WO1993003618A2 - Insecticide compounds for agricultural and horticultural use - Google Patents
Insecticide compounds for agricultural and horticultural use Download PDFInfo
- Publication number
- WO1993003618A2 WO1993003618A2 PCT/US1992/007288 US9207288W WO9303618A2 WO 1993003618 A2 WO1993003618 A2 WO 1993003618A2 US 9207288 W US9207288 W US 9207288W WO 9303618 A2 WO9303618 A2 WO 9303618A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- present
- agricultural
- ppm
- propargite
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
- A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
Definitions
- This invention is directed to mixtures of propargite and synthetic pyrethroids, which exhibit synergistic activity as pesticides.
- Thrips palmi is a transplanted insect from
- compositions of the present invention contain an active ingredient comprising a mixture of A) propargite, and B) a synthetic pyrethroid.
- the presen invention also comprises a method for controlling undesirable insects which comprises applying an effective amount of a composition according to the present invention to a locus to be protected.
- the propargite portion of the active ingredient is a well known insecticide sold under the trademark OMITE (Uniroyal Chemical Company) and has the chemical name 2-(4-tert-butylphenoxy) cyclohexyl prop-2-ynyl sulfite.
- Examples of the synthetic pyrethroid active ingredient are cyfluthrin, fenpropathrin, cyhalothrin, fulvalinate, tralomethrin, etofenprox, fulcytirinate, cypermethrin, permethrin, and fenvalelate.
- the propargite component may be present in the amount of from 3 to 1,000 ppm, or more preferably 100-400 ppm.
- the synthetic pyrethroide type component may be present in the amount of from 1 to 1,000 ppm, or more preferably 10-200 ppm.
- minami-kiiro-azamiuma also known as Thrips palmi
- synthetic pyrethroide type
- insecticides which is also one of the effective
- agents which contain the individual active ingredients are prepared and then mixed together later.
- Polyoxyethylene-alkylphenylether 6 parts The above components were mixed and melted to obtain a 31% emulsion.
- a mixed aqueous solution of propargite (BPPS) and synthetic pyrethroid type insecticides was diluted to the concentrations shown in Table 1, and sprayed on individually potted 20-30 cm tall greenhouse grown eggplants (kind: Kokuyo) which were severely infested by minami-kiiro-azamiuma by using a portable sprayer until the liquid started to drip from the leaves.
- the number of adult and larvae of minami-kiiro-azamiuma were counted before the spraying and a few days after the spraying, and its effectiveness compared with the effectiveness obtained by spraying them individually. The results are shown in Table 1.
- Example 2 The effect of propargite (BPPS) and synthetic pyrethroid mixtures on minami-kiiro-azaiuma was studied in a manner similar to Example 3, except that the emulsion form of Example 2 was used. The results are shown in Table 2.
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Dentistry (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Agronomy & Crop Science (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Compounds comprised of 2-(4-tert-butylphenoxy) cyclohexyl prop-2-ynyl sulfite and a synthetic pyrethroid exhibit synergistic pesticidal activity.
Description
INSECTICIDE COMPOUNDS FOR AGRICULTURAL AND HORTICULTURAL USE BACKGROUND OF THE INVENTION
1. Field of the Invention
This invention is directed to mixtures of propargite and synthetic pyrethroids, which exhibit synergistic activity as pesticides.
Thrips palmi is a transplanted insect from
Southeast Asia which has caused serious damage to cucumber, watermelon, melon, eggplant and green pepper in recent years. It has no strong natural enemy, and believed to cause more serious growth damage or fruit damage than any other known insect. Compounds such as sulbrophos, oxamil, carbosulphane, cypermethrin, pemfracalp, BMPC, DMTP, cyfulbenzron, etc. have been used in the past. However, none of them has had a sufficient protective effect.
SUMMARY OF THE INVENTION
The compositions of the present invention contain an active ingredient comprising a mixture of A) propargite, and B) a synthetic pyrethroid. The presen invention also comprises a method for controlling undesirable insects which comprises applying an effective amount of a composition according to the present invention to a locus to be protected.
DETAILED DESCRIPTION OF THE INVENTION
The propargite portion of the active ingredient is a well known insecticide sold under the trademark OMITE (Uniroyal Chemical Company) and has the chemical name 2-(4-tert-butylphenoxy) cyclohexyl prop-2-ynyl sulfite. Examples of the synthetic pyrethroid active ingredient are cyfluthrin, fenpropathrin, cyhalothrin, fulvalinate, tralomethrin, etofenprox, fulcytirinate, cypermethrin, permethrin, and fenvalelate.
In the insecticide compositions of the present invention, the propargite component may be present in the amount of from 3 to 1,000 ppm, or more preferably 100-400 ppm. The synthetic pyrethroide type component may be present in the amount of from 1 to 1,000 ppm, or more preferably 10-200 ppm.
Propargite, which is one of the effective
components of the insecticide offered by the present invention, shows almost no effect against
minami-kiiro-azamiuma (also known as Thrips palmi) by itself. In addition, synthetic pyrethroide type
insecticides, which is also one of the effective
components of the insecticide compounds offered by the present invention, does not show sufficient effect against minami-kiiro-azamiuma by itself even in the case of cypermethrin which has obtained the Agricultural
Chemical Registration in Japan. The compositions
offered by the present invention give superior
effectiveness which cannot be obtained by each component
alone .
As it is described in the application example, common forms of agricultural agents such as aqueous solutions, emulsions, dry-flowable, flowable, or smoke agent which contain the propargite and the synthetic pyrethroide type insecticides may be prepared.
Alternatevely, agents which contain the individual active ingredients are prepared and then mixed together later.
The present invention is explained in detail by reference to the following examples.
Example 1
Propargite 30 parts
Tralomethrin 1 part
White Carbon (Silica) 2 parts
Diatmaceous Earth 58 parts
Alkylbenzene sodium sulfonate 2 parts
Lignin sodium sulfonate 7 parts
The above components were uniformly mixed, and dissolved in water to obtain a 31% aqueous solution.
Example 2
Propargite 30 parts
Tralomethrin 1 part
Xylene 44 parts
Dimethylformamide 15 parts
Alkylbenzene calcium sulfonate 4 parts
Polyoxyethylene-alkylphenylether 6 parts
The above components were mixed and melted to obtain a 31% emulsion.
Example 3
A mixed aqueous solution of propargite (BPPS) and synthetic pyrethroid type insecticides was diluted to the concentrations shown in Table 1, and sprayed on individually potted 20-30 cm tall greenhouse grown eggplants (kind: Kokuyo) which were severely infested by minami-kiiro-azamiuma by using a portable sprayer until the liquid started to drip from the leaves. The number of adult and larvae of minami-kiiro-azamiuma were counted before the spraying and a few days after the spraying, and its effectiveness compared with the effectiveness obtained by spraying them individually. The results are shown in Table 1.
Example 4
The effect of propargite (BPPS) and synthetic pyrethroid mixtures on minami-kiiro-azaiuma was studied in a manner similar to Example 3, except that the emulsion form of Example 2 was used. The results are shown in Table 2.
Claims
1. An insecticidal composition comprising:
(A) 2-(4-tert-butylρhenoxy) cyclohexyl prop-2-ynyl sulfite; and
(B) a synthetic pyrethroid selected from the group consisting of cyfluthrin, fenpropathrin, cyhalothrin, fulvalinate, tralomethrin, etofenprox, fulcytirinate, cypermethrin, permethrin, and fenvalelate.
2. A composition in accordance with claim 1 wherein component (A) is present in an concentration from 3-1000 ppm and component (B) is present in a concentration from 1-1000 ppm..
3. A process for controlling undesirable pests which comprises applying to a locus to be protected a pesticidally effective amount of a composition in accordance with claim 1.
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AU25432/92A AU656227B2 (en) | 1991-08-27 | 1992-08-27 | Insecticide compounds for agricultural and horticultural use |
| EP92919208A EP0601089A1 (en) | 1991-08-27 | 1992-08-27 | Insecticide compounds for agricultural and horticultural use |
| US08/199,233 US5491168A (en) | 1991-08-27 | 1992-08-27 | Synergistic insecticidal compositions |
| BG98568A BG98568A (en) | 1991-08-27 | 1994-02-24 | Synergetic insecticide compositions |
| US08/636,294 US5631285A (en) | 1991-08-27 | 1996-04-23 | Synergistic insecticidal compositions |
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP238,923 | 1991-08-27 | ||
| JP23892391 | 1991-08-27 | ||
| JP3289157A JPH05112411A (en) | 1991-08-27 | 1991-10-08 | Insecticide composition for agriculture and horticulture |
| JP289,157 | 1991-10-08 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| WO1993003618A2 true WO1993003618A2 (en) | 1993-03-04 |
| WO1993003618A3 WO1993003618A3 (en) | 1993-05-13 |
Family
ID=26533984
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/US1992/007288 Ceased WO1993003618A2 (en) | 1991-08-27 | 1992-08-27 | Insecticide compounds for agricultural and horticultural use |
Country Status (5)
| Country | Link |
|---|---|
| EP (1) | EP0601089A1 (en) |
| JP (1) | JPH05112411A (en) |
| AU (1) | AU656227B2 (en) |
| BG (1) | BG98568A (en) |
| WO (1) | WO1993003618A2 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2003011031A1 (en) * | 2001-07-25 | 2003-02-13 | Syngenta Limited | Insecticidal mixture containing gamma-cyhalothrin |
| CN105494414A (en) * | 2015-12-29 | 2016-04-20 | 南京华洲药业有限公司 | Synergistic insecticidal composition containing propargite and cyfluthrin and application thereof |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH679591A5 (en) * | 1989-08-23 | 1992-03-13 | Rieter Ag Maschf |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3463859A (en) * | 1963-07-18 | 1969-08-26 | Uniroyal Inc | Method of protecting plants with sulfurous acid organic esters |
| EP0412937A1 (en) * | 1989-08-10 | 1991-02-13 | Ciba-Geigy Ag | Plant acaricide |
-
1991
- 1991-10-08 JP JP3289157A patent/JPH05112411A/en active Pending
-
1992
- 1992-08-27 WO PCT/US1992/007288 patent/WO1993003618A2/en not_active Ceased
- 1992-08-27 EP EP92919208A patent/EP0601089A1/en not_active Withdrawn
- 1992-08-27 AU AU25432/92A patent/AU656227B2/en not_active Ceased
-
1994
- 1994-02-24 BG BG98568A patent/BG98568A/en unknown
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2003011031A1 (en) * | 2001-07-25 | 2003-02-13 | Syngenta Limited | Insecticidal mixture containing gamma-cyhalothrin |
| EA005502B1 (en) * | 2001-07-25 | 2005-02-24 | Синджента Лимитед | Insecticidal mixture containing gamma-cyhalothrin |
| AP1669A (en) * | 2001-07-25 | 2006-10-20 | Syngenta Ltd | Insecticidal mixture containing gamma-cyhalothrin. |
| CN1331395C (en) * | 2001-07-25 | 2007-08-15 | 辛甄塔有限公司 | Insecticidal mixture containing gamma-cyhalothrin |
| CN100401893C (en) * | 2001-07-25 | 2008-07-16 | 辛甄塔有限公司 | Insecticidal mixture containing gamma-cyhalothrin |
| EP2087791A3 (en) * | 2001-07-25 | 2009-09-16 | Syngenta Limited | Insecticidal mixture containing gamma-cyhalothrin |
| US7906127B2 (en) | 2001-07-25 | 2011-03-15 | Syngenta Limited | Insecticidal mixture containing gamma-cyhalothrin |
| US8852618B2 (en) | 2001-07-25 | 2014-10-07 | Syngenta Limited | Insecticidal mixture containing gamma-cyhalothrin |
| EP2260708A3 (en) * | 2001-07-25 | 2015-04-15 | Syngenta Limited | Insecticidal mixture containing gamma-cyhalothrin |
| CN105494414A (en) * | 2015-12-29 | 2016-04-20 | 南京华洲药业有限公司 | Synergistic insecticidal composition containing propargite and cyfluthrin and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0601089A1 (en) | 1994-06-15 |
| WO1993003618A3 (en) | 1993-05-13 |
| BG98568A (en) | 1995-02-28 |
| AU656227B2 (en) | 1995-01-27 |
| JPH05112411A (en) | 1993-05-07 |
| AU2543292A (en) | 1993-03-16 |
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