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WO1997001962A1 - Sirops pour gomme a macher contenant du sorbitol, un plastifiant et un anticristallisant - Google Patents

Sirops pour gomme a macher contenant du sorbitol, un plastifiant et un anticristallisant Download PDF

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Publication number
WO1997001962A1
WO1997001962A1 PCT/US1995/008392 US9508392W WO9701962A1 WO 1997001962 A1 WO1997001962 A1 WO 1997001962A1 US 9508392 W US9508392 W US 9508392W WO 9701962 A1 WO9701962 A1 WO 9701962A1
Authority
WO
WIPO (PCT)
Prior art keywords
sorbitol
syrup
agent
chewing gum
mixtures
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US1995/008392
Other languages
English (en)
Inventor
Pamela M. Mazurek
Michael A. Reed
Victor V. Gudas
Albert H. Chapdelaine
Robert J. Yatka
Lindell C. Richey
Marc A. Meyers
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
WM Wrigley Jr Co
Original Assignee
WM Wrigley Jr Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by WM Wrigley Jr Co filed Critical WM Wrigley Jr Co
Priority to AU29159/95A priority Critical patent/AU2915995A/en
Priority to MX9800202A priority patent/MX9800202A/es
Priority to EP95924776.8A priority patent/EP0836389B2/fr
Priority to DE69532593.0T priority patent/DE69532593T3/de
Priority to BR9510621A priority patent/BR9510621A/pt
Publication of WO1997001962A1 publication Critical patent/WO1997001962A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G4/00—Chewing gum
    • A23G4/06—Chewing gum characterised by the composition containing organic or inorganic compounds
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G3/00—Sweetmeats; Confectionery; Marzipan; Coated or filled products
    • A23G3/34—Sweetmeats, confectionery or marzipan; Processes for the preparation thereof
    • A23G3/346—Finished or semi-finished products in the form of powders, paste or liquids
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G4/00—Chewing gum
    • A23G4/02—Apparatus specially adapted for manufacture or treatment of chewing gum
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G4/00—Chewing gum
    • A23G4/06—Chewing gum characterised by the composition containing organic or inorganic compounds
    • A23G4/10—Chewing gum characterised by the composition containing organic or inorganic compounds characterised by the carbohydrates used, e.g. polysaccharides
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G4/00—Chewing gum
    • A23G4/06—Chewing gum characterised by the composition containing organic or inorganic compounds
    • A23G4/12—Chewing gum characterised by the composition containing organic or inorganic compounds containing microorganisms or enzymes; containing paramedical or dietetical agents, e.g. vitamins
    • A23G4/126—Chewing gum characterised by the composition containing organic or inorganic compounds containing microorganisms or enzymes; containing paramedical or dietetical agents, e.g. vitamins containing vitamins, antibiotics
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G4/00—Chewing gum
    • A23G4/18—Chewing gum characterised by shape, structure or physical form, e.g. aerated products
    • A23G4/20—Composite products, e.g. centre-filled, multi-layer, laminated
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23L—FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
    • A23L2/00—Non-alcoholic beverages; Dry compositions or concentrates therefor; Preparation or treatment thereof
    • A23L2/52—Adding ingredients
    • A23L2/60—Sweeteners
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23L—FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
    • A23L27/00—Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
    • A23L27/30—Artificial sweetening agents
    • A23L27/33—Artificial sweetening agents containing sugars or derivatives
    • A23L27/34—Sugar alcohols
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G2200/00—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF containing organic compounds, e.g. synthetic flavouring agents
    • A23G2200/06—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF containing organic compounds, e.g. synthetic flavouring agents containing beet sugar or cane sugar if specifically mentioned or containing other carbohydrates, e.g. starches, gums, alcohol sugar, polysaccharides, dextrin or containing high or low amount of carbohydrate

Definitions

  • the present invention relates generally to chewing gums. More specifically, the present invention relates to chewing gums including sorbitol.
  • alditols such as sorbitol, mannitol, and xylitol
  • Alditols can be used in chewing gum, as well as other confectioneries and food products, as a "sugar substitute.” These sugar substitutes have the advantage that they are not fermented in the mouth of the consumer to form products that can attack dental enamel. Therefore, sorbitol, as well as other alditols, is used in sugarless products. Additionally, sorbitol can be used as a bulking agent.
  • Patent No. 3,857,965 discloses a chewing gum composition made from melting crystalline sorbitol and mixing the melted sorbitol with gum base and a crystallization retardant.
  • U.S. Patent No. 4,156,740 to Glass et al. U.S. Patent No. 4,250,196 to Friello, U.S. Patent No.
  • U.S. Patent No. 4,466,983 to Cifrese et al. disclose liquid compositions containing sorbitol used as a centerfill for chewing gum.
  • U.S. Patent No. 5,120,551 to Yatka et al. discloses a syrup containing sorbitol and other alditols used in chewing gum compositions.
  • a syrup for use in chewing gum which is made by mixing glycerin or propylene glycol with an aqueous hydrogenated starch hydrolysate (HSH) such as Lycasin brand HSH from Roquette, including U.S. Patent Nos. 4,671,961; 4,671,967 and 4,728,515 to Patel et al. , each of which are hereby incorporated by reference. It is believed that Lycasin brand HSH contains, on a dry basis, about 6% sorbitol, about 52% maltitol and about 42% of oligosaccharides having a degree of polymerization (“DP") of 3 or greater.
  • HSH hydrogenated starch hydrolysate
  • Sorbitol can be provided in chewing gum in its crystalline form. It is believed that crystalline sorbitol currently accounts for approximately 50% of typical sugar-free chewing gum formulations.
  • crystalline sorbitol is costly. Although it would be desirable to have a replacement for crystalline sorbitol, heretofore, such possible replacements were not as effective, created product stability problems, created processability issues, were even more expensive than crystalline sorbitol, and/or could not be used with certain formulations.
  • aqueous sorbitol has been explored for use in chewing gum. Sorbitol in an aqueous solution is a less expensive alternative, on a dry basis, than crystalline sorbitol. Unfortunately, the use of aqueous sorbitol in chewing gum at levels above 15% can create problems with respect to product stability. Likewise, the use of aqueous sorbitol at levels above 15% can also create processability problems. This is due, it is believed, to the water content contained in the aqueous sorbitol.
  • the present invention provides an improved chewing gum composition. More specifically, the present invention provides a chewing gum composition that includes an aqueous syrup containing sorbitol, a plasticizing agent and an anticrystallization agent. Additionally, the present invention also provides other products such as food stuffs, beverages, medicaments, and confectioneries that include the aqueous sorbitol syrup. Pursuant to the present invention, the sorbitol syrup can be used in formulations that contain levels of liquid sorbitol solution that were heretofore not possible.
  • the invention is a method of making a chewing gum composition
  • a method of making a chewing gum composition comprising the steps of making a syrup by evaporating water from a mixture comprising an aqueous sorbitol solution containing at least 50% sorbitol; a plasticizing agent selected from glycerin, propylene glycol and mixtures thereof; and an anticrystallization agent selected from alditols other than sorbitol and having a degree of polymerization (DP) of 1 or 2; and mixing the syrup with gum base and additional chewing gum ingredients to produce the chewing gum composition.
  • DP degree of polymerization
  • the invention is a chewing gum composition
  • a chewing gum composition comprising a homogeneous mixture of gum base and a bulking agent wherein the bulking agent comprises an aqueous alditol syrup in which over 50% of the aditols have a DP of 1 and wherein the composition has less than 2% moisture and the syrup comprises over 35% of the composition.
  • the invention is an aqueous syrup for use in chewing gum comprising, on a dry basis, about 50% to about 85% alditols and about 15% to about 50% plasticizing agent selected from glycerin, propylene glycol and mixtures thereof.
  • a degree of polymerization DP
  • Any alditols present in the syrup with a DP of 3 or greater are present at a ratio to the alditols other than sorbitol with a DP of 1 or 2 of less than 2:3.
  • the invention is an aqueous syrup for use in chewing gum comprising, on a dry basis, about 30% to about 80% sorbitol; about 15% to about 56% plasticizing agent selected from glycerin, propylene glycol and mixtures thereof; and about 3% to abut 30% anticrystallization agent comprising alditols other than sorbitol with a DP of 1 or 2, wherein any alditols present with a DP of 3 or greater are present at a ratio to said alditols other than sorbitol with a DP of 1 or 2 of less than 2:3.
  • the invention is a method of making a syrup for use in chewing gum comprising the steps of providing sorbitol in an aqueous solution having a solids content of at least about 50% sorbitol and about 30% to about 50% water; mixing the sorbitol solution with a plasticizing agent selected from glycerin, propylene glycol and mixtures thereof and an anticrystallization agent comprising alditols other than sorbitol with a DP of 1 or 2, wherein any alditols present with a DP of 3 or greater are present at a ratio to the alditols other than sorbitol with a DP of 1 or 2 of less than 2:3; and removing moisture from the mixture to produce a syrup having a moisture content of less than about 10%.
  • a plasticizing agent selected from glycerin, propylene glycol and mixtures thereof and an anticrystallization agent comprising alditols other than sorbitol with a DP of
  • the invention is a method of making a syrup for use in chewing gum comprising the steps of providing sorbitol in an aqueous solution having a solids content of at least about 60% sorbitol; mixing the sorbitol solution with a plasticizing agent and an anticrystallization agent to form a mixture having, on a dry basis, a ratio of sorbitol:plasticizing agent of between about 6:1 and about 1:2 and a ratio of sorbitol:anticrystallization agent of between about 12:1 and about 3:2; and removing moisture from the mixture to produce a syrup having a moisture content of less than about 3%.
  • An advantage of the present invention is that it provides an improved chewing gum formulation, particularly an improved sugarless chewing gum, and improved methods for making chewing gum. Further, an advantage of some embodiments of the invention is an improved method for adding sorbitol to chewing gum in a state other than a crystalline state.
  • an advantage of some embodiments of the invention is a more cost effective method of adding sorbitol to a chewing gum composition.
  • Another advantage of the preferred embodiment of the invention is that it allows greater levels of sorbitol to be added to the chewing gum in a non-crystalline form than heretofore practical from a commercial standpoint.
  • the present invention provides an improved chewing gum formulation and method of making chewing gum.
  • Pursuant to the present invention sorbitol is provided in a non-crystalline state at levels that the inventors believe were not heretofore commercially possible utilizing liquid sorbitol in chewing gum formulations.
  • Sorbitol is a sugarless sweetener that is added to a variety of products. These products include food stuffs, beverages, medicaments, confectioneries and chewing gum. Sorbitol can be added either alone, without other sugarless sweeteners, for example, in sugar-free chewing gum, or in combination with sugar sweeteners. Additionally, the sorbitol can be provided in, for example, the chewing gum entirely in the syrup form of the present invention or along with a crystalline form of sorbitol. Pursuant to the present invention, the sorbitol is added to other components of a chewing gum formulation, as a blend of aqueous sorbitol, a plasticizing agent, and an anticrystallization agent.
  • the blend of aqueous sorbitol is provided as a syrup. This blend can be used to reduce the usage of crystalline sorbitol in standard product formulations. It has been found that the resultant product, including the sorbitol composition of the present invention, exhibits increased binding capacity over currently used binders in sugarfree gum.
  • the syrup of the present invention comprises, on a dry basis, about 30% to about 80% sorbitol, about 15% to about 56% of a plasticizing agent, and about 3% to about 30% of an anticrystallization agent. More preferably, the syrup comprises, on a dry basis, about 40% to about 70% sorbitol, about 20% to about 40% plasticizing agent and about 5% to about 20% anticrystallization agent. For some purposes, the syrup will comprises about 60% to about 80% sorbitol, about 15% to about 37% plasticizing agent and about 3% to about 25% anticrystallization agent. A presently preferred syrup contains about 56% sorbitol, about 38% plasticizing agent and about 6% anticrystallization agent.
  • Sorbitol for use in the inventive syrup will be provided in the form of an aqueous solution.
  • the aqueous sorbitol solution will preferably contain at least 50% sorbitol, more preferably about 60% sorbitol, and most preferably about 70% sorbitol. Preferably the remainder of the solution is water.
  • a commonly available sorbitol solution is Neosorb 70/02 from Roquette Corporation, which contains 70% sorbitol and about 30% water.
  • the plasticizing agent of the syrup of the present invention is selected from glycerin, propylene glycol and mixtures thereof. While the plasticizing agent may help prevent crystallization, its main function is to keep the syrup, with high solids level, fluid at room temperature.
  • the ratio of sorbitol to plasticizing agent in the syrup will preferably be between about 6:1 and about 1:2, more preferably between about 4:1 and about 1:1, and most preferably between about 2:1 and about 5:4.
  • the anticrystallization agent prevents the sorbitol from crystallizing as high solids levels are reached while evaporating water from the syrup. Because the syrup is preferably used in sugarless formulations, the anticrystallization agent is preferably an alditol other than sorbitol. (Sorbitol cannot be used because the sorbitol would not prevent crystallization of the sorbitol in the sorbitol solution.) The alditol should have a degree of polymerization (DP) of l or 2, because alditols with a DP of 3 or greater cause an increased viscosity in the syrup as it is evaporated.
  • DP degree of polymerization
  • Preferable anticrystallization agents are believed to include maltitol, mannitol, lactitol, hydrogenated isomaltulose, xylitol, erythritol and mixtures thereof. Of this group, maltitol and mannitol are presently preferred, with maltitol and a blend of maltitol and mannitol being most preferred.
  • the ratio of sorbitol to anticrystallization agent in the syrup will preferably be between about 12:1 and about 3:2, more preferably between about 10:1 and about 3:1, most preferably between about 9:1 and about 6:1.
  • Preferably over 50% of the combined alditols in the syrup will have a DP of 1, and most preferably the sorbitol comprises over 60% of the alditols.
  • the syrup will preferably comprise about 50-85% alditols, of which about 60% to about 92% will be sorbitol and about 8% to about 40% will be alditols other than sorbitol with a DP of 1 or 2.
  • the ratio of any alditols with a DP of 3 or greater to the alditols other than sorbitol and having a DP of 1 or 2 will preferably be less than 2:3, more preferably less than 1:2, and most preferably less than 1:3.
  • the ratio of sorbitol to alditols other than sorbitol having a DP of 1 or 2 will preferably be between about 10:1 and about 2:1.
  • the alditols will have a DP of 3 or greater.
  • the syrup will consist essentially of sorbitol, a plasticizing agent selected from glycerin, propylene glycol and mixtures thereof, and an anticrystallization agent selected from maltitol, mannitol and mixtures thereof.
  • the syrup preferably includes, on a dry weight basis, about 55% to about 80% sorbitol, about 17% to about 40% glycerin and about 3% to about 10% maltitol.
  • the syrup preferably includes, on a dry weight basis, approximately 40% to about 70% sorbitol, approximately 24% to about 56% glycerin and approximately 4% to about 9% mannitol.
  • the syrup includes, on a dry weight basis, approximately 47% to about 65% sorbitol; approximately 28% to about 45% glycerin, and appoximately 5% to about 7% mannitol.
  • the syrup Prior to any evaporation of the syrup, the syrup will generally contain approximately 20% water. In some products, the syrup can be used in this form. However, it is envisioned that at least some of the water will be driven off through evaporation or other means.
  • aqueous sorbitol, a plasticizing agent and an anticrystallization agent are mixed together and then coevaporated to create a syrup.
  • the aqueous sorbitol, plasticizer agent and anticrystallization agent combination is evaporated so that it contains not more than 10% water. More preferably, the aqueous sorbitol, plasticizing agent and anticrystallization agent mixture is evaporated so that it contains no more than 7% water, even more preferably about 0.5% to about 5% water, and most preferably about
  • the syrup blend is made by hydrolyzing sucrose to dextrose and fructose.
  • the dextrose and fructose are then hydrogenated to sorbitol and mannitol.
  • the result will be a syrup containing sorbitol and mannitol.
  • Glycerin can be added and the whole mixture can be coevaporated to drive off the water.
  • the aqueous sorbitol, plasticizing agent and anticrystallization agent can be provided in different combinations and ratios.
  • the syrup will be made from a mixture of about 52% to about 87% aqueous sorbitol solution, about 10% to about 45% plasticizing agent and about 3% to about 20% anticrystallization agent. More preferably, the syrup will be made from a mixture of about 60% to about 75% sorbitol solution, about 20% to about 35% plasticizing agent and about 4% to about 10% anticrystallization agent.
  • the anticrystallization agent comprises maltitol
  • a presently preferred syrup is made with about 65% sorbitol solution (70% solids) , about 30% glycerin and either about 5% maltitol or about 2.5% each of maltitol and mannitol.
  • mannitol preferably prior to evaporation the aqueous sorbitol comprises approximately 55% to about 75% by weight of the combination, mannitol comprises approximately 3% to about 7% by weight of the combination, and glycerin comprises approximately 25% to about 45% by weight of the combination.
  • the aqueous sorbitol prior to evaporation the aqueous sorbitol comprises approximately 60% to 70% by weight of the combination, mannitol comprises approximately 5% to 6% by weight of the combination and glycerin comprises approximately 25% to 35% by weight of the combination. In an embodiment that has been found to function satisfactorily, prior to evaporation the aqueous sorbitol comprises approximately 65% of the combination, glycerin approximately 30% and mannitol approximately 5%. This syrup will include, on a dry weight basis, 56.5% sorbitol, 37.3% glycerin, and 6.2% mannitol. The aqueous sorbitol syrup of the present invention will most frequently be the only syrup needed in the chewing gum formulation.
  • aqueous syrups or solutions may be desired.
  • HSH coevaporated glycerin and Lycasin brand HSH disclosed in U.S. Patent No. 4,671,961.
  • Lycasin brand HSH has a high level of oligosaccharides with a DP of 3 or greater, it will not be as easy to evaporate the combined syrup to as low of a moisture level as the preferred sorbitol syrup.
  • the aqueous sorbitol syrup can be used to create sugarless chewing gums, because sugarless chewing gum typically contains sorbitol.
  • the present invention can be used to create any chewing gum that includes sorbitol.
  • aqueous sorbitol syrup can be used in any product that uses sorbitol. Such products include confectioneries, medicaments, beverages and food products.
  • Chewing gum generally consists of a water insoluble gum base, a water soluble portion, and flavors.
  • the water soluble portion dissipates with a portion of the flavor over a period of time during chewing.
  • the gum base portion is retained in the mouth throughout the chew.
  • the insoluble gum base generally comprises elastomers, resins, fats and oils, softeners, and inorganic fillers.
  • the gum base may or may not include wax.
  • the insoluble gum base can constitute approximately 5 to about 95 percent, by weight, of the chewing gum. More commonly, the gum base comprises 10 to about 50 percent of the gum, and, in some preferred embodiments, 20 to about 35 percent, by weight, of the chewing gum.
  • the chewing gum base of the present invention contains about 20 to about 60 weight percent synthetic elastomer, 0 to about 30 weight percent natural elastomer, about 5 to about 55 weight percent elastomer plasticizer, about 4 to about 35 weight percent filler, about 5 to about 35 weight percent softener, and optional minor amounts (about one percent or less) of miscellaneous ingredients such as colorants, antioxidants, etc.
  • Synthetic elastomers may include, but are not limited to, polyisobutylene with a GPC weight average molecular weight of about 10,000 to about 95,000, isobutylene-isoprene copolymer (butyl elastomer) , styrene-butadiene copolymers having styrene-butadiene ratios of about 1:3 to about 3:1, polyvinyl acetate having a GPC weight average molecular weight of about 2,000 to about 90,000, polyisoprene, polyethylene, vinyl acetate-vinyl laurate copolymer having vinyl laurate content of about 5 to about 50 percent by weight of the copolymer, and combinations thereof.
  • Preferred ranges are, for polyisobutylene, 50,000 to 80,000 GPC weight average molecular weight; for styrene ⁇ butadiene, 1:1 to 1:3 bound styrene-butadiene; for polyvinyl acetate, 10,000 to 65,000 GPC weight average molecular weight, with the higher molecular weight polyvinyl acetates typically used in bubble gum base; and for vinyl acetate-vinyl laurate, vinyl laurate content of 10-45 percent.
  • Natural elastomers may include natural rubber such as smoked or liquid latex and guayule as well as natural gums such as jelutong, lechi caspi, perillo, sorva, massaranduba balata, massaranduba chocolate, nispero, rosindinha, chicle, gutta hang kang, and combinations thereof.
  • the preferred synthetic elastomer and natural elastomer concentrations vary depending on whether the chewing gum in which the base is used is adhesive or conventional, bubble gum or regular gum, as discussed below.
  • Preferred natural elastomers include jelutong, chicle, sorva and massaranduba balata.
  • Elastomer plasticizers may include, but are not limited to, natural rosin esters such as glycerol esters of partially hydrogenated rosin, glycerol esters of polymerized rosin, glycerol esters of partially dimerized rosin, glycerol esters of rosin, pentaerythritol esters of partially hydrogenated rosin, methyl and partially hydrogenated methyl esters of rosin, pentaerythritol esters of rosin; synthetics such as terpene resins derived from alpha-pinene, beta-pinene, and/or d-limonene; and any suitable combinations of the foregoing.
  • the preferred elastomer plasticizers will also vary depending on the specific application and on the type of elastomer which is used.
  • Fillers/texturizers may include magnesium and calcium carbonate, ground limestone, silicate types such as magnesium and aluminum silicate, clay, alumina, talc, titanium oxide, mono-, di- and tri-calciu phosphate, cellulose polymers, such as wood, and combinations thereof.
  • Softeners/emulsifiers may include tallow, hydrogenated tallow, hydrogenated and partially hydrogenated vegetable oils, cocoa butter, glycerol monostearate, glycerol triacetate, lecithin, mono-, di- and triglycerides, acetylated monoglycerides, fatty acids (e.g. stearic, palmitic, oleic and linoleic acids) , and combinations thereof.
  • fatty acids e.g. stearic, palmitic, oleic and linoleic acids
  • Colorants and whiteners may include FD&C-type dyes and lakes, fruit and vegetable extracts, titanium dioxide, and combinations thereof.
  • the base may or may not include wax.
  • An example of a wax-free gum base is disclosed in U.S. Patent No.
  • a typical chewing gum composition includes a water soluble bulk portion and one or more flavoring agents.
  • the syrup of the present invention containing water soluble ingredients, forms part of the water soluble bulk portion.
  • the water soluble portion can also include powdered bulking agents (most typically bulk sweeteners) , high intensity sweeteners, flavoring agents, softeners, emulsifiers, colors, acidulants, fillers, antioxidants, and other components that provide desired attributes.
  • Softeners are added to the chewing gum in order to optimize the chewability and mouth feel of the gum.
  • the softeners which are also known as plasticizers and plasticizing agents, generally constitute between approximately 0.5 to about 15% by weight of the chewing gum.
  • the softeners may include glycerin, lecithin, and combinations thereof.
  • Aqueous sweetener solutions such as those containing sorbitol, hydrogenated starch hydrolysates, corn syrup and combinations thereof, may also be used as softeners and binding agents in chewing gum. Additionally, the sorbitol syrup of the present invention can be used as a softener and binding agent.
  • Bulk sweeteners include both sugar and sugarless components.
  • Bulk sweeteners and other bulking agents typically constitute 5 to about 95% by weight of the chewing gum, more typically, 20 to 80% by weight, and more commonly, 30 to 60% by weight of the gum.
  • Sugar sweeteners generally include saccharide- containing components commonly known in the chewing gum art, including, but not limited to, sucrose, dextrose, maltose, dextrin, dried invert sugar, fructose, levulose, galactose, corn syrup solids, and the like, alone or in combination.
  • the sorbitol syrup of the present invention comprises about 5% to about 50% of the chewing gum formulation.
  • the syrup will comprise approximately 25% to about 45% by weight of the chewing gum composition.
  • the syrup will comprise at least about 30% of the gum, more preferably more than 35% of the gum and most preferably more than 40% of the gum.
  • the syrup may be preferable that the syrup comprises over 45% of the gum composition.
  • crystalline sorbitol if desired, can also be used.
  • sugarless sweeteners can include, but are not limited to, other sugar alcohols such as mannitol, xylitol, hydrogenated starch hydrolysates, maltitol, and the like, alone or in combination.
  • High intensity artificial sweeteners can also be used in combination with the above.
  • Preferred sweeteners include, but are not limited to sucralose, aspartame, salts of acesulfame, alitame, saccharin and its salts, cycla ic acid and its salts, glycyrrhizin, dihydrochalcones, thaumatin, monellin, and the like, alone or in combination.
  • Such techniques as wet granulation, wax granulation, spray drying, spray chilling, fluid bed coating, coacervation, and fiber extension may be used to achieve the desired release characteristics.
  • usage level of the artificial sweetener will vary greatly and will depend on such factors as potency of the sweetener, rate of release, desired sweetness of the product, level and type of flavor used and cost considerations. Thus, the active level of artificial sweetener may vary from 0.02 to about 8%. When carriers used for encapsulation are included, the usage level of the encapsulated sweetener will be proportionately higher.
  • Combinations of sugar and/or sugarless sweeteners may be used in chewing gum. Additionally, the softener may also provide additional sweetness such as with aqueous sugar or alditol solutions. If a low calorie gum is desired, a low caloric bulking agent can be used.
  • a low caloric bulking agent include: polydextrose, Raftilose, Raftilin, fructooligosaccharides (NutraFlora) , palatinose oligosaccharide, guar gum hydrolysate (Sun Fiber) , and indigestible dextrin (Fibersol) .
  • other low 5 calorie bulking agents can be used.
  • flavoring agents can be used.
  • the flavor can be used in amounts of approximately 0.1 to about 15 weight percent of the gum, and preferably, about 0.2 to about 5%.
  • Flavoring agents may include essential 0 oils, synthetic flavors or mixtures thereof including, but not limited to, oils derived from plants and fruits such as citrus oils, fruit essences, peppermint oil, spearmint oil, other mint oils, clove oil, oil of wintergreen, anise and the like.
  • Artificial flavoring 5 agents and components may also be used. Natural and artificial flavoring agents may be combined in any sensorially acceptable fashion.
  • the present invention can be used with a variety of processes for manufacturing chewing 0 gum.
  • Chewing gum is generally manufactured by sequentially adding the various chewing gum ingredients to commercially available mixers known in the art. After the ingredients have been thoroughly mixed, the chewing 5 gum mass is discharged from the mixer and shaped into the desired form, such as by rolling into sheets and cutting into sticks, extruding into chunks, or casting into pellets.
  • the ingredients are mixed by first 0 melting the gum base and adding it to the running mixer.
  • the gum base may alternatively be melted in the mixer.
  • Color and emulsifiers can be added at this time.
  • sorbitol syrup of the present invention can be added next along with any other syrup softeners or
  • the sugarless syrup containing liquid sorbitol, mannitol and glycerin described above and disclosed in two of the parent applications has been found to be a suitable replacement for most of the crystalline sorbitol and as a way to increase the binding capacity over currently used binders in sugarless gum.
  • maltitol in the syrup provides an improvement of the sugarless syrup containing mannitol.
  • One improved sugarless syrup blend was made by evaporating a mixture of 75% aqueous sorbitol solution (containing 70% sorbitol and 30% water) , 20% glycerin and 5% maltitol to 98% solids. The mixture was placed into a vacuum cooker set at 200°F under a pressure of 5 inches of mercury. The evaporation can also take place in a steam kettle.
  • the sugarless syrup has many properties similar to those of corn syrup, however, the sugarless syrup has a smoother texture.
  • sorbitol syrup can be used to create other products aside from chewing gum.
  • such other products may have the following formulas.
  • Citric Acid/Flavor/Color as needed Procedure: Hard candies can be made by the following procedure:
  • the syrup is cooked and mixed until a temperature of about 300°F and a moisture level of about 1-2% is obtained. 3.
  • the heavy syrup is poured onto a stainless steel cooling table.
  • Citric acid artificial ingredients, flavors and color, and butter are added and mixed by kneading.
  • the resultant product is allowed to cool to room temperature and cut as needed.
  • sorbitol syrup may be used to prepare a sugar- free taffy by the following formula and procedure:
  • Example 16 98% sorbitol syrup may be used to prepare a sugar- free caramel by the following formula and procedure:
  • a suggested final cook temperature is about 245°F

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Nutrition Science (AREA)
  • Inorganic Chemistry (AREA)
  • Proteomics, Peptides & Aminoacids (AREA)
  • Microbiology (AREA)
  • Molecular Biology (AREA)
  • Confectionery (AREA)
  • Medicinal Preparation (AREA)
  • Seasonings (AREA)

Abstract

L'invention concerne une gomme à mâcher comprenant du sorbitol et son procédé de fabrication. La gomme à mâcher est obtenue à partir d'une formulation qui renferme une composition dont les constituants sont les suivants: solution sirupeuse de sorbitol aqueux, plastifiant choisi entre la glycérine, le propylèneglycol et des combinaisons de ces produits, et anticristallisant comprenant des alditols autres qu'un sorbitol dont le degré de polymérisation est égal à 1 ou à 2.
PCT/US1995/008392 1993-09-30 1995-07-05 Sirops pour gomme a macher contenant du sorbitol, un plastifiant et un anticristallisant Ceased WO1997001962A1 (fr)

Priority Applications (5)

Application Number Priority Date Filing Date Title
AU29159/95A AU2915995A (en) 1993-12-29 1995-07-05 Syrups for use in chewing gum containing sorbitol, a plasticizing agent and an anticrystallization agent
MX9800202A MX9800202A (es) 1995-07-05 1995-07-05 Jarabes para usarse en una goma de mascar que contiene sorbitol, un agente plastificante y un agente de anticristalizacion.
EP95924776.8A EP0836389B2 (fr) 1993-12-29 1995-07-05 Sirops pour gomme a macher contenant du sorbitol, un plastifiant et un anticristallisant
DE69532593.0T DE69532593T3 (de) 1995-07-05 1995-07-05 Sirups zur verwendung in sorbitol-enthaltendem kaugummi, ein weichmacher und ein antikristallisationsmittel
BR9510621A BR9510621A (pt) 1995-07-05 1995-07-05 Xaropes para uso em goma de mascar contendo sorbitol um agente plastificante e um agente anticristalização

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
PCT/US1993/009352 WO1995008924A1 (fr) 1993-09-30 1993-09-30 Chewing-gum contenant du maltitol
US17498393A 1993-12-29 1993-12-29
US23913794A 1994-05-06 1994-05-06

Publications (1)

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WO1997001962A1 true WO1997001962A1 (fr) 1997-01-23

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Application Number Title Priority Date Filing Date
PCT/US1993/009352 Ceased WO1995008924A1 (fr) 1993-09-30 1993-09-30 Chewing-gum contenant du maltitol
PCT/US1994/010361 Ceased WO1995008927A1 (fr) 1993-09-30 1994-09-13 Chewing-gum contenant de faibles taux de maltitol et un edulcorant puissant
PCT/US1995/008392 Ceased WO1997001962A1 (fr) 1993-09-30 1995-07-05 Sirops pour gomme a macher contenant du sorbitol, un plastifiant et un anticristallisant

Family Applications Before (2)

Application Number Title Priority Date Filing Date
PCT/US1993/009352 Ceased WO1995008924A1 (fr) 1993-09-30 1993-09-30 Chewing-gum contenant du maltitol
PCT/US1994/010361 Ceased WO1995008927A1 (fr) 1993-09-30 1994-09-13 Chewing-gum contenant de faibles taux de maltitol et un edulcorant puissant

Country Status (4)

Country Link
EP (2) EP0673208A4 (fr)
AU (1) AU694138B2 (fr)
CA (1) CA2171615C (fr)
WO (3) WO1995008924A1 (fr)

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EP0954982A1 (fr) * 1998-05-07 1999-11-10 Roquette FrÀ¨res Composition édulcorante et ses utilisations
WO2004084642A1 (fr) * 2003-03-25 2004-10-07 Council Of Scientific And Industrial Research Composition de sirop sans sucre synergetique et procede de preparation de cette composition
EP1733627A3 (fr) * 2005-06-14 2007-01-10 Kabushiki Kaisha Ueno Seiyaku Oyo Kenkyujo Procédé pour obtenir un produit enrobé
EP1004354B2 (fr) † 1998-11-27 2007-07-18 Roquette FrÀ¨res Composition de polyols concentré
US20100233346A1 (en) * 2007-10-29 2010-09-16 Andreas Redl Cereal-based bar composition of the chewy type and method for preparing such a cereal-based bar composition
US8685474B2 (en) 2006-02-15 2014-04-01 Wm. Wrigley Jr. Company Non-crystallizing syrups containing sorbitol and their use in chewing gum
US8999410B2 (en) 2005-12-29 2015-04-07 Wm. Wrigley Jr. Company Chewing gum containing styrene-diene block copolymers
EP2542099A4 (fr) * 2010-03-01 2015-12-09 Wrigley W M Jun Co Substance de masse amorphe pour gomme à mâcher
WO2015200000A1 (fr) * 2014-06-12 2015-12-30 The Additive Advantage Llc Procédé d'application d'un arôme à une gomme à mâcher et à d'autres substrats comestibles

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US5637334A (en) * 1993-09-30 1997-06-10 Wm. Wrigley Jr. Company Chewing gum containing maltitol
US5651936A (en) * 1993-12-29 1997-07-29 Wm. Wrigley Jr. Company Syrups containing sorbitol, a plasticizing agent and an anticrystallization agent and their use in chewing gum and other products
EP0836389B2 (fr) † 1993-12-29 2015-04-22 Wm. Wrigley Jr. Company Sirops pour gomme a macher contenant du sorbitol, un plastifiant et un anticristallisant
US20030021864A1 (en) * 2001-05-22 2003-01-30 Richey Lindell C. Coated chewing gum products and methods for making same
MXPA05007916A (es) * 2003-01-27 2005-09-30 Wrigley W M Jun Co Jarabes sin azucar y su uso en gomas de mascar y otras confituras.

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US4671967A (en) * 1984-05-18 1987-06-09 Wm. Wrigley Jr. Company Carbohydrate syrups and methods of preparation
US4671961A (en) * 1984-05-18 1987-06-09 Wm. Wrigley Jr. Company Chewing gum compositions and methods of preparation
US5120551A (en) * 1990-12-21 1992-06-09 Wm. Wrigley Jr. Company Low moisture sugarless syrups with maltitol for chewing gum

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US4959225A (en) * 1988-10-28 1990-09-25 Warner-Lambert Company Synergistic sweetening compositions containing chlorodeoxysugars and maltitol and methods for preparing same
WO1989003170A2 (fr) * 1988-12-09 1989-04-20 Wm. Wrigley Jr. Company Procede de regulation de liberation d'acesulfame k dans du chewing-gum et chewing-gum ainsi produit
US5110608A (en) * 1988-12-29 1992-05-05 Warner-Lambert Company Chewing gums having longer lasting sweetness
US4933189A (en) * 1988-12-29 1990-06-12 Warner-Lambert Company Chewing gum having longer lasting sweetness
WO1990007864A2 (fr) * 1990-04-25 1990-07-26 Wm. Wrigley Jr. Company Procede de liberation entretenue de glycyrrhizine dans de la gomme a macher et gomme ainsi obtenue
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WO1991015941A1 (fr) * 1991-06-19 1991-10-31 Wm. Wrigley Jr. Company Gomme a macher contenant du palatinose
WO1992009208A2 (fr) * 1991-09-27 1992-06-11 Wm. Wrigley Jr. Company Chewing-gum contenant de la dextrine non digestible
US5236719A (en) * 1991-09-27 1993-08-17 Wm. Wrigley Jr. Company Chewing gum and other comestibles containing purified indigestible dextrin
WO1992008368A1 (fr) * 1991-09-30 1992-05-29 Wm. Wrigley Jr. Company Gomme a macher contenant des fructooligosaccharides
WO1992008371A2 (fr) * 1991-12-20 1992-05-29 Wm. Wrigley Jr. Company Chewing-gum contenant de l'oligofructose
WO1992008370A2 (fr) * 1991-12-20 1992-05-29 Wm. Wrigley Jr. Company Gomme a macher contenant du polydextrose
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US3857965A (en) * 1973-10-11 1974-12-31 Wrigley W Co Method for making a chewing-gum composition
US4382962A (en) * 1979-06-15 1983-05-10 Societe Roquette Freres Sugarless-type chewing gum
US4671967A (en) * 1984-05-18 1987-06-09 Wm. Wrigley Jr. Company Carbohydrate syrups and methods of preparation
US4671961A (en) * 1984-05-18 1987-06-09 Wm. Wrigley Jr. Company Chewing gum compositions and methods of preparation
US4728515A (en) * 1985-10-16 1988-03-01 Wm. Wrigley Jr. Company Low moisture chewing gum compositions and methods of preparation
US5120551A (en) * 1990-12-21 1992-06-09 Wm. Wrigley Jr. Company Low moisture sugarless syrups with maltitol for chewing gum

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0954982A1 (fr) * 1998-05-07 1999-11-10 Roquette FrÀ¨res Composition édulcorante et ses utilisations
WO1999056562A1 (fr) * 1998-05-07 1999-11-11 Roquette Freres Composition edulcorante et ses utilisations
FR2778317A1 (fr) * 1998-05-07 1999-11-12 Roquette Freres Composition edulcorante et ses utilisations
US6743456B1 (en) 1998-05-07 2004-06-01 Roquette Freres Sweetening composition and its uses
EP1004354B2 (fr) † 1998-11-27 2007-07-18 Roquette FrÀ¨res Composition de polyols concentré
WO2004084642A1 (fr) * 2003-03-25 2004-10-07 Council Of Scientific And Industrial Research Composition de sirop sans sucre synergetique et procede de preparation de cette composition
EP1733627A3 (fr) * 2005-06-14 2007-01-10 Kabushiki Kaisha Ueno Seiyaku Oyo Kenkyujo Procédé pour obtenir un produit enrobé
US7754254B2 (en) 2005-06-14 2010-07-13 Ueno Fine Chemicals Industry, Ltd. Method for providing coated product
US8999410B2 (en) 2005-12-29 2015-04-07 Wm. Wrigley Jr. Company Chewing gum containing styrene-diene block copolymers
US8685474B2 (en) 2006-02-15 2014-04-01 Wm. Wrigley Jr. Company Non-crystallizing syrups containing sorbitol and their use in chewing gum
US20100233346A1 (en) * 2007-10-29 2010-09-16 Andreas Redl Cereal-based bar composition of the chewy type and method for preparing such a cereal-based bar composition
EP2542099A4 (fr) * 2010-03-01 2015-12-09 Wrigley W M Jun Co Substance de masse amorphe pour gomme à mâcher
US9433229B2 (en) 2010-03-01 2016-09-06 Wm. Wrigley Jr. Company Amorphous chewing gum bulk material
WO2015200000A1 (fr) * 2014-06-12 2015-12-30 The Additive Advantage Llc Procédé d'application d'un arôme à une gomme à mâcher et à d'autres substrats comestibles

Also Published As

Publication number Publication date
WO1995008924A1 (fr) 1995-04-06
AU694138B2 (en) 1998-07-16
CA2171615A1 (fr) 1995-04-06
EP0673208A4 (fr) 1997-03-05
AU7727794A (en) 1995-04-18
CA2171615C (fr) 1999-07-13
WO1995008927A1 (fr) 1995-04-06
EP0722274A4 (fr) 1997-03-05
EP0673208A1 (fr) 1995-09-27
EP0722274A1 (fr) 1996-07-24

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