint that tension control during lamination is facilitated and lamination stability is improved. BRIEF DESCRIPTION OF THE FIGURES
図 1は、 本発明に係る樹脂金属板の製造方法を実施するために用いる製造装置 の一例を示す説明図である。 図 2は、 同製造方法に好適に用いることができる一 軸延伸装置の一例を示す説明図である。 発明を実施するための最良の形態 FIG. 1 is an explanatory view showing an example of a manufacturing apparatus used to carry out the method for manufacturing a resin metal plate according to the present invention. FIG. 2 is an explanatory diagram showing an example of a uniaxial stretching apparatus that can be suitably used in the manufacturing method. BEST MODE FOR CARRYING OUT THE INVENTION
請求項 1〜 6記載の製造方法においては、 押し出し機と Tダイとフィルム形成 冷却ロールを用いて製膜した固化樹脂フィルムの厚みが目的とする厚みになるま で必要に応じ両端をトリミングし、 該フィルムを固化榭脂フィルム卷取装置に巻 き取る。 次に、 同様に必要に応じ両端をトリミングし、 該固化樹脂フィルムの厚 みが目的とする厚みになったことを確認した後に、 金属板巻戻し装置から連続的 に巻戻され、 加熱された金属板にラミネートロールにより、 固化樹脂フィルムを 圧着し連続的にラミネートして樹脂被覆金属板を得る。 In the manufacturing method according to claims 1 to 6, the extruder, the T die, and the film forming The trimming of both ends as necessary until the thickness of the solidified resin film formed using the cooling roll reaches the target thickness, The film is wound on a solidified resin film winding device. Next, similarly, if necessary, both ends were trimmed, and after confirming that the thickness of the solidified resin film had reached a target thickness, the film was continuously unwound from a metal plate unwinder and heated. The solidified resin film is pressed against the metal plate with a laminating roll and continuously laminated to obtain a resin-coated metal plate.
請求項 2記載の製造方法においては、 固化榭脂フィルム巻取装置と前記ラミネ 一トロールとの間にフィルム切断装置を設け、 固化樹脂フィルムの金属板へのラ ミネート時とほぽ同期的に、 固化樹脂フィルムの切断を、 切断した固化榭脂フィ ルムがロールや他の装置に巻き付いたり、 榭脂被覆金属板上に付着しない適切な 位置で行う。 In the production method according to claim 2, a film cutting device is provided between the solidified resin film winding device and the laminator roll, and almost synchronously with lamination of the solidified resin film to the metal plate, Cut the solidified resin film at an appropriate position so that the cut solidified resin film does not wrap around rolls or other equipment or adhere to the resin-coated metal plate.
請求項 3記載の製造方法においては、 押し出し機と Tダイとフィルム形成冷却 ロールを用いて製膜した固化樹脂フィルムを金属板の片面のみにラミネートして、 片面樹脂被覆の樹脂被覆金厲板を得る。 請求項 4記載の製造方法においては、 押し出し機と Tダイとフィルム形成冷却 ロールを用いて製膜した固化樹脂フィルムの製膜を金属板の両側方にて行い、 各 々の該固化樹脂フィルムを加熱された金属板の両面にラミネートして、 両面樹脂 被覆の樹脂被覆金属板を得る。 The manufacturing method according to claim 3, wherein the solidified resin film formed by using an extruder, a T-die, and a film forming cooling roll is laminated on only one surface of the metal plate, and a resin-coated metal plate of one-side resin coating is formed. obtain. In the manufacturing method according to claim 4, the solidified resin film formed by using an extruder, a T die, and a film forming cooling roll is formed on both sides of the metal plate, and each of the solidified resin films is formed. Laminated on both sides of the heated metal plate to obtain a resin-coated metal plate with double-sided resin coating.
請求項 5記載の製造方法においては、 両面樹脂被覆の榭脂被覆金属板における 片面の樹脂被覆は押し出し機と Tダイとフィルム形成冷却ロールを用いて製膜し た固化樹脂フィルムにより行い、 他側面の樹脂被覆は既製の樹脂フィルムにより 行う。 In the manufacturing method according to claim 5, the resin coating on one side of the double-sided resin-coated resin-coated metal plate is performed by a solidified resin film formed by using an extruder, a T-die, and a film forming cooling roll, Resin coating is performed with a ready-made resin film.
請求項 6記載の製造方法においては、 少なくとも金厲板の片面の樹脂被覆は押 し出し機と Tダイとフィルム形成冷却ロールを用いて製膜した固化樹脂フィルム をさらに一軸延伸した固化樹脂フィルムにより行う。 In the manufacturing method according to claim 6, the resin coating on at least one side of the metal plate is made of a solidified resin film formed by using an extruder, a T-die and a film forming cooling roll, and further uniaxially stretched. Do.
請求項 7〜 1 2は各々前記請求項 1〜 6の製造方法を実施するための装置であ る。 Claims 7 to 12 are apparatuses for carrying out the manufacturing method of claims 1 to 6, respectively.
請求項 7記載の榭脂被覆金厲板の製造装置は、 金属板巻戻し装置から金属板を 連続的に卷戻すと共に加熱装置で加熱し、 一方、 押し出し機を用いて Tダイから 流下させた溶融樹脂をフィルム形成冷却ロールによって固化樹脂フィルムとなし、 固化榭脂フィルムが目的とする厚みになったことを確認するまで固化樹脂フィル ム巻取装置に巻き取る。 そして、 固化榭脂フィルムが目的とする厚みになったこ とを確認後、 固化榭脂フィルムを加熱された金属板にラミネートロールにより圧 着して連続的にラミネートを行い、 ラミネートされた金属板を冷却装置により冷 却した樹脂被覆金属板を樹脂被覆金属板卷取装置で巻き取る設備を具備するもの である。 In the manufacturing apparatus for a resin-coated metal sheet according to claim 7, the metal sheet is continuously unwound from a metal sheet rewinding apparatus and heated by a heating apparatus, while flowing down from a T-die using an extruder. The molten resin is turned into a solidified resin film by a film forming cooling roll, and is wound around a solidified resin film winding device until it is confirmed that the solidified resin film has a desired thickness. Then, after confirming that the solidified resin film has the desired thickness, the solidified resin film is pressed on a heated metal plate by a laminating roll to continuously laminate the laminated metal plate. The apparatus is provided with equipment for winding the resin-coated metal plate cooled by the cooling device with a resin-coated metal plate winding device.
請求項 8記載の製造装置は、 請求項 7と同様な設備でフィルム形成冷却ロール によって製膜された固化樹脂フィルムの厚みが目的とする厚みになったことを確 認後、 該固化樹脂フィルムをラミネートロールで圧着する時とほぼ同期的に、 固 化樹脂フィルムを前記した様に固化樹脂フィルムとラミネートロール間の適切な 位置で切断して、 切断した固化樹脂フィルムがロールや装置に巻き付いたり、 樹 脂被覆金属板上に付着しないようにして、 固化樹脂フィルムの固化樹脂フィルム 巻取装置への供給を停止し、 請求項 7と同様にして固化榭脂フィルムを加熱され た金属板に連続的にラミネー卜する設備を具備するものである。 The production apparatus according to claim 8, after confirming that the thickness of the solidified resin film formed by the film-forming cooling roll in the same facility as in claim 7 has reached the target thickness, Almost synchronously with the pressing with the laminating roll, the solidified resin film is cut at an appropriate position between the solidified resin film and the laminating roll as described above, and the cut solidified resin film is wound around a roll or a device, The supply of the solidified resin film to the solidified resin film winding device is stopped so that the solidified resin film does not adhere to the resin-coated metal plate, and the solidified resin film is heated in the same manner as in claim 7. It is provided with equipment for continuously laminating a metal plate.
請求項 9記載の製造装置は、 金属板の一側方に配置した、 押し出し機と Tダイ とフィルム形成冷却ロールと、 固化樹脂フィルム巻取装置と、 ラミネートロール とからなる樹脂被覆装置によって、 金属板の片面のみに固化樹脂フィルムを請求 項 7あるいは 8と同様にして連続的にラミネートする設備を具備するものである。 請求項 1 0記載の製造装置は、 金属板の両側方にそれぞれ配置した、 押し出し 機と Tダイとフィルム形成冷却ロールと固化樹脂フィルム巻取装置とラミネ一卜 ロールとからなる樹脂被覆装置によって、 請求項 7あるいは 8と同様にして加熱 された金属板の両面に固化樹脂フィルムを連続的にラミネートする設備を具備す るものである。 なお、 ラミネートロールは前述した様に金属板を介して一対のラ ミネ一トロール一基だけでも良い。 The manufacturing apparatus according to claim 9, wherein the metal coating is performed by a resin coating device disposed on one side of the metal plate and configured by an extruder, a T-die, a film forming cooling roll, a solidified resin film winding device, and a laminating roll. An apparatus for continuously laminating a solidified resin film on only one side of the plate in the same manner as in claim 7 or 8 is provided. The production apparatus according to claim 10, wherein the resin coating apparatus is arranged on both sides of the metal plate, and includes an extruder, a T die, a film forming cooling roll, a solidified resin film winding device, and a laminating roll. A facility for continuously laminating a solidified resin film on both sides of a heated metal plate in the same manner as in claim 7 or 8 is provided. The laminating roll may be a single pair of laminating rolls via a metal plate as described above.
請求項 1 1記載の製造装置においては、 金厲板の片面には押し出し機を用いて Tダイから流下させた溶融樹脂をフィルム形成冷却ロールによって固化樹脂フィ ルムとなし、 該固化榭脂フィルムを請求項 7あるいは 8と同様にしてラミネート するとともに、 金厲板の他側面には既製樹脂フィルム巻き戻し装置を設けること により既製の樹脂フィルムをラミネートする設備を具備するものである。 In the manufacturing apparatus according to claim 11, the molten resin that has flowed down from the T-die is formed into a solidified resin film by a film forming cooling roll on one side of a metal plate using an extruder, and the solidified resin film is formed. Laminating is performed in the same manner as in claim 7 or 8, and a facility for laminating a ready-made resin film is provided by providing a ready-made resin film rewinding device on the other side of the metal plate.
請求項 1 2記載の製造装置は、 請求項 7と同様な設備でフィルム形成冷却ロー ルによって製膜された固化榭脂フィルムをいつたん一軸延伸装置によって一方向 (長手方向) に延伸し、 樹脂フィルムの厚みが目的とする厚みになったことを確 認後、 請求項 7〜1 1と同様にして固化樹脂フィルムを加熱された金属板に連続 的にラミネートする設備を具備するものである。 The production apparatus according to claim 12, wherein the solidified resin film formed by the film-forming cooling roll in the same equipment as in claim 7 is stretched in one direction (longitudinal direction) by a uniaxial stretching device. After confirming that the thickness of the film has reached the target thickness, a facility for continuously laminating the solidified resin film to the heated metal plate is provided in the same manner as in claims 7 to 11.
(実施例) (Example)
以下、 添付図に示す一実施例を参照して、 本発明を具体的に説明する。 Hereinafter, the present invention will be specifically described with reference to an embodiment shown in the accompanying drawings.
まず、 図 1及び図 2を参照して、 本発明の一実施の形態に係る樹脂被覆金属板 の製造装置の構成について説明する。 図 1に樹脂被覆金属板の製造装置の全体構 成を概念的に示す。 図示するように、 樹脂被覆金属板の製造装置は、 大まかには、 金属板移送路と、 この金属板移送路の上 (表) 方に配置した固化樹脂フィルム製 膜兼移送路、 下 (裏) 方に配置した既製樹脂フィルム移送路、 樹脂フィルム圧着 装置とからなる。 金属板移送路は、 図 1に示すように、 連続的に金属板 1 0を巻戻す金属板巻戻 し装置としての金属板巻戻しリール 1 1と、 巻戻された金属板 1 0を加熱する加 熱装置 1 2と、 後述する上 (表) 、 下 (裏) ラミネートロール 2 5、 3 1によつ て金属板の両面にそれぞれ固化樹脂フイルム 1 3、 既製樹脂フィルム 1 4を圧着 し、 連続的にラミネートされた樹脂被覆金属板 1 5を冷却する冷却装置 1 6と、 冷却した樹脂被覆金属板 1 5を巻き取る樹脂被覆金属板卷取装置 1 7とからなる。 また、 状況によってはラミネート後冷却される前にロール夕ツチすると表面外 観を損なうことがあり、 樹脂被覆金属板の冷却は必要に応じ図示しているように ロール夕ツチ前に設置されている冷却装置 3 3を併用、 あるいは冷却装置 3 3だ けで行っても良い。 First, a configuration of a manufacturing apparatus for a resin-coated metal plate according to an embodiment of the present invention will be described with reference to FIGS. Fig. 1 conceptually shows the overall configuration of the manufacturing equipment for resin-coated metal sheets. As shown in the figure, the apparatus for manufacturing a resin-coated metal plate generally includes a metal plate transfer path, a solidified resin film film / transfer path disposed above (front) the metal plate transfer path, and a bottom (back). ) And a resin film transfer path and a resin film crimping device. As shown in Fig. 1, the metal plate transfer path heats the metal plate rewind reel 11 as a metal plate rewinding device that continuously rewinds the metal plate 10 and the metal plate 10 that has been rewound. Heating equipment 12 and upper (front) and lower (rear) laminating rolls 25 and 31 to be described later press the solidified resin film 13 and the ready-made resin film 14 on both sides of the metal plate respectively. It comprises a cooling device 16 for cooling the resin-coated metal plate 15 continuously laminated, and a resin-coated metal plate winding device 17 for winding the cooled resin-coated metal plate 15. Also, depending on the situation, if the roll is set before cooling after lamination, the appearance of the surface may be impaired, and the cooling of the resin-coated metal plate is installed before the roll as shown in the illustration, if necessary. The cooling device 33 may be used together, or the cooling device 33 alone may be used.
また、 金属板移送路の上 (表) 方に配置した固化樹脂フィルム製膜兼移送路は、 図示していないが溶融樹脂を Tダイから流下させる押し出し機と、 溶融樹脂を下 方に流下する Tダイ 1 8と、 流下された溶融榭脂を通過させることによって冷却 固化して固化樹脂フィルム 1 3を製膜するフィルム形成冷却ロール 1 9、 2 0と、 榭脂フィルム 1 3を長手方向に延伸する一軸延伸装置 2 1と、 一軸延伸装置 2 1 の後に配置し、 樹脂フィルム 1 3の支持及び移送方向を変換するフィルム移送方 向変換ロール 2 2、 2 3と、 固化樹脂フィルム 1 3を巻き取る固化樹脂フィルム 卷取装置 2 4と、 固化樹脂フィルム巻取装置 2 4とフィルム移送方向変換ロール In addition, although not shown, the solidified resin film forming / transfer path disposed above (in front of) the metal plate transfer path is an extruder that causes the molten resin to flow down from the T-die, and the molten resin flows down. T-die 18, film-forming cooling rolls 19, 20 for cooling and solidifying by passing the molten resin flowing down to form solidified resin film 13, and resin film 13 in the longitudinal direction The uniaxial stretching device 21 for stretching, the uniaxial stretching device 21, and the film transfer direction conversion rolls 22, 23 for changing the support and transfer direction of the resin film 13, and the solidified resin film 13 are disposed after the uniaxial stretching device 21. Solidified resin film winding up device 24, solidified resin film winding device 24, and film transfer direction changing roll
2 2、 2 3との間に配置され、 固化樹脂フィルム 1 3を金属板 1 0の表面に圧着 させる上 (表) ラミネートロール 2 5及び下 (裏) ラミネートロール 3 1と、 上 ラミネートロール 2 5 (表) と固化樹脂フィルム巻取装置 2 4の間に配置され、 固化樹脂フィルム 1 3を切断するナイフカッターやレーザ一カツ夕一等のフィル ム切断機 2 6と切断した固化樹脂フィルムがロールや他の装置に巻き付いたり、 被覆金属板に付着しないようにするためのピンチロール 3 4、 3 5、 3 6、 3 7 を設けたフィルム切断装置からなる。 ここではピンチロール 3 4、 3 5、 3 6、The upper (table) laminating roll 25 and the lower (rear) laminating roll 31 and the upper laminating roll 2 which are disposed between 22 and 23 and press the solidified resin film 13 against the surface of the metal plate 10 5 (Table) and the solidified resin film take-up device 24, and the solidified resin film cut with a film cutter 26 such as a knife cutter or a laser cutter for cutting the solidified resin film 13 It consists of a film cutting device equipped with pinch rolls 34, 35, 36, 37 to prevent it from wrapping around rolls or other devices or sticking to coated metal plates. Here, pinch rolls 3 4, 3 5, 3 6,
3 7を用いているが状況によっては必ずしも用いる必要はないし、 また前記ピン チロールと同じ機能を有す装置で代替されても良い。 Although 37 is used, it is not always necessary to use it depending on the situation, and a device having the same function as the pinch roll may be used instead.
一方、 下 (裏) 方に配置した既製樹脂フィルム移送路は、 図 1に示すように、 既製の樹脂フィルム 1 4を、 連続的に巻戻し、 金属板 1 0の下 (裏) 面に向けて 移送する既製樹脂フィルム巻戻し装置 2 7と、 榭脂フィルム 1 4の移送方向を変 換するフィルム移送方向変換ロール 2 8、 2 9とからなる。 On the other hand, as shown in Fig. 1, the ready-made resin film transfer path arranged on the lower (back) side continuously rewinds the ready-made resin film 14 and turns it toward the lower (back) surface of the metal plate 10. hand It comprises a pre-made resin film rewinding device 27 for transferring, and film transfer direction changing rolls 28, 29 for changing the transfer direction of the resin film 14.
また、 樹脂フィルム圧着装置は一対のラミネートロール、 即ちラミネートロー ル 2 5とラミネートロール 3 1からなり、 両ラミネ一トロールは、 互いに接近さ せることにより、 前記上 (表) 方の固化樹脂フィルムと下 (裏) 方の既製榭脂フ イルムを金属板に同時に圧着させ連続的にラミネートする機能を有すものである。 また、 フィルム移送方向変換ロールは 2 2と 2 3あるいは 2 8と 2 9は必ずし もフィルムを介して互いに圧着されてなくても良い。 また、 前述した製造装置は あくまでも本発明の基本的な一例を示したものであり、 さらにフィルム形成冷却 ロールや移送方向変換ロールや一対のラミネー卜ロールの数を増やしたりフィル ムの静電除去装置やコロナ放電処理装置等の設備を付加しても良い。 また、 フィ ルムゃ金属板のパスラインロールについても必要に応じて設置されるべきである。 さらに、 図示していないが、 加熱された金属板の温度と同様にラミネートロー ルの温度もラミネート性ゃ樹脂被覆金属板の特性に大きく影響するので、 ラミネ —トロール表面温度の調整機能を有すロールを該ラミネー卜ロールに接触させ、 ラミネートロールの回転に同調回転するラミネートロール表面温度調整ロールを 具備していることが好ましい。 Further, the resin film crimping device is composed of a pair of laminating rolls, that is, a laminating roll 25 and a laminating roll 31. It has the function of simultaneously bonding the lower (back) ready-made resin film to the metal plate and continuously laminating it. Further, the film transfer direction changing rolls 22 and 23 or 28 and 29 need not necessarily be pressed against each other via the film. Further, the above-described manufacturing apparatus merely shows a basic example of the present invention, and further increases the number of film forming cooling rolls, transfer direction changing rolls, a pair of laminating rolls, and a film static eliminator. And equipment such as a corona discharge treatment device. In addition, pass line rolls for film and metal sheets should be installed as necessary. Furthermore, although not shown, the temperature of the laminating roll as well as the temperature of the heated metal plate greatly affects the properties of the laminating resin-coated metal plate. It is preferable to provide a laminating roll surface temperature adjusting roll that makes the roll contact with the laminating roll and rotates in synchronization with the rotation of the laminating roll.
次に上記した構成を有する榭脂被覆金属板の製造装置による樹脂被覆金属板の 製造方法について説明する。 Next, a method of manufacturing a resin-coated metal plate using the apparatus for manufacturing a resin-coated metal plate having the above-described configuration will be described.
金属板巻戻しリール 1 1から金属板 1 0を卷戻すとともに、 金属板 1 0を加熱 装置 1 2により固化樹脂フィルム 1 3、 既製樹脂フィルム 1 4の融着温度 Τ ι 〜 Τ , + 1 5 0 に加熱する。 なお、 融着温度とは、 榭脂フィルムが、 ラミネート ロールにより加熱金厲板に圧着されることにより熱融着した後、 平板で剥離しな い最低の温度をいい、 金属板と接する樹脂の融解開始温度が一つの目安となる。 金属板 1 0をあまり高温に加熱すると、 接触した樹脂が熱分解して好ましくない。 この金属板加熱工程と同一工程にて、 図示していない押し出し機により Τダイ 1 8より溶融した樹脂を所定の速度 V Iで回転している冷却固化機能を有するフ イルム形成冷却ロール 1 9、 2 0に流下し、 冷却固化して得た固化樹脂フィルム 1 3を、 必要に応じ両端をトリミングした後、 一軸延伸装置 2 1によってー軸延 伸して、 固化樹脂フィルム巻取装置 2 4に巻き取る。 また、 フィルム形成冷却口 ール 2 0は、 一軸延伸するしないに拘わらず薄い樹脂フィルムを製膜する場合に は一般的には特に必要ではない。 The metal plate 10 is unwound from the metal plate rewind reel 11 and the metal plate 10 is heated, and the fusion temperature of the solidified resin film 13 and the ready-made resin film 14 is heated by the heating device 12 Τ ι ~ Τ, + 15 Heat to 0. The fusing temperature refers to the lowest temperature at which the resin film does not peel off on a flat plate after being thermally fused by being pressed on a heating metal plate by a laminating roll. The melting onset temperature is one measure. If the metal plate 10 is heated to an excessively high temperature, the contacted resin is thermally decomposed, which is not preferable. In the same step as the metal plate heating step, a film forming cooling roll 19, 2 having a cooling and solidifying function in which the resin melted from the die 18 is rotated at a predetermined speed VI by an extruder (not shown). The solidified resin film 13 obtained by flowing down to 0 and cooling and solidifying is trimmed at both ends as necessary, and then is axially stretched by a uniaxial stretching device 21. It is stretched and wound on a solidified resin film winding device 24. Further, the film forming cooling hole 20 is generally not particularly required when a thin resin film is formed regardless of whether the film is uniaxially stretched.
その後、 巻き取られた固化樹脂フィルム 1 3の外観が良好であり、 かつ、 被覆 する金属板 1 0の幅と同じか若干広い幅あるいは最終的に製品幅を満足できる幅 範囲内で、 膜厚分布が目標膜厚の土 1 5 %の範囲内で且つ ± 6 以内であるこ とを確認する。 Thereafter, the thickness of the wound solidified resin film 13 is good, and the film thickness is within a range that is the same as or slightly larger than the width of the metal plate 10 to be coated, or finally a width that can satisfy the product width. Confirm that the distribution is within the target soil thickness of 15% and within ± 6.
一方、 前記の金属板加熱工程と同一工程で、 既製樹脂フィルム巻戻し装置 2 7 から既製の樹脂フィルム 1 4を卷戻す。 On the other hand, in the same step as the metal plate heating step, the ready-made resin film 14 is rewound from the ready-made resin film rewinding device 27.
前記したように、 固化樹脂フィルム 1 3の膜厚分布が目標膜厚の ± 1 5 %、 か つ、 目標膜厚の土 6 m以内にあることを確認した後、 一定の表面温度を有した 上 (表) ラミネートロール 2 5を図示しているように矢印方向に下げ、 下 (裏) ラミネートロール 3 1を矢印方向に上げることによって、 固化樹脂フィルム 1 3、 既製榭脂フィルム 1 4を、 前述した樹脂フィルムの融着温度 〜T , + 1 5 0 に加熱された金属板 1 0の両面に圧着するとほぼ同期的に、 直ちに、 固化樹脂 フィルム巻取装置 2 4と上 (表) ラミネートロール 2 5間で樹脂フィルム 1 3を、 できるだけ上 (表) ラミネートロール 2 5に近い前述した適切な位置で切断する とほぼ同時にピンチロール 3 4と 3 5及びピンチロール 3 6と 3 7をフィルムを 介して圧着し、 固化樹脂フィルム巻取り装置 2 4による巻取りを停止する。 なお、 ラミネートロール 3 1の後に設置してある既製樹脂フィルム圧着支持ロール 3 0 及び 3 2はラミネート前の既製樹脂フィルムを圧着支持する装置であり、 該既製 樹脂フィルムがラミネートロールにより圧着される時とほぼ同期的に、 圧着支持 ロール 3 0及び 3 2は開放する機能を有すものであり具備されていることが好ま しいが、 状況によっては必ずしも必要でない。 As described above, after confirming that the thickness distribution of the solidified resin film 13 was within ± 15% of the target film thickness and within 6 m of the target film thickness, the solidified resin film 13 had a constant surface temperature. The upper (front) laminating roll 25 is lowered in the direction of the arrow as shown, and the lower (back) laminating roll 31 is raised in the direction of the arrow, so that the solidified resin film 13 and the ready-made resin film 14 are removed. The above-mentioned resin film fusing temperature ~ T, +15 When pressed against both surfaces of the metal plate 10 heated to +150, almost immediately, immediately, the solidified resin film winding device 24 and the upper (table) laminating roll Cut the resin film 13 between 25 as much as possible (Table). At the same time, cut the pinch rolls 34 and 35 and pinch rolls 36 and 3 Pressed through, solidified resin film winding Ri stops the winding by the apparatus 2 4. The ready-made resin film pressure supporting rolls 30 and 32 installed after the laminating roll 31 are devices for pressing and supporting the ready-made resin film before lamination, and are used when the ready-made resin film is pressed by the laminating roll. Almost synchronously, the pressure support rolls 30 and 32 have a function of opening and are preferably provided, but are not necessarily required depending on the situation.
さらに、 固化樹脂フィルム 1 3、 既製榭脂フィルム 1 4を同時にしかも連続的 にラミネートされた金属板を冷却装置 3 3及び 1 6によって冷却して樹脂被覆金 厲板 1 5を樹脂被覆金属板巻き取り装置で巻き取り製造する設備を具備するもの である。 Further, the metal plates on which the solidified resin film 13 and the already-prepared resin film 14 are simultaneously and continuously laminated are cooled by the cooling devices 33 and 16 so that the resin-coated metal plate 15 is wound around the resin-coated metal plate. It is equipped with equipment for winding and manufacturing with a take-up device.
このように、 Tダイ 1 8から押し出した固化樹脂フィルム 1 3のフィルム厚み 1 - が安定するまで固化樹脂フィルム金属板 1 0に圧着せず、 固化樹脂フィルム 1 3 のフィルム厚みが目的とする厚みに安定してなったことを確認後、 初めて、 ラミ ネ—トロール 2 5、 3 1に加熱された金属板 1 0の表面に榭脂フィルム 1 3をラ ミネートするようにしたので、 目的とする厚みでない固化榭脂フィルム 1 3を ラミネートし、 不良製品の発生をすることを防止でき、 樹脂被覆金属板 1 5の歩 留りを高めることができる。 また、 目的とする厚みになるまでに Tダイ 1 8から 押し出された固化樹脂フィルム 1 3は、 未だ金属板には被覆されていない状態に あるので再溶融することによってリサイクルでき、 結果的には製膜に関わる榭脂 の損失をほとんど無くすことが出来る。 Thus, the film thickness of the solidified resin film 13 extruded from the T die 18 After confirming that the film thickness of the solidified resin film 13 has become stable to the target thickness without pressing the solidified resin film metal plate 10 until 1-is stabilized, the laminator roll 25 Since the resin film 13 is laminated on the surface of the metal plate 10 heated to 31 and 31, the solidified resin film 13 which is not of the desired thickness is laminated to generate defective products. Can be prevented, and the yield of the resin-coated metal plate 15 can be increased. In addition, the solidified resin film 13 extruded from the T die 18 until the target thickness is reached is not yet coated on the metal plate, so that it can be recycled by re-melting, and as a result, Almost no loss of resin associated with film formation.
図 2に、 上記した樹脂被覆金厲板の製造方法に好適に用いることができる一軸 延伸装置の構成の一実施例を示しており、 図示するように、 一軸延伸装置は、 固 化樹脂フィルムを適性な延伸温度にする予熱部、 予熱された固化樹脂フィルムを ロールの周速差により一軸延伸する延伸部、 延伸された固化樹脂フィルムの歪み を取り除くためのァニール部の大きくは三部分に分けられる。 詳細にはこの一軸 延伸装置の予熱部で固化樹脂フィルム 1 3をガラス転移温度 T g〜T g + 7 o の温度とし、 通常は延伸部で延伸前の元長の 1 . 5〜6倍の長さになるまで一軸 延伸する。 その後必要によりァニール部で通常は延伸温度以上の温度で且つ該固 化樹脂フィルム外観が正常に保たれる温度範囲内で熱固定する。 なお、 一軸延伸 倍率については固化樹脂フィルムの構成樹脂組成により、 延伸可能な倍率及び膜 厚分布と表面外観をも含んだ特性を良好に発揮できる倍率を勘案して決定する。 本発明に係る樹脂被覆金属板の製造方法においては、 以下の変形例が考えられ る。 FIG. 2 shows an embodiment of the configuration of a uniaxial stretching apparatus that can be suitably used in the above-described method of manufacturing a resin-coated metal sheet. As shown in the figure, the uniaxial stretching apparatus The preheating section for setting an appropriate stretching temperature, the stretching section for uniaxially stretching the preheated solidified resin film depending on the peripheral speed of the roll, and the annealing section for removing the distortion of the stretched solidified resin film are roughly divided into three parts. . In detail, the solidified resin film 13 is set to a glass transition temperature Tg to Tg + 7o in the preheating section of the uniaxial stretching apparatus, and usually 1.5 to 6 times the original length before stretching in the stretching section. Uniaxially stretch to length. Thereafter, if necessary, the film is heat-set at the annealing portion at a temperature usually higher than the stretching temperature and within a temperature range in which the appearance of the solidified resin film can be normally maintained. In addition, the uniaxial stretching ratio is determined in consideration of the stretching ratio and the ratio capable of favorably exhibiting the properties including the film thickness distribution and the surface appearance depending on the constituent resin composition of the solidified resin film. In the method for producing a resin-coated metal plate according to the present invention, the following modifications are conceivable.
①フィルム形成冷却ロールの回転速度、 及び、 延伸倍率を測定し、 手動又は自 動にてラミネート速度を制御する。 (1) Measure the rotation speed and stretching ratio of the film formation cooling roll, and control the lamination speed manually or automatically.
②一軸延伸装置を用いない未延伸の場合は、 巻取り前のラミネート速度を V I 〜 1 . 2 X V , とする。 (2) In the case of non-stretching without using a uniaxial stretching device, the laminating speed before winding is assumed to be VI to 1.2 XV.
③ー軸延伸の場合はラミネート速度を、 V , X延伸倍率 (K) 〜1 . 2 X V , X Kとする。 (3) In the case of axial stretching, the laminating speed is V, X stretching ratio (K) to 1.2 XV, XK.
④被覆前の固化樹脂フィルム 1 3をトリミングして、 目的とする厚み分布に調 整しラミネートする金属板 1 0の幅の 1 0 0 %〜1 2 0 %の範囲の幅のフィルム にする。 この際、 各端のトリミング幅がラミネートする金属板幅の 1 5 %以内で あり、 かつ、 1 5 c m以下とすることが好ましい。 固 Trim the solidified resin film 13 before coating to adjust it to the desired thickness distribution. A film having a width in the range of 100% to 120% of the width of the metal plate 10 to be laid and laminated. At this time, it is preferable that the trimming width at each end is within 15% of the width of the metal plate to be laminated, and 15 cm or less.
⑤被覆前の固化樹脂フィルム 1 3をトリミングすることなしに、 被覆する金属 板 1 0よりも幅広の樹脂フィルム 1 3を、 膜厚分布の良好な部分が金属板 1 0に ラミネートされるようにラミネートし、 ラミネート後に樹脂フィルム 1 3をトリ ミングする。 この際、 目標膜厚土の 1 5 %の膜厚範囲内で且つ ± 6 m以内であ る部分を金属板 1 0にラミネートする。 樹脂 Without trimming the solidified resin film 13 before coating, a resin film 13 wider than the metal plate 10 to be coated is laminated on the metal plate 10 with a good film thickness distribution. Laminate and trim the resin film 13 after lamination. At this time, the portion within the thickness range of 15% of the target thickness soil and within ± 6 m is laminated on the metal plate 10.
⑥好ましくは、 金属板 1 0にラミネート直前の固化樹脂フィルム 1 3の目的と する膜厚分布を有す幅は、 フィルムトリミングしない場合は、 金属板 1 0の幅の ⑥ Preferably, the width of the solidified resin film 13 immediately before lamination on the metal plate 10 having the target film thickness distribution is equal to the width of the metal plate 10 if film trimming is not performed.
1 0 0 %〜 1 3 0 %の範囲とする。 The range is 100% to 130%.
⑦固化樹脂フィルム 1 3のトリミングを金属板 1 0にラミネート後行う。 ト リ Trimming of the solidified resin film 13 is performed after lamination on the metal plate 10.
なお、 本発明に用いられる樹脂の種類は、 押し出し製膜できて金属板に熱融着 可能であれば、 一軸延伸する場合を除き特に制限されるものでなく、 要求特性に 応じて選択されるべきである。 また、 一軸延伸する場合も二軸延伸する場合に比 し延伸倍率を勘案すれば大幅に適用可能な樹脂組成は広くあまり制限される樹脂 の種類は少ない。 本発明に用いることが出来る樹脂被膜構成の例としては、 The type of resin used in the present invention is not particularly limited, except for uniaxial stretching, as long as it can be extruded into a film and can be thermally fused to a metal plate, and is selected according to required characteristics. Should. In addition, when the stretching ratio is taken into consideration in the case of uniaxial stretching and in the case of biaxial stretching, the resin composition which can be widely applied is broadly limited, and there are few types of resins. Examples of the resin film configuration that can be used in the present invention include:
①低密度ポリエチレン榭脂、 (1) Low density polyethylene resin,
②マレイン酸変性ポリプロピレン等の変性ォレフィン樹脂、 ②Modified olefin resin such as maleic acid-modified polypropylene,
③ポリエチレンテレフタレ一ト榭脂あるいはポリエチレンテレフ夕レート/イソ フタレート共重合樹脂とポリカーボネート榭脂のブレンド樹脂、 ③ Polyethylene terephthalate resin or blend resin of polyethylene terephthalate / isophthalate copolymer resin and polycarbonate resin,
④ポリエチレンテレフ夕レート樹脂あるいはポリエチレンテレフ夕レート Zイソ フタレート共重合樹脂とポリ 4メチルー 1ペンテン樹脂とのブレンド樹脂、 ブ レ ン ド Blend resin of polyethylene terephthalate resin or polyethylene terephthalate Z isophthalate copolymer resin and poly 4-methyl-1 pentene resin,
⑤前記③又は④に、 さらにポリブチレンテレフ夕レート榭脂をブレンドした樹脂、 ⑥押し出し機二台とマルチマ二ホールドダイス等のダイスを用いて、 前記①又は④ In addition to the above ③ or 、, use polybutylene terephthalate resin 樹脂 resin blended resin ⑥ ⑥ Use two extruders and dies such as multi-manifold dies
②の上層にポリプロピレン樹脂を積層した二層被膜構成の複層樹脂、 ⑦押し出し機二台とマルチマ二ホールドダイ等のダイを用いて前記③, ④又は⑤ の上層にさらにポリエチレンテレフ夕レート樹脂あるいはポリエチレンテレフ 夕レート/イソフタレート共重合樹脂を積層した二層被膜構成の複層榭脂、 ⑧押し出し機三台とマルチマ二ホールドダイ等のダイを用いて、 強固な密着性を 得ることを目的に、 前記⑦の最下層に、 前記③, ④又は⑤のブレンド樹脂組成 力 ^ら、 金属板との密着性を低下させる傾向を有すポリカーボネート樹脂あるい はポリ 4メチル— 1ペンテン樹脂を除く力 その添加量が少ない樹脂を積層し た三層被膜構成の複層樹脂等が挙げられる。 (2) Multi-layer resin composed of two layers of polypropylene resin laminated on the upper layer. (2) Polyethylene terephthalate resin or ③, ホ ー ル ド or ⑤ is further added to the upper layer of A multi-layer resin consisting of a two-layer film composed of a laminated polyethylene terephthalate / isophthalate copolymer resin, 三 Using the three extruders and a die such as a multi-manifold die, in order to obtain strong adhesion, the lowermost layer of the above ①, the blended resin composition of the above ③, ④ or ⑤, metal, etc. Excludes polycarbonate resin or poly (4-methyl-1-pentene) resin having a tendency to lower the adhesion to the plate. Examples include a multilayer resin having a three-layer coating structure in which a resin having a small addition amount is laminated.
また、 樹脂被膜には単層あるいは複層の各々の層には必要に応じ顔料、 安定剤、 防鯖材等の添加剤が含入されていても良い。 In addition, the resin coating may contain additives such as pigments, stabilizers, and antibacterial materials, if necessary, in each of the single layer or the multiple layers.
一方、 金属板についても特に制限するものではないが、 本発明に使用する金属 板の例としては、 表面アルマイト処理、 脱脂酸洗等の表面清浄化処理、 表面エツ チング処理、 表面浸漬クロム酸処理や電解クロム酸処理を行ったアルミニューム 板、 あるいは無処理、 S n , N i , Z n等のめっき処理を行った後に浸漬クロム酸 処理や電解クロム酸処理を行った鋼板等が挙げられる。 On the other hand, although there is no particular limitation on the metal plate, examples of the metal plate used in the present invention include surface cleaning treatment such as surface alumite treatment, degreasing pickling, surface etching treatment, and surface immersion chromic acid treatment. And an aluminum plate which has been subjected to electrolytic chromic acid treatment, or a steel plate which has been subjected to plating treatment such as untreated, Sn, Ni, Zn, etc., and then subjected to immersion chromic acid treatment or electrolytic chromic acid treatment.
産業上の利用可能性 Industrial applicability
請求項 1〜 6記載の樹脂被覆金属板の製造方法においては、 Tダイから溶融樹 脂を押し出し、 フィルム形成冷却ロールにより製膜した固化榭脂フィルムの厚み が安定するまでは金属板に圧着せず、 固化樹脂フィルムの厚みが安定し、 目的と する膜厚範囲内になったことを確認した段階で、 初めて、 ラミネートロールによ つて金属板の表面に固化樹脂フィルムをラミネートするようにしたので、 目的と する厚みを満足しない固化樹脂フィルム 1 3をラミネートして不良製品を発生す ることを防止でき、 樹脂被覆金属板 1 5の歩留りを高めることができる。 また、 目的とする厚みになるまでに Tダイ 1 8から押し出された固化樹脂フィルム 1 3 は、 未だ金属板には被覆されていない状態にあるので再溶融することによってリ サイクルでき、 結果的には製膜に関わる榭脂の損失をほとんど無くすことが出来 る。 In the method for producing a resin-coated metal sheet according to claims 1 to 6, the molten resin is extruded from a T-die, and pressed on the metal sheet until the thickness of the solidified resin film formed by the film forming cooling roll is stabilized. First, when it was confirmed that the thickness of the solidified resin film was stable and within the target thickness range, the solidified resin film was first laminated on the surface of the metal plate using a laminating roll. However, it is possible to prevent the occurrence of defective products by laminating the solidified resin film 13 that does not satisfy the target thickness, and to increase the yield of the resin-coated metal plate 15. In addition, the solidified resin film 13 extruded from the T die 18 until the target thickness is reached is not yet coated on the metal plate, so that it can be recycled by re-melting, and as a result, Can almost eliminate the loss of resin related to film formation.
請求項 2記載の製造方法においては、 固化樹脂フィルム巻取装置とラミネート ロールとの間にフィルム切断装置を設け、 固化榭脂フィルムの金属板へのラミネ —ト時とほぼ同期的に、 前記固化樹脂フィルムを切断するようにしたので、 ラミ ネ一トロールで固化樹脂フィルムの圧着を加熱された金属板に、 切断したラミネ 3. The manufacturing method according to claim 2, wherein a film cutting device is provided between the solidified resin film take-up device and the laminating roll, and the solidification is performed substantially in synchronization with lamination of the resin film to the metal plate. Since the resin film was cut, the solidified resin film was pressed by a laminator roll onto a heated metal plate.
—卜する側と非ラミネート側の固化榭脂フィルムがロール及び装置や被覆した金 属板に付着しない適切な位置で容易に分離が可能となる。 — Rolls, equipment and coated gold on the solidified resin film Separation can be easily performed at an appropriate position that does not adhere to the metal plate.
請求項 3記載の製造方法においては、 特に固化樹脂フィルムの製膜と金属板の 片面へのラミネートを同一工程で、 しかも榭脂及び金属板の損失を極力少なくし て実施することが可能なため、 片面樹脂被覆被覆金属板を経済的に製造できる。 請求項 4記載の製造方法においては、 特に金属板の両面ラミネート用の固化榭 脂フィルムの製膜と金属板の両面へのラミネートを同一工程で、 しかも榭脂及び 金属板の損失を極力少なくして実施することが可能なため、 両面樹脂被覆金属板 を経済的に製造できる。 In the manufacturing method according to the third aspect, in particular, the formation of the solidified resin film and the lamination on one side of the metal plate can be performed in the same step, and the loss of the resin and the metal plate can be minimized. A single-side resin-coated metal plate can be economically manufactured. In the production method according to claim 4, in particular, the formation of a solidified resin film for double-sided lamination of the metal plate and the lamination on both surfaces of the metal plate are performed in the same step, and the loss of the resin and the metal plate is minimized. Therefore, a double-sided resin-coated metal plate can be manufactured economically.
請求項 5記載の製造方法においては、 金属板の片面にラミネートする固化樹脂 フィルムの組成が一定で、 他側面にラミネートするフィルムの樹脂組成を種々変 更する必要があり、 他側面仕様の頻繁な仕様変更による少ロット対応が要求され る両面樹脂被覆金属板を容易且つ結果的に経済的に製造できる。 In the manufacturing method according to claim 5, the composition of the solidified resin film to be laminated on one side of the metal plate is constant, and the resin composition of the film to be laminated on the other side needs to be variously changed. A double-sided resin-coated metal plate that requires small lot handling due to specification changes can be manufactured easily and consequently economically.
請求項 6記載の製造方法においては、 固化樹脂フィルムの製膜と金属板面への ラミネートを同一工程で、 しかも樹脂及び金属板の損失を極力少なくして実施す ることが可能なだけでなく、 該固化樹脂フィルムを同一工程でラミネート前に一 軸延伸するため、 未延伸の固化樹脂フィルムを金属板にラミネートするよりもよ りフィルム強度が高くなりフィルムテンションコントロールが容易となるため安 定被覆性がより向上するばカゝりか製膜速度も早くなるため生産性が向上しょり経 済性を有した樹脂被覆金属板を製造しやすくなる。 In the manufacturing method according to claim 6, it is possible not only to carry out the film formation of the solidified resin film and the lamination on the surface of the metal plate in the same process, but also to minimize the loss of the resin and the metal plate. Since the solidified resin film is uniaxially stretched before lamination in the same step, the film strength is higher than when an unstretched solidified resin film is laminated on a metal plate, and the film tension is easily controlled. If the productivity is further improved, the film formation speed is also increased, so that the productivity is improved and a resin-coated metal plate having economical efficiency is easily manufactured.
請求項?〜 1 2は各々前記請求項 1〜6の製造方法を実施可能とし、 前記した 効果を得るための装置である。 即ち、 請求項 7、 8、 9、 1 0、 1 1、 1 2はそ れぞれ請求項 1、 2、 3、 4、 5、 6の実施を可能とし、 その実施により前記し た効果を得るための製造装置である。 Claim? References 12 to 12 denote apparatuses for enabling the production method according to claims 1 to 6 to achieve the above-described effects. That is, claims 7, 8, 9, 10, 10, 11, and 12 enable the implementation of claims 1, 2, 3, 4, 5, and 6, respectively, and implement the above-described effects by implementing the claims. It is a manufacturing device for obtaining.
前述したように、 本発明の装置及び製造方法により従来技術では達成できない 高経済性を有した樹脂被覆金属板が得られ、 その適用効果は大である。 As described above, the apparatus and the manufacturing method of the present invention can provide a resin-coated metal plate having high economic efficiency which cannot be achieved by the conventional technology, and the application effect is great.
Claims
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AU57788/96A AU5778896A (en) | 1996-03-04 | 1996-05-23 | Method and device for manufacturing resin-coated metal plates |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8/70903 | 1996-03-04 | ||
| JP8070903A JP2971391B2 (en) | 1996-03-04 | 1996-03-04 | Method and apparatus for manufacturing resin-coated metal sheet |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO1997032715A1 true WO1997032715A1 (en) | 1997-09-12 |
Family
ID=13444962
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/JP1996/001369 Ceased WO1997032715A1 (en) | 1996-03-04 | 1996-05-23 | Method and device for manufacturing resin-coated metal plates |
Country Status (3)
| Country | Link |
|---|---|
| JP (1) | JP2971391B2 (en) |
| AU (1) | AU5778896A (en) |
| WO (1) | WO1997032715A1 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1998039160A1 (en) * | 1997-01-23 | 1998-09-11 | Hoogovens Staal B.V. | Method and apparatus for strip-coating a metallic strip-shaped substrate with a plastic band and strip thus obtained |
| CN105216428A (en) * | 2015-11-24 | 2016-01-06 | 苏州弘瀚自动化科技有限公司 | A kind of intelligence control system of liquid crystal display coat peeling unit |
| CN107053334A (en) * | 2017-05-17 | 2017-08-18 | 深圳市伟铂瑞信科技有限公司 | A kind of die-cutting apparatus of novel high polymer boundary material |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4154662B2 (en) * | 2002-02-01 | 2008-09-24 | 東洋紡績株式会社 | Method for producing resin-coated metal sheet |
| RU2715661C2 (en) * | 2014-10-17 | 2020-03-02 | Тетра Лаваль Холдингз Энд Файнэнс С.А. | Method of producing laminated packaging material |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5073964A (en) * | 1973-11-01 | 1975-06-18 | ||
| JPH04294142A (en) * | 1991-03-25 | 1992-10-19 | Nippon Steel Corp | Manufacture of double-sides resin-coated steel plate |
| JPH06305024A (en) * | 1993-04-23 | 1994-11-01 | Toyo Kohan Co Ltd | Manufacture of resin-coated metal plate |
-
1996
- 1996-03-04 JP JP8070903A patent/JP2971391B2/en not_active Expired - Fee Related
- 1996-05-23 WO PCT/JP1996/001369 patent/WO1997032715A1/en not_active Ceased
- 1996-05-23 AU AU57788/96A patent/AU5778896A/en not_active Abandoned
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5073964A (en) * | 1973-11-01 | 1975-06-18 | ||
| JPH04294142A (en) * | 1991-03-25 | 1992-10-19 | Nippon Steel Corp | Manufacture of double-sides resin-coated steel plate |
| JPH06305024A (en) * | 1993-04-23 | 1994-11-01 | Toyo Kohan Co Ltd | Manufacture of resin-coated metal plate |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1998039160A1 (en) * | 1997-01-23 | 1998-09-11 | Hoogovens Staal B.V. | Method and apparatus for strip-coating a metallic strip-shaped substrate with a plastic band and strip thus obtained |
| US6758933B2 (en) | 1997-01-23 | 2004-07-06 | Corus Staal Bv | Method and apparatus for strip-coating a metallic strip-shaped substrate with a plastic band and strip thus obtained |
| CN105216428A (en) * | 2015-11-24 | 2016-01-06 | 苏州弘瀚自动化科技有限公司 | A kind of intelligence control system of liquid crystal display coat peeling unit |
| CN107053334A (en) * | 2017-05-17 | 2017-08-18 | 深圳市伟铂瑞信科技有限公司 | A kind of die-cutting apparatus of novel high polymer boundary material |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH10309775A (en) | 1998-11-24 |
| AU5778896A (en) | 1997-09-22 |
| JP2971391B2 (en) | 1999-11-02 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR101133970B1 (en) | Process for producing multilayered unstretched film, process for producing multilayered-resin-coated metal sheet, and apparatus for producing multilayered unstretched film | |
| JP3711815B2 (en) | Extruded laminate manufacturing method | |
| JP3931958B2 (en) | Laminate manufacturing method and manufacturing apparatus | |
| RU2396167C1 (en) | Method and installation for manufacturing of metal sheet with coating of organic resin | |
| JP2971391B2 (en) | Method and apparatus for manufacturing resin-coated metal sheet | |
| CA2235903A1 (en) | Method and device for plastic lamination of metal strip by means of direct extrusion | |
| JP3470527B2 (en) | Manufacturing method of resin metal laminate | |
| EP1019248B1 (en) | Method and apparatus for strip-coating a metallic strip-shaped substrate with a plastic band | |
| CN117245878A (en) | Composite film machine for multilayer co-extrusion film coating on substrate | |
| CN114514106B (en) | Method for producing sealable biaxially oriented polyester-based films and film stretching device | |
| JP3941576B2 (en) | Manufacturing method and manufacturing apparatus for resin film laminated metal plate | |
| JP3891031B2 (en) | Manufacturing method and manufacturing apparatus for resin film laminated metal plate | |
| JP3470526B2 (en) | Production method of double-sided resin-coated metal laminate | |
| JP3941577B2 (en) | Manufacturing method and manufacturing apparatus for resin film laminated metal plate | |
| JP3809399B2 (en) | Manufacturing method of organic resin-coated metal plate and manufacturing apparatus of organic resin-coated metal plate | |
| JPH11100006A (en) | Roll for extrusion laminate | |
| WO2006048956A1 (en) | Process for producing nonstretched film, process for producing resin-coated metal sheet, and apparatus for producing nonstretched film | |
| JP2005349787A (en) | Manufacturing method of resin-coated metal plate with excellent resin adhesion | |
| JP2001322152A (en) | Method and apparatus for laminating molten resin | |
| JP4756979B2 (en) | Manufacturing method of organic resin-coated metal plate and manufacturing apparatus of organic resin-coated metal plate | |
| WO2006013633A1 (en) | Multilayer resin film, resin-coated metal plate, multilayer resin film producing method, and resin-coated metal plate producing method | |
| JPH03158235A (en) | Manufacture of laminated metal sheet | |
| JP3060249B2 (en) | Manufacturing method of laminated metal sheet | |
| JP3057333B2 (en) | Manufacturing method of laminated metal sheet | |
| RU2632493C1 (en) | Production method of multilayer material by application of polymer coating by extrusion at calendering |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| AK | Designated states |
Kind code of ref document: A1 Designated state(s): AU BR CA CN KR MX NO NZ PL SG TR US VN |
|
| AL | Designated countries for regional patents |
Kind code of ref document: A1 Designated state(s): AT BE CH DE DK ES FI FR GB GR IE IT LU MC NL PT SE |
|
| DFPE | Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101) | ||
| 121 | Ep: the epo has been informed by wipo that ep was designated in this application | ||
| 122 | Ep: pct application non-entry in european phase | ||
| NENP | Non-entry into the national phase |
Ref country code: CA |