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WO1996018295A1 - Composition pesticide et procede pour combattre la mouche mediterraneenne des fruits et la mouche orientale des fruits - Google Patents

Composition pesticide et procede pour combattre la mouche mediterraneenne des fruits et la mouche orientale des fruits Download PDF

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Publication number
WO1996018295A1
WO1996018295A1 PCT/US1995/015962 US9515962W WO9618295A1 WO 1996018295 A1 WO1996018295 A1 WO 1996018295A1 US 9515962 W US9515962 W US 9515962W WO 9618295 A1 WO9618295 A1 WO 9618295A1
Authority
WO
WIPO (PCT)
Prior art keywords
composition
fly
fruit fly
flies
fruit
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US1995/015962
Other languages
English (en)
Other versions
WO1996018295A9 (fr
Inventor
Nicanor J. Liquido
Roy T. Cunningham
James R. Heintz
John P. Spencer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Photodye International Inc
US Department of Agriculture USDA
US Department of Health and Human Services
Original Assignee
Photodye International Inc
US Department of Agriculture USDA
US Department of Health and Human Services
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US08/414,402 external-priority patent/US5728394A/en
Application filed by Photodye International Inc, US Department of Agriculture USDA, US Department of Health and Human Services filed Critical Photodye International Inc
Priority to AU45964/96A priority Critical patent/AU705515B2/en
Priority to BR9510021A priority patent/BR9510021A/pt
Priority to EP95944072A priority patent/EP0797385A4/fr
Publication of WO1996018295A1 publication Critical patent/WO1996018295A1/fr
Publication of WO1996018295A9 publication Critical patent/WO1996018295A9/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N61/00Biocides, pest repellants or attractants, or plant growth regulators containing substances of unknown or undetermined composition, e.g. substances characterised only by the mode of action
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/002Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing a foodstuff as carrier or diluent, i.e. baits
    • A01N25/006Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing a foodstuff as carrier or diluent, i.e. baits insecticidal
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/14Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
    • A01N43/16Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system

Definitions

  • the fruit flies of the family Tephritidae include several species tha
  • the currently used malathion bai system for control of Mediterranean fruit flies contains as the main
  • bait station or as bait spray component which target Mediterranean fruit
  • a halogenated xanthene such as phloxine B or a mixture of a halogenated xanthene and uranine.
  • fly populations namely malathion, have posed health risks to humans
  • malathion upon contact, malathion is highly potent as a poison, both to insects an
  • the present invention on the other hand, i directed to an active ingredient which is toxic to the targeted
  • toxicity of malathion is 62.5 times greater than that of phloxine B as
  • dye ingredient of the present invention is not harmful unless ingested.
  • the active xanthene dye component is N-(2-aminoethyl)-2-aminoethyl-N-(2-aminoethyl)-2-aminoethyl-N-(2-aminoethyl)-2-aminoethyl-N-(2-aminoethyl)-2-aminoethyl-N-(2-aminoethyl)-2-aminoethyl-N-(2-aminoethyl)-2-aminoethyl-N-(2-aminoethyl)-2-aminoethyl-N-(2-aminoethyl)-2-aminoethyl-N-(2-aminoethyl)-2-aminoethyl-N-(2-aminoethyl)-2-aminoethyl-N-(2-aminoethyl)-2-aminoethyl-N
  • Another aspect of the invention is use of phloxine B in combinatio
  • Uranine is registered as D & C Yellow Dye No. 8 for use a
  • the present insecticidal composition further contemplates th
  • an attractant bait which has the following properties: i
  • Attractant baits include (1 ) carbohydrate sugar source, for example, sugars such as sucrose or
  • fructose or sugar substrates such as molasses or honey
  • sugar substrates such as molasses or honey
  • proteinaceous food bait such as hydrolyzed protein (either by acid
  • composition may
  • anti-foaming agents optionally include anti-foaming agents and other adjuvants to increase the
  • insects and in particular the Mediterranean or oriental fruit fly and other
  • a still further object lies in the provisions of a pesticide which has
  • a still further object of the present invention lies in the provision of
  • a yet further object of the present invention resides in the provision of an insecticidal composition which contains no feeding inhibitors th
  • insecticidal composition which incorporates a bait that stimulates feedin
  • Figure 1 shows percent mortality of adult Mediterranean fruit flie
  • FIG. 1 shows the functional relationship between concentratio
  • FIG. 3 shows the functional relationship between concentratio
  • FIG. 4 shows the functional relationship between concentratio
  • FIGs 5A and 5B show percent mortality of adult oriental fruit fly
  • Figure 6 shows percent mortality of wild oriental fruit fly adults as
  • Figure 7 shows the increase in mortality over time of wild oriental
  • Figure 8 shows the increase in mortality over time of wild oriental
  • Uranine chemically
  • baits in sprays that are used in eradication or suppressing many tephritid
  • composition includes an attractant bait which attracts the target insect
  • Attractant baits include 1 ) a
  • carbohydrate sugar source for example, sugars such as sucrose or
  • fructose or complex sugar substrates such as molasses or honey
  • a proteinaceous food bait such as hydrolyzed protein (either by aci
  • hydrolyzed protein sources are the commerciall
  • Nu-LureTM (44% corn gluten meal, hydrolyzed, an
  • the dye and bait formulation can be used in dispensers set out i
  • the formulation may be applied by various types
  • An exemplary formulation is:
  • photodye from 0.1 to 1 % of total formulation hydrolyzed protein from 35.0 to 99.0% of total formulatio sugar source from 0.0 to 20% of total formulation added water from 0.0 to 70% of total formulation O 96/18295 PCI7US95/ 15962
  • the total formulation should be applied so as to obtain good spray
  • Another exemplary formulation is:
  • photodye from 0.1 to 1 % of total formulation sugar source from 5 to 20% in water
  • bait is suitable for control of oriental fruit flies in male annihilation
  • formulation and use pattern is chosen based on various factors including
  • An exemplary formulation is:
  • Min-U-Gel 400 from 20 to 25 % of total formulation (attapugite clay)
  • the total formulation is applied as about 10 to 1 5 gram globs on tree trunks, telephone poles, etc. at a rate of about 600 spots per squar
  • Another exemplary formulation is:
  • This liquid formulation is adsorbed into various solid carriers such a
  • liquid formulation is from about 20 to 100 lbs per square mil
  • This liquid formulation can also be sprayed without any thickener
  • dilutions consisting of 0.001 %, 0.01 %, 0.1 %, 1 .0 and 10.0% of 1 :1 molar mixture of phloxine B (829 g per mole) and uranin
  • Each feeding chamber had either 20 males or 20 females
  • each feeding chamber was kept 10 cm below two high intensity
  • flies were provided with water and a diet consisting of sucrose, protei
  • Fig. 1 shows the Variation in Mediterranean fruit fly adul
  • Phloxine B and Uranine were mixed in 10% Molasses
  • Control flies were fed with 10% molasses. Based o
  • the LC 50 was 1 .7 x 1 0" 3 M fo
  • Phloxine B and Uranine Mixed in 1 % NuLure. Various dilution
  • protein bait preparation 44% corn gluten meal, hydrolyzed and 56% iner
  • Test adults were not starved (i.e. 24 h prior to their use i
  • Figure 3 shows that when the food carrier for dye was 1 % NuLur
  • the LC50 was 1.6 x 10 _ 3 M for. females. However, the LT 50 at 1.6
  • test adults were provided with a feeding choice of tw
  • oriental fruit fly adults were reduced by 50% in the treated field after th
  • feeding chamber had either 20 males or 20 females.
  • Adult feeding with dye-stock mixtures commenced at 08:00 h and terminated at 12:00 h, providing a 4-h feeding duration.
  • At the onset of feeding each feeding chamber was kept 10 cm below two hig
  • FIGS 5 A and 5B show the variation in oriental fruit fly adult mortality due to
  • Methyl Eugenol as compared to Methyl Eugenol alone or Methyl
  • Treatment 2 additionally, had a
  • Figure 6 shows the average mortality in the three treatments over time. Ther was a high initial rate of mortality in the treatment including the dog collar strip. Two hours after exposure to full sunlight, there was greater than 98% mortality in contain
  • methyl eugenol were set out in a citrus orchard known to have a wild population of
  • Figure 7 shows the increase in mortality overtime in the 4 treatments. By 30 minutes after the exposure of the chambers to full daylight, over 66% of the flies in th
  • Figure 8 shows the increase in mortality over time in the 4 treatments. After 30

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Dentistry (AREA)
  • Engineering & Computer Science (AREA)
  • Plant Pathology (AREA)
  • Agronomy & Crop Science (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Insects & Arthropods (AREA)
  • Food Science & Technology (AREA)
  • Toxicology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

L'invention concerne une composition et un procédé pour éradiquer ou supprimer une population de mouches méditerranéennes des fruits ou de mouches orientales des fruits, sensiblement sans danger pour l'homme, l'agriculture et les animaux vivants non ciblés. La composition insecticide contient au moins un colorant photoactif qui est de préférence un mélange de Phloxine B et d'uranine. On assure l'ingestion de la composition par la mouche visée en pulvérisant ou en appliquant l'insecticide à un emplacement où la mouche se nourrit. Lorsque le composant colorant photoactif de la composition est ingéré par les mouches méditerranéennes des fruits ou les mouches orientales des fruits, il provoque la pénétration dans le corps de la mouche d'une quantité de photons suffisante pour avoir un effet toxique.
PCT/US1995/015962 1994-12-12 1995-12-12 Composition pesticide et procede pour combattre la mouche mediterraneenne des fruits et la mouche orientale des fruits Ceased WO1996018295A1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
AU45964/96A AU705515B2 (en) 1994-12-12 1995-12-12 Pesticide composition and method for controlling the mediterranean fruit fly and the oriental fruit fly
BR9510021A BR9510021A (pt) 1994-12-12 1995-12-12 Composição pesticida e processo para controle de mosca de fruta mediterrânea e a mosca de fruta oriental
EP95944072A EP0797385A4 (fr) 1994-12-12 1995-12-12 Composition pesticide et procede pour combattre la mouche mediterraneenne des fruits et la mouche orientale des fruits

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US35372694A 1994-12-12 1994-12-12
US08/353,726 1994-12-12
US08/414,402 US5728394A (en) 1994-12-12 1995-03-31 Pesticide composition and method for controlling the oriental fruit fly
US08/414,402 1995-03-31

Publications (2)

Publication Number Publication Date
WO1996018295A1 true WO1996018295A1 (fr) 1996-06-20
WO1996018295A9 WO1996018295A9 (fr) 1996-08-29

Family

ID=26998078

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1995/015962 Ceased WO1996018295A1 (fr) 1994-12-12 1995-12-12 Composition pesticide et procede pour combattre la mouche mediterraneenne des fruits et la mouche orientale des fruits

Country Status (5)

Country Link
EP (1) EP0797385A4 (fr)
AU (1) AU705515B2 (fr)
BR (1) BR9510021A (fr)
IL (1) IL116343A (fr)
WO (1) WO1996018295A1 (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1997029637A1 (fr) * 1996-02-19 1997-08-21 Schaffer, Moshe Pesticide contenant un photosensibilisant et un agent d'attraction chimique
WO2007002960A3 (fr) * 2005-06-28 2007-05-24 Schalk Francois Mouton Composition et procede de lutte contre des parasites

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4647578A (en) * 1983-12-02 1987-03-03 Sterling Drug Inc. Phototoxic insecticidal compositions and method of use thereof
US4855133A (en) * 1985-07-18 1989-08-08 Earth Chemical Company, Limited Composition for attracting flies

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3846557A (en) * 1972-05-26 1974-11-05 Univ California Bait for synanthropic flies and method for making same
US4160824A (en) * 1975-08-16 1979-07-10 Ajinomoto Co., Inc. Insect attractive compositions
US4320140A (en) * 1980-10-09 1982-03-16 Sterling Drug Inc. Synergistic insecticidal compositions

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4647578A (en) * 1983-12-02 1987-03-03 Sterling Drug Inc. Phototoxic insecticidal compositions and method of use thereof
US4855133A (en) * 1985-07-18 1989-08-08 Earth Chemical Company, Limited Composition for attracting flies

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP0797385A4 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1997029637A1 (fr) * 1996-02-19 1997-08-21 Schaffer, Moshe Pesticide contenant un photosensibilisant et un agent d'attraction chimique
US6410567B1 (en) 1996-02-19 2002-06-25 Guilio Jori Pesticide containing a photosensitizer and an attractant
WO2007002960A3 (fr) * 2005-06-28 2007-05-24 Schalk Francois Mouton Composition et procede de lutte contre des parasites

Also Published As

Publication number Publication date
MX9704337A (es) 1998-07-31
EP0797385A1 (fr) 1997-10-01
AU4596496A (en) 1996-07-03
BR9510021A (pt) 1998-11-03
EP0797385A4 (fr) 1998-04-29
IL116343A0 (en) 1996-03-31
AU705515B2 (en) 1999-05-27
IL116343A (en) 2000-02-29

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