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WO1995003383A1 - Compositions de detergents aqueux epaissis dotees de performances de nettoyage accrues a l'aide de tensioactifs a chaines courtes - Google Patents

Compositions de detergents aqueux epaissis dotees de performances de nettoyage accrues a l'aide de tensioactifs a chaines courtes Download PDF

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Publication number
WO1995003383A1
WO1995003383A1 PCT/US1994/008089 US9408089W WO9503383A1 WO 1995003383 A1 WO1995003383 A1 WO 1995003383A1 US 9408089 W US9408089 W US 9408089W WO 9503383 A1 WO9503383 A1 WO 9503383A1
Authority
WO
WIPO (PCT)
Prior art keywords
amine oxide
composition according
short chain
aqueous detergent
long chain
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US1994/008089
Other languages
English (en)
Inventor
Panos Iakovides
Rita De Berardinis
Anna Lucia D'orazio
Andrea Soddu
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Co
Original Assignee
Procter and Gamble Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to US08/583,108 priority Critical patent/US5693601A/en
Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co
Priority to CA002167482A priority patent/CA2167482C/fr
Priority to HU9600139A priority patent/HU219162B/hu
Priority to AU73662/94A priority patent/AU7366294A/en
Priority to EP94922613A priority patent/EP0711335A4/fr
Priority to JP50525395A priority patent/JP3923074B2/ja
Priority to DK94202726T priority patent/DK0693548T3/da
Priority to DE69429256T priority patent/DE69429256T2/de
Priority to ES94202726T priority patent/ES2168286T3/es
Priority to AT94202726T priority patent/ATE209674T1/de
Priority to EP94202726A priority patent/EP0693548B1/fr
Publication of WO1995003383A1 publication Critical patent/WO1995003383A1/fr
Priority to CA002153354A priority patent/CA2153354C/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/395—Bleaching agents
    • C11D3/3956—Liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/825—Mixtures of compounds all of which are non-ionic
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/825—Mixtures of compounds all of which are non-ionic
    • C11D1/8255—Mixtures of compounds all of which are non-ionic containing a combination of compounds differently alcoxylised or with differently alkylated chains
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/146—Sulfuric acid esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/722—Ethers of polyoxyalkylene glycols having mixed oxyalkylene groups; Polyalkoxylated fatty alcohols or polyalkoxylated alkylaryl alcohols with mixed oxyalkylele groups
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/75—Amino oxides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10—Objects to be cleaned
    • C11D2111/14—Hard surfaces

Definitions

  • the present invention relates to thickened aqueous detergent compositions suitable for household application. More particularly, the compositions herein are suitable in hard-surface applications including toilet cleaning as well as in dishwashing applications, especially as a pretreatment composition.
  • Liquid detergent compositions comprising the combination of long chain amine oxides and fatty acids are well known in the art.
  • viscosity may be retained even upon the addition of short chain surfactants, by the use of a specific mixture of amine oxides, more specifically a mixture of a C ⁇ 4 chain amine oxide with a C12 chain amine oxide, or a C j g chain amine oxide or mixtures thereof.
  • a further advantage of the present invention is that there is no need for an additional thickening agent.
  • An additional advantage of the compositions of the present invention is that they have a desirable sudsing profile such that suds suppressers are not required.
  • Thickening compositions comprising long chain amine oxides and fully saturated fatty acids are well known in the art.
  • US 4 282 109 discloses a thickened bleach composition
  • a thickened bleach composition comprising hypochlorite and linear and branched long chain C-j Q -C ⁇ g amine oxides as thickeners.
  • EP 274 885 discloses thickened bleaching compositions comprising alkali metal hypochlorite and straight chain C14 amine oxide with a mixture of branched and straight chain C 5 amine oxide. There is no mention of short chain surfactants.
  • the compositions may optionally contain fatty acids as an additional thickening aid.
  • EP 233 666 discloses a process for the manufacture of a thickened bleaching composition
  • a thickened bleaching composition comprising hypochlorite, a hypochlorite-soluble surfactant and an alkali metal salt of a fatty acid.
  • the detergent actives include amine oxides, preferably lauryldimethylamine. There is no mention of short chain surfactants.
  • DE 28 37 880 discloses bleaching compositions comprising alkali metal hypochlorite and mixtures of branched and linear amine oxides of varying chain length, (C5-C17) for increased viscosity.
  • the compositions do not require fatty acids for thickening.
  • EP 30 401 discloses thickened bleaching compositions comprising hypochlorite and a certain number of product characteristics including pH and viscosity. Mixtures of Cg-C-jg amine oxides and fatty acids are preferred as thickening agents. There is no mention of short chain surfactants. Summary of the Invention
  • compositions of the present invention comprise aqueous compositions having a viscosity of from 50 cps to 2000 cps comprising a mixture of long chain amine oxides according to the formula R 1 R 2 R 3 NO nerein R 2 and R 3 are independently C1-C3 alkyl groups, and a short chain surfactant.
  • Said short chain surfactant comprises a hydrophobic portion and a hydrophilic portion, wherein the chain length of said hydrophobic portion is Cg-C-jn-
  • Said mixture of long chain amine oxides comprises a first amine oxide wherein R-j is a C14 alkyl group and a second amine oxide wherein R-
  • the ratio of said first amine oxide to said second amine oxide wherein R ⁇ is a C ⁇ j 2 alkyl group is from 0.3 to 10
  • the ratio of said first amine oxide to said second amine oxide wherein R ⁇ j is a C-15 alkyl group is from 0.2 to 4.5.
  • the present invention further encompasses a process of treating dishes, wherein said dishes are contacted with a composition according to the present invention.
  • the liquid detergent composition according to the present invention comprises a mixture long chain amine oxides and a short chain surfactant.
  • compositions according to the present invention comprise at least one short chain surfactant, or mixtures thereof. All surfactants have in common that they comprise a hydrophobic portion and a hydrophilic portion.
  • short chain surfactant it is meant herein surfactants which comprise a Cg-C ⁇ j Q alkyl chain as their hydrophobic portion.
  • Such short chain surfactants are accordingly those conventionally used in this field, but with a shorter alkyl chain, and can be of any type.
  • suitable short chain surfactants for use herein include Cg-C ⁇ g alkyl sulphates (Cg- C 10 SO 4 ), alkyl ether sulphates (C 6 -C ⁇ o(OCH 2 CH2)eS ⁇ 4), alkyl sulphonates (C 6 -C 0 SO 3 ), alkyl succinates alkyl carboxylates (Cg-C- j gCOOM), alkyl ether carboxylates (C -C- j o(OCH2CH2) e COOM), alkyl sarcosinates (Cg-C ⁇ oCON(CH3)R), alkyl sulpho succinates (Cg-C ⁇ oOOCCH(S ⁇ 3M)CH2COOZ), amine oxides (Cg-C- j oRR'NO), glucose amides (C 6 -C 10 CONR"X), alkyl pyrrolidones (Cg-C-io ⁇ H ON), alkyl
  • compositions according to the present invention may comprise any of the above surfactants alone, or any combination thereof, depending on the end use envisioned.
  • Preferred short chain nonionic surfactants for use herein are alkyl alkoxylates according to the formula Cg-C ⁇ o(OCH2CH2) e ( OCH 2 CH 2 CH 2)p°H where e and p representing respectively the degree of ethoxylation and propoxylation, are independently of from 0 to 20, and that e+p>0.
  • Most preferred short chain nonionic surfactants for use herein are those where e and p are such that e+p is from 3 to 10, particularly those where p is 0 and e is from 3 to 8.
  • most preferred short chain nonionic surfactants for use herein are those where said short chain is a hydrocarbon chain comprising from 7 to 10 carbon atoms.
  • Said preferred short chain nonionic surfactants for use herein can be manufactured by the processes well known to the man skilled in the art, such as condensation of the corresponding alcohol and alkylene oxide, but such short chain surfactants are more conveniently commercially available for instance from Sidobre under the trade name Mergital@C4 (C8E04), from Kolb under the trade names Imbentin® AG/810/050 and AG/810/080 (respectively C8-10EO5 and C8- 10EO8)- Preferred short chain anionic surfactants for use herein are C -C ⁇ o alkyl sulphates (Cg-C 10 SO4) and alkyl sulphonates (Cg-C ⁇ SOs).
  • C6-C8 alkyl sulphates and sulphonates are preferred.
  • Such short chain anionic surfactants can be made by well known sulphation or sulphonation processes followed by neutralization, but said anionic short chain surfactants are more conveniently commercially available, for instance from Rhone Poulenc under the trade name Rhodapon® OLS, or from Witco under the trade name Witconate®.
  • Preferred short chain surfactants for use herein are dimethyloctylamine oxide and octyl sulphate. Suitable short chain surfactants for use herein are preferably hypochlorite compatible. According to the present invention, the compositions comprise from 0.5% to 15%, preferably from 0.5% to 10%, more preferably from 1 % to 6%, and most preferably from 2% to 4% by weight of the total composition of short chain surfactants.
  • suitable mixtures of long amine oxides for use herein are according to the formula R-1R2R3NO comprising a first amine oxide wherein R ⁇ is a C 14 alkyl group and a second amine oxide wherein R-j a C-J2 alkyl group or wherein R- ⁇ is a C ⁇ g alkyl group or mixtures thereof.
  • R 2 and R3 are independently C-
  • the ratio of said first amine oxide to said second amine oxide wherein Rf is a C12 alkyl group is from 0.3 to 10, preferably from 0.5 to 5 and wherein the ratio of said first amine oxide to said second amine oxide wherein in said second amine oxide R-
  • Preferred long chain amine oxides for use herein can be Genaminox R LA, Gemaminox R MY-X (available from Hoechst), C 12 -C-
  • Suitable long chain surfactants for use herein are preferably hypochlorite compatible.
  • said compositions comprise from 1.5% to 10%, preferably from 1.5% to 7% more preferably from 2% to 5% and most preferably from 2.5% to 4% by weight of the total composition of said mixture of long chain amine oxides of the present invention.
  • compositions according to the present invention comprise said mixture of long chain amine oxides so that compositions independently comprise from 0.4% to 6% by weight of the total composition of said first amine oxide, preferably from 0.5% to 4% and from 0.5% to 4% by weight of said second amine oxide, preferably from 0.5% to 3%.
  • compositions according to the present invention comprise said mixture of long chain amine oxides and said short chain surfactants in a ratio of from 0.25 to 3, preferably 0.5 to 2.
  • the long chain amine oxide of the present invention restore the viscosity to a value of from 50cps to 2000 cps, preferably from 100 cps to 700cps, measured with a Brookfield viscosimeter RVT at a temperature of 25°C using spindle numbers 2 or 3 or 4 at 50 r.p.m. or 100 r.p.m.
  • compositions according to the present invention may further comprise as an optional ingredient other long chain surface active agents.
  • Suitable long chain surface actives include alkyl sarcosinates, paraffin sulphonates, alkyl sulphates and alkyl ether sulphates.
  • a preferred optional ingredient is C12 alkyl sulphate, the weight ratio of short chain surfactant to C-J2 alkyl sulphonate being of 1:4 to 4:1.
  • Suitable fatty acids for use herein can be any Cg-C- j g fatty acid, preferably fully saturated, preferably a sodium, potassium or lithium salt, more preferably the sodium salt.
  • Suitable fatty acids may be selected from caprylic acid, capric acid, lauric acid, myristic acid, palmitic acid, stearic acid and mixtures of fatty acids suitably hardened, derived from natural sources such as tallow, coconut oil, ground oil and babassu oil.
  • compositions according to the present invention comprise from 0.2% to 2%, preferably from 0.5% to 1% by weight of the total composition of fatty acids.
  • Said fatty acids may be used as an additional thickening aid and as suds suppressers.
  • compositions according to the present invention comprise said hypochlorite bleaching agents such that the content of active chlorine in the compositions is from 0.4% to 4%, preferably from 1% to 2%. According to the present invention the ingredients of the compositions are selected so that the compositions are hypociorite compatible.
  • compositions according to the present invention that the pH is greater than 12, preferably greater than 12.5, more preferably greater than 12.8. This is achieved by the addition of a caustic alkali.
  • Suitable caustic alkalis for use herein include sodium and potassium hydroxide.
  • compositions according to the present invention may also comprise a number of additional ingredients such as colourants and perfumes. Additionally, the compositions according to the present invention may comprise silicates used as corrosion inhibitors.
  • compositions according to the present invention are prepared by methods well known in the art such as the methods described in GB 1 329 086.
  • the compositions according to the present invention can be prepared by mixing all of the ingredients in a non-metallic apparatus at room temperature.
  • the surfactant blend is first prepared by adding the short chain surfactant to the long chain component. Perfume and the alkali metal hypochlorite are then added whilst stirring. Colourants are added after all the other ingredients have been mixed.
  • compositions of the present invention may be used for a variety of cleaning purposes such as cleaning hard surfaces whereby said compositions thickened nature result in longer adhesion to the surface than non-thickened compositions.
  • Said compositions are particularly suitable in the cleaning of inclined surfaces including toilet bowls.
  • compositions herein are used in dishwashing applications, including hand dishwashing - as well as washing with automatic dishwashing machines.
  • dishwashing applications including hand dishwashing - as well as washing with automatic dishwashing machines.
  • said compositions give particularly good cleaning performance, especially in terms of soil removal when used as a pretreatment composition for treating dishes especially pans, pots kitchen grills and/or any kitchenware soiled by though food stains/encrustations.
  • the present invention encompasses a process of treating dishes which comprises the steps of contacting said dishes with a composition according to the present invention in its diluted or neat form, then allowing said dishes to remain in contact with said composition for a period of time sufficient to treat said dishes, preferably from 2 to 15 minutes, then rinsing said dishes in water to remove said composition.
  • Said process mentioned herein may be followed by a subsequent step where said dishes are washed with a dishwashing product including the one of the present invention or any other coventional diswashing product.
  • said subsequent step may be either a hand dishwashing operation or a dishwashing performed in automatic dishwashing machines.
  • said process of treating dishes mentioned herein before can be preceded by a step where said dishes are soaked in water before being contacted with a composition of the present invention.
  • compositions according to the present invention may be diluted with water.
  • dilution levels are of from 0.5% to 3% by weight of a composition of the present invention in water. Said dilution may occur before or while a composition of the present invention is applied to said dishes.
  • treating includes washing as the compositions according to the present invention comprise surfactants and bleaching as the preferred compositions of the present invention comprise hypochlorite.
  • compositions according to the present invention can be illustrated by the following examples.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

La présente invention concerne une composition de détergent liquide aqueux comprenant un tensioactif à chaînes courtes pour assurer un meilleur effet nettoyant. Ladite composition contient, en outre, un mélange d'oxydes aminés à chaînes longues pour rétablir la viscosité. Utilisée pour le prénettoyage de vaisselle, elle est un excellent éliminateur de salissures; elle est particulièrement efficace lorsqu'elle est appliquée sur des surfaces dures, notamment pour le nettoyage de cuvettes de toilettes.
PCT/US1994/008089 1993-07-23 1994-07-18 Compositions de detergents aqueux epaissis dotees de performances de nettoyage accrues a l'aide de tensioactifs a chaines courtes Ceased WO1995003383A1 (fr)

Priority Applications (12)

Application Number Priority Date Filing Date Title
US08/583,108 US5693601A (en) 1993-07-23 1994-07-10 Thickened aqueous detergent compositions with improved cleaning performance with short chain surfactants
CA002167482A CA2167482C (fr) 1993-07-23 1994-07-18 Compositions aqueuses detergentes epaissies, avec surfactifs a chaine courte, offrant un rendement de nettoyage ameliore
HU9600139A HU219162B (hu) 1993-07-23 1994-07-18 Rövid szénláncú felületaktív anyagokat tartalmazó, javított tisztító hatású viszkózus, vizes mosószerkészítmény és alkalmazása
AU73662/94A AU7366294A (en) 1993-07-23 1994-07-18 Thickened aqueous detergent compositions with improved cleaning performance with short chain surfactants
EP94922613A EP0711335A4 (fr) 1993-07-23 1994-07-18 Compositions de detergents aqueux epaissis dotees de performances de nettoyage accrues a l'aide de tensioactifs a chaines courtes
JP50525395A JP3923074B2 (ja) 1993-07-23 1994-07-18 短鎖界面活性剤を含む改良された洗浄性能を有する濃密化水性洗剤組成物
DE69429256T DE69429256T2 (de) 1994-07-18 1994-09-22 Eine stabile konzentrierte Vormischung und ihre Verwendung zur Herstellung von wässrigen Waschmittelzusammensetzungen
DK94202726T DK0693548T3 (da) 1994-07-18 1994-09-22 Stabil koncentreret præmix og dens anvendelse til fremstilling af vandige detergentsammensætninger
ES94202726T ES2168286T3 (es) 1994-07-18 1994-09-22 Una premezcla concentrada estable y su uso para fabricar composiciones detergentes acuosas.
AT94202726T ATE209674T1 (de) 1994-07-18 1994-09-22 Eine stabile konzentrierte vormischung und ihre verwendung zur herstellung von wässrigen waschmittelzusammensetzungen
EP94202726A EP0693548B1 (fr) 1994-07-18 1994-09-22 Un prémélange concentré stable et son utilisation pour la fabrication des compositions détergentes aqueuses
CA002153354A CA2153354C (fr) 1994-07-18 1995-07-06 Melange prealable, concentre et stable; son utilisation pour l'obtention de compositions aqueuses detergentes

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
EP93202186 1993-07-23
EP93870222 1993-11-22
EP94870002.6 1994-01-10
EP94870002 1994-01-10
EP93202186.8 1994-01-10
EP93870222.2 1994-01-10

Publications (1)

Publication Number Publication Date
WO1995003383A1 true WO1995003383A1 (fr) 1995-02-02

Family

ID=27235316

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1994/008089 Ceased WO1995003383A1 (fr) 1993-07-23 1994-07-18 Compositions de detergents aqueux epaissis dotees de performances de nettoyage accrues a l'aide de tensioactifs a chaines courtes

Country Status (10)

Country Link
EP (1) EP0711335A4 (fr)
JP (1) JP3923074B2 (fr)
CN (1) CN1057790C (fr)
AU (1) AU7366294A (fr)
CA (1) CA2167482C (fr)
CZ (1) CZ20296A3 (fr)
HU (1) HU219162B (fr)
MX (1) MXPA94005640A (fr)
WO (1) WO1995003383A1 (fr)
ZA (1) ZA945410B (fr)

Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1997045520A1 (fr) * 1996-05-24 1997-12-04 Henkel Kommanditgesellschaft Auf Aktien Agents de blanchiment et de desinfection aqueux
WO1998001528A1 (fr) * 1996-07-04 1998-01-15 Henkel Kommanditgesellschaft Auf Aktien Agents s'utilisant pour nettoyer des surfaces dures
EP0779917A4 (fr) * 1994-09-06 1999-03-17 Johnson & Son Inc S C Compositions de nettoyage comprenant une lipase et une amylase
WO1999013036A1 (fr) * 1997-09-10 1999-03-18 Albemarle Corporation Substance permettant de nettoyer les surfaces dures sans frotter
WO1999019441A1 (fr) * 1997-10-14 1999-04-22 The Procter & Gamble Company Compositions de nettoyage et de desinfection
EP0916719A3 (fr) * 1992-11-03 1999-07-14 The Procter & Gamble Company Nettoyage à l'aide d'agents tensio-actifs à courtes chaines
GB2334722A (en) * 1998-02-25 1999-09-01 Reckitt & Colman Inc Hard surface cleaner
US6022840A (en) * 1998-02-25 2000-02-08 Reckitt & Colman Inc. Aqueous cleaning compositions containing 2-ethylhexyl sulfate and C8 -C10 alkyldimethylamine oxide for removing soap scum
EP1516915A1 (fr) * 2003-09-22 2005-03-23 Clariant GmbH Solutions aqueuses concentrées de tensioactifs amphotères
CN101798551A (zh) * 2010-04-30 2010-08-11 北京绿伞化学股份有限公司 一种浓缩型餐具洗涤剂及其制备方法
WO2014160590A1 (fr) * 2013-03-26 2014-10-02 The Procter & Gamble Company Compositions de nettoyage destinées au nettoyage d'une surface dure
EP2978357A1 (fr) * 2013-03-26 2016-02-03 The Procter & Gamble Company Articles pour nettoyer une surface dure
EP3034593A1 (fr) * 2014-12-19 2016-06-22 The Procter and Gamble Company Composition de détergent liquide
EP3078731A1 (fr) * 2015-04-10 2016-10-12 Henkel AG & Co. KGaA Produit de nettoyage contenant des agents de blanchiment
WO2016200343A1 (fr) * 2015-06-09 2016-12-15 Hayat Kimya Sanayi Anonim Sirketi Compositions de blanchiment aqueuses, épaissies et transparentes
EP3257926A1 (fr) * 2016-06-17 2017-12-20 The Procter and Gamble Company Composition de détergent liquide
EP3670637A1 (fr) * 2018-12-18 2020-06-24 Henkel AG & Co. KGaA Régulation de la viscosité dans les agents de rinçage à la main

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6585417B2 (ja) * 2015-08-04 2019-10-02 花王株式会社 ガラス又は陶器製食器の洗浄方法
JP7626513B2 (ja) * 2018-03-09 2025-02-07 株式会社ニイタカ 発泡洗浄剤組成物及び洗浄方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3892669A (en) * 1972-10-27 1975-07-01 Lever Brothers Ltd Clear fabric-softening composition
US3928249A (en) * 1972-02-07 1975-12-23 Procter & Gamble Liquid detergent composition
US3953382A (en) * 1973-05-30 1976-04-27 Lever Brothers Company Detergent compositions

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ATE17595T1 (de) * 1981-11-07 1986-02-15 Procter & Gamble Reinigungsmittelzusammensetzungen.
GB8630845D0 (en) * 1986-12-24 1987-02-04 Ici Plc Bleaching compositions
GB8917626D0 (en) * 1989-08-02 1989-09-20 Quest Int Perfumed bleach compositions

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3928249A (en) * 1972-02-07 1975-12-23 Procter & Gamble Liquid detergent composition
US3892669A (en) * 1972-10-27 1975-07-01 Lever Brothers Ltd Clear fabric-softening composition
US3953382A (en) * 1973-05-30 1976-04-27 Lever Brothers Company Detergent compositions

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP0711335A4 *

Cited By (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0916719A3 (fr) * 1992-11-03 1999-07-14 The Procter & Gamble Company Nettoyage à l'aide d'agents tensio-actifs à courtes chaines
EP0779917A4 (fr) * 1994-09-06 1999-03-17 Johnson & Son Inc S C Compositions de nettoyage comprenant une lipase et une amylase
WO1997045520A1 (fr) * 1996-05-24 1997-12-04 Henkel Kommanditgesellschaft Auf Aktien Agents de blanchiment et de desinfection aqueux
WO1998001528A1 (fr) * 1996-07-04 1998-01-15 Henkel Kommanditgesellschaft Auf Aktien Agents s'utilisant pour nettoyer des surfaces dures
WO1999013036A1 (fr) * 1997-09-10 1999-03-18 Albemarle Corporation Substance permettant de nettoyer les surfaces dures sans frotter
WO1999019441A1 (fr) * 1997-10-14 1999-04-22 The Procter & Gamble Company Compositions de nettoyage et de desinfection
EP0916718A1 (fr) * 1997-10-14 1999-05-19 The Procter & Gamble Company Compositions de nettoyage et de désinfection
US6537955B1 (en) 1997-10-14 2003-03-25 The Procter & Gamble Company Cleaning and disinfecting compositions comprising C6- C7 alkyl sulfate
GB2334722A (en) * 1998-02-25 1999-09-01 Reckitt & Colman Inc Hard surface cleaner
US6022840A (en) * 1998-02-25 2000-02-08 Reckitt & Colman Inc. Aqueous cleaning compositions containing 2-ethylhexyl sulfate and C8 -C10 alkyldimethylamine oxide for removing soap scum
US6036789A (en) * 1998-02-25 2000-03-14 Reckitt & Colman Inc. Aqueous cleaning compositions containing 2-ethylhexyl sulfate and optionally myristyldimethylamine oxide for removing soap scum
GB2334722B (en) * 1998-02-25 2002-04-24 Reckitt & Colman Inc Aqueous cleaning composition for removing soap scum
EP1516915A1 (fr) * 2003-09-22 2005-03-23 Clariant GmbH Solutions aqueuses concentrées de tensioactifs amphotères
CN101798551A (zh) * 2010-04-30 2010-08-11 北京绿伞化学股份有限公司 一种浓缩型餐具洗涤剂及其制备方法
US9757006B2 (en) 2013-03-26 2017-09-12 The Procter & Gamble Company Articles for cleaning a hard surface
WO2014160590A1 (fr) * 2013-03-26 2014-10-02 The Procter & Gamble Company Compositions de nettoyage destinées au nettoyage d'une surface dure
EP2978357A1 (fr) * 2013-03-26 2016-02-03 The Procter & Gamble Company Articles pour nettoyer une surface dure
EP3034593A1 (fr) * 2014-12-19 2016-06-22 The Procter and Gamble Company Composition de détergent liquide
WO2016100122A1 (fr) * 2014-12-19 2016-06-23 The Procter & Gamble Company Composition de détergent liquide
US9969956B2 (en) 2014-12-19 2018-05-15 The Procter & Gamble Company Liquid detergent composition
WO2016162190A1 (fr) * 2015-04-10 2016-10-13 Henkel Ag & Co. Kgaa Composition de nettoyage comprenant un agent de blanchiment
EP3078731A1 (fr) * 2015-04-10 2016-10-12 Henkel AG & Co. KGaA Produit de nettoyage contenant des agents de blanchiment
WO2016200343A1 (fr) * 2015-06-09 2016-12-15 Hayat Kimya Sanayi Anonim Sirketi Compositions de blanchiment aqueuses, épaissies et transparentes
EP3257926A1 (fr) * 2016-06-17 2017-12-20 The Procter and Gamble Company Composition de détergent liquide
WO2017218863A1 (fr) * 2016-06-17 2017-12-21 The Procter & Gamble Company Composition de détergent liquide
EP3670637A1 (fr) * 2018-12-18 2020-06-24 Henkel AG & Co. KGaA Régulation de la viscosité dans les agents de rinçage à la main

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CA2167482C (fr) 1999-12-28
EP0711335A1 (fr) 1996-05-15
CN1057790C (zh) 2000-10-25
HU219162B (hu) 2001-02-28
MXPA94005640A (es) 2005-08-19
ZA945410B (en) 1995-02-28
HU9600139D0 (en) 1996-03-28
CA2167482A1 (fr) 1995-02-02
HUT73751A (en) 1996-09-30
EP0711335A4 (fr) 1997-07-09
CZ20296A3 (en) 1996-07-17
CN1129951A (zh) 1996-08-28
JP3923074B2 (ja) 2007-05-30
AU7366294A (en) 1995-02-20
JPH09500680A (ja) 1997-01-21

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