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WO1992011952A1 - Stratifies enduits de resine de barriere - Google Patents

Stratifies enduits de resine de barriere Download PDF

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Publication number
WO1992011952A1
WO1992011952A1 PCT/US1992/000003 US9200003W WO9211952A1 WO 1992011952 A1 WO1992011952 A1 WO 1992011952A1 US 9200003 W US9200003 W US 9200003W WO 9211952 A1 WO9211952 A1 WO 9211952A1
Authority
WO
WIPO (PCT)
Prior art keywords
vinylidene chloride
coating
chloride copolymer
group
metal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US1992/000003
Other languages
English (en)
Inventor
Clifford Cheng-Shiou Chang
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Priority to JP4-504417A priority Critical patent/JP3007155B2/ja
Priority to FI933160A priority patent/FI933160L/fi
Priority to KR1019930702061A priority patent/KR930703089A/ko
Publication of WO1992011952A1 publication Critical patent/WO1992011952A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/14—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/14—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies
    • B05D7/16—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies using synthetic lacquers or varnishes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2201/00—Polymeric substrate or laminate
    • B05D2201/04—Laminate
    • B05D2201/06—Laminate of which the last layer is not a polymer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2506/00—Halogenated polymers
    • B05D2506/20—Chlorinated polymers

Definitions

  • the invention relates to materials that have improved heat seal properties.
  • the invention relates to metallized polymer films that have improved heat seal properties for use in packaging.
  • the polymer films typically are coated with polymeric, barrier layer compositions.
  • These barrier layer compositions typically include coating additives such as aluminum silicates, talc, waxes and the like to impart desired film properties such as jaw release, printability, film slip and the like.
  • coating additives such as aluminum silicates, talc, waxes and the like to impart desired film properties such as jaw release, printability, film slip and the like.
  • these additives tend to reduce the coating adhesion and heat seal properties of the coated polymer film.
  • Metal foils such as aluminum foil also have been used as packaging materials for products such as food stuffs. Metal foils are useful for packaging due to their low permeability to oxygen and water vapor. Metal foils, however, are subject to significant cost variability, have poor heat seal properties, and poor flex-crack resistance.
  • Japanese 6223174, published October 12, 1987, shows production of metallized sheets of paper and plastic.
  • the process comprises applying a polyvinylidene chloride copolymer of methacrylic ester, acrylonitrile, vinyl chloride, and methacrylic acid onto the metallized surface of a sheet of paper or plastic.
  • the polyvinylidene chloride copolymer then is oxidized.
  • the invention is directed to metallized materials that have a a metallic coating on one or more surfaces that show improved barrier layer coating adhesion and heat seal properties.
  • These metallized materials include a coating of vinylidene copolymer on the metallic coating.
  • the polyvinylidene chloride copolymer has at least 80% vinylidene chloride, at least 4% of an ethylenically unsaturated acrylic monomer, as well as. coating additives for modifying film properties.
  • the metallized materials that show improved barrier layer coating adhesion and heat seal properties are made by treating a substrate material that has at least one metallic surface thereon with a formulated solution of coating additives and vinylidene chloride copolymer.
  • the polyvinylidene chloride copolymer comprises at least 80% by weight polyvinylidene chloride, at least 4% by weight of an ethylenically unsaturated acrylic ester.
  • the solution of copolymer of vinylidene chloride and coating additives forms a barrier layer that imparts surprisingly improved adhesion and heat seal properties to materials such as polyesters that bear metal layers thereon.
  • Such substrate materials include, but are not limited to plastics, regenerated cellulose, paper, metallized plastics, metallized regenerated cellulose, metallized paper and the like.
  • Suitable plastics for use in the invention include, but are not limited to polyesters, polyolefins, polyamides, vinyl chlorides, copolymers thereof, as well as blends thereof.
  • Additional examples of materials whose adhesive and heat seal properties may be improved by the vinylidene chloride copolymer of the invention include but are not limited to metal foils such as aluminum foil.
  • the formulated solution of vinylidene chloride copolymer and coating additives may be applied to the substrate materials by any conventional method known in the art. Such methods include solvent solution coating, emulsion coating, melt coating, and the like.
  • the vinylidene chloride copolymer is applied in a conventional coating tower by passing the substrate material through a solvent solution of formulated vinylidene chloride copolymer and coating additives, and thereafter evaporating the solvent to yield a layer of formulated vinylidene chloride polymer and coating additives on the substrate.
  • the substrate materials preferably metallized polymeric films, that are coated with the formulated solution of vinylidene chloride copolymer and coating additives have particular utility in packaging for materials such as foodstuffs. These coated substrate materials can be employed as produced. Alternatively, but without limitation, the coated metallized substrate materials may be used in the form of a laminated film structure. The coated substrate materials produced by the invention also may be used in applications such as, but not limited to, insulation materials for the construction industry. Having briefly summarized the invention, the invention will now be described in detail by reference to the following specification and non-limiting examples. Unless otherwise specified, all percentages are by weight and all temperatures are in degrees Celsius.
  • a formulated solution of vinylidene chloride (VDC) copolymer and up to 10% by weight of copolymer of coating additives is applied to a metal bearing substrate, preferably metallized polymer film, most preferably metallized polyethylene terephthalate.
  • the VDC copolymer has at least 80%, but not more than 95% vinylidene chloride.
  • the balance of the vinylidene chloride copolymer comprises an ethylenically unsaturated acrylate, preferably methyl methacrylate (MMA) .
  • the ethylenically unsaturated acrylate comprises at least 4% of the VDC copolymer.
  • ethylenically unsaturated polyacrylates may be employed in place of MMA or in combination with MMA.
  • suitable ethylenically unsaturated acrylates include, but are not limited to, aliphatic C_-C 6 acrylates, aliphatic C 2 -C 8 methacrylates, and the like.
  • ethylenically unsaturated acrylates include, but are not limited to butyl acrylate, methyl acrylate, ethyl acrylate and the like.
  • aliphatic methacrylates include methyl metha ⁇ rylate, ethyl methacrylate, and the like.
  • acrylonitrile (AN) may be included in the vinylidene chloride copolymer provided that the copolymer has at least 4% of ethylenically unsaturated polyacrylate.
  • the copolymer has 80 to 95% vinylidene chloride and 4 to 20% ethylenically unsaturated acrylate, most preferably 88 to 92% vinylidene chloride and 6 to 12% ethylenically unsaturated acrylate.
  • the metal bearing materials that can be coated with the formulated solution of vinylidene chloride copolymer and coating additives preferably are metallized polymers.
  • suitable polymers include polyesters, polyolefins, polyamides, polyvinylchloride, copolymers thereof, and blends thereof. Any oxidizable metal such as Fe, Cu, Al, Ti, alloys thereof, and the like, most preferably aluminum, may form the metal component of the metallized polymer films.
  • the metallized polymeric film is alu inized polyethylene terephthalate.
  • Such metallized polymers are made by processes known in the art, as described for example in ''Encyclopedia of Chemical Technology", Kirk-Othmer, 3rd Edition, Volume 15, pp.
  • metal bearing materials that may be coated may be other than metallized polymers.
  • additional metal bearing materials that may be employed in the invention include metallized regenerated cellulose and polyolefins such as metallized paper, metallized oriented polypropylene, and the like.
  • the improved products of the invention are preferably prepared by applying a coating solution of more than 90% by weight of a vinylidene chloride copolymer that has at least four percent of ethylenically unsaturated acrylate and up to 10% by weight of coating additives to at least the metal bearing surface of a metal bearing substrate.
  • coating additives include talc, waxes, aluminum silicates, and the like.
  • the formulated solution of vinylidene chloride copolymer may be applied to both the metal bearing surface and the non-metal bearing surface of the substrate material.
  • the formulated solution of vinylidene chloride copolymer and coating additives preferably is applied to the metallized substrate. Thereafter the solvent of the vinylidene chloride copolymer solution is evaporated to provide a coating of vinylidene chloride copolymer and coating additives on at least the metallized surface of the substrate.
  • Application of the solution of formulated polyvinylidene chloride copolymer conveniently can be performed in a conventional coating tower, as is known in the art.
  • the formulated solution of vinylidene chloride copolymer and coating additives may be applied by emulsion coating of a solution of formulated vinylidene chloride copolymer onto the substrate.
  • the copolymer of vinylidene chloride and ethylenically unsaturated monomer, preferably MMA is dissolved in a solvent such as tetrahydrofuran (THF) , toluene, methyl ethyl ketone, nonpolar solvents such as 1,3-dibromopropane, bromobenzene, alpha-chloronaphthalene, 2-methylnaphthalene, o-dichlorobenzene, polar aproctic solvents such as tetramethylene sulfoxide, N-methyl pyrrolidone, trimethylene sulfide, isopropyl sulfoxide, N-acetyl pyrrolidine, N,N-dimethyl acetamide, or mixtures thereof.
  • a solvent such as tetrahydrofuran (THF) , toluene, methyl ethyl ketone, nonpolar solvents such as 1,3-di
  • the solvent is a mixture of at least 15% THF, the balance being toluene, most preferably 60-75% THF and 25-40% toluene.
  • the formulated solution of vinylidene chloride copolymer then is applied to at least the metal bearing surface of a polymer substrate, preferably polyester, most preferably polyethylene terephthalate, in an air drying, laboratory-scale coating tower.
  • the inlet temperature and the outlet temperature of the coating tower may be in the range of 70''C to 130"C.
  • the inlet temperature is 120"C and the outlet temperature is 80"C.
  • the coated polyethylene terephthalate is passed through the coating tower at the rate of 30 to 90 feet per minute, preferably 90 feet per minute.
  • coated materials achieved by the invention have properties which make them particularly suited for use as packaging materials for foodstuffs where deterioration due to oxidation and change of moisture content is a concern.
  • properties are determined by the tests described below.
  • Heat seal strength is measured by cutting three samples of the coated metallized substrates that measure 1 x 10 inches. These samples are cut with the grain or machine direction of the film running in the long dimension of the sample. The samples are taken from the east, west and center edges of the coated, metallized substrate. Each sample is folded in half in the machine direction. The halves of the sample are sealed together at each end at right angles to the grain by applying a 0.75 inch wide sealing bar under carefully controlled conditions of temperature, pressure and contact time. The resulting three sets of strips are tested by opening each set at the free end, placing them in a Suter testing machine, and 5 pulling them apart while maintaining the folded end perpendicular to the pull direction. The highest force in grams required to pull the strips apart is taken as a measure of the heat seal bond strength.
  • Heat seals are measured on the coated material as is.
  • Q The laminate bond strength is measured by laminating a film sample to a 2-mil thick polyethylene film by using an adhesive such as a two-component curing type adhesive system.
  • the adhesive coating weight applied is typically 1-1.5 lb dry solids per 5 ream.
  • a heated pressure-nip roll is set at a lamination temperature of 170-2207, typically 215"F.
  • the laminates While preparing the laminate of sample film to polyetherylene film, 15 or more sheets of release paper are inserted between the film sample and the polyethylene film at approximately 5 ft intervals to provide non-bonded areas in the laminate in order to assist initiation of delamination during bond strength tests.
  • the laminates are cured at 25 ⁇ C for at least 7 days before being tested for bond strength.
  • both sides are reinforced from outside with a polyimide adhesive tape to prevent the test films from tearing.
  • Five 1 x 8 inch specimens per test are cut with the long dimension parallel to the web direction. Samples are obtained from various locations across the web width. The laminate sample is tested "as is" for bond strength, or tested after being moisture conditioned.
  • the moisture conditioning can be done in two ways. Samples with the non-bonded starting area exposed are conditioned in an enclosed dessicator at 40 ⁇ C for 1, 3, or 7 days, respectively. The bottom of each dessicator is filled with water.
  • the laminate bond strength is recorded as "grams per inch width" by pulling apart the two films of the laminate (as separated by the release paper) in a tensile machine while holding the tail of the specimen at right angles to the direction of pull so that a constant shear peel is established.
  • the bond strength reported for one sample is typically an average value of five film specimens tested under duplicating conditions.
  • the vinylidene chloride copolymer employed has the following weight percentage composition: vinylidene chloride 91.3, acrylonitrile 1.8, methyl methacrylate 6.9; A formulated solution of 90.64% of the copolymer, 1.01% talc, 8.12% waxes, and a 0.23% aromatic polyester resin is prepared in a solvent of 65% THF and 35% toluene. The mixture is heated to 40"C to 45°C until the polymer is dissolved. The solid content of the bath solution is 18%.
  • the aromatic polyester resin used in the formulated solution is prepared by trans-esterifying the bis-(ethylene glycol) esters of terephthalic acid. isophthalic acid, adipic acid, and azelaic acid using a tetraisopropyl titanate catalyst and following the procedures of U.S. patent 2,892,747.
  • a conventional solvent coating tower is used to apply the formulated solution to both the metallized and non-metallized surfaces of a 1/2 mil aluminized polyethylene terephthalate film moving at 90 feet per minute.
  • the formulated solution is placed in a dip tank maintained at 40"C and transferred to the metallized polyethylene terephthalate by a doctor roll.
  • the doctor roll setting is 0.003 inches.
  • Inlet and outlet tower temperatures of the coating tower are 120 ⁇ C and 80°C respectively.
  • Inlet and outlet tower air supply is 250 and 300 cubic feet per minute respectively.
  • the coating weight is determined by the weight difference between the coated and uncoated samples.
  • the coated samples are tested for heat seal and laminate bond strength properties both as is, and after conditioning. Conditioning entails leaving the samples in a dessicator for periods of either 24 hours, 72 hours, or 1 week. The bottom of the dessicator is filled with water. The results are shown in Table 1.
  • Example 1 The procedure of Example 1 is followed except that the vinylidene chloride copolymer has the following weight percentage composition: vinylidene chloride 90.5, methyl ethacrylate 9.5.
  • the heat seal and laminate bond strength properties are shown in Table 1.
  • Example 1 The procedure of Example 1 is followed except that the vinylidene chloride copolymer has the following weight percentage composition: vinylidene chloride 90.9, methyl methacrylate 9.1.
  • the heat seal and laminate bond strength properties are shown in Table 1.
  • Example 1 The procedure of Example 1 is followed except that the vinylidene chloride copolymer has the following weight percentage composition: vinylidene chloride 91.6, acrylonitrile 4.0, methyl methacrylate 4.4.
  • the heat seal and laminate bond strength properties are shown in Table 1. COMPARISON EXAMPLE 1
  • Example 2 The procedure of Example 1 is followed except that the vinylidene chloride copolymer has the following weight percentage co positon: vinylidene chloride 92.1, acrylonitrile 5.5, methyl methacrylate 2.5. The heat seal and laminate bond strength properties are shown in Table 1.
  • COMPARISON EXAMPLE 2 The procedure of Comparison Example 1 is followed except that no coating additives are included in the formulated solution.
  • the vinylidene chloride copolymer employed has the following weight percentage composition: vinylidene chloride 92.1, acrylonitrile 5.5, methyl methacrylate 2.5.
  • the heat seal and laminate bond strength properties are show in in Table 1.
  • Table 1 shows that the heat seal and laminate bond strength properties of the coated metallized side improve significantly as the quantity of methyl methacrylate in the vinylidene chloride copolymer contains at least 4% MMA or more. This improvement occurs despite the presence of coating additives.

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Laminated Bodies (AREA)
  • Wrappers (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

Matériaux métallisés dont une ou plusieurs surfaces sont dotées d'un enduit métallique et présentent des propriétés améliorées d'adhésion de la couche de barrière et de soudure à chaud. Ces matériaux comprennent un enduit en copolymère de vinylidène à au moins 80 % de chlorure de vinylidène, au moins 4 % d'un monomère acrylique insaturé par éthylène, ainsi que des additifs d'enduction servant à modifier les caractéristiques du film.
PCT/US1992/000003 1991-01-10 1992-01-02 Stratifies enduits de resine de barriere Ceased WO1992011952A1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
JP4-504417A JP3007155B2 (ja) 1991-01-10 1992-01-02 障壁樹脂被覆ラミネート
FI933160A FI933160L (fi) 1991-01-10 1992-01-02 Med barriaerharts oeverdragna laminat
KR1019930702061A KR930703089A (ko) 1991-01-10 1992-01-02 배리어(barrier) 수지로 피복된 라미네이트

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US63978691A 1991-01-10 1991-01-10
US639,786 1991-01-10

Publications (1)

Publication Number Publication Date
WO1992011952A1 true WO1992011952A1 (fr) 1992-07-23

Family

ID=24565542

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1992/000003 Ceased WO1992011952A1 (fr) 1991-01-10 1992-01-02 Stratifies enduits de resine de barriere

Country Status (11)

Country Link
EP (1) EP0566669A1 (fr)
KR (1) KR930703089A (fr)
AU (1) AU1205292A (fr)
CA (1) CA2103920A1 (fr)
FI (1) FI933160L (fr)
MX (1) MX9200084A (fr)
NZ (1) NZ241247A (fr)
TW (1) TW212155B (fr)
WO (1) WO1992011952A1 (fr)
ZA (1) ZA92191B (fr)
ZW (1) ZW592A1 (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4344438A1 (de) * 1993-12-24 1995-06-29 Renker Gmbh & Co Kg Barrierefolie
DE4445193A1 (de) * 1993-12-24 1995-07-06 Renker Gmbh & Co Kg Barrierepapier/-karton
WO2022238280A1 (fr) 2021-05-12 2022-11-17 Societe Des Produits Nestle S.A. Matériau d'emballage de papier recyclable comprenant des couches barrières métallisées et polymères attachées par un liant

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3353992A (en) * 1964-03-09 1967-11-21 Dow Chemical Co Coating of polymer film and sheet
FR2516860A1 (fr) * 1981-11-26 1983-05-27 Moplefan Spa Feuilles couplees pour des emballages impermeables aux gaz, a base de pellicules de polyolefines
EP0096581A1 (fr) * 1982-06-07 1983-12-21 Idemitsu Petrochemical Co. Ltd. Matériaux stratifiés

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3353992A (en) * 1964-03-09 1967-11-21 Dow Chemical Co Coating of polymer film and sheet
FR2516860A1 (fr) * 1981-11-26 1983-05-27 Moplefan Spa Feuilles couplees pour des emballages impermeables aux gaz, a base de pellicules de polyolefines
EP0096581A1 (fr) * 1982-06-07 1983-12-21 Idemitsu Petrochemical Co. Ltd. Matériaux stratifiés

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
WORLD PATENTS INDEX LATEST Week 40, 1983 Derwent Publications Ltd., London, GB; AN 83-780660 & JP,A,58 145 734 (DAICEL CHEM IND.K.K.) 30 August 1983 *
WORLD PATENTS INDEX Week 08, 1976 Derwent Publications Ltd., London, GB; AN 76-14116X & JP,A,51 002 738 (ASAHI DOW K.K.) 10 January 1976 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4344438A1 (de) * 1993-12-24 1995-06-29 Renker Gmbh & Co Kg Barrierefolie
DE4445193A1 (de) * 1993-12-24 1995-07-06 Renker Gmbh & Co Kg Barrierepapier/-karton
WO2022238280A1 (fr) 2021-05-12 2022-11-17 Societe Des Produits Nestle S.A. Matériau d'emballage de papier recyclable comprenant des couches barrières métallisées et polymères attachées par un liant

Also Published As

Publication number Publication date
AU1205292A (en) 1992-08-17
FI933160A7 (fi) 1993-07-09
NZ241247A (en) 1994-07-26
ZW592A1 (en) 1992-04-01
JPH06504497A (ja) 1994-05-26
KR930703089A (ko) 1993-11-29
FI933160A0 (fi) 1993-07-09
EP0566669A1 (fr) 1993-10-27
ZA92191B (en) 1993-07-12
TW212155B (fr) 1993-09-01
MX9200084A (es) 1992-07-01
CA2103920A1 (fr) 1992-07-11
FI933160L (fi) 1993-07-09

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