USRE19612E - Coating composition - Google Patents
Coating composition Download PDFInfo
- Publication number
- USRE19612E USRE19612E US19612DE USRE19612E US RE19612 E USRE19612 E US RE19612E US 19612D E US19612D E US 19612DE US RE19612 E USRE19612 E US RE19612E
- Authority
- US
- United States
- Prior art keywords
- abietic acid
- chlorinated rubber
- acid ester
- composition including
- rubber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000008199 coating composition Substances 0.000 title description 13
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 28
- 239000000203 mixture Substances 0.000 description 26
- BQACOLQNOUYJCE-FYZZASKESA-N Abietic acid Natural products CC(C)C1=CC2=CC[C@]3(C)[C@](C)(CCC[C@@]3(C)C(=O)O)[C@H]2CC1 BQACOLQNOUYJCE-FYZZASKESA-N 0.000 description 23
- -1 propyl abietate Chemical compound 0.000 description 21
- 125000000217 alkyl group Chemical group 0.000 description 18
- 125000003710 aryl alkyl group Chemical group 0.000 description 16
- 150000002148 esters Chemical class 0.000 description 14
- 239000002904 solvent Substances 0.000 description 11
- BTXXTMOWISPQSJ-UHFFFAOYSA-N 4,4,4-trifluorobutan-2-one Chemical compound CC(=O)CC(F)(F)F BTXXTMOWISPQSJ-UHFFFAOYSA-N 0.000 description 9
- 239000004615 ingredient Substances 0.000 description 9
- 239000011347 resin Substances 0.000 description 7
- 229920005989 resin Polymers 0.000 description 7
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 5
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 5
- 229910052801 chlorine Inorganic materials 0.000 description 5
- 239000000460 chlorine Substances 0.000 description 5
- 239000011877 solvent mixture Substances 0.000 description 5
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 5
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 235000019198 oils Nutrition 0.000 description 4
- 239000002383 tung oil Substances 0.000 description 4
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 230000001680 brushing effect Effects 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 238000007598 dipping method Methods 0.000 description 3
- 235000010985 glycerol esters of wood rosin Nutrition 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- OVXRPXGVKBHGQO-UYWIDEMCSA-N methyl (1r,4ar,4br,10ar)-1,4a-dimethyl-7-propan-2-yl-2,3,4,4b,5,6,10,10a-octahydrophenanthrene-1-carboxylate Chemical compound C1CC(C(C)C)=CC2=CC[C@H]3[C@@](C(=O)OC)(C)CCC[C@]3(C)[C@H]21 OVXRPXGVKBHGQO-UYWIDEMCSA-N 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- IANQTJSKSUMEQM-UHFFFAOYSA-N 1-benzofuran Chemical compound C1=CC=C2OC=CC2=C1 IANQTJSKSUMEQM-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 239000005864 Sulphur Substances 0.000 description 2
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 2
- OVXRPXGVKBHGQO-UHFFFAOYSA-N abietic acid methyl ester Natural products C1CC(C(C)C)=CC2=CCC3C(C(=O)OC)(C)CCCC3(C)C21 OVXRPXGVKBHGQO-UHFFFAOYSA-N 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000000944 linseed oil Substances 0.000 description 2
- 235000021388 linseed oil Nutrition 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- 239000004636 vulcanized rubber Substances 0.000 description 2
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 1
- AGUBCDYYAKENKG-UHFFFAOYSA-N Abietinsaeure-aethylester Natural products C1CC(C(C)C)=CC2=CCC3C(C(=O)OCC)(C)CCCC3(C)C21 AGUBCDYYAKENKG-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- AGUBCDYYAKENKG-YVNJGZBMSA-N Ethyl abietate Chemical compound C1CC(C(C)C)=CC2=CC[C@H]3[C@@](C(=O)OCC)(C)CCC[C@]3(C)[C@H]21 AGUBCDYYAKENKG-YVNJGZBMSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229940023878 hydrogenated methyl abietate Drugs 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D115/00—Coating compositions based on rubber derivatives
- C09D115/02—Rubber derivatives containing halogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L93/00—Compositions of natural resins; Compositions of derivatives thereof
- C08L93/04—Rosin
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S524/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S524/925—Natural rubber compositions having nonreactive materials, i.e. NRM, other than: carbon, silicon dioxide, glass titanium dioxide, water, hydrocarbon or halohydrocarbon
Definitions
- This invention relates to an improvement in coating compositions and more particularly to coating compositions which while adaptable for use generally lend themselves especially for use 5 where a corrosion and abrasion resistant coating is desired, as for example, various metal surfaces, pipes to be buried in the ground, etc.
- Coating compositions in accordance with this invention will contain essentially chlorinated rubber and an ester of abietic acid, as, for example, alkyl and aralkyl derivatives.
- the ester of abietic acid or rosin as contained in the compositions in accordance with this invention may be hydrogenated either by hydrogenation of the ester or by producing the ester from hydrogenated abietic acid or rosin.
- compositions in accordance with this invention may contain various other ingredients, as, for example, gums, oils, etc. and will contain a suitable solvent or solvent mixture to give to the compositions desired viscosity or fluidity to enable their application, as for example, by spraying, brushing, dipping or otherwise, as may be desired.
- suitable solvent or solvent mixture to give to the compositions desired viscosity or fluidity to enable their application, as for example, by spraying, brushing, dipping or otherwise, as may be desired.
- the chlorinated rubber comprising one of the essential ingredients of coating compositions in accordance with this invention may be either chlorinated raw rubber or chlorinated vulcan- 30 lzed rubber, or mixtures thereof, both being contemplated as within the term chlorinated rubber as used herein. While the chlorinated rubber will preferably have a relatively high percentage of chlorine, say above 67%, it will be understood that rubber containing any substantial percentage of chlorine, say as low as 50%, will be usable.
- the chlorinated rubber may be obtained from any source, or may be produced in any suitable manner.
- suitable chlorinated rubber may be produced from raw or vulcanized rubber by dissolving the rubber in a solvent, as carbon tetrachloride, which will be unaiiected by chlorine, heating the solution to a temperature within the range 80-110 C. and introducing chlorine into the heated solution.
- a solvent as carbon tetrachloride
- the sulphur will be separated out by the chlorine, appearing as a chloride of sulphur, 50 all, as for example, is more fully disclosed in U. S. Patent No. 1,852,043 to Deseniss and Nielson.
- esters of abietic acid or rosin may be used in the composition in accordance with this invention, as for example, ethyl abietate, methyl abietate, propyl abietate, benzyl abietate, etc., etc.
- Abietic acid or rosin esters as used may be hydrogenated as has been indicated, and it will be understood that with reference to such esters in the description of compositions in accordance with this invention heretofore and as used in the claims appended hereto, bythe term "abietic acid or rosin ester" such esters, either hydrogenated or not hydrogenated, is'contemplated.
- compositions in accordance with this invention may be included in compositions in accordance with this invention, as for example, oils, as linseed oil, China wood oil, etc., etc., gums or resins, as ester gum, coumarone, phenol-iormaldehyde condensation resins etc., pigments and other ingredients which may be desirable and which are compatible with the essential ingredients, chlorinated rubber and abietic acid or resin ester.
- oils as linseed oil, China wood oil, etc., etc.
- gums or resins as ester gum, coumarone, phenol-iormaldehyde condensation resins etc.
- pigments and other ingredients which may be desirable and which are compatible with the essential ingredients, chlorinated rubber and abietic acid or resin ester.
- Any suitable solvent or solvent mixture may be used in the preparation 01' solvent mixtures in accordance with this invention and, for example, a mixture of xylol and toluol, ethylene dichloride, monoalkylated ether oi ethylene glycol, ethyl acetate, etc., may be used.
- compositions in accordance with this invention the essential ingredients may be used in widely varying proportions and other ingredients which may be included may likewise be included in widely varying proportions.
- chlorinated rubber may be used in amount within say about the range 10-40%, while an abietic acid or resin acid ester may be included within say about the range 2-20%.
- the solvent or solvent mixture may be used in any desired amount with consideration for the viscosity or fluidity desired for the composition.
- the solvent or solvent mixture may be in amount within say about the range 85-40%, to give compositions which may be readily applied as by brushing, spraying, dipping or the like.
- abietic acid or resin ester as methyl abietate which has not been bydrogenated, may be substituted for hydrogenated methyl abietate given in the above formula.
- composition in accordance with the above formula! will be found desirable for various uses and will be found especially desirable where a corrosion resistant coating is desired.
- formulations given above for purposes of illustration may be widely varied depending upon the particular uses for which they are intended within the scope of this invention.
- compositions in accordance with this invention may be applied to various surfaces such as wood, metal and the like, by spraying, brushing, dipping, etc., and on evaporation of the volatile ingredients will form a coating having excellent adherence to the surface, of desirable appearance, flexibility, etc., etc., and a very high resistance to corrosion.
- a coating composition including chlorinated rubberandanabieticacidesteroithegroup alkyl and aralhl esters and a solvent.
- a coating composition including chlorinated rubber and a by abietic acid ester ofthegrmipalhlandaralkylestersandasolvent.
- a coating composition including chlorinated rubberandanabieticacidesterofthegroup alkyland aralkylesters, aresinandasolvent.
- a coating co including chlorinated rubberandanabieticscidesterofthegrmp alkyl and aralkyl esters. a drying oil and a solvent.
- a coating composition including chlorinated rubber and an abietic acid ester d the group aikylandaralkylesteraaresimadryingoiland a solvent.
- a coating composition including chlorinated rubberabout 10-40%andanabieflcacidester abouts-20% ofihegroupalkylandaralkylesters and a solvent.
- a coating composition including chlorinated rubber about 20% and an abietic acid ester about 24% of the group alkyl and aralkvl esters and a solvent about 9.
- chlorinated rubber about 20% and an abietic acid ester about 24% of the group alkyl and aralkvl esters and a solvent about 9.
- a composition including chlorinated rubber and an abietic acid ester of the group alkyl and aralkyl esters.
- a composition including chlorinated rubber and a hydrogenated abietic acid ester of the group alkyl and aralkyl esters.
- a composition including chlorinated rubber, an abietic acid ester of the group alkyl and aralkyl esters and a resin.
- a composition including chlorinated rubber, an abietic acid ester of the group alkyl and aralkylesters,aresinandadryingoil.
- a composition including chlorinated rubher, an abietic acid ester of the group alkyl and aralkyl esters. a resin and linseed oil.
- a composition including chlorinated rubber within the range about 10%-40% and an ahietic acid ester of the group alkyl and aralkyl esters within the range about 2%-20%.
- a composition including chlorinated rubber, a hydrogenated abietic acid ester of the group alkyl and aralkyl esters, a resin and a drying oil.
- a composition including chlorinated rubher, an abietic acid ester of the group allryl and aralkyl esters, and a softening agent for the chlorinated rubber.
- a composition including chlorinated rubber, an abietic acid ester of the group alkyl and aralkyl esters and China-wood oil.
- a composition including chlorinated rubber, an abietic acid ester of the group alkyl and aralkyl esters, and boiled China-wood oil.
- a composition including chlorinated rubher, an abietic acid ester of the group alkyl and aralkyl esters, China-wood oil and ester gum.
- a composition includedin chlorinated rubher, an abietic acid ester of the group alkyl and aralkyl esters, and ester gum.
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Description
Reiuued June 18, 1935 UNITED STATES PATENT OFFICE COATING COMPOSITION William Koch, Wilmington, Del., uelgnor to Hercules Powder Company, Wilmington, DeL, a corporation of Delaware No Drawing.
Orlg'inal No. 1,957,786, dated M1! 8, 1934, Serial No. 626,226. Jill! 29. 1932.
This invention relates to an improvement in coating compositions and more particularly to coating compositions which while adaptable for use generally lend themselves especially for use 5 where a corrosion and abrasion resistant coating is desired, as for example, various metal surfaces, pipes to be buried in the ground, etc.
Coating compositions in accordance with this invention will contain essentially chlorinated rubber and an ester of abietic acid, as, for example, alkyl and aralkyl derivatives. The ester of abietic acid or rosin as contained in the compositions in accordance with this invention may be hydrogenated either by hydrogenation of the ester or by producing the ester from hydrogenated abietic acid or rosin.
Compositions in accordance with this invention, in addition to the essential ingredients described above, may contain various other ingredients, as, for example, gums, oils, etc. and will contain a suitable solvent or solvent mixture to give to the compositions desired viscosity or fluidity to enable their application, as for example, by spraying, brushing, dipping or otherwise, as may be desired.
The chlorinated rubber comprising one of the essential ingredients of coating compositions in accordance with this invention may be either chlorinated raw rubber or chlorinated vulcan- 30 lzed rubber, or mixtures thereof, both being contemplated as within the term chlorinated rubber as used herein. While the chlorinated rubber will preferably have a relatively high percentage of chlorine, say above 67%, it will be understood that rubber containing any substantial percentage of chlorine, say as low as 50%, will be usable.
The chlorinated rubber, either raw or vulcanized, may be obtained from any source, or may be produced in any suitable manner. Thus, for example, suitable chlorinated rubber may be produced from raw or vulcanized rubber by dissolving the rubber in a solvent, as carbon tetrachloride, which will be unaiiected by chlorine, heating the solution to a temperature within the range 80-110 C. and introducing chlorine into the heated solution. Where vulcanized rubber is treated the sulphur will be separated out by the chlorine, appearing as a chloride of sulphur, 50 all, as for example, is more fully disclosed in U. S. Patent No. 1,852,043 to Deseniss and Nielson.
Other methods for the production of suitably chlorinated rubber are disclosed, tor example. in the United States patents to Carlton Ellis No. 1,544,530 and No. 1,544,529, to Peachey No.
1,234,381 and to Desenlss and Nielsen No. 1,852,- 043. It will, of course, be understood that suitably chlorinated rubber ior use in connection with this invention may be produced in any desired manner, the reierences made herein being for illustrative purposes only.
Various esters of abietic acid or rosin may be used in the composition in accordance with this invention, as for example, ethyl abietate, methyl abietate, propyl abietate, benzyl abietate, etc., etc. Abietic acid or rosin esters as used may be hydrogenated as has been indicated, and it will be understood that with reference to such esters in the description of compositions in accordance with this invention heretofore and as used in the claims appended hereto, bythe term "abietic acid or rosin ester" such esters, either hydrogenated or not hydrogenated, is'contemplated.
As has been indicated, various ingredients in addition to those indicated above as essential may be included in compositions in accordance with this invention, as for example, oils, as linseed oil, China wood oil, etc., etc., gums or resins, as ester gum, coumarone, phenol-iormaldehyde condensation resins etc., pigments and other ingredients which may be desirable and which are compatible with the essential ingredients, chlorinated rubber and abietic acid or resin ester.
Any suitable solvent or solvent mixture may be used in the preparation 01' solvent mixtures in accordance with this invention and, for example, a mixture of xylol and toluol, ethylene dichloride, monoalkylated ether oi ethylene glycol, ethyl acetate, etc., may be used.
In the formation of compositions in accordance with this invention the essential ingredients may be used in widely varying proportions and other ingredients which may be included may likewise be included in widely varying proportions.
For illustration, for example, chlorinated rubber may be used in amount within say about the range 10-40%, while an abietic acid or resin acid ester may be included within say about the range 2-20%. The solvent or solvent mixture may be used in any desired amount with consideration for the viscosity or fluidity desired for the composition. Thus, for example, the solvent or solvent mixture may be in amount within say about the range 85-40%, to give compositions which may be readily applied as by brushing, spraying, dipping or the like.
As illustrative of the practical adaptation of this invention, for example, satisfactory compositionsforvarioususesmaybemadeuponthe following formula:
It will be understood that abietic acid or resin ester, as methyl abietate which has not been bydrogenated, may be substituted for hydrogenated methyl abietate given in the above formula.
The composition in accordance with the above formula! will be found desirable for various uses and will be found especially desirable where a corrosion resistant coating is desired. As will be appreciated, the formulations given above for purposes of illustration may be widely varied depending upon the particular uses for which they are intended within the scope of this invention.
As has been indicated. the compositions in accordance with this invention may be applied to various surfaces such as wood, metal and the like, by spraying, brushing, dipping, etc., and on evaporation of the volatile ingredients will form a coating having excellent adherence to the surface, of desirable appearance, flexibility, etc., etc., and a very high resistance to corrosion.
What I claim and desire to protect by Letters Patent is:
1. A coating composition including chlorinated rubberandanabieticacidesteroithegroup alkyl and aralhl esters and a solvent.
2. A coating composition including chlorinated rubber and a by abietic acid ester ofthegrmipalhlandaralkylestersandasolvent.
3. A coating composition including chlorinated rubberandanabieticacidesterofthegroup alkyland aralkylesters, aresinandasolvent.
4. A coating co including chlorinated rubberandanabieticscidesterofthegrmp alkyl and aralkyl esters. a drying oil and a solvent.
5. A coating composition including chlorinated rubber and an abietic acid ester d the group aikylandaralkylesteraaresimadryingoiland a solvent.
6. A coating composition including chlorinated rubberabout 10-40%andanabieflcacidester abouts-20% ofihegroupalkylandaralkylesters and a solvent.
'1. A coating composition inclmling chlorinated rubber about 20% and an abietic acid ester about 2-6% ufthegrmipalkyisndaralkylestersand a solvent.
8. A coating composition including chlorinated rubber about 20% and an abietic acid ester about 24% of the group alkyl and aralkvl esters and a solvent about 9. In combination a surface and a dim containing chlorinated rubber and an abietic acid ester of the group alkyl and aralkyl esters adhered to and supported on said surface.
10. In combination a surface and a film containing chlorinated rubber and a hydrogenated abietic acid ester of the group alkyl and aralkyl esters adhered to and supported on said surface.
11. In combination a metal surface and a film containing chlorinated rubber and an abietic acid ester of the group alkyl and aralkyl adhered to and supported on said surface.
12. A composition including chlorinated rubber and an abietic acid ester of the group alkyl and aralkyl esters.
13. A composition including chlorinated rubber and a hydrogenated abietic acid ester of the group alkyl and aralkyl esters.
14. A composition including chlorinated rubber, an abietic acid ester of the group alkyl and aralkyl esters and a resin.
15. A composition including chlorinated rubber, an abietic acid ester of the group alkyl and aralkylesters,aresinandadryingoil.
16. A composition including chlorinated rubher, an abietic acid ester of the group alkyl and aralkyl esters. a resin and linseed oil.
17. A composition including chlorinated rubber within the range about 10%-40% and an ahietic acid ester of the group alkyl and aralkyl esters within the range about 2%-20%.
18. A composition including chlorinated rubber, a hydrogenated abietic acid ester of the group alkyl and aralkyl esters, a resin and a drying oil.
19. A composition including chlorinated rubher, an abietic acid ester of the group allryl and aralkyl esters, and a softening agent for the chlorinated rubber.
20. A composition including chlorinated rubber, an abietic acid ester of the group alkyl and aralkyl esters and China-wood oil.
21. A composition including chlorinated rubber, an abietic acid ester of the group alkyl and aralkyl esters, and boiled China-wood oil.
22. A composition including chlorinated rubher, an abietic acid ester of the group alkyl and aralkyl esters, China-wood oil and ester gum.
23. A composition includin chlorinated rubher, an abietic acid ester of the group alkyl and aralkyl esters, and ester gum.
wnmni xocn.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US626226A US1957786A (en) | 1932-07-29 | 1932-07-29 | Coating composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| USRE19612E true USRE19612E (en) | 1935-06-18 |
Family
ID=24509484
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US19612D Expired USRE19612E (en) | 1932-07-29 | Coating composition | |
| US626226A Expired - Lifetime US1957786A (en) | 1932-07-29 | 1932-07-29 | Coating composition |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US626226A Expired - Lifetime US1957786A (en) | 1932-07-29 | 1932-07-29 | Coating composition |
Country Status (1)
| Country | Link |
|---|---|
| US (2) | US1957786A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2904455A (en) * | 1956-05-31 | 1959-09-15 | Alois C Baggenstoss | High tensile strength textile materials |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3117100A (en) * | 1957-07-31 | 1964-01-07 | Du Pont | Polyethylene ahesives |
| US7399800B2 (en) * | 2005-04-15 | 2008-07-15 | E.I. Du Pont De Nemours And Company | Temperature switchable adhesives comprising crystallizable abietic acid derivative-based tackifiers |
| US8828181B2 (en) | 2010-04-30 | 2014-09-09 | E I Du Pont De Nemours And Company | Temperature switchable adhesives comprising a crystallizable oil |
| US8409703B2 (en) | 2010-07-23 | 2013-04-02 | E I Du Pont De Nemours And Company | Temperature switchable adhesive assemblies with temperature non-switchable tack |
-
0
- US US19612D patent/USRE19612E/en not_active Expired
-
1932
- 1932-07-29 US US626226A patent/US1957786A/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2904455A (en) * | 1956-05-31 | 1959-09-15 | Alois C Baggenstoss | High tensile strength textile materials |
Also Published As
| Publication number | Publication date |
|---|---|
| US1957786A (en) | 1934-05-08 |
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