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WO1983000370A1 - Appareil et procede de reduction de la pression d'une boue abrasive de haute pression - Google Patents

Appareil et procede de reduction de la pression d'une boue abrasive de haute pression Download PDF

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Publication number
WO1983000370A1
WO1983000370A1 PCT/US1981/001748 US8101748W WO8300370A1 WO 1983000370 A1 WO1983000370 A1 WO 1983000370A1 US 8101748 W US8101748 W US 8101748W WO 8300370 A1 WO8300370 A1 WO 8300370A1
Authority
WO
WIPO (PCT)
Prior art keywords
slurry
pressure
deceleration zone
foamed slurry
velocity
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US1981/001748
Other languages
English (en)
Inventor
Pittsburg & Midway Coal Mining Co. The
Carl D. Ackerman
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Pittsburgh and Midway Coal Mining Co
Original Assignee
Pittsburgh and Midway Coal Mining Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Pittsburgh and Midway Coal Mining Co filed Critical Pittsburgh and Midway Coal Mining Co
Priority to AU80873/82A priority Critical patent/AU8087382A/en
Publication of WO1983000370A1 publication Critical patent/WO1983000370A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/008—Controlling or regulating of liquefaction processes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal

Definitions

  • This invention relates to process control of multi phase -flowin .streams. More particularly this inven ⁇ tion relates to an improved method and apparatus for reducing the pressure of high pressure abrasive slurries.
  • the present invention will be particularly useful in processes designed to convert naturally occurring carbonaceous material having high ash and sulfur content to low-ash, low-sulfur fuels wherein the effluent from the reactor includes gases, liquids, and abrasive solids.
  • Solvent refined coal processes have been described in U.S. Patent Nos. 4,159,238; 3,892,654; 3,884,796; 3,884,795; 3,884,794; 3,808,119; and 3,341,447.
  • OMPI U.S. Patent No. 4,159,23a discloses separation of a product slurry from a coal liquefaction process into two components.
  • the first component is recirculated for use as slurry at the beginning of the process.
  • Tnis recycle ⁇ 5 stream comprises solvent, normally dissolved coal ana catalytic mineral residue.
  • the non-recycled portion ot this slurry passes to an atmospheric fractionator for separation of the major products of tne process.
  • tne slurry stream should be near atmospheric pressure. however, the pro ⁇ uct slurry leaves the vapor liqui ⁇ separator upstream at a very high pressure and temperature.
  • the 5 pressure of the slurry has been reduced by passing the slurry through two or more let- ⁇ own stages. It has been found that the slurry stream quickly wears out multiple stage let down valves.
  • Gas/liquid separation systems are typically used after each let down to brea the foam o effluent from the let ⁇ own valve. The apparatus for gas/liquid separation is expensive and its use in a coal liquefaction process has cause ⁇ some operating difficulties.
  • the present invention provides a method and appara ⁇ tus which effectively overcome the deficiencies in the processes noted above.
  • the flow characteristics of a high temperature, high pressure slurry containing abrasive solids are modified in order to facilitate treatment of the slurry at reduced pressure.
  • Use of the apparatus and method of the present invention will minimize the abrasive effect of the slurry on process equipment without a * simultaneous decrease in mass flow rate and slurry velocity.
  • the method of the present inven ⁇ tion comprises passing a slurry through a first pres- sure reducing stage for a first reduction of pressure to generate foamed slurry; immediately introducing the foamed slurry to a deceleration zone for reducing the velocity and abrasive characteristics of the foamed slurry; and passing the foamed slurry through a second pressure reducing valve for a second reduction of pressure.
  • This desirable result is accomplished by passing the slurry through two sequential pressure let down stages, each designed and sized to effect the desired pressure reduction and evolution of gas.
  • the pressure reduction accomplished by the first let down stage should be suffi ⁇ cient to effect liberation of enough gas to create a homogenous foam or foamy liquid.
  • This foam or foamy liquid should then behave as if it contained one phase rather than three.
  • the two pressure reduction stages are separated by a deceleration zone. In the ⁇ eceleration zone the velocity of the slurry, which is a foam or foamy liquid because of the gas evolved, is lowered to bring this foamed slurry to substantially non-turbulent flow as it enters the second pressure reduction stage.
  • An apparatus built in accordance with the present invention will comprise a first pressure reduction control valve for receiving a high temperature high pressure flowing slurry and cause it to be flashed to an interme ⁇ diate pressure and to generate sufficient gas to convert - the slurry into a foam or foamy liquid travelling at or about sonic velocity.
  • the first stage pressure reducing valve is in fluid communication with a deceleration zone.
  • the deceleration zone has an exit conduit which communi ⁇ cates with a second pressure reduction control valve.
  • the forward velocity of the slurry foam at the neck of the first stage valve is reduced in the deceleration zone such that at least in the area immediately adjacent the walls of the deceleration zone and at tne exit conduit from the deceleration zone, the slurry flow is substantially non-turbulent whereby a protective film is created which reduces abrasion of the walls of the equipment.
  • the foamed slurry is passed through a second stage pressure reducing control valve.
  • the inlet of the second stage pressure reducing valve will be sized larger than the first stage valve in order to accommodate the increased volume of the foamed slurry.
  • the inlet and outlet of the second pressure reducing stage will be sized such that the mass flow rate and slurry velocity are substantially equal to the flow rate and velocity at the inlet of the first pressure reducing stage.
  • the apparatus of the present invention comprises a first pressure reducing control valve for receiving a high temperature high pressure flowing slurry at a first pressure and discharging it at a lower pressure as a foamed slurry; a second pressure reducing control valve downstream of the first pressure reducing control valve for effecting a second reduction of pressure; a deceleration zone having an inlet in direct fluid communi- cation with the low pressure side of said first pressure reducing control valve for receiving and reducing the effective forward velocity of the foamed slurry flow at the lower pressure, and being shaped to hold foamed slurry such that newly injected foamed slurry flows directly into previously injected foamed slurry, and further shaped to convey foamed slurry to the second pressure reducing control valve in a foamed condition.
  • deceleration zone as used throughout this specification and its claims should be interpreted to mean an " apparatus constructed such that slurry injected into the zone through the first stage let down valve as a foam or foamy liquid comes into contact first with a pre ⁇ existing volume of foamed slurry rather than with the walls or bottom of the deceleration apparatus.
  • the kinetic energy of the injected slurry is dissipated within a swirling, mixing volume of slurry as opposed to impinging directly on the deceleration appa ⁇ ratus itself.
  • the slurry foam can be processed at acceptable velocities while the flow adjacent to the process equipment walls remains in a substantially non-turbulent condition since a thin layer . of the foamed slurry is believed to dessipate creating a protective film flowing at a slower velocity than the stream in the middle of the lines.
  • allowable velocity is intended to indicate that maximum acceptable velocity at which the slurry can be moved through the system without undue erosion of the equipment.
  • slurry velocity within the decelera ⁇ tion zone should not reach below the level at which significant amounts of solid matter will no longer remain in suspension.
  • the foam which is ordinarily produced as some of the liquid at the higher pressure is converted into the gas phase upon passing through the pressure reduction valve becomes a significant asset, rather than a liability, as was previously believed.
  • the foam can flow at a much lower velocity in the deceler- ation zone, substantially approaching non-turbulent flow, without a serious concern over loss of suspended par ⁇ ticles.
  • a protective film of slurry liquid * will be created adjacent the inner surfaces of the flow conduits and other process equipment, effectively inhibiting direct contact of the abrasive particles with the metallic surfaces.
  • this thin protective film of nonfoamed liquid which - ' exhibits laminar flow will continue to exist when the velocity is first lowered substantially and thereafter increased to a velocity higher than the rate at which laminar flow first resulted as the velocity was decreased.
  • the flow through subsequent process equipment will be at reduced turbulence with a concomitant reduction of abrasion.
  • the increased volume resulting from the production of the foam can be accommodated by adjusting the volumetric dimensions of the apparatus.
  • the pressure drop at each stage can be regu ⁇ lated by upstream level controls and thus automatically split between the two stages to the degree suitable for process conditions.
  • the portion of the total pressure drop effected by the individual valves can be adjusted by a secondary or bias control between the valves.
  • the overall mass flow rate and process velocity can be maintained.
  • the deceleration zone apparatus may be equipped with means for introducing a quench liquid or adapted to include a heat exchange cooler.
  • a quench liquid or adapted to include a heat exchange cooler.
  • these modifi ⁇ cations may only be desirable for special system reasons, such as the provision of extra control over process varia ⁇ bles and corrosion reduction.
  • the energy loss associated with quenching, or cooling the slurry stream wil decrease the overall efficiency of the coal liquefaction system and should be otherwise avoided.
  • use ⁇ of a heat exchanger may result in clogging of the exchanger lines because the slurry tends to cool at different rates.
  • FIGURE 1 shows a schematic diagram of the apparatus incorporating the principles of the invention.
  • FIGURE 2 shows a schematic diagram of the apparatus of the present invention which has been modified to allow cooling of the slurry stream in the deceleration zone.
  • the apparatus and process will be used in an integrated coal liquefaction-gasification process such as that described in ⁇ . S 4 . Patent No. 4,159,-238.
  • system pulverized raw coal is mixed with a slurry feed and then with hydrogen prior to introduction through a tubular preheater furnace where the coal is partially dissolved in the recycled solvent.
  • the effluent from the tubular preheater furnace is discharged to a dissolver for f-urther reaction.
  • the effluent from the dissolver passes to a vapor/liquid separation system.
  • the hot overhead vapor stream is removed through one outlet while a liquid distillate from the separator is removed through another outlet.
  • the slurry effluent of this first vapor/liquid separator can then be passed through the apparatus of the present invention for reduction of pressure. Once the pressure has been reduced the slurry stream can be split into two components, one for recycle and the other for separation of the major products of the process.
  • FIGURE 1 for a system designed to process slurry at a rate of 10,000 lbs./min. (4,545 Kg/min) , where the slurry exiting from the hot separator upstream at 2000 p.s.i.g. (140 Kg/cm 2 ) and 790 ⁇ F (421 ⁇ C) is to be let down in two stages to 150 p.s.i.g. (10.6 Kg/cm 2 ).
  • the apparatus has three distinct zones: a first valve 10 for reducing pressure, a deceleration zone 20, and a second valve 30 for reducing pressure.
  • a first valve 10 for reducing pressure
  • a deceleration zone 20 for reducing pressure.
  • Applicant believes that a person or ordinary skill will be able to calculate the dimensions, flow rates, and pressures required for any given stream of materials with knowledge of the approximate composition of the stream tne pressures at which sufficient gas is liberated to generate a foam or foamy liquid.
  • the first valve 10 for reducing pressure will have an inlet conduit 11, a valve mechanism 12, and an outlet conduit 13.
  • the interior diameter of the conduit 11 at its entrance to the valve mechanism 12 must be sufficient to accommodate the volume of slurry at the desired flow rate.
  • 160 cubic feet per minute (4.53 cubic meters/min) of slurry will be processed at a rate of 20 f.p.s. (6.1 M/sec).
  • the cross- sectional area of the opening to conduit 11 must be 0.1333 square feet (0.012 square meters) which requires an inside diameter of approximately 5 inches (12.7 cm).
  • the type of valve mechanism 12 used in the first valve 10 to reduce the pressure of the slurry is not critical to the present
  • the preferred valve mechanism 12 will be a blunt needle valve having a throat diameter of two to three inches (5 cm to 7.6 cm).
  • the first stage valve will be sized to achieve a pressure drop to 550 p.s.i.g. (38.8 Kg/cm 2 ), which is sufficient to liberate gas and create a foamy liquid or a foam.
  • the valve should be sized to effect sufficient pressure drop to generate a foam or foamy liquid. As explained above enough gas is liberated when the stream, at the flow rate throughout the letdown apparatus, thereafter behaves effectively as one phase even though it in fact contains three phases. The volume of liquid in the stream will remain approximately the same at 160 cubic feet per minute (4.53 cubic meters/min).
  • the slurry which enters the deceleration zone 20 will have a pressure reduced from 2000 p.s.i.g. (140 Kg/cm 2 ) to 550 p.s.i.g. (38.8 Kg/cm 2 )
  • the velocity of a slurry flashed through a valve like the one described above will be in excess of a 100 f.p.s. (30.48 M/sec) and more likely approximately 500 f.p.s. 152 (M/sec). Accordingly the slurry will enter the deceleration zone as a jet of foam or foamy liquid.
  • the volume of the deceleration zone 20 must be sufficient to accommodate an additional 237 cubic feet per minute (6.7 cubic meters/min) of gas.
  • the deceleration zone 20 must be able to accommodate a com- bined volume of 397 cubic feet per minute (11.23 cubic meters/min).
  • the deceleration zone 20 will be constructed as a closed cylinder with an inlet from the first valve 10 at the top of the cylinder in the vicinity of its axis.
  • the cylinder will be constructed wide enough to allow the jet of foam to turn on itself so that the velocity of slurry moving near the walls will be approximately 5 f.p.s. (1.52 M/sec). It is believed that a small portion of the foam will dissipate in the region im ⁇ mediately adjacent the walls of the deceleration zone. Thi thin layer of nonturbulent slurry will substantially elimi ⁇ nate erosion.
  • the flow characteristics of the foam will change from very turbulent at the valve outlet to laminar a the slow velocity of 5.f.p.s. (1.52 M/sec).
  • the inside diameter of the cylinder must be 15.5 inches (39.4 cm) in order for the desired velocity drop to occur.
  • the deceleration zone should be large enough to cause a significant velocity drop; however, if the velocity drops too much, significant amounts of solid will fall out of the slurry.
  • the deceleration zone should be constructed so that only a small amount of solid falls out of suspension.
  • a small build up of solid matter in the deceleration zone resulting from a slightly oversized deceleration zone will be better than undue wear caused by a too small deceleration zone.
  • the cylinder should be long enough to accommodate the volume of material passing through the cylinder.
  • the cylinder will also be fitted with an exit conduit 23 leading from the side of the cylinder near its top to the second pressure reducing valve 30.
  • the inside diame ⁇ ter of this exit conduit 23 will be approximately 8 inches (20.32 cm) to accommodate a flow of 397 cubic feet per minute (11.24 cubic meters/sec) at a velocity of 20 f.p.s. (6.1 M/sec).
  • the velocity of the foam can be increased from the very slow velocity in the deceleration zone to the allow ⁇ able velocity for the foamy slurry at an intermediate pressure.
  • This allowable velocity will be higher when the velocity has been reduced to a very low rate causing dissipation of foam in a thin layer along the walls of the equipment, and creation of a protective slurry film rather than merely reduced to an acceptable velocity directly from the sonic velocity at the valve outlet.
  • the wall film described above can be maintained at a velocity higher than the velocity at which a wall film develops when the rate of the slurry is decreased from a sonic velocity.
  • a velocity equal to or higher than the velocity at the inlet 11 to the first valve 10 can be used.
  • a velocity of 20 f.p.s. (6.1 M/sec) is sufficiently low to avoid breaking the wall film of the fluid.
  • valve mechanism 32 for the second ⁇ let down valve 30 is not critical to the present invention.
  • the valve mechanism 32 will be a blunt needle valve having a throat diameter approximately the same size or slightly larger
  • the slurry stream which enters the second pressure reduction valve 30 at a pressure of 550 p.s.i.g. (38.80 Kg/cm 2 ) will exit with a reduced pressure of 150 p.s.i.g. (10.6 Kg/cm 2 ).
  • the exit conduit 33 for the second pressure reduction valve 30 must be constructed with sufficient volumetric dimensions to accommodate the in ⁇ creased volume associated with further liberation of gas from the liquid slurry. In the system described the volume of the liquid in the stream will decrease to 150 cubic feet per minute (4.23 cubic meters/min) after passing through the second let down valve 30.
  • the gas volume will increase to 811 cubic feet per minute (22.95 cubic meters/min) on the down side of the second let down valve 30.
  • the inside diameter of the exit conduit 33 should be 27.5 inches (69.9 cm) to accommodate this volume of material at a flow rate of 5 f.p.s. (1.5 M/sec).
  • the opening of the two valves 10 and 30 will be controlled by a regulator 40 which automatically adjusts both openings to accommodate changes in flow conditions upstream of the let down apparatus. Additionally, the portion of the total pres- sure drop effected by each valve can be adjusted by a bias control 41. There may be occasions where it would be undesirable to split the drop equally between the two stages. For example, a slurry with non-volatile compo ⁇ nents may need a very large pressure drop at the first stage in order to liberate sufficient gas to form a foamy liquid. Conversely, in a system with a large portion of volatile components it may be desirable to have a small pressure drop at the first stage, thereby increasing the life of the first valve.
  • the deceleration zone can be modified for introduction of a quench liquid.
  • the quench liquid will be intro ⁇ quizzed through inlet 24 shown in Fig. 2.
  • Suitable quench liquids would include water at 80 ⁇ F (26.7 ⁇ C) and heavy oil at 200°F (93°C).
  • Use of an oil as a liquid quench at a rate of 33 cubic feet per minute (0.94 cubic meters/min) would be deleterious to valve sizing, because the volume of liquid would be increased to 1 3 cubic feet per minute (5.46 cubic meters/min) while the gas volume would be increased to 251 cubic feet per minute (7.1 cubic meters/ in).
  • a further alternative embodiment requires modifica ⁇ tion of the exit conduit 23 leading from the deceleration zone 20 to the second let down valve 30.
  • the exit conduit is fitted with a heat exchanger 25 to cool the slurry as it passes through the exit conduit 23.
  • the heat exchanger 25 will not be used because of operational difficulties associated with heat exchangers. In operation, heat exchangers tend to cool the liquid unevenly. Clogging of the lines can result.
  • the slurry will pass into the deceleration zone 20 as a jet of swirling foam or foamy liquid.
  • the entering stream will first contact other slurry so that the swirling action of the slurry will be accommodated by the slurry rather than the walls of deceleration zone 20.
  • the velocity of the mixture will slow down to 5 f.p.s. (1.5 M/sec) near the walls of the deceleration 20.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Treatment Of Sludge (AREA)

Abstract

Un nouvel appareil ayant une première vanne de réduction (10) en communication fluide directe avec une zone de décélération (20), et la zone de décélération (20) en communication fluide directe avec une seconde vanne de réduction (30), permet que se passer d'un appareil de séparation gaz/liquide. Dans des variantes de mode de réalisation l'appareil peut être modifié pour ajouter un liquide de trempe ou refroidissement avec un échangeur de chaleur. En laissant la boue passer au travers d'étages successifs de réduction sous la forme d'une mousse ou d'un liquide mousseux, des vitesses d'écoulement admissibles supérieures peuvent être obtenues. En fonctionnement, la boue de haute pression sera chassée au travers d'une première vanne (10) et sa pression sera réduite jusqu'à atteindre une pression intermédiaire. La boue sortira par la première vanne (10) à une très haute vitesse sous la forme d'une mousse ou d'un liquide mousseux et entrera directement dans la zone de décélération (20). Dans la zone de décélération (20), la boue entrera d'abord en contact avec une autre boue de sorte que, lorsqu'elle atteindra les parois (21) de la zone de décélération (20), sa vitesse sera suffisamment faible pour éviter toute érosion. A partir de la zone de décélération (20), la boue passera au travers d'une seconde vanne (30) avec une nouvelle réduction de pression. Il est possible de faire passer la boue au travers de nombreuses vannes avec une zone de décélération entre ces vannes.
PCT/US1981/001748 1981-07-27 1981-12-28 Appareil et procede de reduction de la pression d'une boue abrasive de haute pression Ceased WO1983000370A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU80873/82A AU8087382A (en) 1981-07-27 1981-12-28 Apparatus and method for let down of a high pressure abrasiveslurry

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US28603481A 1981-07-27 1981-07-27
US286,034810727 1981-07-27

Publications (1)

Publication Number Publication Date
WO1983000370A1 true WO1983000370A1 (fr) 1983-02-03

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ID=23096769

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PCT/US1981/001748 Ceased WO1983000370A1 (fr) 1981-07-27 1981-12-28 Appareil et procede de reduction de la pression d'une boue abrasive de haute pression

Country Status (6)

Country Link
EP (1) EP0071320A2 (fr)
DD (1) DD202392A5 (fr)
IL (1) IL64771A0 (fr)
PL (1) PL235246A1 (fr)
WO (1) WO1983000370A1 (fr)
ZA (1) ZA82269B (fr)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8801859B2 (en) 2011-05-04 2014-08-12 Renmatix, Inc. Self-cleaning apparatus and method for thick slurry pressure control
US8840995B2 (en) 2011-05-04 2014-09-23 Renmatix, Inc. Lignin production from lignocellulosic biomass
US9963555B2 (en) 2011-12-30 2018-05-08 Renmatix, Inc. Compositions comprising lignin
US10053745B2 (en) 2010-01-19 2018-08-21 Renmatix, Inc. Production of fermentable sugars and lignin from biomass using supercritical fluids
US10793646B2 (en) 2014-09-26 2020-10-06 Renmatix, Inc. Adhesive compositions comprising type-II cellulose

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2741262A (en) * 1950-11-24 1956-04-10 Exxon Research Engineering Co Apparatus for controlling and releasing pressure
US3341447A (en) * 1965-01-18 1967-09-12 Willard C Bull Solvation process for carbonaceous fuels
US3884796A (en) * 1974-03-04 1975-05-20 Us Interior Solvent refined coal process with retention of coal minerals
US4159238A (en) * 1978-05-12 1979-06-26 Gulf Oil Corporation Integrated coal liquefaction-gasification process
US4219403A (en) * 1976-05-28 1980-08-26 Kobe Steel, Ltd. Coal liquefaction process and apparatus therefor
US4236896A (en) * 1978-02-09 1980-12-02 Kerr-Mcgee Corporation Slurry removal process

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2741262A (en) * 1950-11-24 1956-04-10 Exxon Research Engineering Co Apparatus for controlling and releasing pressure
US3341447A (en) * 1965-01-18 1967-09-12 Willard C Bull Solvation process for carbonaceous fuels
US3884796A (en) * 1974-03-04 1975-05-20 Us Interior Solvent refined coal process with retention of coal minerals
US4219403A (en) * 1976-05-28 1980-08-26 Kobe Steel, Ltd. Coal liquefaction process and apparatus therefor
US4236896A (en) * 1978-02-09 1980-12-02 Kerr-Mcgee Corporation Slurry removal process
US4159238A (en) * 1978-05-12 1979-06-26 Gulf Oil Corporation Integrated coal liquefaction-gasification process

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10053745B2 (en) 2010-01-19 2018-08-21 Renmatix, Inc. Production of fermentable sugars and lignin from biomass using supercritical fluids
US10858712B2 (en) 2010-01-19 2020-12-08 Renmatix, Inc. Production of fermentable sugars and lignin from biomass using supercritical fluids
US8801859B2 (en) 2011-05-04 2014-08-12 Renmatix, Inc. Self-cleaning apparatus and method for thick slurry pressure control
US8840995B2 (en) 2011-05-04 2014-09-23 Renmatix, Inc. Lignin production from lignocellulosic biomass
US9963555B2 (en) 2011-12-30 2018-05-08 Renmatix, Inc. Compositions comprising lignin
US10793646B2 (en) 2014-09-26 2020-10-06 Renmatix, Inc. Adhesive compositions comprising type-II cellulose

Also Published As

Publication number Publication date
DD202392A5 (de) 1983-09-14
ZA82269B (en) 1983-02-23
PL235246A1 (en) 1983-01-31
EP0071320A2 (fr) 1983-02-09
IL64771A0 (en) 1982-03-31

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