US931944A - Process for electrolytic deposition of metals. - Google Patents
Process for electrolytic deposition of metals. Download PDFInfo
- Publication number
- US931944A US931944A US49134909A US1909491349A US931944A US 931944 A US931944 A US 931944A US 49134909 A US49134909 A US 49134909A US 1909491349 A US1909491349 A US 1909491349A US 931944 A US931944 A US 931944A
- Authority
- US
- United States
- Prior art keywords
- metals
- perchloric acid
- metal
- cathode
- salt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910052751 metal Inorganic materials 0.000 title description 26
- 239000002184 metal Substances 0.000 title description 26
- 150000002739 metals Chemical group 0.000 title description 11
- 230000008021 deposition Effects 0.000 title description 3
- 238000000034 method Methods 0.000 title description 3
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical class OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 37
- 150000003839 salts Chemical class 0.000 description 19
- 239000002253 acid Substances 0.000 description 6
- 239000000126 substance Substances 0.000 description 5
- 229910045601 alloy Inorganic materials 0.000 description 4
- 239000000956 alloy Substances 0.000 description 4
- 238000000151 deposition Methods 0.000 description 4
- 238000007792 addition Methods 0.000 description 3
- 238000005868 electrolysis reaction Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- 244000000188 Vaccinium ovalifolium Species 0.000 description 2
- 239000010405 anode material Substances 0.000 description 2
- 238000007747 plating Methods 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 238000007670 refining Methods 0.000 description 2
- GOLCXWYRSKYTSP-UHFFFAOYSA-N Arsenious Acid Chemical compound O1[As]2O[As]1O2 GOLCXWYRSKYTSP-UHFFFAOYSA-N 0.000 description 1
- QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 241000282326 Felis catus Species 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 229910001115 Zinc-copper couple Inorganic materials 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000001464 adherent effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- TVZPLCNGKSPOJA-UHFFFAOYSA-N copper zinc Chemical compound [Cu].[Zn] TVZPLCNGKSPOJA-UHFFFAOYSA-N 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 239000011133 lead Substances 0.000 description 1
- 210000004914 menses Anatomy 0.000 description 1
- 239000000203 mixture Chemical class 0.000 description 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000001648 tannin Substances 0.000 description 1
- 235000018553 tannin Nutrition 0.000 description 1
- 229920001864 tannin Polymers 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/56—Electroplating: Baths therefor from solutions of alloys
Definitions
- the metal or alloy whose insoluble salt is to be formed is used as anode material in an electrolyte containing a salt or salts of perchloric acid or perchloricacid or a mixture of perchloric acid and a, salt or salts of perchloric acid.
- the anode material dissolves and the insoluble salt may be prepared by precipitating this soluble perchloratethus formed with a suitable reagent.
- a plating or refining bath should be made from saltsand acids that are very soluble in water, that are stable, that is are neither. oxidized nor reduced by electrolysis and are unchanged by the air etc, that give good deposits upon the cathode and that give good efiiciencies of corrosion at the anode and of deposition upon the cathode.
- Perchloric acid HlOQ and its salts (RS10 fulfil these demands in a satisfactory manner.
- Perchlorates of the heavy Inetals are very soluble in water so that solutions maybe prepared of almost any desired strength up to one part of saltin one part of Water in many cases'which is much be: yond an concentration that is ever used-in commercial plating or refining by electrolysis.
- the acid radical of perchloric acid and of perchlorates is very stable,-it is not reduced even by a zinc-copper couple neither is it oxidized under any conditions. It is only decomposed when ignited or fused, a
- the solution should be circulated or stirred to prevent undue changes in concentration.
- the solution should be of the proper concentration and should contain the proper amount of free acid. I prefer a bath containing from 5 to '10 per cent. of metallic perchlorate and from 2 to 5 per cent. of free perchloric acid,
- the cathode should be clean and free from grease. If it is desired to strip the deposited metal from the cathode, a greased cathode should be employed. The addition of small quantities of certain substances greatly improves the character of the deposit in regard to smoothness, brightness, and denseness.
- metals which consists in subjectas'new and desire to secure anode to an electric current in a solution containing salts of perchloric acid and in electrodepositing the metal upon the cathode substantially as described.
- That improvement in the art of electrodepositing metals which consists in subjecting the metal or an alloy of the metal as ano e to an electric current in a solution containing a salt of perchloric acid and of free perchloric acid and in electrodepositing the metal upon the cathode substantially as described.
- That improvement in the art of electrodepositing metals which consists in subjecting the metal or an alloy of the metal as anode to an electric current in a solution containing salts of perchloric acid and of free perchloric acid and in electrodepositing the metal upon the cathode substantially as de- I scribed.
- That improvement in the art of electro depositing metals which consists in subjecting to an electric current a solution containing a salt of perchloric acid and in electrodepositing the metal contained in said salt' upon the cathode substantially as described.
- That improvement in the art of electrodepositing metals which consists in subjecting to an electric current a solution containing a salt of perchloric acid and of free perchloric acid and in elec'trodepositin the metal contained in said salt upon the cat ode substantially as described.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electroplating Methods And Accessories (AREA)
- Electroplating And Plating Baths Therefor (AREA)
Description
.. 31, ilioiitawing,
UNI-TED 'sTA'TEs PATENT oF IcE."
" rn amr c, menses, or nteonnwe'ron, INDIANA.
1 rnocnss non. nt'noanomr'rrc 'nnrosrrxon for mavens.
To. aHQwhom it may concern: lij altknown :thatl, FRAnK-C. MATHERS, a citizen of the Unlted States, residing at Bloomington, in the county of Monroe and State of Indiana, have invented a new and useful Process. for the Electrolytic Deposition of Metals, which the following is a specification.
soluble anode like platinum inwhich case the metal that isdeposited upon the cathode comes from the bath which'may *be brought back to the proper strength in any suitable manner. To. form insoluble salts off-the metals or alloys, the metal or alloy" whose insoluble salt is to be formed is used as anode material in an electrolyte containing a salt or salts of perchloric acid or perchloricacid or a mixture of perchloric acid and a, salt or salts of perchloric acid. Upon electrolysis the anode material dissolves and the insoluble salt may be prepared by precipitating this soluble perchloratethus formed with a suitable reagent.
- It is very desirable that a plating or refining bath should be made from saltsand acids that are very soluble in water, that are stable, that is are neither. oxidized nor reduced by electrolysis and are unchanged by the air etc, that give good deposits upon the cathode and that give good efiiciencies of corrosion at the anode and of deposition upon the cathode. Perchloric acid (HClOQ and its salts (RS10 fulfil these demands in a satisfactory manner. Perchlorates of the heavy Inetalsare very soluble in water so that solutions maybe prepared of almost any desired strength up to one part of saltin one part of Water in many cases'which is much be: yond an concentration that is ever used-in commercial plating or refining by electrolysis. The acid radical of perchloric acid and of perchlorates is very stable,-it is not reduced even by a zinc-copper couple neither is it oxidized under any conditions. It is only decomposed when ignited or fused, a
treatment to which it need not be subjected in the process described in this s ecification. The current eificiency at both e ectrodes is almost theoretical. The deposits upon the 1 m massessment. Patented Aug. 24 1909. a pearance A ril. 21. 1911 semina- 491,319.
Isfining and who understands how to use the knowledge that is commonly practiced in these arts. For. example: The solution should be circulated or stirred to prevent undue changes in concentration. The solution should be of the proper concentration and should contain the proper amount of free acid. I prefer a bath containing from 5 to '10 per cent. of metallic perchlorate and from 2 to 5 per cent. of free perchloric acid,
with such metals as copper, lead, silver, etc.
which are easily deposited while with zinc, cadmium, etc. a lower concentration of acid shouldbe used. If'an adherent protective deposit is desired upon the cathode, the cathode should be clean and free from grease. If it is desired to strip the deposited metal from the cathode, a greased cathode should be employed. The addition of small quantities of certain substances greatly improves the character of the deposit in regard to smoothness, brightness, and denseness. The beneficial effects of these substances have been long known and are described in many books and original articles upon the subject.- Among the substances that have been suggested as additions to the bath are :arsenious acid, stannous chlorid, .(Watt Electrometallw'gy, 1895, page 46) carbon disulfid, collodion, iodin andguttapercha in chloroform, etc. MMillen, A Treatise on Electrometallm'gy 1890, page 9). Experiments in connection with this work have shown that tannin is also an excellent addition substance. I prefer to use from 0.1 to 0.4 per cent-.. of these substances. The current .density must be regulated depending upon the concentration of the solution, the amount of free acid that is'present, the temperature, the amount of stirring, the nature of the ,metal that is to be plated or refined, etc. I
depositing metals which consists in subjectas'new and desire to secure anode to an electric current in a solution containing salts of perchloric acid and in electrodepositing the metal upon the cathode substantially as described.
3. That improvement in the art of electrodepositing metals which consists in subjecting the metal or an alloy of the metal as ano e to an electric current in a solution containing a salt of perchloric acid and of free perchloric acid and in electrodepositing the metal upon the cathode substantially as described.
4. That improvement in the art of electrodepositing metals which consists in subjecting the metal or an alloy of the metal as anode to an electric current in a solution containing salts of perchloric acid and of free perchloric acid and in electrodepositing the metal upon the cathode substantially as de- I scribed.
5. That improvement in the art of electro depositing metals which consists in subjecting to an electric current a solution containing a salt of perchloric acid and in electrodepositing the metal contained in said salt' upon the cathode substantially as described.
6. That improvement in the art ofelectrodepositing metals which consists in subjecting to an electric current a solution containing salts of perchloric acid and in electrodepositing the metal contained in said salt upon the' cathode substantially as described.-
7. That improvement in the art of electrodepositing metals which consists in subjecting to an electric current a solution containing a salt of perchloric acid and of free perchloric acid and in elec'trodepositin the metal contained in said salt upon the cat ode substantially as described.
8. That improvement in the art of electrodepositing metals which consists in subjecting to an electric current a solution containing, salts of perchloric acid and of free pe'rchloric acid and in electrodepositing the metal contained in said salt'upon the cathode substantially as described.
Witnesses THOMAS J. SAR'E, ROBERT E. LYONS.
FRANK o. MATHERS. i
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US49134909A US931944A (en) | 1909-04-21 | 1909-04-21 | Process for electrolytic deposition of metals. |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US49134909A US931944A (en) | 1909-04-21 | 1909-04-21 | Process for electrolytic deposition of metals. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US931944A true US931944A (en) | 1909-08-24 |
Family
ID=3000368
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US49134909A Expired - Lifetime US931944A (en) | 1909-04-21 | 1909-04-21 | Process for electrolytic deposition of metals. |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US931944A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2516515A (en) * | 1948-01-22 | 1950-07-25 | American Metal Co Ltd | Method for making iron powder |
| US2567934A (en) * | 1945-12-13 | 1951-09-18 | Vandervell Products Ltd | Process of electrodepositing an alloy of lead and indium |
| US2577833A (en) * | 1949-07-23 | 1951-12-11 | Westby George | Process for electrowinning chromium |
| US3227636A (en) * | 1964-10-29 | 1966-01-04 | Internat Protected Metals Inc | Method of bonding coatings |
| US5456819A (en) * | 1991-12-26 | 1995-10-10 | The United States Of America As Represented By The Secretary Of Commerce | Process for electrodepositing metal and metal alloys on tungsten, molybdenum and other difficult to plate metals |
-
1909
- 1909-04-21 US US49134909A patent/US931944A/en not_active Expired - Lifetime
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2567934A (en) * | 1945-12-13 | 1951-09-18 | Vandervell Products Ltd | Process of electrodepositing an alloy of lead and indium |
| US2516515A (en) * | 1948-01-22 | 1950-07-25 | American Metal Co Ltd | Method for making iron powder |
| US2577833A (en) * | 1949-07-23 | 1951-12-11 | Westby George | Process for electrowinning chromium |
| US3227636A (en) * | 1964-10-29 | 1966-01-04 | Internat Protected Metals Inc | Method of bonding coatings |
| US5456819A (en) * | 1991-12-26 | 1995-10-10 | The United States Of America As Represented By The Secretary Of Commerce | Process for electrodepositing metal and metal alloys on tungsten, molybdenum and other difficult to plate metals |
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