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WO1988009399A1 - Procede d'electrolyse utilisant un tambour - Google Patents

Procede d'electrolyse utilisant un tambour Download PDF

Info

Publication number
WO1988009399A1
WO1988009399A1 PCT/NO1988/000002 NO8800002W WO8809399A1 WO 1988009399 A1 WO1988009399 A1 WO 1988009399A1 NO 8800002 W NO8800002 W NO 8800002W WO 8809399 A1 WO8809399 A1 WO 8809399A1
Authority
WO
WIPO (PCT)
Prior art keywords
cathode
drum
electrolyte
anode
electrolysis
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/NO1988/000002
Other languages
English (en)
Inventor
Thomas Thomassen
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Cheminvest AS
Original Assignee
Cheminvest AS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from NO872243A external-priority patent/NO872243D0/no
Application filed by Cheminvest AS filed Critical Cheminvest AS
Publication of WO1988009399A1 publication Critical patent/WO1988009399A1/fr
Priority to FI890338A priority Critical patent/FI88178C/fi
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C1/00—Electrolytic production, recovery or refining of metals by electrolysis of solutions
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C7/00—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells
    • C25C7/002—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells of cells comprising at least an electrode made of particles
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C7/00—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells
    • C25C7/007—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells of cells comprising at least a movable electrode

Definitions

  • the present invention concerns a process for electrolysis wherein there is used a movable electrode in addition to one loose and freely moving solid medium present in the electrode, and a device for performing the process.
  • anode at such electrolysis is placed inside a rotatable, for instance cylindrical, cathode, it might be expected that the cathode gradually would grow solid and become useless from the deposited metal.
  • a freely movable, solid medium inside the cathode drum may inter alia comprise metal particles or -spheres of the same metal as in the electrolyte, or of another conducting or non-conducting or inert material.
  • a freely movable medium may inter alia comprise metal particles or -spheres of the same metal as in the electrolyte, or of another conducting or non-conducting or inert material.
  • sepa ⁇ rated material will be deposited on the inner medium (spheres) and not on the cathode surface.
  • the free, solid medium inside the cathode drum need not necessarily be round or sperical, but can have any shape which accomplishes the above mentioned effects, and which makes the metal deposit on the particle surface of the medium.
  • the medium inside the the rotating or otherwise movable, f.ex. shaking or vibrating, cathode also may comprise other devices, f.ex. scrapes or knives, which accomplishes a similar effect as the above mentioned solid medium.
  • an electrolyte optionall containing free particles of solid medium
  • Fig. 1 shows a cathode drum with anode discs therein reaching down into the electrolyte.
  • Fig. 2 shows a cathode drum as in fig. 1, but seen from the side and with marked roll bearings.
  • Fig. 3 shows another embodiment of a drum cathode which i ⁇ shown in fig. 1, but where the anode comprises an anode tube with holes for adding and discharging electrolyte and gasses
  • Fig. 4 shows an additional embodiment of a cathode drum, where the drum is placed obliquely for suitable sedimentatio of the particle material, and where the anode tube is sur ⁇ rounded by a non-conducting sheet for refining electrolysis.
  • a suited device for performing the electrolysis according to the present invention is shown in fig. 1 and 2, wherein the rotating cathode drum 1 with electrically isolated end plates 2 is suspended on roll bearings 3.
  • the penetrating anode comprises a conducting anode rod 4 with anode plates 5, optionally made of lead or some other siuted material, hanging down into the electrolyte.
  • the anode rod is connect to a positive terminal of a not shown current source.
  • the freely movable, particulate medium inside the rotatable end rotating cathode drum 1, is given by the reference number 7.
  • the particle material does not have any direct contact with the anode plate 5.
  • Electrolyte 8 which electrolyte may be drained, optionall together with produced silt and/or waste material, through a drinage opening 10, where the elctrolyte which is drained at 10 is poor in the current cation which is being electro ⁇ lysed.
  • Electrolyte for electrolysis, and possibly containing particulate solid medium, is supplied at 9, and the drum cathode 1 is connected to a negative terminal of a not shown current scource at 11, f.ex. inter a/lia through a sliding connection .
  • the direction of rotation for the cathode drum is given by outer arrows i fig. 2, and the current movement of the particulate medium is given by inner arrows in fig. 2.
  • Another possible embodiment of the device according to the invention is where the side walls 2 are removed, and where the particulate material may migrate towards the open ends of the cathode drum 1, and from there be taken out during rotation or shaking/vibrating of the cathode drum.
  • FIG. 3 Another embodiment of the device according to the present invention is depicted in fig. 3, where each part is provided with the same reference numbers as in figs. 1 and 2, but where the anode does not encompass anode plates, but only a tube which is perforated, and where the electrolyte solution stands in direct contact with the tube 4.
  • This embodiment makes it simple to remove produced gass by suction or blowing at 10.
  • FIG. 4 Yet another device for performing the process by electro- lysis according to the invention is given in fig. 4, wherein the anode tube 4 is perforated here as well, but where the middle anode section 16-17 is provided with a non ⁇ conducting cloth 18 and where this section 14 has separate supplying devices 13 and exit devices 15 for particulate material, silt and solutions.
  • suc a device may be used for refining of metals or electrolysis where so- called red/ox-pairs are present, such as in f.ex.
  • the purpose for this experiment vas to determine the effect of the process according to the invention during production of metal, i.e. to determine whether metal did not deposit on the cathode walls but on the particulate material in the cathode drum only.
  • the anode comprised in this trial 19 lead anode plates with a mutual distance of 5 cm inside the cathode drum.
  • the electrolysis device was mounted on rolls, and a variable motor rotated the drum with 17 rpm while the anode was stationary.
  • the device was heated by help of heating cables placed around the drum (2 x 400 W) and received their energy via two sliding contacts of 220 V.
  • a contact thermostate regulated the temperature with 5 C accuracy.
  • the positive end of a rectifier was connected to the anode rod which protruded from openings in the end walls of the cathode drum.
  • the negative pole was connected to a 5 mm lead plate which slided against teh rotating cylinder and was kept in place by a spring, somehting which gave good contact without tendencies to spark production.
  • the system coud withstand 200 A. Elelctrolyte was supplied through the one end of the cathode drum, and drained from the other end. Current was supplied when the working temperature was reached while the drum rotated continously. 5 Continous repacement of the particulate medium was not performed in htis experiment, and the particles were allowed to grow. The experiment was done during 9k hours at only 25-28 C by using 60 A. This gave a current density of
  • the current density was increased to 800 A/m , while the temperature was kept to 55-60°C with a supply of 32 g/1 Cu.
  • the trial was performed with a cell voltage of 3,0-3,6 V,
  • Experiment 5 shows as in experiment 4 that the drained solution contains very little metal ions, and that the selectivity for depositing copper against antimony and arsenic is very good. Table 5.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Electrolytic Production Of Metals (AREA)
  • Electrical Discharge Machining, Electrochemical Machining, And Combined Machining (AREA)
  • Discharge Heating (AREA)

Abstract

Un procédé d'électrolyse d'un métal à partir d'un électrolyte placé à l'intérieur d'un tambour rotatif servant de cathode permet d'obtenir, grâce à l'utilisation d'un matériau particulaire solide insoluble se déplaçant librement et présent dans le tambour, que le métal soumis à l'électrolyse ne se dépose pas sur les parois du tambour mais se dépose sur le matériau particulaire présent dans le tambour.
PCT/NO1988/000002 1987-05-27 1988-01-08 Procede d'electrolyse utilisant un tambour Ceased WO1988009399A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
FI890338A FI88178C (fi) 1987-05-27 1989-01-24 Trumelektrolys

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
NO872243 1987-05-27
NO872243A NO872243D0 (no) 1987-05-27 1987-05-27 Trommelelektrolyse.
NO872388A NO164921C (no) 1987-05-27 1987-06-05 Fremgangsmaate ved elektroutvinning av metall samt anordning for utfoerelse av fremgangsmaaten.
NO872388 1987-06-05

Publications (1)

Publication Number Publication Date
WO1988009399A1 true WO1988009399A1 (fr) 1988-12-01

Family

ID=26648034

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/NO1988/000002 Ceased WO1988009399A1 (fr) 1987-05-27 1988-01-08 Procede d'electrolyse utilisant un tambour

Country Status (9)

Country Link
EP (1) EP0319552A1 (fr)
JP (1) JPH01501951A (fr)
CN (1) CN88103116A (fr)
AU (1) AU598097B2 (fr)
CA (1) CA1335435C (fr)
FI (1) FI88178C (fr)
MX (1) MX170337B (fr)
NO (1) NO164921C (fr)
WO (1) WO1988009399A1 (fr)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0458395A1 (fr) * 1990-05-23 1991-11-27 Stork Screens B.V. Procédé de charge d'un accumulateur à suspension de zinc; accumulateur à suspension de zinc et suspension de zinc utilisable dans un accumulateur
WO1992014865A1 (fr) * 1991-02-14 1992-09-03 Materials Research Pty. Ltd. Appareil de recuperation de mineraux
WO1994002663A1 (fr) * 1992-07-17 1994-02-03 Mallonbury Pty. Ltd. Methode et appareil de recuperation de mineraux
WO1994004720A1 (fr) * 1992-08-26 1994-03-03 Spunboa Pty. Ltd. Systeme d'oxydation electrolytique
RU2380437C2 (ru) * 2007-11-01 2010-01-27 Институт вулканологии и сейсмологии ДВО РАН Способ извлечения меди из оксидных или сульфидных руд и их концентратов
DE102021211142A1 (de) 2021-10-04 2023-04-06 Robert Bosch Gesellschaft mit beschränkter Haftung Kugelmühle und Verfahren zur Gewinnung mindestens eines Metalls

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102296325B (zh) * 2011-06-15 2016-05-04 马光甲 旋转阴极连续固相电解处理废铅蓄电池工艺
CN102787330B (zh) * 2012-08-04 2015-01-28 昆明理工大学 一种电解方法
CN112877538A (zh) * 2021-01-11 2021-06-01 中南大学 一种自旋流电场强化置换回收镉绵的装置及方法
CN115838215A (zh) * 2022-07-22 2023-03-24 苏州科技大学 一种处理难降解有机废水的装置及方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2031615A1 (de) * 1969-06-26 1971-01-14 Clevite Corp , Cleveland, Ohio (VStA) Gerat zur kontinuierlichen elektro lytischen Erzeugung von Nickelfohe
US3974049A (en) * 1973-08-03 1976-08-10 Parel. Societe Anonyme Electrochemical process
EP0129523A1 (fr) * 1983-06-17 1984-12-27 ElectroCell Systems AB Unité de chambre à électrode pour une cellule électrochimique ayant une électrode poreuse percolante
EP0151055A2 (fr) * 1984-01-09 1985-08-07 Yves Heroguelle Perfectionnements aux dispositifs de récupération galvanique de métaux en solutions diluées

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5335883A (en) * 1976-09-14 1978-04-03 Toshiba Corp Production management data computing system

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2031615A1 (de) * 1969-06-26 1971-01-14 Clevite Corp , Cleveland, Ohio (VStA) Gerat zur kontinuierlichen elektro lytischen Erzeugung von Nickelfohe
US3974049A (en) * 1973-08-03 1976-08-10 Parel. Societe Anonyme Electrochemical process
EP0129523A1 (fr) * 1983-06-17 1984-12-27 ElectroCell Systems AB Unité de chambre à électrode pour une cellule électrochimique ayant une électrode poreuse percolante
EP0151055A2 (fr) * 1984-01-09 1985-08-07 Yves Heroguelle Perfectionnements aux dispositifs de récupération galvanique de métaux en solutions diluées

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
Chem Techn 36 (1984): 11, D SCHAB, K HIEN, "Elektrolytische Metallruckgewinnung in Elektrolyse-Zellen mit Bewegter Schuttgutkatode", pp 451-455, see page 452, fig 1 and column 2, line 46-page 453, column 1, line 9 *
Metall 35 (1981): 5 C H YAMAUCHI et al, "Nickelfeinstein-Elektrolyse mit Partikelelektroden", pp 401-407, see page 402, center column and fig No 3 *

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0458395A1 (fr) * 1990-05-23 1991-11-27 Stork Screens B.V. Procédé de charge d'un accumulateur à suspension de zinc; accumulateur à suspension de zinc et suspension de zinc utilisable dans un accumulateur
WO1992014865A1 (fr) * 1991-02-14 1992-09-03 Materials Research Pty. Ltd. Appareil de recuperation de mineraux
US5529672A (en) * 1991-02-14 1996-06-25 Material Research Pty. Ltd. Mineral recovery apparatus
WO1994002663A1 (fr) * 1992-07-17 1994-02-03 Mallonbury Pty. Ltd. Methode et appareil de recuperation de mineraux
WO1994004720A1 (fr) * 1992-08-26 1994-03-03 Spunboa Pty. Ltd. Systeme d'oxydation electrolytique
US5595645A (en) * 1992-08-26 1997-01-21 Spunboa Pty Ltd Electrolytic oxidation process
AU677963B2 (en) * 1992-08-26 1997-05-15 Spunboa Pty Ltd Electrolytic oxidizer
RU2380437C2 (ru) * 2007-11-01 2010-01-27 Институт вулканологии и сейсмологии ДВО РАН Способ извлечения меди из оксидных или сульфидных руд и их концентратов
DE102021211142A1 (de) 2021-10-04 2023-04-06 Robert Bosch Gesellschaft mit beschränkter Haftung Kugelmühle und Verfahren zur Gewinnung mindestens eines Metalls

Also Published As

Publication number Publication date
CA1335435C (fr) 1995-05-02
AU598097B2 (en) 1990-06-14
AU1155488A (en) 1988-12-21
EP0319552A1 (fr) 1989-06-14
MX170337B (es) 1993-08-17
CN88103116A (zh) 1988-12-28
NO872388D0 (no) 1987-06-05
NO164921B (no) 1990-08-20
FI88178C (fi) 1993-04-13
FI890338A0 (fi) 1989-01-24
NO164921C (no) 1990-11-28
NO872388L (no) 1988-11-28
FI88178B (fi) 1992-12-31
JPH01501951A (ja) 1989-07-06
FI890338L (fi) 1989-01-24

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