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WO1993017658A1 - Compositions de laque pour cheveux, a base aqueuse, contenant des polymeres multiples - Google Patents

Compositions de laque pour cheveux, a base aqueuse, contenant des polymeres multiples Download PDF

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Publication number
WO1993017658A1
WO1993017658A1 PCT/US1993/000655 US9300655W WO9317658A1 WO 1993017658 A1 WO1993017658 A1 WO 1993017658A1 US 9300655 W US9300655 W US 9300655W WO 9317658 A1 WO9317658 A1 WO 9317658A1
Authority
WO
WIPO (PCT)
Prior art keywords
water
mole
group
hair spray
acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US1993/000655
Other languages
English (en)
Inventor
Deborah R. Pierce
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ISP Investments LLC
Original Assignee
ISP Investments LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ISP Investments LLC filed Critical ISP Investments LLC
Priority to AU34840/93A priority Critical patent/AU3484093A/en
Publication of WO1993017658A1 publication Critical patent/WO1993017658A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
    • A61K8/8182—Copolymers of vinyl-pyrrolidones. Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/85—Polyesters
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/59—Mixtures
    • A61K2800/594—Mixtures of polymers

Definitions

  • This invention relates to hair spray resin compositions, and more particularly, to water-based
  • compositions which contain a multiple polymer system which contain a multiple polymer system.
  • VOC volatile organic compound
  • Aerosol hair spray formulations also require hydrocarbons or other propellants which add to the VOC content of the composition.
  • Recent state legislation moreover, has required that hair spray compositions have a lower VOC level than is presently found in commercial hairspray compositions. More particularly, it is now necessary that such compositions contain VOC materials at a weight level of no more than 80% of the composition. Accordingly, it is an object of the present invention to provide new water-based hair spray
  • compositions which meet VOC standards while retaining the effective properties of presently available compositions for hair preparation and treatment.
  • Another object of the invention is to provide water-based hair spray compositions capable of providing a fine finishing mist at a high resin solids level and which is substantially moisture resistant, which also forms a stiff resin film on the hair of the user, and provides a good hold and curl retention, with superior shine, and feel, and low drying times, which approach the properties of alcohol-based systems.
  • a water-based hair spray composition is provided herein which is capable of delivering a fine finishing mist at a high resin solids level.
  • the composition provides a stiff resin film having excellent hair holding power, with superior shine, and feel, and low drying times, which properties approach those of alcohol-based systems.
  • the composition of the invention attains its unique attributes by including a predetermined blend of at least two hair spray polymers, one being a water soluble polymer, and the other being a water dispersible polyester or
  • composition of the invention comprises
  • M is hydrogen, or metal ion or ammonium ion or the cationic radical of an organic amine
  • polyesteramide improves the set time (tac-free time) and shine of the water soluble polymers thereby expanding the use of commercially available water soluble polymers into an aqueous-based hair spray composition which has a drying character, time and feel which approaches to an
  • Polymer blends particularly useful herein for incorporation into the hair grooming composition comprise:
  • compositions comprises:
  • a neutralizing agent to obtain 65 to 100% neutralization based on the acid monomer in the water soluble polymer, including metal hydroxides and aliphatic, cyclic, or aromatic amines;
  • the final hair grooming composition preferably comprises:
  • the polyester or polyesteramide has an inherent viscosity of from about 0.28 to about 0.38, an acid moiety of from about 75 to about 84 mole % isophthalic acid and conversely from about 25 to about 16 mole %
  • 5-sodiosulfoisophthalic acid and a glycol moiety of from abut 45 to about 60 mole % diethylene glycol and conversely from about 55 to about 40 mole % 1,4-cyclohexanedimethanol or ethylene glycol or mixtures thereof.
  • the polyester or polyesteramide comprises an acid moiety comprising from about 80 to about 83 mole % isophthalic acid and conversely from about 20 to about 17 mole % 5-sodiosulfoisophthalic acid, and said glycol moiety comprises from about 52 to about 56 mole % diethylene glycol and conversely from about 48 to about 44 mole % 1,4-cyclohexanedimethanol.
  • the water soluble polymers useful herein are preferably prepared from monomers of one or more of the following structures:
  • R 1 is a C 1 -C 5 aliphatic group, preferably a C 1 -C 3 alkyl group, or is of the structure
  • R 6 and R 7 are,
  • R 2 is a C 1 -C 10 aliphatic group, preferably a C 1 -C 3 alkyl group,
  • R 3 is a C 1 -C 16 aliphatic group, preferably a C 8 alkyl group,
  • R is H or a C 1 -C 8 aliphatic group
  • R 5 is a C 1 -C 10 aliphatic group, preferably a C 9 alkyl group.
  • suitable water soluble polymers include polyvinyl pyrrolidone (PVP), polyvinyl caprolactam (PVC), polyvinyl acetate (VA), polyacrylates and
  • methacrylates and copolymers and terpolymers of such monomers, such as VP/VA, VA/crotonic acid/vinyl
  • neodecanoate neodecanoate, VA/crotonic acid, or
  • Gaffix ® VC-713 (GAF Chemicals Corporation) which is a terpolymer derived from the polymerization of vinyl caprolactam, vinylpyrrolidone and an ammonium derivative monomer having from 6-12 carbon atoms selected from the group consisting of dialkyl dialkenyl ammonium halide and a dialkylamino alkyl acrylate or methacrylate (see U.S.
  • Patent 4,521,404 The commercial product is available as a ethanolic solution having a 37% solids level.
  • Gantrez ® SP-215 (GAF Chemicals Corporation) is the ethyl half-ester of a linear copolymer of methyl vinyl ether and maleic anhydride.
  • Gantrez ® ES-225 (GAF Chemicals Corporation) is the ethyl half-ester of a linear copolymer of methyl vinyl ether and maleic anhydride having a molecular weight of 978,000.
  • Gantrez ® ES-425 (GAF Chemicals Corporation) is the butyl half-ester of a linear copolymer of methyl vinyl ether and maleic anhydride having a molecular weight of 1,000,000.
  • Resin 1212 (GAF Chemicals Corporation) is a terpolymer derived from the polymerization of vinyl
  • the polymer blend is prepared as follows: the sulfonate group-containing polymer is prepared, generally by melt polymerization, and an aqueous dispersion containing from about 10% to 30% total solids is prepared from the polyester or polyesteramide directly. Then the water soluble polymer or polymers are added to the aqueous dispersion of the polyester or
  • the aqueous dispersion so produced can be prepared with a total solids content of from about 1 to about 30.
  • the pH is, or is adjusted to be, within the range of about 4-8 in order to minimize hydrolysis of the polyester.
  • a preferred polymer blend system comprises:
  • G An aliphatic or cycloaliphatic glycol residue
  • a typical formulation of the composition of the invention is the following:

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Cosmetics (AREA)

Abstract

L'invention se rapporte à une composition de laque pour cheveux à base aqueuse, cette composition pouvant être libérée en une vaporisation fine de finition pour former un film résineux rigide présentant d'excellentes capacités de maintien de la chevelure, un éclat et une sensation supérieurs, ainsi qu'un temps de séchage relativement court, proche des systèmes à base d'alcool. La composition de l'invention atteint ces qualités uniques grâce à un mélange prédéterminé d'au moins deux résines pour laque, l'une étant une résine soluble dans l'eau, l'autre étant un polyester ou polyesteramide dispersible dans l'eau.
PCT/US1993/000655 1992-03-09 1993-01-25 Compositions de laque pour cheveux, a base aqueuse, contenant des polymeres multiples Ceased WO1993017658A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU34840/93A AU3484093A (en) 1992-03-09 1993-01-25 Water-based hair spray compositions containing multiple polymers

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US848,473 1992-03-09
US07/848,473 US5158762A (en) 1992-03-09 1992-03-09 Water-based hair spray compositions containing multiple polymers

Publications (1)

Publication Number Publication Date
WO1993017658A1 true WO1993017658A1 (fr) 1993-09-16

Family

ID=25303371

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1993/000655 Ceased WO1993017658A1 (fr) 1992-03-09 1993-01-25 Compositions de laque pour cheveux, a base aqueuse, contenant des polymeres multiples

Country Status (3)

Country Link
US (1) US5158762A (fr)
CA (1) CA2128531A1 (fr)
WO (1) WO1993017658A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6153179A (en) * 1995-03-27 2000-11-28 Basf Aktiengesellschaft Hair setting lotions

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CA2074293C (fr) * 1991-07-25 2002-03-19 John R. Horoschak Fixatif aqueux pour les cheveux
US5266308A (en) * 1991-12-20 1993-11-30 Chesebrough-Pond's Usa Co. Hair treatment composition
ES2104859T3 (es) * 1991-12-20 1997-10-16 Unilever Nv Composicion para el tratamiento del cabello.
US5266322A (en) * 1992-05-29 1993-11-30 Eastman Kodak Company Cosmetic film forming compositions
US5266303A (en) * 1992-11-30 1993-11-30 Eastman Kodak Company Aerosol hair spray formulations
US5320836A (en) * 1993-01-04 1994-06-14 Eastman Kodak Company Hair spray formulations containing a polyethylene glycol ester of caprylic and capric acids
US5389363A (en) * 1993-04-23 1995-02-14 Revlon Consumer Products Corporation Cosmetic compositions for lengthening, coloring and curling eyelashes
AU671924B2 (en) * 1993-06-25 1996-09-12 Eastman Chemical Company Hair spray formulations having increased clarity
US5674479A (en) * 1993-06-25 1997-10-07 Eastman Chemical Company Clear aerosol hair spray formulations containing a linear sulfopolyester in a hydroalcoholic liquid vehicle
US5662893A (en) * 1993-06-25 1997-09-02 Eastman Chemical Company Clear pump hair spray formulations containing a linear sulfopolyester in a hydroalcoholic liquid vehicle
US6007794A (en) * 1993-06-25 1999-12-28 Eastman Chemical Company Clear aerosol hair spray formulations containing a sulfopolyester in a hydroalcoholic liquid vehicle
US5599524A (en) * 1993-07-21 1997-02-04 National Starch And Chemical Investment Holding Corporation Low VOC hair sprays with improved spray characteristics
US5407958A (en) * 1993-07-30 1995-04-18 Beauticontrol Cosmetics, Inc. Therapeutic skin composition
FR2715064B1 (fr) * 1994-01-14 1996-02-09 Oreal Compositions cosmétiques en aérosol, aérosols les contenant et utilisations.
US5589162A (en) * 1994-04-28 1996-12-31 Kao Corporation Hair setting agent composition
FR2719995A1 (fr) * 1994-05-19 1995-11-24 Oreal Composition cosmétique aqueuse pour la fixation de la chevelure à base de l'association d'un polycondensat hydrodispersible et d'un copolymère hydrosoluble.
US5626835A (en) * 1994-06-07 1997-05-06 Isp Investments Inc. Low VOC hair spray composition
DE4421562C2 (de) * 1994-06-20 1996-05-02 Goldwell Gmbh Haarspray
US5441728A (en) * 1994-06-22 1995-08-15 Chesebrough-Pond's Usa Co., A Division Of Conopco, Inc. Hairspray compositions
DE4428003A1 (de) 1994-08-08 1996-02-15 Basf Ag Sulfonatgruppentragende Polyamide und deren Verwendung in Haarfestigungsmitteln
US5637296A (en) * 1994-08-31 1997-06-10 Isp Investments Inc. Low VOC hair spray resin composition of improved spray properties
US5626836A (en) * 1994-12-28 1997-05-06 Isp Investments Inc. Low VOC hair spray compositions containing terpolymers of vinyl pyrrolidone, vinyl caprolactam and 3-(N-dimethylaminopropyl) methacrylamide
US5597551A (en) * 1995-01-05 1997-01-28 Isp Investments Inc. Low VOC hair spray composition
US5603919A (en) * 1995-01-05 1997-02-18 Isp Investments Inc. Low VOC hair spray fixative compositions containing a tetramer
US5620683A (en) * 1995-09-13 1997-04-15 National Starch And Chemical Investment Holding Corporation Aqueous, acrylic hair fixatives and methods of making same
US5686062A (en) * 1995-12-29 1997-11-11 National Starch And Chemical Investment Holding Corporation Acrylic hair fixatives and methods of making same
DE19605076A1 (de) 1996-02-12 1997-08-14 Basf Ag Sulfonatgruppentragende Polyamide und deren Verwendung zur Behandlung von keratinhaltigen Strukturen
US6136884A (en) * 1997-02-04 2000-10-24 Eastman Chemical Company Hair care compositions
US6752983B1 (en) * 1997-09-17 2004-06-22 Eastman Chemical Company Hair spray and consumer sprays with reduced volatile organic compounds
US5989527A (en) * 1998-01-26 1999-11-23 Inolex Investment Corporation Compositions and methods for improving the performance of chemical exfoliating agents, sunless tanning agents, skin lightening agents and insect repellents
US6638992B1 (en) 1998-01-30 2003-10-28 Eastman Chemical Company Hair care compositions
US6749836B1 (en) 1998-01-30 2004-06-15 Eastman Chemical Company Hair care compositions
DE19850363A1 (de) 1998-11-02 2000-05-04 Basf Ag Polymere für kosmetische Formulierungen
FR2801199B1 (fr) * 1999-09-16 2002-01-11 Oreal Composition cosmetique comprenant au moins un copolymere silicone/acrylate et au moins un polymere non ionique a motif vynil lactame
DE19957947C1 (de) † 1999-12-02 2001-08-09 Wella Ag Polymerkombination für Haarbehandlungsmittel
FR2822061A1 (fr) * 2001-03-13 2002-09-20 Oreal Dispositif aerosol contenant une composition capillaire comprenant un polysaccharide greffe par un polysiloxane
FR2822059A1 (fr) * 2001-03-13 2002-09-20 Oreal Composition capillaire epaissie comprenant un polysaccharide greffe par un polysiloxane
US20050101740A1 (en) * 2003-09-01 2005-05-12 Nathalie Mougin Block ethylenic copolymers comprising a vinyllactam block, cosmetic compositions containing them and cosmetic use of these copolymers
US20050238594A1 (en) * 2003-09-15 2005-10-27 Nathalie Mougin Block ethylenic copolymers comprising a vinyllactam block, cosmetic or pharmaceutical compositions comprising them and cosmetic use of these copolymers
FR2859728B1 (fr) * 2003-09-15 2008-07-11 Oreal Copolymeres ethyleniques sequences comprenant une sequence vinyllactame, compositions cosmetiques ou pharmaceutiques les contenant, et utilisation de ces copolymeres en cosmetique
FR2863884B1 (fr) * 2003-12-19 2007-06-29 Oreal Composition coiffante comprenant, dans un milieu majoritairement aqueux, un polyurethane cationique elastique, procedes la mettant en oeuvre et utilisations
US7294152B2 (en) * 2004-01-07 2007-11-13 L'oreal S.A. Dyeing composition comprising at least one fluorindine compound for the dyeing of keratinic fibers, dyeing process comprising the composition and compound
US20050226829A1 (en) * 2004-04-07 2005-10-13 Inolex Investment Corporation Personal care products containing high refractive index esters and methods of preparing the same
FR2869319B1 (fr) * 2004-04-23 2008-03-14 Oreal Gel concentre en polyester sulfonique ramifie et procede de preparation de ce gel
AU2005244222B2 (en) * 2004-04-29 2008-08-14 Aveda Corporation Natural fast-drying hair fixative compositions
US7923526B2 (en) * 2004-09-01 2011-04-12 Eastman Chemical Company Sulfopolyesters having improved clarity in water-dispersible formulations and products made therefrom
US20060058438A1 (en) * 2004-09-16 2006-03-16 Williams Thomas H Fluid sulfopolyester formulations and products made therefrom
EP1802679A1 (fr) * 2004-09-16 2007-07-04 Eastman Chemical Company Formulations fluides de sulfopolyester et produits fabriques a partir desdites formulations
US20060177399A1 (en) * 2004-11-16 2006-08-10 Herve Jourdan Pressurized device for hair fiber styling and use of the same for hair fiber styling and/or hair
FR2877927B1 (fr) 2004-11-16 2007-01-26 Oreal Dispositif pressurise pour le coiffage des fibres capilaires et utilisation d'un tel dispositif pour la mise en forme et/ou le maintien de la coiffure.
FR2877926B1 (fr) 2004-11-16 2007-01-26 Oreal Dispositif pressurise pour le coiffage des fibres capillaires et utilisation d'un tel dispositif pour la mise en forme et/ou le soin des fibres capillaires.
US7429275B2 (en) * 2004-12-23 2008-09-30 L'oreal S.A. Use of at least one compound chosen from porphyrin compounds and phthalocyanin compounds for dyeing human keratin materials, compositions comprising them, a dyeing process, and compounds therefor
FR2882560B1 (fr) 2005-02-28 2007-05-18 Oreal Composition anhydre sous forme de film comprenant un polymere filmogene et un colorant d'oxydation, preparation et procede de coloration la mettant en oeuvre
US20060230546A1 (en) * 2005-02-28 2006-10-19 Eric Bone Anhydrous composition in the form of a film comprising at least one film-forming polymer and at least one oxidation dye, preparation, and dyeing process
FR2882559B1 (fr) 2005-02-28 2008-03-21 Oreal Composition anhydre sous forme de film comprenant un polymere filmogene et un agent oxydant, preparation et procede de traitement de fibres keratiniques la mettant en oeuvre
FR2882561B1 (fr) 2005-02-28 2007-09-07 Oreal Composition anhydre sous forme de film comprenant un polymere filmogene et un colorant direct, preparation et procede de coloration la mettant en oeuvre
US20060236469A1 (en) * 2005-02-28 2006-10-26 Eric Bone Anhydrous composition in the form of a film comprising a film-forming polymer and oxidizing agent, preparation and process for coloring keratinous fibers employing the anhydrous composition
FR2882519B1 (fr) * 2005-02-28 2008-12-26 Oreal Coloration de matieres keratiniques notamment humaines par transfert thermique a sec d'un colorant direct azomethinique composition comprenant ledit colorant et son procede de preparation
FR2882518B1 (fr) * 2005-02-28 2012-10-19 Oreal Coloration de matieres keratiniques notamment humaines par transfert thermique a sec d'un colorant direct anthraquinonique, composition comprenant ledit colorant et son procede de preparation
US20060242771A1 (en) * 2005-02-28 2006-11-02 Eric Bone Anhydrous composition in the form of a film comprising a film-forming polymer and a direct dye, preparation and dyeing process using the composition
FR2882521B1 (fr) 2005-02-28 2008-05-09 Oreal Coloration de matieres keratiniques notamment humaines par transfert thermique a sec d'un colorant direct, composition comprenant ledit colorant et son procede de preparation
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US8106111B2 (en) 2009-05-15 2012-01-31 Eastman Chemical Company Antimicrobial effect of cycloaliphatic diol antimicrobial agents in coating compositions
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WO2013061477A1 (fr) 2011-10-26 2013-05-02 L'oreal Coloration capillaire par transfert thermique
US10646415B1 (en) 2018-10-31 2020-05-12 L'oreal Hair-coloring compositions, aerosol products, and methods for coloring hair

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Also Published As

Publication number Publication date
US5158762A (en) 1992-10-27
CA2128531A1 (fr) 1993-09-16

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