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UY24731A1 - PROCEDURE FOR THE MANUFACTURE OF AROMATIC VINYL POLYMERS REINFORCED WITH RUBBER - Google Patents

PROCEDURE FOR THE MANUFACTURE OF AROMATIC VINYL POLYMERS REINFORCED WITH RUBBER

Info

Publication number
UY24731A1
UY24731A1 UY24731A UY24731A UY24731A1 UY 24731 A1 UY24731 A1 UY 24731A1 UY 24731 A UY24731 A UY 24731A UY 24731 A UY24731 A UY 24731A UY 24731 A1 UY24731 A1 UY 24731A1
Authority
UY
Uruguay
Prior art keywords
rubber
continuously
solution
order
reactor
Prior art date
Application number
UY24731A
Other languages
Spanish (es)
Inventor
Luca Monti
Romagnoli Giuseppe
Original Assignee
Enichem Spa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Enichem Spa filed Critical Enichem Spa
Publication of UY24731A1 publication Critical patent/UY24731A1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F257/00—Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
    • C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02—Monomers containing only one unsaturated aliphatic radical
    • C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/06—Hydrocarbons
    • C08F212/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F287/00—Macromolecular compounds obtained by polymerising monomers on to block polymers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Graft Or Block Polymers (AREA)

Abstract

Procedimiento para fabricar polímeros vinilo-aromáticos reforzados con caucho y morfología bimodal de la fase de caucho, que consiste en: a-alimentar continuamente a un primer reactor tipo PFR, una primera solución de n caucho en un medio líquido, esencialmente constituida por lo menos por un monómero vinilo-aromático; b- alimentar continuamente a un segundo reactor CFSTR, una segunda solución de caucho en medio líquido, esencialmente constituida por lo menos por un monómero vinilo-aromático; c- polimerizar continuamente dicha primera solución en dicho primer reactor PFR, hasta obtener una conversión 10- 50%, base el peso total de monómeros presentes, en fin de producir una primera composición basada en un primer prepolímero conteniendo una fase de caucho con un diámetro promedial, en volumen, (Dv) de las partículas de caucho dispersadas y unidas a la matriz polimérica, comprendido dentro de la gama de 0,04 a 1,8 micrómetros; d- polimerizar continuamente dicha segunda solución en dicho reactor CFSTR, hasta obtener una conversión 10- 50%, base el peso total de monómeros presentes, en fin de producir una segunda composición basada en un segundo prepolímero conteniendo una fase de caucho con un diámetro promedial, en volumen, (Dv) de las partículas de caucho dispersadas y unidas a la matriz polimérica, comprendido dentro de la gama de 0,6 a 12 micrómetros, con dicho diámetro promedial de las partículas de caucho de dicho segundo prepolímero siendo por lo menos del doble del tamaño de las partículas del primer prepolímero; e- descargar continuamente dichas primera y segunda composición (mezclarlas) a fin de producir una tercera composición; f- seguir polimerizando, todavía continuamente, dicha tercera composición, y separar el polímero resultante de los monómeros sin reaccionar a fin de obtener un polímero vinilo-aromático reforzado con caucho, con morfología bimodal de la fase de caucho.Procedure to manufacture rubber-reinforced vinyl-aromatic polymers and bimodal morphology of the rubber phase, which consists of: continuously feeding a first PFR type reactor, a first solution of n rubber in a liquid medium, essentially constituted at least by a vinyl aromatic monomer; b- continuously feeding to a second CFSTR reactor, a second solution of rubber in liquid medium, essentially constituted by at least one vinyl-aromatic monomer; c- continuously polymerize said first solution in said first PFR reactor, until obtaining a 10-50% conversion, based on the total weight of monomers present, in order to produce a first composition based on a first prepolymer containing a rubber phase with a diameter volume average (Dv) of the rubber particles dispersed and bound to the polymeric matrix, comprised within the range of 0.04 to 1.8 microns; d- continuously polymerize said second solution in said CFSTR reactor, until obtaining a 10-50% conversion, based on the total weight of monomers present, in order to produce a second composition based on a second prepolymer containing a rubber phase with an average diameter , by volume, (Dv) of the rubber particles dispersed and attached to the polymeric matrix, comprised within the range of 0.6 to 12 micrometers, with said average diameter of the rubber particles of said second prepolymer being at least twice the size of the particles of the first prepolymer; e- continuously discharging said first and second compositions (mixing them) in order to produce a third composition; f- continue to polymerize said third composition, still continuously, and separate the resulting polymer from the unreacted monomers in order to obtain a rubber-reinforced vinyl-aromatic polymer, with bimodal morphology of the rubber phase.

UY24731A 1996-09-27 1997-09-29 PROCEDURE FOR THE MANUFACTURE OF AROMATIC VINYL POLYMERS REINFORCED WITH RUBBER UY24731A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT96MI001978A IT1284599B1 (en) 1996-09-27 1996-09-27 PROCEDURE FOR THE PREPARATION OF RUBBER REINFORCED VINYLAROMATIC POLYMERS

Publications (1)

Publication Number Publication Date
UY24731A1 true UY24731A1 (en) 1997-10-07

Family

ID=11374931

Family Applications (1)

Application Number Title Priority Date Filing Date
UY24731A UY24731A1 (en) 1996-09-27 1997-09-29 PROCEDURE FOR THE MANUFACTURE OF AROMATIC VINYL POLYMERS REINFORCED WITH RUBBER

Country Status (16)

Country Link
US (1) US5942575A (en)
EP (1) EP0832904B1 (en)
JP (1) JP2922484B2 (en)
KR (1) KR100256132B1 (en)
CN (1) CN1115354C (en)
AR (1) AR009095A1 (en)
AT (1) ATE186921T1 (en)
BR (1) BR9704917A (en)
DE (1) DE69700829T2 (en)
DK (1) DK0832904T3 (en)
ES (1) ES2138851T3 (en)
GR (1) GR3031977T3 (en)
IT (1) IT1284599B1 (en)
RU (1) RU2142475C1 (en)
SI (1) SI0832904T1 (en)
UY (1) UY24731A1 (en)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999009081A1 (en) * 1997-08-13 1999-02-25 The Dow Chemical Company High gloss high impact monovinylidene aromatic polymers
IT1314260B1 (en) 1999-12-03 2002-12-06 Enichem Spa PROCEDURE FOR THE PRODUCTION OF VINYLAROMATIC POLYMERS EVENTUALLY CONTAINING AN ETHYLENICALLY UNSATURATED NITRILE.
HK1055978A1 (en) * 2000-06-02 2004-01-30 Dow Global Technologies, Inc. Monovinylidene aromatic polymers with improved toughness and rigidity and a process for their preparation
KR100455102B1 (en) * 2001-11-23 2004-11-06 제일모직주식회사 High Impact Polystyrene Resin with Good Heat Resistance and Falling Dart Impact Prepared by Continuous Mass Polymerization Process
RU2217442C1 (en) * 2002-05-06 2003-11-27 Открытое акционерное общество "Пластполимер" Method for preparing impact-strength polystyrene
ITMI20031420A1 (en) * 2003-07-11 2005-01-12 Polimeri Europa Spa REINFORCED VINYLAROMATIC POLYMERS WITH RUBBER
ITMI20040752A1 (en) * 2004-04-16 2004-07-16 Polimeri Europa Spa PROCEDURE FOR THE PREPARATION OF VINYLAROMATIC CO POLYMERS SEAMED ON ELASTOMETER IN A CONTROLLED WAY
ITMI20042401A1 (en) * 2004-12-16 2005-03-16 Polimeri Europa Spa PROCEDURE FOR THE PREPARATION OF VINYLAROMATIC SEALED SHOCKFORM CO-POLYMERS ON ELASTOMER
US7488774B2 (en) 2005-12-21 2009-02-10 Fina Technology, Inc. Reactor system for the production of high impact polystyrene
EP1903064A1 (en) * 2006-09-20 2008-03-26 Ineos Europe Limited Process for producing a polystyrene
EP2291409B1 (en) * 2008-06-18 2013-04-24 Styron Europe GmbH Low chloride polybutadiene
IT1393666B1 (en) * 2008-12-16 2012-05-08 Polimeri Europa Spa (CO) VINYLAROMATIC POLYMER REINFORCED WITH RUBBER HAVING AN EXCELLENT BALANCE OF PHYSICAL-MECHANICAL PROPERTIES AND A HIGH GLOSS
CN109180871A (en) * 2018-01-01 2019-01-11 杨青岚 Rubber-modified styrene continuous bulk polymerization process

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1518412A (en) * 1975-05-15 1978-07-19 Labofina Sa High-impact polystyrene and process for the production thereof
US4146589A (en) * 1978-05-19 1979-03-27 Monsanto Company Method for preparing a monoalkenyl aromatic polyblend having a dispersed rubber phase as particles with a bimodal particle size distribution
US4214056A (en) * 1978-05-19 1980-07-22 Monsanto Company Method for preparing a monoalkenyl aromatic polyblend having a dispersed rubber phase as particles with a bimodal particle size distribution
DE3035570A1 (en) * 1980-09-20 1982-05-06 Basf Ag, 6700 Ludwigshafen IMPACT RESISTANT THERMOPLASTIC SHAPE
GB8918157D0 (en) * 1989-08-09 1989-09-20 Dow Benelux A process for the preparation of rubber-reinforced monovinylidene aromatic polymers
IT1274361B (en) * 1995-02-16 1997-07-17 Enichem Spa PROCESS FOR THE PREPARATION OF VINYLAROMATIC COPOLYMERS REINFORCED WITH RUBBER

Also Published As

Publication number Publication date
CN1179436A (en) 1998-04-22
KR100256132B1 (en) 2000-05-15
JP2922484B2 (en) 1999-07-26
GR3031977T3 (en) 2000-03-31
DE69700829D1 (en) 1999-12-30
RU2142475C1 (en) 1999-12-10
JPH10130343A (en) 1998-05-19
EP0832904A1 (en) 1998-04-01
US5942575A (en) 1999-08-24
CN1115354C (en) 2003-07-23
KR19980025058A (en) 1998-07-06
DK0832904T3 (en) 2000-04-17
EP0832904B1 (en) 1999-11-24
ES2138851T3 (en) 2000-01-16
BR9704917A (en) 1998-12-22
IT1284599B1 (en) 1998-05-21
SI0832904T1 (en) 2000-02-29
DE69700829T2 (en) 2000-05-18
ATE186921T1 (en) 1999-12-15
AR009095A1 (en) 2000-03-08
ITMI961978A1 (en) 1998-03-27

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Legal Events

Date Code Title Description
VENC Patent expired

Effective date: 20170929