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WO1992012929A3 - Chromite de lanthane enrichi pour operations de cuisson a basses temperatures - Google Patents

Chromite de lanthane enrichi pour operations de cuisson a basses temperatures Download PDF

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Publication number
WO1992012929A3
WO1992012929A3 PCT/US1992/000509 US9200509W WO9212929A3 WO 1992012929 A3 WO1992012929 A3 WO 1992012929A3 US 9200509 W US9200509 W US 9200509W WO 9212929 A3 WO9212929 A3 WO 9212929A3
Authority
WO
WIPO (PCT)
Prior art keywords
beneficiated
lanthanum chromite
low temperature
temperature firing
ranges
Prior art date
Application number
PCT/US1992/000509
Other languages
English (en)
Other versions
WO1992012929A2 (fr
Inventor
Ned E Cipollini
Beili Li Wu
Stephen Haig
Jean Yamanis
Original Assignee
Allied Signal Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Allied Signal Inc filed Critical Allied Signal Inc
Priority to JP4506220A priority Critical patent/JPH0733257B2/ja
Priority to DE69200395T priority patent/DE69200395T2/de
Priority to EP92905974A priority patent/EP0568640B1/fr
Publication of WO1992012929A2 publication Critical patent/WO1992012929A2/fr
Publication of WO1992012929A3 publication Critical patent/WO1992012929A3/fr

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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/02—Details
    • H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
    • H01M8/0204—Non-porous and characterised by the material
    • H01M8/0215—Glass; Ceramic materials
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G37/00—Compounds of chromium
    • C01G37/006—Compounds containing chromium, with or without oxygen or hydrogen, and containing two or more other elements
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/42—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on chromites
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/624—Sol-gel processing
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
    • H01M8/1213—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte characterised by the electrode/electrolyte combination or the supporting material
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/02—Amorphous compounds
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/50—Solid solutions
    • C01P2002/52—Solid solutions containing elements as dopants
    • C01P2002/54—Solid solutions containing elements as dopants one element only
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/10—Solid density
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/12—Surface area
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
    • H01M2008/1293—Fuel cells with solid oxide electrolytes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0017—Non-aqueous electrolytes
    • H01M2300/0065—Solid electrolytes
    • H01M2300/0068—Solid electrolytes inorganic
    • H01M2300/0071—Oxides
    • H01M2300/0074—Ion conductive at high temperature
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Ceramic Engineering (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Structural Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Compositions Of Oxide Ceramics (AREA)
  • Fuel Cell (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)

Abstract

L'invention se rapporte à un mélange de poudres de céramique au chromite de lanthane, qui est constitué essentiellement par 1 mole de LaCr1-xMxO3, où M représente un métal bivalent choisi dans le groupe du magnésium, du calcium et de mélanges de ceux-ci et x est compris entre 0,03 et 0,3; y moles de B2O3, où y est compris entre 0,005 et 0,04; et z moles de La2O3, où le rapport z/y est compris entre 1,1 et 3. Ce mélange est produit sous la forme de comprimés de poudre et il est fritté à des températures aussi basses que 1400 °C jusqu'à présenter une compacité presque totale.
PCT/US1992/000509 1991-01-22 1992-01-21 Chromite de lanthane enrichi pour operations de cuisson a basses temperatures WO1992012929A2 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
JP4506220A JPH0733257B2 (ja) 1991-01-22 1992-01-21 低温焼成に特に適した亜クロム酸ランタン
DE69200395T DE69200395T2 (de) 1991-01-22 1992-01-21 Angereichertes lanthancrhomit zum brennen bei niederen temperaturen.
EP92905974A EP0568640B1 (fr) 1991-01-22 1992-01-21 Chromite de lanthane enrichi pour operations de cuisson a basses temperatures

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US07/643,255 US5169811A (en) 1991-01-22 1991-01-22 Beneficiated lanthanum chromite for low temperature firing
US643,255 1991-01-22

Publications (2)

Publication Number Publication Date
WO1992012929A2 WO1992012929A2 (fr) 1992-08-06
WO1992012929A3 true WO1992012929A3 (fr) 1992-09-17

Family

ID=24580027

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1992/000509 WO1992012929A2 (fr) 1991-01-22 1992-01-21 Chromite de lanthane enrichi pour operations de cuisson a basses temperatures

Country Status (5)

Country Link
US (1) US5169811A (fr)
EP (1) EP0568640B1 (fr)
JP (1) JPH0733257B2 (fr)
DE (1) DE69200395T2 (fr)
WO (1) WO1992012929A2 (fr)

Families Citing this family (38)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5286686A (en) * 1990-04-20 1994-02-15 Allied-Signal Inc. Air-sinterable lanthanum chromite and process for its preparation
US5298469A (en) * 1991-01-22 1994-03-29 Alliedsignal Inc. Fluxed lanthanum chromite for low temperature air firing
US5403461A (en) * 1993-03-10 1995-04-04 Massachusetts Institute Of Technology Solid electrolyte-electrode system for an electrochemical cell
EP0669296B1 (fr) * 1994-02-23 1998-03-04 Samsung Electronics Co., Ltd. Procédé de formage d'un oxide métallique composite et procédé de fabrication d'une électrode utilisant cela
JP3656882B2 (ja) * 1997-11-17 2005-06-08 日本碍子株式会社 電気化学的素子の製造方法
US6296962B1 (en) 1999-02-23 2001-10-02 Alliedsignal Inc. Design for solid oxide fuel cell stacks
US7163713B2 (en) * 1999-07-31 2007-01-16 The Regents Of The University Of California Method for making dense crack free thin films
US6767662B2 (en) 2000-10-10 2004-07-27 The Regents Of The University Of California Electrochemical device and process of making
ATE508488T1 (de) * 2001-12-18 2011-05-15 Univ California Verfahren zur herstellung dichter dünnfilme
EP1456900A4 (fr) 2001-12-18 2008-05-07 Univ California Collecte metallique de courant protegee par un film d'oxyde
WO2003092046A2 (fr) * 2002-04-24 2003-11-06 The Regents Of The University Of California Dispositif electrochimique planaire
JP4960593B2 (ja) * 2002-05-07 2012-06-27 ザ・リージェンツ・オブ・ザ・ユニバーシティ・オブ・カリフォルニア 電気化学的電池スタック組立体
KR101089623B1 (ko) * 2002-10-04 2011-12-06 더 리전츠 오브 더 유니버시티 오브 캘리포니아 불소 분리 및 발생 장치
US8618436B2 (en) 2006-07-14 2013-12-31 Ceramatec, Inc. Apparatus and method of oxidation utilizing a gliding electric arc
EP2116105A4 (fr) * 2007-02-23 2014-04-16 Ceramatec Inc Electrode en ceramique pour arc electrique glissant
US9561476B2 (en) 2010-12-15 2017-02-07 Praxair Technology, Inc. Catalyst containing oxygen transport membrane
US9115032B2 (en) * 2011-02-24 2015-08-25 Praxair Technology, Inc. Sintering aids for lanthanide ceramics
KR101342921B1 (ko) 2011-11-10 2013-12-18 (재)울산테크노파크 수열합성법을 이용한 고체산화물 연료전지 접속자용 ＬａＣｒＯ₃ 나노분말의 제조방법
US8795417B2 (en) 2011-12-15 2014-08-05 Praxair Technology, Inc. Composite oxygen transport membrane
US9486735B2 (en) 2011-12-15 2016-11-08 Praxair Technology, Inc. Composite oxygen transport membrane
EP2935155B1 (fr) 2012-12-19 2019-02-13 Praxair Technology Inc. Procédé de scellement d'un ensemble membrane de transport d'oxygène
US9453644B2 (en) 2012-12-28 2016-09-27 Praxair Technology, Inc. Oxygen transport membrane based advanced power cycle with low pressure synthesis gas slip stream
US9296671B2 (en) 2013-04-26 2016-03-29 Praxair Technology, Inc. Method and system for producing methanol using an integrated oxygen transport membrane based reforming system
US9212113B2 (en) 2013-04-26 2015-12-15 Praxair Technology, Inc. Method and system for producing a synthesis gas using an oxygen transport membrane based reforming system with secondary reforming and auxiliary heat source
US9938145B2 (en) 2013-04-26 2018-04-10 Praxair Technology, Inc. Method and system for adjusting synthesis gas module in an oxygen transport membrane based reforming system
US9611144B2 (en) 2013-04-26 2017-04-04 Praxair Technology, Inc. Method and system for producing a synthesis gas in an oxygen transport membrane based reforming system that is free of metal dusting corrosion
WO2015054228A2 (fr) 2013-10-07 2015-04-16 Praxair Technology, Inc. Réacteur à réseau de membranes de transport d'oxygène céramiques et procédé de reformage
US9573094B2 (en) 2013-10-08 2017-02-21 Praxair Technology, Inc. System and method for temperature control in an oxygen transport membrane based reactor
WO2015084729A1 (fr) 2013-12-02 2015-06-11 Praxair Technology, Inc. Procédé et système de production d'hydrogène au moyen d'un système de reformage à base de membrane de transport d'oxygène avec un reformage secondaire
WO2015123246A2 (fr) 2014-02-12 2015-08-20 Praxair Technology, Inc. Procédé à base de réacteur à membrane de transport d'oxygène et système pour la production d'énergie électrique
WO2015160609A1 (fr) 2014-04-16 2015-10-22 Praxair Technology, Inc. Procédé et système pour cycle combiné à gazéificateur intégré (igcc) amélioré par une membrane de transport d'oxygène
US9789445B2 (en) 2014-10-07 2017-10-17 Praxair Technology, Inc. Composite oxygen ion transport membrane
US10441922B2 (en) 2015-06-29 2019-10-15 Praxair Technology, Inc. Dual function composite oxygen transport membrane
US10118823B2 (en) 2015-12-15 2018-11-06 Praxair Technology, Inc. Method of thermally-stabilizing an oxygen transport membrane-based reforming system
US9938146B2 (en) 2015-12-28 2018-04-10 Praxair Technology, Inc. High aspect ratio catalytic reactor and catalyst inserts therefor
JP2019513081A (ja) 2016-04-01 2019-05-23 プラクスエア・テクノロジー・インコーポレイテッド 触媒含有酸素輸送膜
EP3797085A1 (fr) 2018-05-21 2021-03-31 Praxair Technology, Inc. Panneau de gaz de synthèse otm avec reformeur chauffé au gaz
DE102020006598A1 (de) 2020-10-27 2022-04-28 Technische Universität Bergakademie Freiberg, Körperschaft des öffentlichen Rechts Feuerfester Keramikwerkstoff auf der Basis von La2O3 und Verfahren zu seiner Herstellung

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1988003332A1 (fr) * 1986-10-23 1988-05-05 University Of Chicago Additif de frittage pour materiaux refractaires a base de chromite de lanthane
WO1989003806A1 (fr) * 1987-10-23 1989-05-05 Allied-Signal Inc. Preparation de poudres de chromite de lanthane par sol-gel
WO1991016276A1 (fr) * 1990-04-20 1991-10-31 Allied-Signal Inc. Chromite de lanthane reactif au frittage et procede de production

Family Cites Families (1)

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Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1988003332A1 (fr) * 1986-10-23 1988-05-05 University Of Chicago Additif de frittage pour materiaux refractaires a base de chromite de lanthane
WO1989003806A1 (fr) * 1987-10-23 1989-05-05 Allied-Signal Inc. Preparation de poudres de chromite de lanthane par sol-gel
WO1991016276A1 (fr) * 1990-04-20 1991-10-31 Allied-Signal Inc. Chromite de lanthane reactif au frittage et procede de production

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
GLASS AND CERAMICS. vol. 38, no. 11, November 1981, NEW YORK US pages 634 - 636; V. L. BALKEVICH ET ALL: 'SINTERING LANTHANUM CHROMITE IN AN OXIDIZING MEDIUM' *
JOURNAL OF POWER SOURCES. vol. 1, no. 2, 1976, LAUSANNE CH pages 203 - 213; W. BAUKAL ET ALL: 'DAS ELEKTRODENVERBINDUNGSMATERIAL, EIN ZENTRALES BAUELEMENT IN HOCHTEMPERATUR-BRENSTOFFZELLEN' *
PATENT ABSTRACTS OF JAPAN vol. 14, no. 318 (C-738)9 July 1990 & JP,A,02 111 632 ( AGENCY OF IND. SCIENCE & TECHNOL. ) 24 April 1990 *

Also Published As

Publication number Publication date
WO1992012929A2 (fr) 1992-08-06
EP0568640A1 (fr) 1993-11-10
DE69200395D1 (de) 1994-10-13
EP0568640B1 (fr) 1994-09-07
JPH05508830A (ja) 1993-12-09
US5169811A (en) 1992-12-08
JPH0733257B2 (ja) 1995-04-12
DE69200395T2 (de) 1995-02-23

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