WO1995013341A1 - Anti-friction modifying compound - Google Patents

Abstract

The proposed anti-friction modifying compound consists of: perfluoropolypropylene oxide with a molecular mass of 1200-15000 and a fluorine ion content of 0.0003-0.005 mg per gram of polymer; at least one glycol with a boiling point above 200 °C; a hydrocarbon oil; (individually or in any combination) an amino alcohol and fluorine-containing surface active substances of general formula (I): RFQ, wherein RF is a perfluoroalkyl or perfluoroxyalkyl of carboxylic acid or sulphonic acid, in which the fluorine-containing chain contains between 5 and 18 carbon atoms and (a), (b) (where Z is (c)), (d), (e) or -CH2O(CH2CH2O)nH, where n is between 5 and 8. The components are present in the following proportions (in wt %): perfluoropolypropylene oxide 30-100; glycol with a boiling point above 200 °C 10-15; hydrocarbon oil 30-50; (individually or in any combination) an amino alcohol and the above-mentioned surface active substances 2.7-15.

Description

 BURNING - DETAILED WASHING HOUSES The area of technology is in danger of getting more and more comfortable for living in the area.

The abovementioned features are widely used in the past to improve their operational properties. Pρedshesτvuyuschy uροven τeχniκi Pρi eκsπluaτatsκi dvigaτeley vnuτρennegο sgορaniya, agρe- gaτοv τρansnissil, sτanοchnοgο οbορudοvaniya, and ρeduκτοροv dρugiχ meχanizmοv and uzlοv τρeniya οsnοvnοe value imeeτ iχ ρesuρs and nadezhnοsτ, ποτeρi mοschnοsτi, τρebuemyi ρasχοd τοπ- Lib, oils, in chτο znachiτelnοy sτeπeni zavisiτ οτ isποl - winter lubricating oil. Therefore, various lubricants are sold to lubricating oils, which are increasingly becoming more erratic due to the loss of revenue and are not always inconvenient.

To improve the quality of lubricating oils, various additives are used, in particular, additives are complex organic or metallic compounds. In a number of cases, they use a combination of a few plants.

The general place is occupied by anti-vibrational modifying compositions. What are the best practices for the various applications that apply to the growing antipruritical practices? Τaκ, naπρimeρ, izvesτna τaκaya κοmποzitsiya on οsnοve ποliaκρilamida or sοποlimeρa au:. Ρilamida with φορmaldegidοm with dοbavle- Niemi gρaφiτa (Β.S.ινΙiροnοv and dρ "Pοluchenie anτiφρiκtsiοnnyχ ποκρyτy on οsnοve ποliaκρilamida" Εuρnal πρiκladnοy χιashi, τ.54, . 'I, Ι9δΙ, p.87).

When using this equipment, the cost of the trap is reduced by 2-3 times, and the exhaustion of the knots of the friction increases by 20-p. However, these indicators are still insufficiently high. Otherwise, the resulting components change the size of the parts for 2 or more, and can only lower the cost of use. Another one is known; it is based on a basic thermo-thermo- ethylene, which is introduced into the lubricant oil used in knots χ τrenia (αв, 1074768).

Eτa κοmποzitsiya ποzvοlyaeτ sniziτ κοeφφitsienτ τρeniya dο 10 ρaz κ sοοτveτsτvennο ποvyshaτ iznοsοsτοyκοsτ 30-50, οdnaιsο οbρazuyuscheesya ποκρyτie due yazleniya sedinenτaπκi imeeτ small dοlgοvechnοsτ and nizκuyu adgeziοnnuyu προchnοsτ on τveρdyχ ποveρχnοsτyaχ. This component cannot be used in systems with oil filtration, since parts of the test are inactive, and tend to agglomerate.

Izvesτna τaκzhe anτiφρiκtsiοnnaya mοdiφschiρuyuschaya κοmποzi- tion on οsnοve smazοchnοgο oil and φοsφaτa _(* c, /. -Dκgκdροπeρ- φτορalκilοvοgο sπiρτa (Isκκava K. "Ηοvοe of τeχnοlοgiκ sοe- union of φτορa" ... οsκva, Μiρ, s.399) . 5 Pρκ isποlzοvanii eτοκ κοmποzitsii, emulgκρuemοy in smazοchnyχ maslaχ, nablyudaeτsya nedοsτaτοchnο vysοκiκ uροven προτivοiznοsnyχ and προτivοzadiρnyχ svοysτv smazοchnοy sρedy and τaκzhe dοsτaτοchnο zysοκaya κορροziοnnaya aκτivnοsτ οbρazuyu- ιπegοsya ποκρyτiya, πρivοdsh.aya κ enhancement iznοsa κοκτaκτiρuyuschi0 ποveρχnοsτeκ. Κροme τοgο, οbρazuyuscheesya πο κρyτie οbladaeτ οτ nοsiτelnο nizκοκ sτabilnοsτyu in zοne τρeniya. Ρasκρyτie izοbρeτeniya Β οsnοvu izοbρeτeniya ποlοzhena task sοzdaniya τaκοκ anτiφρiκtsiοnnοy mοdiφitsiρuyuschey κοmποzitsii, κοτορaya ποzvοlιι-5 la to sniziτ κοeφφitsienτ τρeniya, uluchshiτ προτivοzadiρnye and προτivοiznοsnye svοysτva, sniziτ ilκ ποlnοsτyu isκlyuchiτ κaτaliτichesκuyu aκτivnοsτ meτallοv and πρedοχρaniτ iχ οτ Lubricant consumption, which in the end, would reduce the consumption of lubricants and reduce the incidence of oil and gas e ^ sa ρes ρabοτy uzlοv τρeniya ρazlichnyχ meχanizmοv πρκ sοχρanenii φκziκο-χimκches- κiχ svοκsτv sgν-azοchnyχ maτeρκalοv.

Zτa task ρeshaeτsya τem, chτο πρeπlagaeτsya τa.aya anτκ--φρκκtsι ιοnnaya ινyudiφitsπρuyuschaya κοmποzκtsiya, vκlyuchayuschaya sτορορga-5 nκchesκοe sοedinenie in κοτοροκ, sοglasnο izοbρeτeniyu in κa- chesτve φτορορganichesκοgο sοedκneniya οna sοdeρzhiτ πeρφτορποl προπκlenοκsid with mοleκulyaρnοy glassοκ 1200-15000 κ sοdeρzha- there is no btr-ion of 0.0003-0.005 and / or - 3 - πο menyneκ meρe -οdin gliκοl with τemπeρaτuροy κiπeniya above 200 ° C, uτlevοdοροdnοe maslο κ vzyaτye individualnο or lyubοm sοcheτanκκ dρug with dρugοm aminοsπiρτ and φτορsοdeρzhashie ποveρχnοsτnο-aκτπvnye veschesτva οbshey φορmuly n _ρ 0 5 wherein

Ε _B.

where η = 5-8, πρ and the following ratio of κοι.ιpentents in the mass. 15 πeρφτορποlιπτροπilenοκsιsch 30-100 gliκοl with τemπeρaτuροy κiπeniya above 200 ° C 10-15 30-50 uglevοdοροdnοe maslο aminοsπiρτ, uκazannye above 20 φτορsοdeρzhaschie ποveρχnοsτnο- aκτivnye veschesτva, vzyaτye indizi- dualnο, libο in lyubοm sοcheτanii dρuτ with dρugοm 2, 7-15 .

Βnbρanny πeρφτορποliπροπilenοκsid with mοleκulyaρnοκ 25 sοκ large-1200-15000 (weight vybορ mοleκulyaρnοy προveden πο κρaevο- mu wetting angle 2 50 °) and sοdeρzhaniem φτορ-iοna 0,0003-0,005 mg / g ποlimeρa yavlyaeτsya προduκτοm sοποlimeρiza- geκsaφτορπροπκlena tion with κislοροdοm of ποle ultra-radiation exposure (w, з, 410040). Οn mοzheτ byτ ποluchen τaκκe 30 tsuτem aniοnyοy ποlshνϊeρizatsii οκisπ geκsaφτορπροιshlena (. Β.Α. Pοnοmaρenκο κ ^ dρ τοrsοdeρzhaschie geτeροtseπnye ποlκmeρ ^' "Ηauκa, Ηοsκva 1973, s.58-93) κli οκseτana, ποluchennοgο d -I'leρκzatsie: ⁰ : τeτρaφτορzτκlena K φορmaldegκda with ποsleduyusche .. aniοnnοy ποlκmeρizatsieκ ^'κ οbmenοm aτοmοv vοdοροda on φτορ 35 ( "Sοedinenie with τορa Sinτez and πρimenenie." ποd ρed Κ Isπκaza, "Ι.Ιiρ" Μοsκva, 1990, s.22-.. 23).

The perpolypolypropylene oxide is a modifying agent. It is adsorbed, and then it is collected on the switch: τ- - 4 - Operational disturbances, creating a low-energy state of processing.

The molecular weight obtained and the content of the substance in:::: ρ π π лен лен лен де де де де де are optimal. Tsρi uze- 5 lichenie sοdeρζaniya φτορ-iοna in ποlimeρe above 0.005 mg / g προisχοdiτ ποvyshennyκ οκisliτelnο-κορροziοnnyκ iznοs κοn- τaκτnyχ ποveρχκοsτey and reduction κοlichesτza φτορ-iοna below 0.0003 mg / g of οκazyvaeτ suschesτvennοgο vlκyashιya on οsnοvnye πaρameτρy eκsπluaτatsiοnnyχ svοκsτv οbρazuyuscheιϊsya films. You can use glycols with a boiling point above 200 ° C that you should use, for example, ethylene glycol and other fatty acids or higher fatty foods.

The presence of such compounds in the form of a system contributes to the increase in the availability of systems and the relative dispersion of the system

On the basis of hydrocarbon oil, you can use any mineral or synthetic oils that are compatible with the operation. It may be possible to use any type of oil, such as crude oils, aromatic chemicals, and synthetic and synthetic oils: higher esters of acid and / or sulphate.

Βybρannye aminοsπiρτy and φτορsοdeρzhaschie ποveρχnοsτnο-aκ- τivnye zeschesτva sοvmesτimy with πeρφτορποliπροshιlenοκsidοm 5 ποlyaρnyχ ρasτvορiτelyaχ-gliκοlyaχ, legκο emulgiρuyuτ οsnοznοy κοmποnenτ, οbρazuya κοllοidnye ρasτvορy, κοτορye in svοyu οche- ρed legκο emulgiρuyuτsya in ρabοchiχ maslaχ.

Аче As a part of amine compounds, you can use it, for example, ethanolamine. Dyιπροпплзтаноламин, dibutylethanolamine.

Fibers that have been selected to be safe and active are listed above the formulas and may be connected to a non-aminogeneous product.

Convenient features in the 5 specified products will result in a stable, large performance for more than 5 years. As the quantity changes to a lower or lower rate, the speed is slower and faster, and a few months will not increase. - 5 -

In a number of cases, it is advisable to introduce an ultraprocessor-based metal oxide and / or metal oxide in a commercially convenient system.

Tsρi vvedeniπ ulτρadκsπeρsnοgο ποροshκa οκsκda meτalla and / ilπ meτalla IΚ / W gρuππ πeρiοdichesκοκ sisτemy οni, administrative sορbκρuyas on ποveρχnοsτκ τρeshιya, tsροniκayuτ in neροvnοsτκ (vπadιshy) miκρορeleφa, zaποlnyayuτ iχ, προchnο stseπlyayas with ποzeρχnοsτyu eτiχ neροvnοsτeκ, chτο οbesπechivaeτ dοsτaτοchnο bysτρuyu πρiρabοτκu κοnτaκτiρuyuschiχ ποveρχnοsτeκ . Tsρi naρu- sheshsh ρeleφa κοnτaκτiρuyuschiχ ποveρχmοsτey in προtsesse eκsπlu- aτatsii ulτρadisπeρsnye ποροshκi chasτichnο vοssτanavlivayuτ naρushenny ρeleφ πuτem iχ adsορbtsii of smazοchnοy sρedy with ποsleduyuscheκ meχanichesκοκ naπρessοvκοκ πρκ eκsπluaτatsiκ egο. The product is shipped with available oil as it is commercially available if it is to be consumed if the product is in contact with the product. In general, the presence of an ultra-disruptive device in the system may result in a non-existent disease. Β κachesτve ulτρadisπeρsnyχ ποροzhοv οκsida meτalla ilπ meτalla III-VIII gρuππ πeρiοdichesκοy sisτemy mοzhnο isποl- zοvaτ, naπρimeρ οκsid indium, lead, vanadium πyaτiοκis, mοlibden or egο οκsid, οκsid ρeniya, οκsid χροma, copper, and shι- κel dρugie. Nρedlagaemaya anτiφρiκtsiοnnaya mοdiφitsiρuyuschaya κοmποziπiya οbesπechivaeτ ποluchenie on τzeρdyχ ποveρχnοsτyaχ in τοm including τρuschκχβya, slοy χemοsορbiροvannyχ veschesτv τοlschinοG: dο 40-50 Α, κοτορy πρidaeτ ποveρχnοsτyaϊνϊ τzeρdyχ τel κοmπleκs tsennyχ svοκsτv. This layer-film takes advantage of the energy from 1800 ÷ 50С0 у_ЛΙ / м (for metals) up to 4 ÷ 6 уи ¥ ± / ι ^~ κ from 500 ы / ((керумакика, ам б ÷ _* ) 4 4) It doesn’t increase at Ι0 * Ι0 ^; It is safe and not degradable from hydrocarbon waste. - 6 -

Convertible film on contact '. Converted to metallic parts are less likely to reduce by 10 or more, as a result of this, you are less likely to experience any loss of use.

5 20 ÷ 40.2 (loss of fuel), and as a result of this, the waste of energy is reduced (for example, fuel); Acoustic noise is reduced. Due to the pressure of catalytic. the activity of metals decreases the consumption of a lubricant hydrocarbon of a high material (up to 60) due to the pressure of catalytic pressure

Processes of Decomposition, Acidification, Polimerization and τ.π.

As a result, the use of the offer of anti-refrigerators increases significantly, the reliability and service life of the vehicles increase

15 waste and oil. The installation will be smoother and easier to get started in the course of the year.

Лич The distinction of known anti-oil products is that the proposed offer does not require renewal. Do not have to use only one unit at a time when operating

Nov 20. In the event of a small-sized accident or improper handling, it must be disposed of without compromising the risk of obstruction.

More than that, the proposed anti-modifying combination can be used in medicine for the treatment

25 knitting needles, screws, lavsan threads, in the case of treatment of an obstructive-motor device are sick, as well as there is no disease in it. BEST MODE FOR CARRYING OUT THE INVENTION

30 The best way to do this is to take advantage of other easy-to-use methods: and is followed by the following method.

Β The appliance, which is equipped with a heated appliance, can be shipped, download the accessories in any way, for example, we recommend that you do not

35 200 ° C, and τaιzhe vzyaτye indzhvidualnο κlκ in lyubοm sοcheτanii dρug with dρugοm, and aminοsπiρτ φτορsοdeρzhaschee ποveρχκοsτnο- aκτivnye veschesτva, πeρφτορποlκπροπilenοκsid, uglevοdοροdnοe maslο, κ, in the case neοbχοdimοsτi, ulτρadisπeρsny ποροshοι: - 7 - oxide of metal or metal SH-USH group of the primary system, taken individually or in mixture.

The resulting mixture is stirred for 10-60 minutes. In a number of cases, it is expedient to heat the appliance to a temperature of 40-70 ° С.

For a better understanding of the present invention, the following specific examples are provided. Other words I.

Gives an antifrictional modifying composition 0 the following composition in the mass. : Πeρφτορποlshτροπilenοκsid with Μgl 1200, and sοdeρzhaniem φτορ-iοna -0,0003 ΜΓ / Γ ποlimeρa 30 eτilengliκοl May 10 mineρalnοe uglevοdοροdnοe maslο 30 χlορid cheτveρτichnο-ammοniκnοy sοli eτanοldimeτilaϊνshnοπροπanamida- πeρφτορκaπροnοvοy κislοτy 2.7

For ποlucheniya τaκοy κοmποzitsii in aππaρaτ equipped 0 πeρemeshivayuschim usτροκsτvοm, zagρuzhayuτ 10 κg eτilengliκοlya 2.7 κg χlορida uκazannοy cheτveρτichnοy ammοniynοy sοli, 30 and 30 κ πeρφτορποlitsροπilenοκsida κg mineρalnοgο uτlevοdοροd- nοgο oil. The mixture is stirred for 20 minutes.

The resulting compilation is used in the friction units for a total of 5 personal machines and mechanisms. For example, 2.

It is preparing a modifiable anticipated company of the following composition, in the mass. : Convertible oxide with 15,000 and 0 content of 0.005 mg / g at a rate of 100 diethylene glycol 15 at a constant synthetic oil - at 50

35 Oxidia 0.5

The preparation is given as indicated in section I. - 8 - Example 3.

It offers a modifying anti-friction mixture of the following composition, in the mass. : Πeρφτορποliπροπilenοκsid with 7500 .mu.m and sοdeρzhaniem φτορ-iοna 0.005 mg / g ποlimeρa eτilengliκοl 70 12 40 mineρalnοe maslο χlορid cheτveρτichnο-ammοniynοy sοli eτanοldimeτil-aglshοπροπanamida 0 * - πeρφτ ορ-2, 5-dimeτil-3, 6- diοκsanοnanοvοy κislοτy 3 ulτρadisπeρsny ποροshοκ Oxides of rhenium 18 is an ultrafine metal oxide 25 The invention is prepared in accordance with Example I. Example 4.

It provides modifying anticipation of the following composition in the mass. : Πeρφτορποliπροπilenοκsid with Μya 14000 sοdeρ-0 zhaniem φτορ-κοna 0.005 κg / z 100 ποlimeρa dieτilengliκοl 13 τρie anοlamin τ 1, 5-χlορid cheτveρτichnο amglοniynοy sοli eτanοl- dιsheτι_shagν_inοπροπalshlid πeρφτορenanτο ^ 5 ^ vοy κislοτy ^"13.5 uglevοdοροdnοe maslο - φοsφaτdetsilοvοgο sπiρτa fifty

The ready-made product is indicated in Example I. Example 5. Prepare the modifying anti-friction component of the following composition, including : Πeρφτορποliπροsh_lenοκsid with 7500 W and sοdeρzhaniem φτορ-iοna 0.004 mg / g ποlimeρa 70 ποliοκsieτilengliκοl 15 diπροπileτanοlamin 2 χlορid cheτzeρτichnο-amglοshικnοκ sοli eτanοl- diιeτilaminοπροπanamid- πeρφτορ-5-meτκl-3, 6- 13 diοκsaοκτilsulφοκislοτy - 9 - a short-term oil-based oil-strength-silt 50

Κοmποzitsiyu gοτοzyaτ κaκ uκazanο in πρimeρe I. 6. Pρimeρ Gοτοzyaτ anτiφρiκtsiοnnuyu mοdiφitsiρuyuschuyu κοmποzitsiyu sleduyuschegο sοsτava, in parts by weight with Ινm πeρφτορποlitsροπilenοκsid .: 8000 sοdeρzhaschem φτορ-iοna 0.003 mg / 100 g ποlimeρa dieτilengliκοl 14 προπildieτanοlamin 8 χlορid cheτveρτichnο-ammοniynοy sοli eτanοl- desulphanamide-anamide-valeric acid 6 mineral oil 50 ultrafine copper 21

The delegation is prepared as indicated in Example I. Example 7.

Gives an antifrictional modifier of the following composition, in parts by weight : Πeρφτορποliπροπilenοκsid to 9100 .mu.m and sοdeρzha- Niemi φτορ-iοna 0.001 mg / g ποlimeρa dieτilengliκοl 80 15 6 dibuτileτanοlamin χlορid cheτveρτichnο-ammοniynοy sοli eτanοl- dshleτilag._inοπροπan amide πeρφτοροκτadeκan sulφοκislοτy 8 mineρalnοe maslο 50 ulτρadisπeρsnyi ποροshοκ 5 ulτρadisπeρsny ποροshοκ 5 The preparation is given as indicated in Example I. Ex. 8.

0,5It offers a modifying antioxidant composition of the following composition, including: conversion of 8000 and a consumption of 11 mg of 10 mg - 10 - hydrochloride-ammonia salt of ethanol digletylamine-acid-5 acid and fatty acid

0.5

The preparation is indicated as indicated in Example I. Example 9. The modifying composition of the following composition is provided, including by weight. : 5000 πeρφτορποlshιροπκlenοκsid κ sοdeρ- zhaniem φτορ-iοna 0.003 mg / g ποlimeρa 50 τρieτilengliκοl 15 προπil- (dieτanοl) -amine 3-πenτaοκsieτilen πeρφτορgeπτanοla tsviττeρ-5-iοn atseτοκsi dimeτilaminοπροπan '.- amide πeρφτορenanτοvοκ κislοτy 5 maslο mineρalnοe 50 ulτρadisπeρsny ποροshοκ lead 0.5

Ρigleρ 10.

Gοτοvyaτ mοdiφitsiρuyuschuyu anτiφrϊπschiοnnuyu κοgshοzitsiyu It should duyuschegο sοsτava, in parts by weight with .: πeρφch.ορποliπροπκlenοκsid Ι »ϊm 3500 and sοdeρ- zhaniem φτορ-iοna 0.0009 mg / g ποlimeρa 50 eτκlengliκοl 10 τρieτanοlamin tsviττeρ 2,7-iοn sulφοπροιshldimeτilaminο- προπanaglid -perephthalic acid-borne acid • ^' ϋ oily mineral 50 ultra-dispersive acid ν ο, 2

I am preparing the statement: indicated in the case of I. I. II. It is preparing a modifying antifreeze ΚΟΓ._ΠΟZITSYu following composition, in parts : ΠeρφτορποliπροπilenοκsΕD with ^'2700 w κ sοdeρ_τ.aniem φτορ-iοna 0.004 m: g / 40 g ποlimeρa - II - tetraethylene glycol 12 viethite diethylamine 1, 5 octoxyethyl - conversion of 13.5 mineral oil 40 omega- Example 12.

It offers an amphibious combination of the following. in parts by weight : Πeρφτορποlκπροshιlenοκsϊϊd to 4300 .mu.m and sοdeρzha- Niemi φτορ-iοna 0.005 HLH / g ποlimeρa 45 τρizτilengliκοl II dieτanοl eτilenοκsaeτanοlamin-I, 0-tsziττeρ iοn κaρbοκsiπροπiddshleτilaϊνshnο- προπanamid πeρφτορπelaρgοnοvοy κislοτy 13 uglevοdοροdnοe sinτeτichesκοe maslο 40 ulτρadisπeρsnyi ποροshοκ niκelya 2

The specification is indicated in Example I. There has been a test of the antipfirmed antiparasitic machine. Аче In terms of quality, the following were divided: Wear indicator (Bi) of steel quick-contact performance at a constant load of 196 mm (new); κρ and tesical load (Ρκ), in Η. Οπρedelyalsya τaκzhe κοeφφshιienτ τρeniya in sοοτveτsτvii with meτοdοm κvaliφitsiροvannοy οπenκi anτiφρiκtsiοnnyχ svοysτv mοτορnyχ oils and πρisadοκ and τaκzhe ρabοτοsποsοbnοsτ (sτabϊϊlnοsτ) smazοchnοy πlenκi in zοne τρ Niya, κοτορuyu οtsenivayuτ πο sleduyuscheκ meτοdiκe. In addition, the product is supplied with a quantity of working oil with a proposed modifying anti-condensing oil. Bytes κachesτve κρiτeρiya stsenκi πρκnyaτο vρemya sτabilnοκ ρabοτy sτenda (s h) from mοmenτa πρilοzhenκya ρabοchey nagρu ^g zκi dο mοmenτa avτοmaτichesκο :: οsτanοvκi sτenda πρκ vοzρasτanκκ mοmenτa τρenϊϊya, chτο svideτelsτzueτ ο zοznκκnοzeniκ suχοgο τρeniya. (Β.Α.ωΚnaev д dr. "Laboratories" on the basis of the assessment of traditional oil products ", Bryansk, 1991). - 12 - Tests were made when using a pre-treated oil - a generic original oil used in automobiles. For comparison, the proposed products were tested in the same conditions under identical conditions, and there is an improper use of this equipment. The test results are shown in the table.

Saturday

From πρizedennyχ in τablitse ρezulτaτοv isπyτaniκ zidnο, chτο πρedlagaemaya anτiφρiιschiοnnaya mοdiφιschiρuyuschaya κοmποzitsiya ποzvοlyaeτ ποvysiτ κρiτichesκuyu nagρuzκu in 1,3-1, 43 ρaza, κοeσ φitsienτ τρenϊ th sniziτ ___ B1 66-3,33 ρaza and iznοs τρenκya - 2-8 In comparison with the well-known combination.

Intended use

The proposed anti-corruption module may be used in the following areas:

- when using a major consensus - in engines of internal combustion;

- πρκ using transmis- sion oil - with oil - 13 - Transmission, drive the main part of the vehicle, in the case of general injuries, in the case of the manual drive of the vehicle: the vehicle, the vehicle, the vehicle, the vehicle, - use of industrial oil - for lubrication of directional systems, transmission, transmission, gears, gears;

- Use of commercially available oil - for lubrication - your cylinders, valves, pressurization chamber for compression - non-exhausting and non-exhausting.

Claims

- 14 - Φ0Η.ΙULΑ IZΟBΡΕΤΕΗIYA I. Αnτiφρiκtsiοnnaya mοdiφitsiρuyuschaya κοmποzitsiya, vκlyuchayu- schaya φτορορganichesκοe sοedinenie, χaρaκτeρizuyuschayasya τem, chτο in κachesτve φτορορganichesκοgο sοedineniya οna sοdeρzhiτ πeρφτορ- ποliπροπilenοκsid with mοleκulyaρnοy massοi 1200-15000 and sοdeρzha- Niemi φτορ-iοna 0,0003-0,005 mg / g and ποlimeρa sοdeρzhiτ τaκzhe πο at meρe οdin gliκοl with τemπeρaτuροy κiπeniya above 200 ° C, and uglevοdοροdnοe maslο vzyaτye κndividualnο or lyubοm sο- cheτashιi dρug with dρugοm aminοsπiρτ and φτορsοdeρzhaschie ποveρχnο- sτnο-aκτivnye veschesτva sρορmuly κ _~ β, where ^B Ι- πeρφτορalκil or πeρφτοροκsialκil κaρbοnοvοy or sulφοκislοτy with sοdeρzhaniem ugleροdnyχ aτοmοv in φτορsοdeρzha- boiling tseπi οτ C-g dο Sτρ, -σn ₂ σοο

-σn ₂ ο (σn ₂ σn ₂ ο) _η n where: ^η = 5 - 8 π and the following is the ratio of the components in the mass part: conversion of 30-100 glycol with a temperature of above 30 ° C to 20 ° C 50 taken individually or in any other way with a friend of the amine-alcohol, the above mentioned active substances 2.7-15. 5 2. Αnτiφρiκtsiοnnaya mοdiφitsiρuyuschaya κοmποziπiya πο π.Ι, χaρaκτeρizuyuschayasya τem, chτο οna sοdeρzhiτ τaκzhe ulτρadis- πeρsny ποροshοκ οκsida meτalla and / or III-VIII meτalla gρuππy πeρiοdichesκοy sisτemy in κοlichesτve 0,5-21 mas.Chο