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WO1992006063A3 - Carbonylation d'alcools allyliques et synthese d'un compose de parfum a base d'ambre gris - Google Patents

Carbonylation d'alcools allyliques et synthese d'un compose de parfum a base d'ambre gris Download PDF

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Publication number
WO1992006063A3
WO1992006063A3 PCT/US1991/006832 US9106832W WO9206063A3 WO 1992006063 A3 WO1992006063 A3 WO 1992006063A3 US 9106832 W US9106832 W US 9106832W WO 9206063 A3 WO9206063 A3 WO 9206063A3
Authority
WO
WIPO (PCT)
Prior art keywords
carbonylation
fragrance compound
synthesis
allylic alcohols
ambergris fragrance
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US1991/006832
Other languages
English (en)
Other versions
WO1992006063A2 (fr
Inventor
Jonathan M Cassel
Steven M Hoagland
James M Renga
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Cognis Corp
Original Assignee
Henkel Research Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel Research Corp filed Critical Henkel Research Corp
Priority to EP91918961A priority Critical patent/EP0553205B1/fr
Priority to DE69118709T priority patent/DE69118709T2/de
Priority to JP3517257A priority patent/JPH06501687A/ja
Publication of WO1992006063A2 publication Critical patent/WO1992006063A2/fr
Publication of WO1992006063A3 publication Critical patent/WO1992006063A3/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/52—Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
    • C07C69/587—Monocarboxylic acid esters having at least two carbon-to-carbon double bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • C07C51/12—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Procédé de carbonylation d'alcools allyliques, tels que le nérolidol, le farnésol et leurs analogues monocycliques, avec un monoxyde de carbone à une pression d'au moins 30 bar en présence d'un solvant polaire et d'un catalyseur à base d'halogénure de palladium, éventuellement d'un sel d'halogénure métallique alcalin, et éventuellement un solvant à base d'alcool. Le produit carbonylé peut alors être réduit en l'alcool correspondant, qui est cyclisé en présence d'acides de lewis ou de Brönsted pour produire le composé de parfum d'ambre gris.
PCT/US1991/006832 1990-10-09 1991-09-23 Carbonylation d'alcools allyliques et synthese d'un compose de parfum a base d'ambre gris Ceased WO1992006063A2 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
EP91918961A EP0553205B1 (fr) 1990-10-09 1991-09-23 Carbonylation d'alcools allyliques et synthese d'un compose de parfum a base d'ambre gris
DE69118709T DE69118709T2 (de) 1990-10-09 1991-09-23 Carbonylierung von allylalkoholen und synthese eines riechstoffes des grauen ambras
JP3517257A JPH06501687A (ja) 1990-10-09 1991-09-23 アリル型アルコールのカルボニル化およびアンバーグリス芳香性化合物の合成

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US594,249 1990-10-09
US07/594,249 US5326888A (en) 1990-10-09 1990-10-09 Carbonylation of allylic alcohols and synthesis of an ambergris fragance compound

Publications (2)

Publication Number Publication Date
WO1992006063A2 WO1992006063A2 (fr) 1992-04-16
WO1992006063A3 true WO1992006063A3 (fr) 1992-08-20

Family

ID=24378138

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1991/006832 Ceased WO1992006063A2 (fr) 1990-10-09 1991-09-23 Carbonylation d'alcools allyliques et synthese d'un compose de parfum a base d'ambre gris

Country Status (6)

Country Link
US (2) US5326888A (fr)
EP (1) EP0553205B1 (fr)
JP (1) JPH06501687A (fr)
DE (1) DE69118709T2 (fr)
ES (1) ES2089239T3 (fr)
WO (1) WO1992006063A2 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US12172956B2 (en) 2018-02-13 2024-12-24 Basf Se Method for the isomerization of a 3-(Z)-unsaturated carboxylic acid to the 3-(E)-isomer

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5326888A (en) * 1990-10-09 1994-07-05 Henkel Research Corporation Carbonylation of allylic alcohols and synthesis of an ambergris fragance compound
NZ599365A (en) 2009-10-02 2013-11-29 Univ Idaho Potato products with enhanced resistant starch content and moderated glycemic response and methods thereof
US20130273619A1 (en) 2012-04-16 2013-10-17 Basf Se Process for the Preparation of (3E, 7E)-Homofarnesol
JP6226954B2 (ja) 2012-04-16 2017-11-08 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ （３ｅ，７ｅ）−ホモファルネソールの改良製造方法
ES2610413T3 (es) 2012-11-23 2017-04-27 Firmenich Sa Hidrocarbonilación o metoxicarbonilación de derivados de 1,3-dieno con complejo de paladio
PL3319951T3 (pl) 2015-07-10 2022-02-28 Basf Se Sposób hydroformylowania 2-podstawionych butadienów oraz wytwarzania ich produktów pochodnych, w szczególności ambroksu
CN110312701B (zh) 2017-02-24 2022-06-03 巴斯夫欧洲公司 通过烯丙醇及其酰化产物的羰基化制备不饱和羧酸的方法
EP3476822A1 (fr) * 2017-10-31 2019-05-01 Givaudan SA Procédé de fabrication de composés organiques
GB202010072D0 (en) 2020-07-01 2020-08-12 Givaudan Sa Enzyme-mediated process
EP4613868A2 (fr) 2020-09-02 2025-09-10 International Flavors & Fragrances Inc. Dérivés de squalene hopene cyclase et leur utilisation pour la production d'ambrox
GB202020331D0 (en) 2020-12-22 2021-02-03 Givaudan Sa Process of making organic compounds
GB202020330D0 (en) 2020-12-22 2021-02-03 Givaudan Sa Process of making organic compounds
WO2025093710A1 (fr) 2023-11-02 2025-05-08 Basf Se Procédé de cyclisation stéréosélective de polyène

Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4189608A (en) * 1976-02-19 1980-02-19 Chevron Research Company Carboxylic acid preparation
EP0063818A1 (fr) * 1981-04-27 1982-11-03 National Distillers And Chemical Corporation Procédé de préparation d'esters alkyliques de l'acide nonadiénoique
EP0107857A1 (fr) * 1982-10-28 1984-05-09 Consortium für elektrochemische Industrie GmbH Procédé de préparation du 8,12-époxy-13,14,15,16-tétranorlabdane
EP0124160A1 (fr) * 1983-05-02 1984-11-07 Shell Internationale Researchmaatschappij B.V. Procédé de préparation d'acides carboxyliques et/ou d'esters
EP0165458A2 (fr) * 1984-05-14 1985-12-27 T. Hasegawa Company, Ltd. (+/-)-Ambrox, procédé pour sa préparation et son utilisation
US4585594A (en) * 1984-12-11 1986-04-29 Basf Aktiengesellschaft Preparation of 4-substituted but-3-ene-1-carboxylic acids and their esters
US4801743A (en) * 1981-06-22 1989-01-31 National Distillers And Chemical Corporation Process for preparing carboxylic acids
EP0338730A1 (fr) * 1988-04-16 1989-10-25 The British Petroleum Company p.l.c. Carbonylation d'alcools allyliques
EP0395546A2 (fr) * 1989-04-28 1990-10-31 Rhone-Poulenc Chimie Procédé de préparation d'acides beta,gamma-insaturés
EP0403945A2 (fr) * 1989-06-19 1990-12-27 Firmenich Sa Carbinols cycloaliphatiques et leur utilisation à titre de produits de départ pour la préparation de dérivés furanniques
EP0433191A1 (fr) * 1989-12-13 1991-06-19 Rhone-Poulenc Chimie Procédé de préparation d'acides hexènedioiques-1,6 à partir de butènediol
EP0433190A1 (fr) * 1989-12-13 1991-06-19 Rhone-Poulenc Chimie ProcÀ©dé de préparation d'acides hexènedioiques-1,6

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3655745A (en) * 1968-09-06 1972-04-11 Union Oil Co Preparation of methacrylic acid
US4681707A (en) * 1982-09-30 1987-07-21 The British Petroleum Company P.L.C. Process for the production of carboxylic acid esters and/or carboxylic acids
US5326888A (en) * 1990-10-09 1994-07-05 Henkel Research Corporation Carbonylation of allylic alcohols and synthesis of an ambergris fragance compound

Patent Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4189608A (en) * 1976-02-19 1980-02-19 Chevron Research Company Carboxylic acid preparation
EP0063818A1 (fr) * 1981-04-27 1982-11-03 National Distillers And Chemical Corporation Procédé de préparation d'esters alkyliques de l'acide nonadiénoique
US4801743A (en) * 1981-06-22 1989-01-31 National Distillers And Chemical Corporation Process for preparing carboxylic acids
EP0107857A1 (fr) * 1982-10-28 1984-05-09 Consortium für elektrochemische Industrie GmbH Procédé de préparation du 8,12-époxy-13,14,15,16-tétranorlabdane
EP0124160A1 (fr) * 1983-05-02 1984-11-07 Shell Internationale Researchmaatschappij B.V. Procédé de préparation d'acides carboxyliques et/ou d'esters
EP0165458A2 (fr) * 1984-05-14 1985-12-27 T. Hasegawa Company, Ltd. (+/-)-Ambrox, procédé pour sa préparation et son utilisation
US4585594A (en) * 1984-12-11 1986-04-29 Basf Aktiengesellschaft Preparation of 4-substituted but-3-ene-1-carboxylic acids and their esters
EP0338730A1 (fr) * 1988-04-16 1989-10-25 The British Petroleum Company p.l.c. Carbonylation d'alcools allyliques
EP0395546A2 (fr) * 1989-04-28 1990-10-31 Rhone-Poulenc Chimie Procédé de préparation d'acides beta,gamma-insaturés
EP0403945A2 (fr) * 1989-06-19 1990-12-27 Firmenich Sa Carbinols cycloaliphatiques et leur utilisation à titre de produits de départ pour la préparation de dérivés furanniques
EP0433191A1 (fr) * 1989-12-13 1991-06-19 Rhone-Poulenc Chimie Procédé de préparation d'acides hexènedioiques-1,6 à partir de butènediol
EP0433190A1 (fr) * 1989-12-13 1991-06-19 Rhone-Poulenc Chimie ProcÀ©dé de préparation d'acides hexènedioiques-1,6

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US12172956B2 (en) 2018-02-13 2024-12-24 Basf Se Method for the isomerization of a 3-(Z)-unsaturated carboxylic acid to the 3-(E)-isomer

Also Published As

Publication number Publication date
ES2089239T3 (es) 1996-10-01
WO1992006063A2 (fr) 1992-04-16
DE69118709T2 (de) 1996-08-08
DE69118709D1 (de) 1996-05-15
US5639894A (en) 1997-06-17
EP0553205A1 (fr) 1993-08-04
JPH06501687A (ja) 1994-02-24
US5326888A (en) 1994-07-05
EP0553205B1 (fr) 1996-04-10

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