[go: up one dir, main page]

WO1996033867A1 - Materiau non-tisse en fibres non cellulosiques et procede de fabrication - Google Patents

Materiau non-tisse en fibres non cellulosiques et procede de fabrication Download PDF

Info

Publication number
WO1996033867A1
WO1996033867A1 PCT/US1996/005356 US9605356W WO9633867A1 WO 1996033867 A1 WO1996033867 A1 WO 1996033867A1 US 9605356 W US9605356 W US 9605356W WO 9633867 A1 WO9633867 A1 WO 9633867A1
Authority
WO
WIPO (PCT)
Prior art keywords
latex binder
nonwoven fabric
fibers
cellulose fibers
styrene
Prior art date
Application number
PCT/US1996/005356
Other languages
English (en)
Inventor
David F. Diehl
Original Assignee
Gencorp Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Gencorp Inc. filed Critical Gencorp Inc.
Priority to US08/945,544 priority Critical patent/US6034005A/en
Priority to JP8532604A priority patent/JPH11504398A/ja
Priority to EP96912868A priority patent/EP0831995A4/fr
Publication of WO1996033867A1 publication Critical patent/WO1996033867A1/fr

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/693—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural or synthetic rubber, or derivatives thereof
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/58—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
    • D04H1/587—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives characterised by the bonding agents used
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/58—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
    • D04H1/64—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives the bonding agent being applied in wet state, e.g. chemical agents in dispersions or solutions
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/02—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with hydrocarbons
    • D06M13/03—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with hydrocarbons with unsaturated hydrocarbons, e.g. alkenes, or alkynes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/152—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen having a hydroxy group bound to a carbon atom of a six-membered aromatic ring
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
    • D06M13/252—Mercaptans, thiophenols, sulfides or polysulfides, e.g. mercapto acetic acid; Sulfonium compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
    • D06M13/256—Sulfonated compounds esters thereof, e.g. sultones
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/227—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/227—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated
    • D06M15/233—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated aromatic, e.g. styrene

Definitions

  • the present invention relates to a nonwoven fabric of chemically bonded non-cellulose fibers. More particularly, the present invention relates to a nonwoven fabric including a random arrangement of non- cellulose fibers and an essentially formaldehyde free latex binder capable of developing maximum tensile properties at temperatures less than the melt bonding temperature of the non-cellulose fibers, of significance polypropylene and polyethylene.
  • a nonwoven fabric is a preformed web or mat of fibers laid down mechanically.
  • the fibers may be deposited in a random manner or oriented primarily in one direction.
  • Most widely used fibers include cellulosics, polya ides, polyesters, polypropylene and polyethylene.
  • the spun fibers, which may be drawn, are laid down directly onto a porous belt by carding, air- laying or wet-laying.
  • the sheet is then bonded together with a binder subsequently treated in an oven or a calendar to complete the bonding process.
  • a number of methods have been developed for applying a binder to randomly-dispersed fibers.
  • a water based emulsion binder system is used in which a thermoplastic or thermoset synthetic polymer latex is prepared and a loose preformed web of fibers to be treated is immersed therein, saturated or sprayed using special equipment in view of the structural weakness of the preformed web; the thus treated preformed web is dried and cured to effect proper bonding.
  • an aqueous or solvent solution binder system of a thermoplastic or thermoset resin may be used to impregnate the fibrous preformed web.
  • thermoplastic or thermoset resin powders to the fibers, before or after making a preformed web of the same, and passing the preformed web through hot rolls or a hot press to bind the fibers together.
  • thermoplastic fibers having a softening point below that of the base fibers may be interdispersed in a preformed web of the latter and sufficient heat and pressure applied, such as by the use of heated rolls, to soften the thermoplastic fibers and bind the fiber network together.
  • latices for non-woven fabrics are those prepared from polymers of butadiene-styrene, butadiene-acrylonitrile, vinyl acetate, acrylic monomers such as methyl acrylate, ethyl acrylate, methyl methacrylate and the like. While the emulsion binder system is the most popular method of forming non-woven fabrics, the homopolymers, copolymers and terpolymers heretofore used therein have suffered from one or more disadvantages. To be useful as a textile material, the synthetic polymer must possess several physical properties. The desired properties include adequate tensile strength over a fairly wide temperature range, a high modulus or stiffness under certain conditions, and good textile qualities such as tenacity, handle and drape.
  • non-cellulose fibers are below the temperature required for proper crosslinking, e.g., polypropylene is around 250" F, conventional latices cannot be used. Accordingly, non elt bonded polypropylene fiber in the nonwoven industry has never enjoyed large success. The problem has been in the specific development of a suitable latex binder to give acceptable tensile properties.
  • the nonwovens in accordance with the present invention chemically bond at temperatures below the melt bonding point of the non-cellulose fibers. Accordingly, the nonwovens in accordance with the present invention provide reduced energy costs for nonwoven manufacturers due to lower temperature requirements and the ability to chemically bond the fibers.
  • a nonwoven fabric including a random arrangement of non-cellulose fibers and an essentially formaldehyde free latex binder.
  • the latex binder is capable of developing maximum tensile properties at temperatures of no more than about 225 degrees fahrenheit to chemically bond the non-cellulose fibers and form a dimensionally stable non-woven fabric.
  • Suitable non-cellulose fibers include glass fibers or fibers made from high polymers.
  • the high polymers include polyolefins, polyesters, and acrylics, polyamides and the like.
  • the polyolefin fibers include polypropylene, polyethylene, polybutene and their copolymers.
  • the polyester fibers include any long chain synthetic polymer composed of at least 85% by weight of an ester of a dihydric alcohol and terephthalic acid such as polyethylene terephthalate, and, in addition liquid crystal polyesters and the like.
  • the acrylic fibers include any fiber forming substance containing a long chain synthetic polymer composed of at least 85% by weight acrylonitrile units -CH 2 CH(CN)-. It will be appreciated that other types of non-cellulose fibers may also be employed in accordance with the teachings of the present invention. For example, high modulus fibers more commonly known as graphite fibers made from polyacrylonitrile or petroleum pitch may also be used.
  • the nonwoven fabric of non-cellulose fibers is formed by providing a random arrangement of non- cellulose fibers.
  • an essentially formaldehyde free latex binder capable of developing maximum tensile properties at temperatures of no more than about 225 degrees fahrenheit is applied to the fibers.
  • the latex binder is heat treated to chemically bond the non-cellulose fibers to form a dimensionally stable nonwoven fabric.
  • the latex binder in accordance with the present invention is an essentially formaldehyde free latex binder prepared by emulsion polymerization of an emulsion polymerizable mixture.
  • the emulsion polymerizable mixture includes ethylenically unsaturated monomers, a polymeric surfactant in an amount of from about 10 to about 50 wt% and a chain transfer agent in an amount of from about 0.1 to about 2 wt%.
  • the ethylenically unsaturated monomers include at least one conjugated diene monomer and at least one vinyl substituted aromatic monomer.
  • the ethylenically unsaturated monomers consist essentially of about 90 to about 30 wt% conjugated diene monomer and about 10 to about 70 wt% vinyl substituted aromatic monomer.
  • the latex binder has a gel content of less than about 10 wt% and is capable of developing maximum tensile properties in the nonwoven fabric at temperatures less than about 225 degrees fahrenheit.
  • Figure 1 is plot of wet tensile development of a latex binder versus the mat time exposed on a metal surface heated to 225 ⁇ F.
  • the present invention relates to a nonwoven fabric of chemically bonded non-cellulose fibers.
  • the fabric may be used for soft and drapable fabrics such as diapers, feminine hygiene cover stock, medical gowns, masks, caps and drapes, and for stiff and resilient fabrics such as apparel interliners, furniture skirting, quilts, water bed baffles and clothing insulation and padding.
  • the fabric of the present invention is made by forming a mat of randomly arranged non-cellulose fibers which are chemically bonded by an essentially formaldehyde free latex binder.
  • the essentially formaldehyde free latex binder is capable of developing maximum tensile properties at temperatures less than the melt bonding point of the fibers to chemically bond the non-cellulose fibers and form a dimensionally stable nonwoven fabric.
  • the latex binder may be applied to the layer of randomly arranged non-cellulose fibers in a spaced, intermittent pattern of binder sites, or uniformly applied throughout the layer of non-cellulose fibers.
  • the term "essentially formaldehyde free” refers to a latex binder which does not liberate more than 0.7 (PPM) parts formaldehyde per million parts of latex binder during the conventional dry/cure cycle of the latex binder as determined by Nash/HPLC (high performance liquid chromatography) as well known in the art and the term “chemically bonded” as used herein refers to a bond that is not formed as a result of a heat treatment, for example, as by melt bonding as evidenced by a physical change in the fibers.
  • the non-cellulose fibers of the fabric may be glass fibers or fibers made from high polymers.
  • the glass fibers are of a type well known in the art and manufactured of molten glass extruded through small orifices and then spun at high speeds.
  • Suitable high polymers include polyolefins, polyesters, and acrylics, polyamides and the like.
  • the polyolefin fibers include polypropylene, polyethylene, polybutene and their copolymers.
  • the polyester fibers include any long chain synthetic polymer composed of at least 85% by weight of an ester of a dihydric alcohol and terephthalic acid such as polyethylene terephthalate, and, in addition liquid crystal polyesters and the like.
  • the acrylic fibers include any fiber forming substance containing a long chain synthetic polymer composed of at least 85% by weight acrylonitrile units -CH 2 CH(CN)-. It will be appreciated that other types of non-cellulose fibers may also be employed in accordance with the teachings of the present invention. For example, high modulus fibers more commonly known as graphite fibers made from polyacrylonitrile or petroleum pitch may also be used.
  • the non-cellulose fibers may be of most any suitable size and randomly arranged to most any suitable thickness depending upon the desired end use of the nonwoven fabric.
  • the non-cellulose fibers are typically of a length of about 0.25 to about 2 inches and typically about 1.2 to about 6 denier.
  • the non- cellulose fibers may be laid in an overlapping, intersecting random arrangement to form a mat of non- cellulose fibers.
  • the non-cellulose fibers may be arranged by most any convenient known manner such as by wet laying, air-laying or carding.
  • the latex binder is an essentially formaldehyde free latex binder capable of developing maximum tensile properties at a temperature of no more than about 225* fahrenheit, i.e., below the melt bonding point of the non-cellulose fibers.
  • the latex binder of the present invention contains a controlled gel content of less than about 10 wt% and preferably less than about 6 wt% and a monomodal particle size of between about 600 A to about 1200 A, and preferably between about 600 A to about 900 A.
  • the particle size of the latex binder may be determined by means of simple light transmission methods or capillary hydrodynamic fractioning (CHDF) as well known in the art.
  • CHDF capillary hydrodynamic fractioning
  • the latex binder is employed in an effective amount which will result in the resulting fabric having sufficient strength and cohesiveness for the intended end use application. It will be appreciated that the exact amount of the latex binder employed depends, in part, upon factors such as the type of fiber, weight of fibrous layer, nature of latex binder and the like. For example, end uses which require a stronger fabric may utilize more binder.
  • a typical content of latex binder applied on a non-cellulose fiber mat is about 15 to about 40 wt%. It is preferred that the minimum amount of latex binder be applied to obtain the minimum desired required physical properties of the nonwoven fabric such as tensile, hand and the like as well known in the art.
  • the latex binder utilized in accordance with the present invention may be prepared by well-known conventional emulsion polymerization techniques using one or more ethylenically unsaturated monomers and a polymeric surfactant as herein disclosed and additional conventional additives such as free-radical initiators, optional chain transfer agents, various emulsifiers (such as anionic or nonionic surfactants) , chelating agents and the like can be utilized as set forth in U.S. Patent No. 5,166,259 to Schmeing and White, incorporated herein by reference.
  • Suitable ethylenically unsaturated monomers in the emulsion polymerization reaction include conjugated diene monomers and vinyl substituted aromatic monomers.
  • the conjugated diene monomers generally contain 4 to 10 carbon atoms, and preferably 4 to 6 carbon atoms.
  • Examples of specific conjugated diene monomers include piperylene, isoprene, 2,3-dimethyl-l,3-butadiene, and the like, and preferably 1,3-butadiene, and most preferably a mix of cis-trans butadiene.
  • the amount of conjugated diene monomers utilized is from about 90 to about 30 wt%, preferably from about 75 to about 45 wt%, and most preferably about 60 wt% of the total amount of reactive monomers.
  • the vinyl substituted aromatic monomers generally contain 8 to 12 total carbon atoms. Examples of specific vinyl substituted aromatic monomers include ⁇ -methyl styrene, p-tertiary butyl styrene, m-vinyl toluene, p-vinyl toluene, 3-ethyl styrene, and the like, and preferably styrene.
  • the amount of vinyl substituted aromatic monomers utilized is from about 10 to about 70 wt%, preferably from about 25 to about 55 wt%, and most preferably about 40 wt% of the total amount of reactive monomers.
  • the polymeric surfactant is an acrylic resin neutralized in solution.
  • the polymeric surfactant is a resin containing about 25 to about 27 wt% styrene/acrylic acid/ ⁇ -methyl styrene copolymer in water neutralized with a base such as ammonium hydroxide, potassium hydroxide calcium hydroxide and the like and having an acid value of about 100 to about 300 and a weight average molecular weight greater than about 7,000.
  • the polymeric surfactant is neutralized with about 6 to about 7 wt% ammonium hydroxide and has an acid value of about 205 and a weight average molecular weight of about 8,500 and an average weight ratio of monomers in parts by weight of about 37:32:31 of ⁇ -methyl styrene, styrene and acrylic acid.
  • the resin is prepared in accordance with the process described in U.S. Patent No. 4,529,787 to Schmidt et al., incorporated herein by reference, using a minor amount of diethylene glycol monoethyl ether as a solvent. Additional resins useful in accordance with the present invention may be made in accordance with the teachings of U.S. Patent Nos. 4,414,370 to Hamielec et al. and U.S. Patent No. 4,546,160 to Brandt et al., incorporated herein by reference.
  • the amount of polymeric surfactant utilized is from about 10 to about 50, preferably from about 15 to about 35, and most preferably about 30 wt% of the total amount of reactive monomers on a dry latex basis.
  • the free-radical initiators utilized to polymerize the various above latex binder forming monomers include sodium persulfate, ammonium persulfate, potassium persulfate and the like.
  • Other free radical initiators can be used which decompose or become active at the temperature utilized during polymerization such as various peroxides, e.g., cumene hydroperoxide, dibenzoyl peroxide, diacetyl peroxide,
  • the chain transfer agent can generally be any suitable chain transfer agent well known in the art. Suitable chain transfer agents include mercaptans such as the alkyl and/or aryl mercaptans having from 8 to about 18 carbon atoms and preferably from about 12 to about 14 carbon atoms. The tertiary alkyl mercaptans having from 12 to 14 carbon atoms are highly preferred.
  • Suitable mercaptans include n-octyl mercaptan, n-dodecyl mercaptan, t-octyl mercaptan, t- dodecyl mercaptan, tridecyl mercaptan, tetradecyl mercaptan, hexadecyl mercaptan, and the like as well as combinations thereof.
  • the amount of the chain transfer agent is generally from about 0.2 to about 2 parts per hundred parts monomer, preferably about 0.4 to about 0.9 parts per hundred parts monomer, more preferably about 0.7 parts per hundred parts monomer.
  • the chain transfer agent is a dodecyl mercaptan chain transfer agent such as Sulfole 120 commercially available from Phillips 66 Co.
  • Chelating agents may also be used during polymerization to tie up various metal impurities as well as to achieve a uniform polymerization.
  • the amount of such chelating agents is generally small, such as from about 0.02 to about 0.08, and preferably about 0.05 parts chelating agent per hundred parts total monomer.
  • suitable chelating agents include ethylene diamine tetraacetic acid, nitrilotriacetic acid, citric acid and their ammonium, potassium and sodium salts.
  • Preferred chelating agents include those chelating agents commercially available under the name Hamp-ene from Hampshire Chemical.
  • the gel content of the latex binder is determined as the weight percentage fraction of dried polymer to total polymer that is insoluble in tetrahydrofuran at 68 * ' F after 8 hours immersion.
  • the gel content was determined using a modified version of a Baker Cell test commonly used in the styrene-butadiene latex industry.
  • the modified version of the Baker Cell test involved weighing about 0.225 ⁇ 0.001 grams of the latex to the nearest 0.1 milligram and placing the latex in a flask containing tetrahydrofuran. The flask was then stirred for eight hours and then the content of the flask was filtered through a #4 Whatman filter paper from Whatman
  • the #4 Whatman Filter Paper has a particle retention of greater than about 20 ⁇ to about 25 ⁇ .
  • 25 ml. of the filtered solution was poured from the flask to a separate container and then evaporated. The residue remaining after evaporation was then weighed. The residue remaining represents the soluble polymer in 25 ml. of filtered solution. Based upon the amount of soluble polymer the amount of insoluble polymer or gel may be determined. It has been found that this technique provides a gel measurement within about + 2 percent of the conventional Baker Cell test commonly used to determine gel content. •
  • the gel content is an indication of the extent of cross-linking present between polymer chains in the final structure of the latex binder.
  • a low gel content indicates reduced cross-linking, a lower molecular weight polymer and a lower glass transition temperature (Tg) which facilitates, it is believed, a low cure temperature for the latex binder, e.g. , capable of developing maximum tensile properties at temperatures less than about 225 degrees fahrenheit. It is believed that an additional benefit of a low gel content latex binder is improved film formation and wetting of the noncellulose fibers.
  • the polymerization of the ethylenically unsaturated monomers and polymeric surfactant occurs sequentially. The following examples are illustrative of the sequential addition of the ethylenically unsaturated monomers and polymeric surfactant to form the latex binder.
  • a charge of deionized water, polymeric surfactant and Hamp-ene were added to a reactor having a volume of about 20 gallons and having a capacity to hold about 140 lb. of latex.
  • the reactor was then evacuated with a vacuum (about 20 inches of mercury) , purged with nitrogen and heated to a desired temperature. Ammonium persulfate was then added to the reactor as about a 10% solution in deionized water.
  • a charge comprising styrene, butadiene and dodecyl mercaptan was then charged to the reactor sequentially in equal batches.
  • Table 1 is an example of a charge comprising styrene, butadiene and dodecyl mercaptan which was added to the reactor.
  • the first batch was charged to the reactor approximately 5 minutes after the ammonium persulfate was added. Additional batches were then charged to the reactor at staged intervals of about 15 or 20 minutes. The batches may be added over most any suitable number of staged intervals depending upon the amount of latex binder to be polymerized. For example, the batches may be added in equal increments from 6 stages up to 12 or more stages. After the last batch was added to the reactor the reaction was monitored until the solid level of the latex in the reactor indicated an acceptable conversion level. In instances where the rate of reaction during the hold was undesirably slow an additional amount of ammonium persulfate was charged. After the desired conversion level was reached, the latex was placed in a 60 gallon vessel and steam and vacuum stripped.
  • Bostex 362-C is an aqueous mixture of ditridecyl thiodipropionate, 4- methyl phenol and reaction product of dicyclopentadiene and isobutylene, sodium dodecylbenzene sulfonate. Representative physical properties of the preferred styrene-butadiene latex binder are shown in Table 2. Table 2
  • the measured glass transition temperature (Tg) of the latex binder is approximately equal to the glass transition temperature of the latex binder when calculated by a weight fraction method.
  • the glass transition temperature when calculated by a weight fraction method for a styrene/butadiene ratio of 40/60 is as follows:
  • W s ⁇ y weight fraction of styrene
  • Tg s ⁇ glass transition temperature of polystyrene
  • T 9B D 9l ass transition temperature of polybutadiene
  • the glass transition temperature value of a mix of cis-trans polybutadiene measured by DSC is 193 ⁇ 2.
  • the resulting latex binder was then applied to selected nonwoven non-cellulose fibers of a type as previously described using most any suitable method well known in the art such as saturation, immersion or spraying. Reference is made to the nonwoven fabric industry literature generally for detailed descriptions on the various apparatus and processing structures and conditions for applying a latex binder to fibers to form a fabric. After applying the latex binder to the nonwoven non-cellulose fibers the latex binder was air dried and then heat treated to bond the non-cellulose fibers and form a dimensionally stable nonwoven fabric.
  • the latex binder may also be dried by passing it over the surface of a plurality of steam heated cans or through a heating tunnel or oven which may use circulating hot air or infrared lamps to dry the latex binder.
  • the drying time will be a function of a number of factors such as the heat capacity of the non-cellulose fibers, the type of heating, the oven temperature, air velocities (if circulating air is used) , and the rate of passage of the non-cellulose fibers through the oven or heating tunnel.
  • the latex binder may be heat treated by heating and drying the fibers at a temperature of about 225" F (fahrenheit) for approximately 60 seconds.
  • the latex binder bonds and develops maximum tensile properties on a nonwoven non- cellulose polyester fabric at a temperature less than 230° F.
  • the heat treat rate is determined by plotting wet tensile development of a latex binder versus the mat time exposed on a metal surface heated to 225° F (Table 3) .
  • Table 3
  • Example 1 Latex Binder Wet
  • Example 2 latex Binder Wet Tensile (grams)
  • non-cellulose fibers such as polyesters, polyolefins, glass fibers and acrylic nonwovens
  • melt bonding points i.e., up to the temperature at which a physical change occurs in the fiber structure.
  • a latex binder having a heat treat temperature less than the melt bonding point of the fiber may now be used for the chemical bonding of fibers that would have melted at temperatures previously required for the curing of conventional self crosslinking and melamine formaldehyde resin containing systems.
  • Conventional self crosslinking and melamine formaldehyde resins with latices were typically used to give improved wet and dry tensile properties to a nonwoven product.
  • the weight of the fiber (F) was obtained before applying the latex binder (L) .
  • the fiber was allowed to air dry and the final weight of the fabric was obtained (F + L) .
  • the latex binder content reported below was then determined in accordance with the equation L/(F + L) x 100.
  • the basis weight of each of the neat fiber of a particular fiber (Tables 4, 5, 6 and 7) was maintained constant. Sample squares approximately 10 inches by 10 inches were cut and sorted into weight ranges having only a 0.1 gram variance per 100 square inches within a particular Table.
  • Latex Binder 37.3 35.5 34.3 charge (wt%) styrene 39.8 59.6 19.9 butadiene 59 39.8 79.4 dodecyl mercaptan 0.7 0.7 0.7
  • Latex Binder 36.9 37.1 charge (wt%) styrene 39.8 59.6 butadiene 59 39.7 dodecyl mercaptan 0.7 0.6
  • Latex Binder 385 38.3 charge (wt%) styrene 39.7 39.7 butadiene 593 593 dodecyl mercaptan 0.7 0.7
  • Tables 4-7 illustrate the performance of various nonwoven, non-cellulose fabrics having applied thereto a latex binder as previously described.
  • the nonwoven, non-cellulose fabrics exhibit acceptable tensile properties without requiring a melamine formaldehyde resin as an additive in the latex binder to increase tensile properties.
  • melamine formaldehyde resins are often difficult to mix with the latex binder, require a fairly high temperature to cure, and contribute formaldehyde to the workplace and to the end use product.
  • acceptable tensile properties are obtained in accordance with the present invention for polyester fibers, acrylic fibers, polypropylene fibers and polyethylene fibers. It is believed that similar comparisons are obtainable on other fibers such as glass fibers, polyamide fibers and the like.
  • latices in the nonwoven area are either self-crosslinking or contain a melamine formaldehyde resin to increase tensile properties to a desired level.
  • the temperature to activate the self crosslinking mechanism or the melamine formaldehyde resin reaction is the same and is approximately 280° F.
  • Cure cans and ovens are typically set at 330° F in order to obtain a preformed web temperature of 300° F for proper cure.
  • a typical cure of a self crosslinking latex develops maximum tensiles at 300° F usually in 40-50 seconds.
  • a nonwoven in accordance with the present invention obtains acceptable tensiles in about 30 to about 40 seconds, and as low as 15 seconds and at a temperature as low as 225° F.
  • the fabric In addition to improved tensile properties of the nonwoven, non-cellulose fabric, the fabric also exhibited improved resistance to heat, light and gas exposure thereby providing a more durable fabric.
  • the improved resistance to heat, light and gas exposure of the latex binder was evidenced by the addition of an anti-oxidant of a type as previously described to the emulsion shortly after polymerization.
  • an anti-oxidant of a type as previously described to the emulsion shortly after polymerization.
  • about .1 to about 3 parts anti-oxidant may be added to the dry latex, most preferably about .5 to about 1.5 parts.
  • a latex binder of a type described herein was prepared and separated into two separate batches. An anti-oxidant was added to only one of the latex binder batches. Free films of the latex binders were tested in accordance with ASTM D 1925-70 entitled “Standard Method of Test for Yellowness Index Of Plastics” published in the 1970 Annual Book of ASTM Standards.
  • FADE-O-METER (exposed to a carbon arc lamp)
  • HEAT AGE (exposed to a temperature of 200 °F)
  • GAS FADE (exposed to the combustion gas of a bunsen burner flame in a sealed chamber)
  • the latex binder in accordance with the present invention was subjected to various conditions and measured for Yellow Index on a Hunterlab Colorimeter. Light resistance was evaluated with the use of a carbon-arc fade-o-meter, heat aging was carried out in a forced air oven at 200° F and gas fade was exposed to the combustion products of a bunsen burner with a squirrel cage, holder. As shown by the Yellowing Index values provided in Table 8, the latex binder including an anti-oxidant exhibited enhanced resistance to heat, light, and gas exposure.
  • a nonwoven fabric having a latex binder including an anti-oxidant will also provide enhanced resistance to heat, light, and gas exposure and more durable fabric applications than experienced in the past with heretofore known styrene/butadiene type latices which were generally restricted to disposable applications because of their tendency to discolor and embrittle upon exposure to long periods of heat, light and gas.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Nonwoven Fabrics (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

L'invention porte sur un matériau non-tissé fait de fibres non cellulosiques liées chimiquement, comportant un agencement aléatoire des fibres non cellulosiques et un liant à base de latex sensiblement exempt de formaldéhyde, à même de renforcer des propriétés de traction maximales à des températures inférieures à celle de la liaison par fusion des fibres non cellulosiques.
PCT/US1996/005356 1995-04-24 1996-04-18 Materiau non-tisse en fibres non cellulosiques et procede de fabrication WO1996033867A1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
US08/945,544 US6034005A (en) 1996-04-18 1996-04-18 Nonwoven fabric of non-cellulose fibers and a method of manufacture
JP8532604A JPH11504398A (ja) 1995-04-24 1996-04-18 非セルローズ繊維の不織布および加工方法
EP96912868A EP0831995A4 (fr) 1995-04-24 1996-04-18 Materiau non-tisse en fibres non cellulosiques et procede de fabrication

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US42736595A 1995-04-24 1995-04-24
US08/427,365 1995-04-24

Publications (1)

Publication Number Publication Date
WO1996033867A1 true WO1996033867A1 (fr) 1996-10-31

Family

ID=23694559

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1996/005356 WO1996033867A1 (fr) 1995-04-24 1996-04-18 Materiau non-tisse en fibres non cellulosiques et procede de fabrication

Country Status (4)

Country Link
EP (1) EP0831995A4 (fr)
JP (1) JPH11504398A (fr)
CA (1) CA2218889A1 (fr)
WO (1) WO1996033867A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3329830B2 (ja) 1997-02-07 2002-09-30 オムノヴア ソリューシヨンズ インコーポレーテツド 改良された湿潤引張強さを有する、非セルロース繊維の不織布

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7879229B2 (en) 2003-10-29 2011-02-01 Zenon Technology Partnership Water treatment plant with immersed membranes
JP6100470B2 (ja) * 2012-03-27 2017-03-22 日本エイアンドエル株式会社 熱成型性を有する接着剤組成物

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5021529A (en) * 1989-09-05 1991-06-04 The B. F. Goodrich Company Formaldehyde-free, self-curing interpolymers and articles prepared therefrom
US5028655A (en) * 1987-12-15 1991-07-02 Union Oil Company Of California Fast cure, zero formaldehyde binder for cellulose
US5302446A (en) * 1992-03-30 1994-04-12 International Paper Company Two-sided skin care wipe material and method for its manufacture
US5326853A (en) * 1993-09-16 1994-07-05 Gencorp Inc. Low formaldehyde, high gel fraction latex binder

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6038415A (ja) * 1983-08-12 1985-02-28 Nippon Zeon Co Ltd 共重合体ラテツクスの製造方法

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5028655A (en) * 1987-12-15 1991-07-02 Union Oil Company Of California Fast cure, zero formaldehyde binder for cellulose
US5021529A (en) * 1989-09-05 1991-06-04 The B. F. Goodrich Company Formaldehyde-free, self-curing interpolymers and articles prepared therefrom
US5302446A (en) * 1992-03-30 1994-04-12 International Paper Company Two-sided skin care wipe material and method for its manufacture
US5326853A (en) * 1993-09-16 1994-07-05 Gencorp Inc. Low formaldehyde, high gel fraction latex binder

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP0831995A4 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3329830B2 (ja) 1997-02-07 2002-09-30 オムノヴア ソリューシヨンズ インコーポレーテツド 改良された湿潤引張強さを有する、非セルロース繊維の不織布

Also Published As

Publication number Publication date
EP0831995A4 (fr) 1998-08-26
JPH11504398A (ja) 1999-04-20
EP0831995A1 (fr) 1998-04-01
CA2218889A1 (fr) 1996-10-31

Similar Documents

Publication Publication Date Title
US5021529A (en) Formaldehyde-free, self-curing interpolymers and articles prepared therefrom
US6034005A (en) Nonwoven fabric of non-cellulose fibers and a method of manufacture
US6300409B2 (en) Polymer compositions
EP0651088B1 (fr) Procédé pour renforcer des substrats cellulosiques
DE60304361T2 (de) Wässrige formaldehydfreie zusammensetzung sowie sie enthaltende glasfaserisolierung
US20030105190A1 (en) Latex binder for nonwoven fibers and article made therewith
US4406660A (en) Non woven fabrics suitable for diaper and diaper coverstock
US5520997A (en) Formaldehyde-free latex for use as a binder or coating
US6425978B1 (en) Latex binder for nonwoven fibers and article made therewith
JPH09291482A (ja) ラテックス
US4743498A (en) Emulsion adhesive
EP0302588A2 (fr) Liant pour étoffes non tissées ne dégageant pas de formaldéhyde
US3546059A (en) Composite fibrous article bonded with novel copolymer compositions and method of making same
US3125462A (en) Textile fabrics treated with ethylene-
GB2145097A (en) Addition of resins to latex bonded non-woven fabrics for improved strength
US5629047A (en) Method of making functionalized styrene butadiene type latex binders
DE2811071C2 (de) Latex eines Copolymeren
EP0831995A1 (fr) Materiau non-tisse en fibres non cellulosiques et procede de fabrication
EP0012033B2 (fr) Articles non-tissés et leur préparation
US5824610A (en) Nonwoven fabric of non-cellulose fibers having improved water tensile properties
US6372675B1 (en) Nonwoven fabric non-cellulose fibers having improved wet tensile strength
US3925293A (en) Low-temperature curable latices of vinyl and acrylic monomers
CA2279913C (fr) Non-tisse de fibres non cellulosiques a resistance accrue en milieu humide
WO1992008835A1 (fr) Ameliorations relatives a des matieres fibreuses non-tissees
KR100365544B1 (ko) 향상된 습윤 인장 강도를 갖는 비-셀룰로오스 섬유의 부직포

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A1

Designated state(s): CA JP US

AL Designated countries for regional patents

Kind code of ref document: A1

Designated state(s): AT BE CH DE DK ES FI FR GB GR IE IT LU MC NL PT SE

DFPE Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101)
121 Ep: the epo has been informed by wipo that ep was designated in this application
ENP Entry into the national phase

Ref document number: 2218889

Country of ref document: CA

Ref country code: CA

Ref document number: 2218889

Kind code of ref document: A

Format of ref document f/p: F

ENP Entry into the national phase

Ref country code: JP

Ref document number: 1996 532604

Kind code of ref document: A

Format of ref document f/p: F

WWE Wipo information: entry into national phase

Ref document number: 08945544

Country of ref document: US

WWE Wipo information: entry into national phase

Ref document number: 1996912868

Country of ref document: EP

WWP Wipo information: published in national office

Ref document number: 1996912868

Country of ref document: EP

WWW Wipo information: withdrawn in national office

Ref document number: 1996912868

Country of ref document: EP