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WO1996034398A1 - Materiau contenant du mica - Google Patents

Materiau contenant du mica Download PDF

Info

Publication number
WO1996034398A1
WO1996034398A1 PCT/DE1996/000773 DE9600773W WO9634398A1 WO 1996034398 A1 WO1996034398 A1 WO 1996034398A1 DE 9600773 W DE9600773 W DE 9600773W WO 9634398 A1 WO9634398 A1 WO 9634398A1
Authority
WO
WIPO (PCT)
Prior art keywords
mica
containing material
material according
flat
range
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/DE1996/000773
Other languages
German (de)
English (en)
Inventor
Dieter Grafl
Bernd Bretschneider
Kai Lemke
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Reinz Dichtungs GmbH
Original Assignee
Reinz Dichtungs GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Reinz Dichtungs GmbH filed Critical Reinz Dichtungs GmbH
Publication of WO1996034398A1 publication Critical patent/WO1996034398A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/24Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing alkyl, ammonium or metal silicates; containing silica sols
    • C04B28/26Silicates of the alkali metals
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02BINTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
    • F02B77/00Component parts, details or accessories, not otherwise provided for
    • F02B77/11Thermal or acoustic insulation
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00612Uses not provided for elsewhere in C04B2111/00 as one or more layers of a layered structure

Definitions

  • the invention relates to a mica-containing material made from expanded or expanded and unexpanded mica powder, which is applied to a support having flat openings, and to a method for producing the mica material and its use.
  • mica Because of its excellent insulation properties, mica has been used as an insulation material for some time.
  • DE 39 22 636 describes a heat shield for motor vehicles in which mica powder with water glass as a binder is applied to a substrate in layer form and then subsequently baked on the substrate by temperature treatment.
  • Another application is known from DE 35 12 842.
  • This document relates to a flat gasket made from a flat mica material.
  • the mica material itself consists of a large number of superimposed flat mica disks, a binder layer being introduced in the overlapping areas of the mica disks lying directly one above the other.
  • the mica disks are produced in such a way that mica raw material is split into mica layers by treatment with a reaction solution, possibly with the additional action of higher temperatures.
  • a carrier material for example a thin steel wire mesh
  • a disadvantage of the mica material described above for the sealing application is in particular that its production is very complex. As described above, it is namely necessary in this case that the mica disks are first produced from the mica powder by chemical treatment. These mica disks must then be subsequently provided with binders in order to connect them to the sealing material. Another disadvantage is that, due to the binder (synthetic resins), harmful emissions caused by decomposition of the organic binder cannot be prevented at higher temperatures.
  • the mica material according to the invention is thus distinguished by the fact that expanded or expanded and unexpanded mica powder is bound to a flat support body having openings. Surprisingly, it has been shown that a connection to the mica powder is only possible through the flat supporting body having openings.
  • the mica powder is here by clinging to one another and with the perforations. stabilizes the flat support body. Obviously, this is achieved by compressing the inflated individual layers during manufacture. It is particularly surprising that the composite has such a high strength that it can also be used without a binder for most applications. On the other hand, in this case the bond can be released again by a correspondingly long mechanical treatment, so that on the one hand the planar support body and on the other hand the mica powder can be recycled separately. Since the mica material in this embodiment also contains no binder, no emissions occur even at high temperatures (> 600/700 ° C). The manufacturing process is extremely cheap owing to the inexpensive products used, such as expanded mica powder and, for example, glass fiber fabric as the carrier body.
  • the carrier body is preferably used in the form of woven fabrics, grids, nets, braids, nonwovens or perforated sheets.
  • the material of the carrier bodies described above can consist of non-fibrous or fibrous material, such as, for example, glass, ceramic, plastic, metal, cellulose or carbon.
  • Support bodies which are already commercially available, such as glass fiber fabrics or nets, are preferably used here. It has been found in numerous tests that the opening width of the openings can be a maximum of up to 50 mm. However, it is preferred if the opening widths of the openings in the supporting bodies are in the range from 3 mm to 10 mm.
  • the web width, ie the areas between the openings, are preferably between 0.001 and 10 mm, particularly preferably between 0.1 and 5 mm. It is advantageous if the openings are evenly distributed over the supporting bodies.
  • the supporting bodies can have a basis weight of 30 to 10,000 g / m 2 , preferably a basis weight of 30 to 2000 g / m
  • mica powders or mica platelets which are expanded are used as the mica powder, a grain size of up to 20 mm, especially up to 5 mm, being preferred.
  • mica powder also includes the degradation products of the mica, e.g. Understand vermiculite.
  • Vermiculite is a three-layer phyllosilicate (see Römpp Chemie Lexikon, 9th edition, volume 6, p. 4896). It has been shown that in particular these vermiculites, which are also commercially available, are particularly suitable.
  • the mica material according to the invention can also be produced if expanded mica powder with a low proportion (approx. 5 to 20%) of unexpanded mica powder is used.
  • a binder in the mica material according to the invention it is of course possible, as previously provided for in the prior art, for a binder to be added to the mica powder or to the mica platelets.
  • binders such as, for example, water glass, resins or elastomers
  • binders can be used as binders.
  • the composite made of mica material can also be solidified by subsequent impregnation or coating.
  • the mica material according to the invention has a composite material thickness of 0.2 to 50 mm, preferably 0.5 to 2 mm, and a basis weight of 1,000 to 50,000 g / m 2 , preferably 500 to 3000 g / m 2 .
  • a particularly advantageous variant provides for the mica material described above to be introduced between at least two flat materials.
  • an extremely effective heat shield for internal combustion engines in the vehicle area can be realized.
  • the mica material is used without a binder. This not only has the advantage of a cheap and simple production, but this heat shield is (up to about 900 ⁇ C) even at the occurring here high temperatures with appropriate selection of Trä ⁇ gers, such as glass, metal or ceramic, completely free of emissions. It has been shown that such
  • Heat shields not only show good heat insulation, but also excellent sound insulation.
  • Heat shields which consist of at least two flat materials, are known from the prior art.
  • an insulating material made of laminates is arranged between the flat materials.
  • the invention expressly provides for the use of such heat shields in relation to the flat materials and from the prior art Known prior art, but with an inventive mica material as an insulating agent.
  • a heat shield can also be realized, which consists of at least one flat material and an inflated mica material. This can e.g. be produced in that the mica material is applied to a sheet metal as flat material.
  • the production of the mica material is extremely simple and inexpensive.
  • the mica powder or the mica flakes are advantageously applied to the flat support body with the aid of rollers and / or presses.
  • a more or less firm bond between the mica powder or the mica platelets and the perforated flat support body can be achieved by increasing or decreasing the pressure.
  • the application of pressure obviously means that the compression of the expanded individual mica layers achieves a firm bond.
  • the mica material according to the invention can itself be used as an insulating material for high temperatures up to 1,100 ° C., for example in automobile construction, furnace construction or the construction material sector.
  • the mica material according to the invention can also be shaped or formed into 3D parts.
  • the use of the mica material for heat shields is particularly preferred. For this it is necessary that the mica material described above is introduced between at least two flat materials, preferably between two sheets. The two flat materials are then, for example, as if in and of themselves from the stand the technology for heat shields known, connected at least on one side. However, a connection is also possible, for example by riveting at any point on the heat shield.
  • vermiculite is applied to a glass filament fabric by rolling.
  • the glass filament fabric with a thread count (DIN 53853) of 5 * 2.1 has an opening width of approx. 4 mm, a web width of approx. 0.7 mm, a basis weight (DIN) 53854) of 160 g / m 2 .
  • the binding (DIN 61101) is a "lathe”.
  • the fabric is made slip-resistant thanks to a silicate coating.
  • the mica powder is a palabora vermiculite (expanded) with a grain size of KO ( ⁇ 1 mm).
  • the material compacted between a pair of rollers has a thickness of 1.2 mm and a weight per unit area of approximately 1,200 g / m 2 .
  • the mica intermediate layer is punched with the required contour and inserted between two aluminum-clad pieces of sheet metal.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Acoustics & Sound (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Laminated Bodies (AREA)

Abstract

L'invention concerne un matériau contenant du mica utilisé à des fins d'isolation et/ou d'amortissement, pour lequel de la poudre de mica soufflée ou à la fois soufflée et non soufflée est liée à un support plan comportant des évidements.
PCT/DE1996/000773 1995-04-28 1996-04-26 Materiau contenant du mica Ceased WO1996034398A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19515779.6 1995-04-28
DE19515779A DE19515779C2 (de) 1995-04-28 1995-04-28 Glimmerhaltiger Werkstoff

Publications (1)

Publication Number Publication Date
WO1996034398A1 true WO1996034398A1 (fr) 1996-10-31

Family

ID=7760678

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/DE1996/000773 Ceased WO1996034398A1 (fr) 1995-04-28 1996-04-26 Materiau contenant du mica

Country Status (2)

Country Link
DE (1) DE19515779C2 (fr)
WO (1) WO1996034398A1 (fr)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19700628C2 (de) * 1997-01-10 2003-03-20 Reinz Dichtungs Gmbh Verfahren zur Herstellung eines Hitzeschildes und ein mit dem Verfahren hergestelltes Hitzeschild
DE19719509C2 (de) * 1997-05-09 1999-06-02 Porextherm Daemmstoffe Gmbh Verfahren zur Herstellung einer Wärmedämmverbundplatte und damit hergestellte Wärmedämmverbundplatte
AU746503B2 (en) * 1998-05-15 2002-05-02 Welding Institute, The Heat resistant product and method
DE102010005164A1 (de) * 2010-01-20 2011-07-28 Federal-Mogul Sealing Systems GmbH, 57562 Wärme-Abschirmblech
DE102013110155A1 (de) * 2013-09-16 2015-03-19 Elringklinger Ag Dichtung

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1184171A (en) * 1965-10-21 1970-03-11 R P Barley Ltd Improvements relating to Bodies of Polyester Resin/Glass Fibre Composition
FR2512735A1 (fr) * 1981-09-11 1983-03-18 Lechler Elring Dichtungswerke Bande ou plaque renforcee par un support et procede pour la fabrication d'une telle bande ou d'une telle plaque
FR2534851A2 (fr) * 1981-09-11 1984-04-27 Lechler Elring Dichtungswerke Bande ou plaque renforcee par un support, notamment pour la fabrication de joints d'etancheite plats et d'isolants thermiques
DE3905871A1 (de) * 1989-02-24 1990-08-30 Reinz Dichtungs Gmbh Verbundmaterial

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3025341T1 (de) * 1979-02-05 1981-01-08 Hollingsworth & Vose Co Sheet material containing exfoliated vermiculite
SE466299B (sv) * 1983-08-04 1992-01-27 Micropore International Ltd Vaermeisolerande kropp och saett att framstaella den, innefattande en armerande bikakestruktur och ett vaermeisolationsmaterial
DE19850766B4 (de) * 1998-11-04 2004-01-22 Continental Aktiengesellschaft Fahrzeugluftreifen

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1184171A (en) * 1965-10-21 1970-03-11 R P Barley Ltd Improvements relating to Bodies of Polyester Resin/Glass Fibre Composition
FR2512735A1 (fr) * 1981-09-11 1983-03-18 Lechler Elring Dichtungswerke Bande ou plaque renforcee par un support et procede pour la fabrication d'une telle bande ou d'une telle plaque
FR2534851A2 (fr) * 1981-09-11 1984-04-27 Lechler Elring Dichtungswerke Bande ou plaque renforcee par un support, notamment pour la fabrication de joints d'etancheite plats et d'isolants thermiques
DE3905871A1 (de) * 1989-02-24 1990-08-30 Reinz Dichtungs Gmbh Verbundmaterial

Also Published As

Publication number Publication date
DE19515779C2 (de) 1999-02-11
DE19515779A1 (de) 1996-10-31

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