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WO1994021690A3 - Method for the oxidation of vicinal diols, including carbohydrates - Google Patents

Method for the oxidation of vicinal diols, including carbohydrates Download PDF

Info

Publication number
WO1994021690A3
WO1994021690A3 PCT/NL1994/000065 NL9400065W WO9421690A3 WO 1994021690 A3 WO1994021690 A3 WO 1994021690A3 NL 9400065 W NL9400065 W NL 9400065W WO 9421690 A3 WO9421690 A3 WO 9421690A3
Authority
WO
WIPO (PCT)
Prior art keywords
oxidation
vicinal diols
including carbohydrates
hydrogen peroxide
catalytic amount
Prior art date
Application number
PCT/NL1994/000065
Other languages
French (fr)
Other versions
WO1994021690A2 (en
Inventor
WIT Dirk DE
Sarah Veelaert
Hubert Tournois
Original Assignee
Inst Voor Agrotech Onderzoek
Wit Dirk De
Sarah Veelaert
Hubert Tournois
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Inst Voor Agrotech Onderzoek, Wit Dirk De, Sarah Veelaert, Hubert Tournois filed Critical Inst Voor Agrotech Onderzoek
Priority to AU64381/94A priority Critical patent/AU6438194A/en
Priority to EP94912096A priority patent/EP0690877A1/en
Publication of WO1994021690A2 publication Critical patent/WO1994021690A2/en
Publication of WO1994021690A3 publication Critical patent/WO1994021690A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
    • C08B37/00—Preparation of polysaccharides not provided for in groups C08B1/00 - C08B35/00; Derivatives thereof
    • C08B37/0006—Homoglycans, i.e. polysaccharides having a main chain consisting of one single sugar, e.g. colominic acid
    • C08B37/0051—Homoglycans, i.e. polysaccharides having a main chain consisting of one single sugar, e.g. colominic acid beta-D-Fructofuranans, e.g. beta-2,6-D-fructofuranan, i.e. levan; Derivatives thereof
    • C08B37/0054—Inulin, i.e. beta-2,1-D-fructofuranan; Derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
    • C08B15/00—Preparation of other cellulose derivatives or modified cellulose, e.g. complexes
    • C08B15/02—Oxycellulose; Hydrocellulose; Cellulosehydrate, e.g. microcrystalline cellulose
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
    • C08B31/00—Preparation of derivatives of starch
    • C08B31/18—Oxidised starch

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Biochemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Polysaccharides And Polysaccharide Derivatives (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

A method is described for the oxidation of vicinal diols, including carbohydrates, to dicarboxy compounds by reaction of the diol in an aqueous medium with hydrogen peroxide or via an electrochemical route, in the presence of a catalytic amount of a transition metal salt. Oxidation with hydrogen peroxide in the presence of a catalytic amount of an alkali metal halide, alkaline earth metal halide or ammonium halide is also described.
PCT/NL1994/000065 1993-03-25 1994-03-25 Method for the oxidation of vicinal diols, including carbohydrates WO1994021690A2 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
AU64381/94A AU6438194A (en) 1993-03-25 1994-03-25 Method for the oxidation of vicinal diols, including carbohydrates
EP94912096A EP0690877A1 (en) 1993-03-25 1994-03-25 Method for the oxidation of vicinal diols, including carbohydrates

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
NL9300540 1993-03-25
NL9300540A NL9300540A (en) 1993-03-25 1993-03-25 Method for oxidizing carbohydrates.

Publications (2)

Publication Number Publication Date
WO1994021690A2 WO1994021690A2 (en) 1994-09-29
WO1994021690A3 true WO1994021690A3 (en) 1994-11-24

Family

ID=19862222

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/NL1994/000065 WO1994021690A2 (en) 1993-03-25 1994-03-25 Method for the oxidation of vicinal diols, including carbohydrates

Country Status (4)

Country Link
EP (1) EP0690877A1 (en)
AU (1) AU6438194A (en)
NL (1) NL9300540A (en)
WO (1) WO1994021690A2 (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9512562B2 (en) 2009-05-28 2016-12-06 Gp Cellulose Gmbh Modified cellulose from chemical kraft fiber and methods of making and using the same
US9512237B2 (en) 2009-05-28 2016-12-06 Gp Cellulose Gmbh Method for inhibiting the growth of microbes with a modified cellulose fiber
US9512563B2 (en) 2009-05-28 2016-12-06 Gp Cellulose Gmbh Surface treated modified cellulose from chemical kraft fiber and methods of making and using same
US9511167B2 (en) 2009-05-28 2016-12-06 Gp Cellulose Gmbh Modified cellulose from chemical kraft fiber and methods of making and using the same

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2767271B1 (en) * 1997-08-13 2001-05-25 Roquette Freres OZONATION CATALYST AND METHOD FOR OZONATION OF CARBON HYDRATES USING SUCH A CATALYST
US8669397B2 (en) 2009-06-13 2014-03-11 Rennovia, Inc. Production of adipic acid and derivatives from carbohydrate-containing materials
US8501989B2 (en) 2009-06-13 2013-08-06 Rennovia, Inc. Production of adipic acid and derivatives from carbohydrate-containing materials
WO2010144871A2 (en) 2009-06-13 2010-12-16 Rennovia, Inc. Production of glutaric acid and derivatives from carbohydrate-containing materials
US8669393B2 (en) 2010-03-05 2014-03-11 Rennovia, Inc. Adipic acid compositions
US9770705B2 (en) 2010-06-11 2017-09-26 Rennovia Inc. Oxidation catalysts
AU2012268700B2 (en) 2011-05-23 2017-02-02 Gp Cellulose Gmbh Softwood kraft fiber having improved whiteness and brightness and methods of making and using the same
BR112014017164A8 (en) 2012-01-12 2017-07-04 Gp Cellulose Gmbh method for producing oxidized kraft pulp and softwood kraft fibers
EP2839071B1 (en) 2012-04-18 2019-01-23 GP Cellulose GmbH The use of surfactant to treat pulp and improve the incorporation of kraft pulp into fiber for the production of viscose and other secondary fiber products
KR102180512B1 (en) 2013-02-08 2020-11-19 게페 첼루로제 게엠베하 Softwood kraft fiber having an improved a-cellulose content and its use in the production of chemical cellulose products
CN105121735B (en) 2013-03-14 2018-06-29 Gp 纤维素股份有限公司 Process for producing highly functionalized low viscosity sulfate fibers using an acid bleaching sequence and fibers produced by this process
JP6521873B2 (en) 2013-03-15 2019-05-29 ゲーペー ツェルローゼ ゲーエムベーハー Low viscosity kraft fiber with enhanced carboxyl content and method of making and using the same
US10865519B2 (en) 2016-11-16 2020-12-15 Gp Cellulose Gmbh Modified cellulose from chemical fiber and methods of making and using the same

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE544693C (en) * 1929-03-23 1932-02-20 Chem Fab Gedeon Richter A G Process for the preparation of mixtures of organic acids from carbohydrates and materials containing carbohydrates
JPS55102528A (en) * 1979-02-01 1980-08-05 Mitsui Petrochem Ind Ltd Preparation of carbonyl compound

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE544693C (en) * 1929-03-23 1932-02-20 Chem Fab Gedeon Richter A G Process for the preparation of mixtures of organic acids from carbohydrates and materials containing carbohydrates
JPS55102528A (en) * 1979-02-01 1980-08-05 Mitsui Petrochem Ind Ltd Preparation of carbonyl compound

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
DATABASE WPI Week 8038, Derwent World Patents Index; AN 66701C *

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9512562B2 (en) 2009-05-28 2016-12-06 Gp Cellulose Gmbh Modified cellulose from chemical kraft fiber and methods of making and using the same
US9512237B2 (en) 2009-05-28 2016-12-06 Gp Cellulose Gmbh Method for inhibiting the growth of microbes with a modified cellulose fiber
US9512563B2 (en) 2009-05-28 2016-12-06 Gp Cellulose Gmbh Surface treated modified cellulose from chemical kraft fiber and methods of making and using same
US9511167B2 (en) 2009-05-28 2016-12-06 Gp Cellulose Gmbh Modified cellulose from chemical kraft fiber and methods of making and using the same
US9512561B2 (en) 2009-05-28 2016-12-06 Gp Cellulose Gmbh Modified cellulose from chemical kraft fiber and methods of making and using the same

Also Published As

Publication number Publication date
WO1994021690A2 (en) 1994-09-29
NL9300540A (en) 1994-10-17
AU6438194A (en) 1994-10-11
EP0690877A1 (en) 1996-01-10

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