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WO1991012224A3 - Reacteur a conversion a lit circulant et a charge d'alimentation double et procede pour convertir des hydrocarbures legers en olefines, essence et methanol - Google Patents

Reacteur a conversion a lit circulant et a charge d'alimentation double et procede pour convertir des hydrocarbures legers en olefines, essence et methanol Download PDF

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Publication number
WO1991012224A3
WO1991012224A3 PCT/US1991/000937 US9100937W WO9112224A3 WO 1991012224 A3 WO1991012224 A3 WO 1991012224A3 US 9100937 W US9100937 W US 9100937W WO 9112224 A3 WO9112224 A3 WO 9112224A3
Authority
WO
WIPO (PCT)
Prior art keywords
light hydrocarbons
gasoline
methanol
olefins
cofeed
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US1991/000937
Other languages
English (en)
Other versions
WO1991012224A2 (fr
Inventor
Charanjit Singh Bains
Martin Paul Grosboll
Behzad Jazayeri
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Lyondell Chemical Co
Original Assignee
Lyondell Petrochemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lyondell Petrochemical Co filed Critical Lyondell Petrochemical Co
Priority to EP91904659A priority Critical patent/EP0515500A1/fr
Priority to PCT/US1991/000937 priority patent/WO1991012224A2/fr
Priority to CA002075891A priority patent/CA2075891A1/fr
Publication of WO1991012224A2 publication Critical patent/WO1991012224A2/fr
Publication of WO1991012224A3 publication Critical patent/WO1991012224A3/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/1516—Multisteps
    • C07C29/1518—Multisteps one step being the formation of initial mixture of carbon oxides and hydrogen for synthesis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/1845—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with particles moving upwards while fluidised
    • B01J8/1863—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with particles moving upwards while fluidised followed by a downward movement outside the reactor and subsequently re-entering it
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/24—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
    • B01J8/38—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique with fluidised bed containing a rotatable device or being subject to rotation or to a circulatory movement, i.e. leaving a vessel and subsequently re-entering it
    • B01J8/384—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique with fluidised bed containing a rotatable device or being subject to rotation or to a circulatory movement, i.e. leaving a vessel and subsequently re-entering it being subject to a circulatory movement only
    • B01J8/388—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique with fluidised bed containing a rotatable device or being subject to rotation or to a circulatory movement, i.e. leaving a vessel and subsequently re-entering it being subject to a circulatory movement only externally, i.e. the particles leaving the vessel and subsequently re-entering it
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/76—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/76—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen
    • C07C2/82—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen oxidative coupling
    • C07C2/84—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen oxidative coupling catalytic
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/152—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the reactor used
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/04—Liquid carbonaceous fuels essentially based on blends of hydrocarbons
    • C10L1/06—Liquid carbonaceous fuels essentially based on blends of hydrocarbons for spark ignition
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • C07C2523/04—Alkali metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/32—Manganese, technetium or rhenium
    • C07C2523/34—Manganese
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S585/00—Chemistry of hydrocarbon compounds
    • Y10S585/929—Special chemical considerations
    • Y10S585/943—Synthesis from methane or inorganic carbon source, e.g. coal

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

Cette invention concerne une méthode de conversion des hydrocarbures légers en oléfines, essence et méthanol. Dans la phase initiale, un gaz contenant un ou plusieurs hydrocarbures est synthétisé de façon à produire des hydrocarbures supérieurs, y compris de l'essence brute. Cependant, à des sélectivités commercialement acceptables, utilisant un catalyseur actuellement disponible, la majeure partie des hydrocarbures légers demeurent non synthétisés. De plus, le procédé de synthèse produit des quantités importantes de dioxyde de carbone et une certaine quantité de monoxyde de carbone. Selon cette méthode, les hydrocarbures légers non synthétisés et les oxydes de carbone sont utilisés pour produire du méthanol, qui peut être utilisé à plusieurs fins, dont la synthèse d'essence ou d'éthylène.
PCT/US1991/000937 1990-02-12 1991-02-12 Reacteur a conversion a lit circulant et a charge d'alimentation double et procede pour convertir des hydrocarbures legers en olefines, essence et methanol Ceased WO1991012224A2 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
EP91904659A EP0515500A1 (fr) 1990-02-12 1991-02-12 Reacteur a conversion a lit circulant et a charge d'alimentation double et procede pour convertir des hydrocarbures legers en olefines, essence et methanol
PCT/US1991/000937 WO1991012224A2 (fr) 1990-02-12 1991-02-12 Reacteur a conversion a lit circulant et a charge d'alimentation double et procede pour convertir des hydrocarbures legers en olefines, essence et methanol
CA002075891A CA2075891A1 (fr) 1990-02-12 1991-02-12 Reacteur de transformation a lit circulant et alimentation mixte et methode de transformation d'hydrocarbures legers en olefines, essence et methanol

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
US479,086 1990-02-12
US07/479,086 US5026934A (en) 1990-02-12 1990-02-12 Method for converting light hydrocarbons to olefins, gasoline and methanol
US53191090A 1990-06-01 1990-06-01
US531,910 1990-06-01
PCT/US1991/000937 WO1991012224A2 (fr) 1990-02-12 1991-02-12 Reacteur a conversion a lit circulant et a charge d'alimentation double et procede pour convertir des hydrocarbures legers en olefines, essence et methanol
CN91101783.6A CN1064474A (zh) 1990-02-12 1991-02-25 轻质烃转化成烯烃、汽油和甲醇的方法

Publications (2)

Publication Number Publication Date
WO1991012224A2 WO1991012224A2 (fr) 1991-08-22
WO1991012224A3 true WO1991012224A3 (fr) 1992-04-02

Family

ID=36764652

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1991/000937 Ceased WO1991012224A2 (fr) 1990-02-12 1991-02-12 Reacteur a conversion a lit circulant et a charge d'alimentation double et procede pour convertir des hydrocarbures legers en olefines, essence et methanol

Country Status (6)

Country Link
US (1) US5026934A (fr)
EP (1) EP0515500A1 (fr)
CN (1) CN1064474A (fr)
CA (1) CA2075891A1 (fr)
NZ (1) NZ237096A (fr)
WO (1) WO1991012224A2 (fr)

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JP2925963B2 (ja) * 1994-12-05 1999-07-28 石油公団 メタンの酸化カップリング方法とその装置
US6201029B1 (en) 1996-02-13 2001-03-13 Marathon Oil Company Staged combustion of a low heating value fuel gas for driving a gas turbine
US5733941A (en) * 1996-02-13 1998-03-31 Marathon Oil Company Hydrocarbon gas conversion system and process for producing a synthetic hydrocarbon liquid
US5861441A (en) * 1996-02-13 1999-01-19 Marathon Oil Company Combusting a hydrocarbon gas to produce a reformed gas
US6313361B1 (en) 1996-02-13 2001-11-06 Marathon Oil Company Formation of a stable wax slurry from a Fischer-Tropsch reactor effluent
US6130259A (en) * 1996-02-13 2000-10-10 Marathon Oil Company Hydrocarbon gas conversion system and process for producing a synthetic hydrocarbon liquid
EP0909258A1 (fr) * 1996-06-21 1999-04-21 Syntroleum Corporation Systeme et methode de production de gaz de synthese
PE17599A1 (es) 1996-07-09 1999-02-22 Syntroleum Corp Procedimiento para convertir gases a liquidos
US5950732A (en) * 1997-04-02 1999-09-14 Syntroleum Corporation System and method for hydrate recovery
US6011073A (en) * 1997-10-10 2000-01-04 Syntroleum Corporation System and method for converting light hydrocarbons to heavier hydrocarbons with separation of water into oxygen and hydrogen
US6096934A (en) * 1998-12-09 2000-08-01 Uop Llc Oxidative coupling of methane with carbon conservation
US7838708B2 (en) 2001-06-20 2010-11-23 Grt, Inc. Hydrocarbon conversion process improvements
US6794417B2 (en) 2002-06-19 2004-09-21 Syntroleum Corporation System and method for treatment of water and disposal of contaminants produced by converting lighter hydrocarbons into heavier hydrocarbon
US7161051B2 (en) * 2002-12-30 2007-01-09 Exxonmobil Chemical Patents Inc. Integration of a methanol synthesis system with a methanol to olefin reaction system
US7151198B2 (en) * 2002-12-30 2006-12-19 Exxonmobil Chemical Patents Inc. Integration of a methanol synthesis system with a methanol to olefin reaction system
MXPA06000470A (es) 2003-07-15 2006-08-23 Grt Inc Sintesis de hidrocarburos.
US20050171393A1 (en) 2003-07-15 2005-08-04 Lorkovic Ivan M. Hydrocarbon synthesis
US20080275284A1 (en) 2004-04-16 2008-11-06 Marathon Oil Company Process for converting gaseous alkanes to liquid hydrocarbons
US8642822B2 (en) 2004-04-16 2014-02-04 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons using microchannel reactor
US20060100469A1 (en) 2004-04-16 2006-05-11 Waycuilis John J Process for converting gaseous alkanes to olefins and liquid hydrocarbons
US7244867B2 (en) 2004-04-16 2007-07-17 Marathon Oil Company Process for converting gaseous alkanes to liquid hydrocarbons
US7674941B2 (en) 2004-04-16 2010-03-09 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons
US8173851B2 (en) 2004-04-16 2012-05-08 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons
US7579510B2 (en) 2006-02-03 2009-08-25 Grt, Inc. Continuous process for converting natural gas to liquid hydrocarbons
SG187456A1 (en) 2006-02-03 2013-02-28 Grt Inc Separation of light gases from halogens
JP2010528054A (ja) 2007-05-24 2010-08-19 ジーアールティー インコーポレイテッド 可逆的なハロゲン化水素の捕捉及び放出を組み込んだ領域反応器
US7989507B2 (en) * 2008-05-20 2011-08-02 Siemens Aktiengesellschaft Production of fuel materials utilizing waste carbon dioxide and hydrogen from renewable resources
US8282810B2 (en) 2008-06-13 2012-10-09 Marathon Gtf Technology, Ltd. Bromine-based method and system for converting gaseous alkanes to liquid hydrocarbons using electrolysis for bromine recovery
AU2009270801B2 (en) 2008-07-18 2014-04-24 Reaction 35, Llc Continuous process for converting natural gas to liquid hydrocarbons
CN102639676B (zh) * 2009-11-10 2015-05-27 国际壳牌研究有限公司 用于生产烯烃的方法
US8367884B2 (en) 2010-03-02 2013-02-05 Marathon Gtf Technology, Ltd. Processes and systems for the staged synthesis of alkyl bromides
US8198495B2 (en) 2010-03-02 2012-06-12 Marathon Gtf Technology, Ltd. Processes and systems for the staged synthesis of alkyl bromides
US8815050B2 (en) 2011-03-22 2014-08-26 Marathon Gtf Technology, Ltd. Processes and systems for drying liquid bromine
US8436220B2 (en) 2011-06-10 2013-05-07 Marathon Gtf Technology, Ltd. Processes and systems for demethanization of brominated hydrocarbons
US8829256B2 (en) 2011-06-30 2014-09-09 Gtc Technology Us, Llc Processes and systems for fractionation of brominated hydrocarbons in the conversion of natural gas to liquid hydrocarbons
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US10793490B2 (en) 2015-03-17 2020-10-06 Lummus Technology Llc Oxidative coupling of methane methods and systems
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WO2017180910A1 (fr) 2016-04-13 2017-10-19 Siluria Technologies, Inc. Couplage oxydant de méthane pour la production d'oléfines
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WO2023034253A1 (fr) 2021-08-31 2023-03-09 Lummus Technology Llc Procédés et systèmes pour la mise en œuvre du couplage oxydatif du méthane

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US2604479A (en) * 1949-08-05 1952-07-22 Standard Oil Dev Co Selective oxidation with suspended catalyst
US3041273A (en) * 1953-09-09 1962-06-26 Sinclair Research Inc Process for the conversion of hydrocarbons with the use of an expanding transfer line reactor
US4788372A (en) * 1987-02-13 1988-11-29 Atlantic Richfield Company Methane conversion process
US4795849A (en) * 1987-08-04 1989-01-03 Atlantic Richfield Company Methane conversion process

Also Published As

Publication number Publication date
CA2075891A1 (fr) 1991-08-13
WO1991012224A2 (fr) 1991-08-22
EP0515500A1 (fr) 1992-12-02
US5026934A (en) 1991-06-25
CN1064474A (zh) 1992-09-16
NZ237096A (en) 1992-09-25

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