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WO1991011390A3 - Materiau synthetique cristallin et poreux, et procede de synthese et d'utilisation - Google Patents

Materiau synthetique cristallin et poreux, et procede de synthese et d'utilisation Download PDF

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Publication number
WO1991011390A3
WO1991011390A3 PCT/US1991/000350 US9100350W WO9111390A3 WO 1991011390 A3 WO1991011390 A3 WO 1991011390A3 US 9100350 W US9100350 W US 9100350W WO 9111390 A3 WO9111390 A3 WO 9111390A3
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WO
WIPO (PCT)
Prior art keywords
porous crystalline
synthesis
crystalline material
calcination
synthetic porous
Prior art date
Application number
PCT/US1991/000350
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English (en)
Other versions
WO1991011390A1 (fr
WO1991011390A2 (fr
Inventor
Jeffrey Scott Beck
Cynthia Ting-Wah Chu
Ivy Dawn Johnson
Charles Theodore Kresge
Michael Edward Leonowicz
Wieslaw Jerzy Roth
James Clarke Vartuli
Original Assignee
Mobil Oil Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=27504140&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=WO1991011390(A3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Priority claimed from US07/470,008 external-priority patent/US5102643A/en
Priority claimed from US07/625,171 external-priority patent/US5057296A/en
Priority claimed from US07/625,238 external-priority patent/US5108725A/en
Application filed by Mobil Oil Corp filed Critical Mobil Oil Corp
Priority to DE69106121T priority Critical patent/DE69106121T2/de
Priority to KR1019920701599A priority patent/KR0172612B1/ko
Priority to CA002072352A priority patent/CA2072352C/fr
Priority to EP91903549A priority patent/EP0512026B1/fr
Publication of WO1991011390A1 publication Critical patent/WO1991011390A1/fr
Publication of WO1991011390A2 publication Critical patent/WO1991011390A2/fr
Publication of WO1991011390A3 publication Critical patent/WO1991011390A3/fr

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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B01D53/8621—Removing nitrogen compounds
    • B01D53/8625—Nitrogen oxides
    • B01D53/8628—Processes characterised by a specific catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
    • B01J20/041—Oxides or hydroxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
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    • B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
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    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
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    • B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
    • B01J20/08—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04 comprising aluminium oxide or hydroxide; comprising bauxite
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    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/103—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate comprising silica
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    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16—Alumino-silicates
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    • B01J29/03—Catalysts comprising molecular sieves not having base-exchange properties
    • B01J29/0308—Mesoporous materials not having base exchange properties, e.g. Si-MCM-41
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    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
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    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
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    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/82—Phosphates
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J29/82—Phosphates
    • B01J29/83—Aluminophosphates [APO compounds]
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    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/82—Phosphates
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    • C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
    • C01B37/02—Crystalline silica-polymorphs, e.g. silicalites dealuminated aluminosilicate zeolites
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    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
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    • C01B37/06—Aluminophosphates containing other elements, e.g. metals, boron
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
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    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
    • C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
    • C10G47/12—Inorganic carriers
    • C10G47/16—Crystalline alumino-silicate carriers
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    • B01J2229/10—After treatment, characterised by the effect to be obtained
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    • B01J2229/32—Reaction with silicon compounds, e.g. TEOS, siliconfluoride
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    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
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    • B01J2229/34—Reaction with organic or organometallic compounds
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    • B01J2229/36—Steaming
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    • B01J2229/30—After treatment, characterised by the means used
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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Dispersion Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Catalysts (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)

Abstract

Composition comportant un matériau inorganique en phase cristalline poreuse présentant après la calcination un diagramme de diffraction des rayons X qui comporte au moins une crête à espacement d supérieur à 1,8 nm, et ayant un taux d'adsorption de benzène supérieur à 15 grammes de benzène pour 100 grammes dudit matériau à 6,7 kPa (50 torr) et à 25 °C. De préférence, le matériau en phase cristalline a une configuration hexagonale de pores de taille uniforme dont le diamètre est égal ou supérieur à 1,3 nm, et qui présentent après la calcination un diagramme hexagonal de diffraction des électrons pouvant s'indexer avec une valeur d100 supérieure à 1,8 nm.
PCT/US1991/000350 1990-01-25 1991-01-23 Materiau synthetique cristallin et poreux, et procede de synthese et d'utilisation WO1991011390A2 (fr)

Priority Applications (4)

Application Number Priority Date Filing Date Title
DE69106121T DE69106121T2 (de) 1990-01-25 1991-01-23 Synthetisches poröses kristallines material, dessen herstellung und verwendung.
KR1019920701599A KR0172612B1 (ko) 1990-01-25 1991-01-23 합성 다공성 결정성 물질, 그의 합성방법 및 용도
CA002072352A CA2072352C (fr) 1990-01-25 1991-01-23 Materiau cristallin poreux de synthese, procede de synthese et applications
EP91903549A EP0512026B1 (fr) 1990-01-25 1991-01-23 Materiau synthetique cristallin et poreux, et procede de synthese et d'utilisation

Applications Claiming Priority (8)

Application Number Priority Date Filing Date Title
US07/470,008 US5102643A (en) 1990-01-25 1990-01-25 Composition of synthetic porous crystalline material, its synthesis
US470,008 1990-01-25
US625,245 1990-12-10
US625,171 1990-12-10
US07/625,171 US5057296A (en) 1990-12-10 1990-12-10 Method for synthesizing mesoporous crystalline material
US625,238 1990-12-10
US07/625,245 US5098684A (en) 1990-01-25 1990-12-10 Synthetic mesoporous crystaline material
US07/625,238 US5108725A (en) 1990-01-25 1990-12-10 Synthesis of mesoporous crystalline material

Publications (3)

Publication Number Publication Date
WO1991011390A1 WO1991011390A1 (fr) 1991-08-08
WO1991011390A2 WO1991011390A2 (fr) 1991-08-08
WO1991011390A3 true WO1991011390A3 (fr) 1991-11-14

Family

ID=27504140

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1991/000350 WO1991011390A2 (fr) 1990-01-25 1991-01-23 Materiau synthetique cristallin et poreux, et procede de synthese et d'utilisation

Country Status (8)

Country Link
EP (1) EP0512026B1 (fr)
JP (1) JP3403402B2 (fr)
AU (1) AU644136B2 (fr)
CA (1) CA2072352C (fr)
DE (1) DE69106121T2 (fr)
DK (1) DK0512026T3 (fr)
ES (1) ES2072602T3 (fr)
WO (1) WO1991011390A2 (fr)

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US5198203A (en) * 1990-01-25 1993-03-30 Mobil Oil Corp. Synthetic mesoporous crystalline material
US5145816A (en) * 1990-12-10 1992-09-08 Mobil Oil Corporation Method for functionalizing synthetic mesoporous crystalline material
CA2069648A1 (fr) * 1991-06-21 1992-12-22 Quang N. Le Craquage du naphta
US5288395A (en) 1991-07-24 1994-02-22 Mobil Oil Corporation Production of high viscosity index lubricants
JP3388737B2 (ja) * 1991-07-24 2003-03-24 モービル・オイル・コーポレイション 超大孔寸法触媒による水素化分解
CA2113896C (fr) 1991-07-24 2004-02-24 Minas Robert Apelian Production de lubrifiants d'hydrocraquage
AU676338B2 (en) * 1993-05-14 1997-03-06 Akzo Nobel N.V. Process for hydrocracking hydrocarbons
EP0685455B1 (fr) * 1993-12-20 2000-09-27 Nippon Shokubai Co., Ltd. Procédé pour la préparation d'esters d'aryle
DE4407326A1 (de) * 1994-03-04 1995-09-21 Basf Ag Mesoporöse Molekularsiebe
AU682116B2 (en) * 1994-05-10 1997-09-18 Shell Internationale Research Maatschappij B.V. Process for preparing a large pore molecular sieve
US5560748A (en) * 1994-06-10 1996-10-01 The Procter & Gamble Company Detergent compositions comprising large pore size redox catalysts
DE4424221A1 (de) 1994-07-09 1996-01-11 Basf Magnetics Gmbh Ferromagnetische Pigmente
IT1273514B (it) 1995-04-07 1997-07-08 Eniricerche Spa Procedimento per la preparazione di un gel micro-mesoporoso
EP0739856A2 (fr) * 1995-04-25 1996-10-30 The Institute Of Physical & Chemical Research Composite silice-agent tensio-actif et son procédé de préparation
NL1001553C2 (nl) * 1995-11-02 1997-05-13 Akzo Nobel Nv Werkwijze voor de synthese van poreuze keramische materialen.
DE19543638A1 (de) 1995-11-23 1997-05-28 Basf Ag Mesoporöse Molekularsiebe
US5990039A (en) * 1996-01-11 1999-11-23 Southwest Research Institute Metal complex derived catalyst and method of forming
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DE69106121T2 (de) 1995-05-04
DE69106121D1 (de) 1995-02-02
EP0512026B1 (fr) 1994-12-21
CA2072352C (fr) 1999-06-01
AU7214891A (en) 1991-08-21
AU644136B2 (en) 1993-12-02
JPH05503499A (ja) 1993-06-10
EP0512026A1 (fr) 1992-11-11
DK0512026T3 (da) 1995-03-20
CA2072352A1 (fr) 1991-07-26
JP3403402B2 (ja) 2003-05-06
WO1991011390A2 (fr) 1991-08-08
ES2072602T3 (es) 1995-07-16

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