US9447354B2 - Spent grain fuel product and process - Google Patents
Spent grain fuel product and process Download PDFInfo
- Publication number
- US9447354B2 US9447354B2 US13/199,505 US201113199505A US9447354B2 US 9447354 B2 US9447354 B2 US 9447354B2 US 201113199505 A US201113199505 A US 201113199505A US 9447354 B2 US9447354 B2 US 9447354B2
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- US
- United States
- Prior art keywords
- grain
- spent
- particles
- spent grain
- percent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
- C10L5/00—Solid fuels
- C10L5/40—Solid fuels essentially based on materials of non-mineral origin
- C10L5/44—Solid fuels essentially based on materials of non-mineral origin on vegetable substances
- C10L5/445—Agricultural waste, e.g. corn crops, grass clippings, nut shells or oil pressing residues
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12F—RECOVERY OF BY-PRODUCTS OF FERMENTED SOLUTIONS; DENATURED ALCOHOL; PREPARATION THEREOF
- C12F3/00—Recovery of by-products
- C12F3/06—Recovery of by-products from beer and wine
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
- C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
- C10L2290/02—Combustion or pyrolysis
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
- C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
- C10L2290/08—Drying or removing water
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
- C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
- C10L2290/28—Cutting, disintegrating, shredding or grinding
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
- C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
- C10L2290/54—Specific separation steps for separating fractions, components or impurities during preparation or upgrading of a fuel
- C10L2290/544—Extraction for separating fractions, components or impurities during preparation or upgrading of a fuel
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
- C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
- C10L2290/54—Specific separation steps for separating fractions, components or impurities during preparation or upgrading of a fuel
- C10L2290/547—Filtration for separating fractions, components or impurities during preparation or upgrading of a fuel
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
Definitions
- the present invention generally relates to a fuel product made from grain, preferably spent grain such as that which is a byproduct of brewing.
- the present invention relates to a novel and improved process for making a fuel product from spent grain.
- the present invention also relates to the novel use of such a fuel product of spent grain as a primary fuel for a steam boiler such as could be used in a brewing process.
- Spent grain from the brewing of alcoholic products has been used as a food product such as cattle feed.
- a food product such as cattle feed.
- it is known to reduce the moisture content of the spent grain through press and/or drying operations.
- attempts to use spent grain as a major part of the fuel used for a steam boiler, such attempts have been unsuccessful due to insufficient or failure of combustion and excessive smoke produced thereby.
- attempts to use spent grain as a minor part of the fuel for a steam boiler attempts to use spent grain as the sole or primary fuel have been unsuccessful due to insufficient or failure of combustion and excessive smoke produced thereby.
- a primary object of the present invention is to provide a novel fuel product made from spent grain and a novel and improved process for making this fuel product. Included herein is such a fuel product that can be used in a steam boiler or other combustion chambers in conformance with present day environmental and emission laws and regulations. Further included herein is such a fuel product that can be successfully used as the sole or primary fuel for a steam boiler used such as in brewing.
- a further object of the present invention is to provide a novel and improved process for making a fuel product from spent grain using machines or devices that are commercially available in industry.
- Another object of the present invention is to provide heat for a brewing process using a steam boiler fueled by a novel fuel product made from the spent grain byproduct of the brewing process.
- a fuel product is made from the spent grain byproduct of a process for brewing beer from malt and other grains.
- the spent grain is processed to sufficiently reduce the particle size with the median particle size preferably in the range of 0.25 mm to 0.6 mm with less than 1% of the grain greater than 2 mm.
- the wet spent grain is pressed on a mash filter press to reduce moisture below sixty-five percent (65%) and reduce soluble sugars and proteins. No longer needed for brewing, the spent grain is next dried to reduce its moisture content to ten percent (10%) or less by weight.
- the spent grain is then moved downward through a combustion chamber of a steam boiler and is agitated or vibrated during its combustion to further break up the structure of the burning spent grain thereby preventing the formation of a solid mass of spent grain which will prevent sufficient combustion.
- the present invention provides a novel fuel product made from spent grain that is processed to change its composition and structure in order to sufficiently increase its combustibility to allow it to be used as a fuel product in accordance with air quality standards and other environmental regulations and law.
- the spent grain is primarily malt byproduct of a beer brewing process shown for illustrative purposes only in the drawing.
- the grain is first crushed or pulverized by a hammer mill 10 to reduce it to a finely ground particles whose median particle size is generally within the range of 0.25 mm to 0.6 mm with less than 1% of the grain greater than 2 mm.
- the preferred, median, particle size between 0.25 mm to 0.6 mm means that fifty percent (50%) of the grain particle mass is greater than and fifty percent (50%) of grain particle mass is smaller than the median size.
- Pulverizing of the grain reduces the binding and adhesion among the elements of the grain which normally serve to solidify the grain into one cohesive and air-impermeable mass upon combustion. It also increases the surface area of the particles to facilitate the reduction of moisture and increase combustibility.
- the mill used in this instance is a Meura ClassicMill model CLM3 fine grinding hammer mill with horizontal shaft. This grinding process to obtain the desired particle size, for combustion, can be accomplished before or after the brewing and drying process, prior to combustion. Any other suitable device may be used to pulverize the grain.
- the grain is moved such as by a drag chain conveyor to a mash vessel 12 and hydrated from which the resulting hydrated grain slurry is moved such as by a centrifugal pump to a mash filter press 14 where it is pressed.
- the latter process reduces its moisture content below 65% and removes soluble sugar and protein contents which act as adhesive during subsequent drying of the spent grain. With these compounds reduced, the tendency of the grain particles to establish cohesion and structural integrity during subsequent drying and burning as a fuel will be significantly reduced.
- the fact that the spent grain has been pulverized also enables the filter to be a cloth through which the moisture passes when the spent grain is pressed on the cloth. The latter also reduces the energy needed to further dry the spent grains before its use as fuel.
- a Meura 2001 mash filter press available in the industry may be used. However other methods and devices may also be used to press the moisture and other soluble compounds from spent grain as described above. Due to the compression of the spent grains to remove moisture, it is preferred that air pulses be directed into the spent grain on the filter cloth before opening the filter to help break up the spent grain cake to facilitate release of the spent grain from adhering to the filter cloth when the filter is opened.
- the spent grain is then moved to a hopper by a pneumatic pump from which it is moved to a grain drying drum 18 by an auger.
- the next step in the process is that the present spent grain is dried to further reduce the moisture content from sixty-five percent (65%) to ten percent (10%) by weight or less.
- a rotating dryer drum 18 is used to receive the spent grain and is rotated while heated air in the drum subjects the spent grain to the desired drying while the drum is rotating and the spent grain is pulled through the drier drum by a pneumatic fan, for example.
- the small size of the finely ground spent grain particles helps speed up the drying process to reach the desired moisture level, preferably ten percent (10%) or less by weight, in order to increase its combustibility.
- a suitable dryer drum that can be used is one made by Baker Rullman which is readily available on the market. Other methods of drying the spent grain to sufficiently reduce its moisture content may of course be used. Also, grinding the dried spent grain can be done after the drying process to achieve the desired particle size distribution.
- the spent grain can be stored in a hopper 20 for immediate or eventual use as the sole fuel for example in the boiler 22 in a brewery used to produce steam such as for heating the brew house vessels.
- the dried spent grain is moved to the hopper 20 by a cyclone 24 .
- An auger is used to convey the spent grain fuel into the combustion chamber 28 .
- the spent grain is moved in any suitable manner preferably down an inclined grate 26 through the combustion chamber 28 while the grate 26 is agitated or vibrated.
- a motor 30 connected by linkage 32 to the grate 26 is employed to vibrate the grate as the spent grain is moved through the combustion chamber 28 .
- the timing frequency and intensity of the inclined grate agitation can be controlled and adjusted as needed for best combustion.
- the angle of the inclined grate being combined with the agitation or vibration of the grate helps to keep the spent grain moving through the combustion chamber while it burns and inhibits cohesion and agglomeration of its particles.
- spent grain that has not been processed as described above, when heated tends to adhere strongly to itself forming a less permeable, cohesive mass which inhibits the transfer of oxygen and heat to the interior of the mass and thereby prevents sufficient combustion which generates excessive smoke while also causing an excessive buildup of material within the combustion chamber.
- the process of the present invention not only sufficiently reduces the moisture and particle size in the spent grain, it also reduces the amount of soluble proteins and sugars which act as binding agents during heating which can inhibit combustion.
- the vibration and continual movement of the spent grain through the combustion chamber breaks up the agglomerating burning spent grain into smaller clumps thereby avoiding cohesion of the particles into a less-porous, large agglomerated mass with insufficient heat transfer and oxygen into the interior of the mass.
- a King Coal combustion chamber may be used.
- the process of the present invention provides effective combustion of the spent grain to allow it to be used as the sole source of fuel, that is, without the need of combining it with wood, oil, gas, coal or other combustibles.
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Biochemistry (AREA)
- Bioinformatics & Cheminformatics (AREA)
- General Engineering & Computer Science (AREA)
- General Health & Medical Sciences (AREA)
- Genetics & Genomics (AREA)
- Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Agronomy & Crop Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Solid Fuels And Fuel-Associated Substances (AREA)
Abstract
Description
Claims (17)
Priority Applications (8)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US13/199,505 US9447354B2 (en) | 2011-09-01 | 2011-09-01 | Spent grain fuel product and process |
| US14/756,904 US10364400B2 (en) | 2011-09-01 | 2015-10-28 | Spent grain fuel product and process |
| US15/469,074 US10781388B2 (en) | 2011-09-01 | 2017-03-24 | High protein organic materials as fuel and processes for making the same |
| US16/345,151 US10982162B2 (en) | 2011-09-01 | 2017-05-01 | High protein organic materials as fuel and processes for making the same |
| US17/205,394 US11441090B2 (en) | 2011-09-01 | 2021-03-18 | High protein organic materials as fuel and processes for making the same |
| US17/845,676 US11866669B2 (en) | 2011-09-01 | 2022-06-21 | High protein organic materials as fuel and processes for making the same |
| US18/491,522 US12378492B2 (en) | 2011-09-01 | 2023-10-20 | High protein organic materials as fuel and processes for making the same |
| US19/243,482 US20250313497A1 (en) | 2011-09-01 | 2025-06-19 | High Protein Organic Materials as Fuel and Processes for Making the Same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US13/199,505 US9447354B2 (en) | 2011-09-01 | 2011-09-01 | Spent grain fuel product and process |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US14/756,904 Continuation-In-Part US10364400B2 (en) | 2011-09-01 | 2015-10-28 | Spent grain fuel product and process |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| US20130055622A1 US20130055622A1 (en) | 2013-03-07 |
| US9447354B2 true US9447354B2 (en) | 2016-09-20 |
Family
ID=47752051
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US13/199,505 Active 2035-02-14 US9447354B2 (en) | 2011-09-01 | 2011-09-01 | Spent grain fuel product and process |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US9447354B2 (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2018080593A1 (en) | 2016-10-28 | 2018-05-03 | Akbev Group, Llc | High protein organic materials as fuel and processes for making the same |
| CN110903877A (en) * | 2019-12-09 | 2020-03-24 | 中车环境科技有限公司 | Method for preparing granular fuel by using organic waste |
| US10982162B2 (en) | 2011-09-01 | 2021-04-20 | Akbev Group, Llc | High protein organic materials as fuel and processes for making the same |
| US11441090B2 (en) | 2011-09-01 | 2022-09-13 | Akbev Group, Llc | High protein organic materials as fuel and processes for making the same |
| US11866669B2 (en) | 2011-09-01 | 2024-01-09 | Akbev Group, Llc | High protein organic materials as fuel and processes for making the same |
| US12378492B2 (en) | 2011-09-01 | 2025-08-05 | Akbev Group, Llc | High protein organic materials as fuel and processes for making the same |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10781388B2 (en) | 2011-09-01 | 2020-09-22 | Akbev Group, Llc | High protein organic materials as fuel and processes for making the same |
| US10364400B2 (en) * | 2011-09-01 | 2019-07-30 | Akbev Group, Llc | Spent grain fuel product and process |
| ITMI20131169A1 (en) * | 2013-07-11 | 2015-01-12 | Michele Chiodi | SYSTEM, PRODUCT, USE AND PROCESS FOR THE TREATMENT OF ORGANIC WASTE AND FOR THE PRODUCTION OF BIO-COMBUSTIBLE. |
| ES2719714T3 (en) * | 2014-03-13 | 2019-07-12 | Livio Franco | Apparatus for the treatment of substances of plant origin to produce biomass to be used to generate electrical and thermal energy from renewable sources and relative method |
| EP3459359A1 (en) * | 2017-09-25 | 2019-03-27 | Cordeiro & Peça Lda. | Process of dehydration and granulation of brewers´ grain |
| CN116747911B (en) * | 2023-04-11 | 2025-07-15 | 国家纳米科学中心 | Thermal plasmon@COF composite photocatalyst and preparation method and application thereof |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2494544A (en) * | 1944-08-01 | 1950-01-17 | Wisconsin Malting Company | Grain preparation |
| US4290269A (en) | 1979-10-09 | 1981-09-22 | Modo-Chemetics Ab | Process for the efficient conversion of water-containing organic materials as fuels into energy |
| US4464402A (en) | 1978-04-24 | 1984-08-07 | F.I.N.D. Research Corporation | Process for manufacturing a high protein food material |
| US5536650A (en) * | 1991-01-11 | 1996-07-16 | Heineken Technical Services B.V. | Process for the continuous preparation of wort |
| US5637336A (en) | 1994-04-29 | 1997-06-10 | Kannenberg; James R. | Process for drying malt |
| US6167636B1 (en) * | 1996-11-20 | 2001-01-02 | Brau-Union {Umlaut Over (O)}Sterreich Aktiengesselschaft | Process for thermally utilizing spent grains |
| PT104494B (en) * | 2009-04-06 | 2010-03-25 | Inst Superior Tecnico | INTEGRATED FILTRATION, COMPRESSION AND VACUUM UNIT FOR INTEGRATED PROCESS OF FILTRATION, COMPRESSION AND DRYING VACUUM OF THE CERAMIC INDUSTRY DRÊCHE, AND RESPECTIVE APPLICATION OF THE FINAL PRODUCTS |
-
2011
- 2011-09-01 US US13/199,505 patent/US9447354B2/en active Active
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2494544A (en) * | 1944-08-01 | 1950-01-17 | Wisconsin Malting Company | Grain preparation |
| US4464402A (en) | 1978-04-24 | 1984-08-07 | F.I.N.D. Research Corporation | Process for manufacturing a high protein food material |
| US4290269A (en) | 1979-10-09 | 1981-09-22 | Modo-Chemetics Ab | Process for the efficient conversion of water-containing organic materials as fuels into energy |
| US5536650A (en) * | 1991-01-11 | 1996-07-16 | Heineken Technical Services B.V. | Process for the continuous preparation of wort |
| US5637336A (en) | 1994-04-29 | 1997-06-10 | Kannenberg; James R. | Process for drying malt |
| US6167636B1 (en) * | 1996-11-20 | 2001-01-02 | Brau-Union {Umlaut Over (O)}Sterreich Aktiengesselschaft | Process for thermally utilizing spent grains |
| PT104494B (en) * | 2009-04-06 | 2010-03-25 | Inst Superior Tecnico | INTEGRATED FILTRATION, COMPRESSION AND VACUUM UNIT FOR INTEGRATED PROCESS OF FILTRATION, COMPRESSION AND DRYING VACUUM OF THE CERAMIC INDUSTRY DRÊCHE, AND RESPECTIVE APPLICATION OF THE FINAL PRODUCTS |
| WO2010117288A1 (en) * | 2009-04-06 | 2010-10-14 | Instituto Superior Tecnico | Integrated process of filtration to dry brewer's spent grain |
Non-Patent Citations (2)
| Title |
|---|
| Sky News Article dated Feb. 1, 2010, Author Gerard Tubb, Entitled "Heineken Forced to Con Green Power Plants", 2 Pages, copyright 2011 BSKYB. 2 Page. |
| Wartsila Corp. Press Release Mar. 3, 2008. Entitled Wartsila delivers Worlds first Bro Power plant using brewery Spent Grain . . . © 2010 Wartsila. |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10982162B2 (en) | 2011-09-01 | 2021-04-20 | Akbev Group, Llc | High protein organic materials as fuel and processes for making the same |
| US11441090B2 (en) | 2011-09-01 | 2022-09-13 | Akbev Group, Llc | High protein organic materials as fuel and processes for making the same |
| US11866669B2 (en) | 2011-09-01 | 2024-01-09 | Akbev Group, Llc | High protein organic materials as fuel and processes for making the same |
| US12378492B2 (en) | 2011-09-01 | 2025-08-05 | Akbev Group, Llc | High protein organic materials as fuel and processes for making the same |
| WO2018080593A1 (en) | 2016-10-28 | 2018-05-03 | Akbev Group, Llc | High protein organic materials as fuel and processes for making the same |
| CN110903877A (en) * | 2019-12-09 | 2020-03-24 | 中车环境科技有限公司 | Method for preparing granular fuel by using organic waste |
Also Published As
| Publication number | Publication date |
|---|---|
| US20130055622A1 (en) | 2013-03-07 |
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