US702172A - Process of effecting the drying of non-drying oils and product produced by such process. - Google Patents
Process of effecting the drying of non-drying oils and product produced by such process. Download PDFInfo
- Publication number
- US702172A US702172A US4970801A US1901049708A US702172A US 702172 A US702172 A US 702172A US 4970801 A US4970801 A US 4970801A US 1901049708 A US1901049708 A US 1901049708A US 702172 A US702172 A US 702172A
- Authority
- US
- United States
- Prior art keywords
- drying
- oil
- paint
- pigment
- compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000001035 drying Methods 0.000 title description 38
- 239000003921 oil Substances 0.000 title description 22
- 238000000034 method Methods 0.000 title description 10
- 239000000049 pigment Substances 0.000 description 25
- 239000003973 paint Substances 0.000 description 24
- 150000001875 compounds Chemical class 0.000 description 21
- 239000000344 soap Substances 0.000 description 20
- 235000019198 oils Nutrition 0.000 description 17
- 239000010685 fatty oil Substances 0.000 description 14
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 7
- 239000011701 zinc Substances 0.000 description 7
- 229910052725 zinc Inorganic materials 0.000 description 7
- 235000012343 cottonseed oil Nutrition 0.000 description 5
- 239000002385 cottonseed oil Substances 0.000 description 5
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000011787 zinc oxide Substances 0.000 description 3
- 235000014692 zinc oxide Nutrition 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000003981 vehicle Substances 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 235000004431 Linum usitatissimum Nutrition 0.000 description 1
- 240000006240 Linum usitatissimum Species 0.000 description 1
- 235000019486 Sunflower oil Nutrition 0.000 description 1
- 229910000004 White lead Inorganic materials 0.000 description 1
- FMRLDPWIRHBCCC-UHFFFAOYSA-L Zinc carbonate Chemical compound [Zn+2].[O-]C([O-])=O FMRLDPWIRHBCCC-UHFFFAOYSA-L 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- AYJRCSIUFZENHW-DEQYMQKBSA-L barium(2+);oxomethanediolate Chemical compound [Ba+2].[O-][14C]([O-])=O AYJRCSIUFZENHW-DEQYMQKBSA-L 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000002285 corn oil Substances 0.000 description 1
- 235000005687 corn oil Nutrition 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 235000004426 flaxseed Nutrition 0.000 description 1
- BDAGIHXWWSANSR-NJFSPNSNSA-N hydroxyformaldehyde Chemical compound O[14CH]=O BDAGIHXWWSANSR-NJFSPNSNSA-N 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000011656 manganese carbonate Substances 0.000 description 1
- 235000006748 manganese carbonate Nutrition 0.000 description 1
- 229940093474 manganese carbonate Drugs 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 229910000016 manganese(II) carbonate Inorganic materials 0.000 description 1
- XMWCXZJXESXBBY-UHFFFAOYSA-L manganese(ii) carbonate Chemical compound [Mn+2].[O-]C([O-])=O XMWCXZJXESXBBY-UHFFFAOYSA-L 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910000018 strontium carbonate Inorganic materials 0.000 description 1
- 239000002600 sunflower oil Substances 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 235000016804 zinc Nutrition 0.000 description 1
- 239000011667 zinc carbonate Substances 0.000 description 1
- 235000004416 zinc carbonate Nutrition 0.000 description 1
- 229910000010 zinc carbonate Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D43/00—Separating particles from liquids, or liquids from solids, otherwise than by sedimentation or filtration
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/105—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing three carbon atoms only
Definitions
- the object of this'invention is to utilizethe non-drying fatty oils as paint-oils by'so combining them with certain"pigments-that the compounds formed when applied as paints will dryand harden and produce economical and satisfactory results.
- the non-drying fatty oils at present falling within the economicalscope of my process are cotton-oil, sunflower-oil, corn-oil, and-the
- the pigments which may be used are I like. such'metallic and earthy oxids and salts as willform hard insoluble soaps when ground in the oil. Examples of such pigments are oxid of zinc or zinc-white, zinc carbonate,
- the oil and pigment should be combined in substantially equal" parts-for example, one hundred parts of cottonseed oil and one hundred to one hundred and twenty parts of zinc-white-in order. that a compound may be ,7
- pigmeuts for example, sixty parts of zinc-white and forty parts of chalk-can be combined and that two or more non-drying fatty oils-for example, eighty parts of cotton-oil and twenty parts of sunflower-oilmay be mixed to form the vehicle.
- a paint compound possessing drying properties, composed of a non-drying fatty oil and a pigment capable of forming a hard metallic soap therewith, combined substantially in the proportions specified.
- a paint compound possessing drying properties, composed of a non-drying fatty oil and a pigment capable of forming a hard metallic soap therewith, combined substantially in the proportions specified, and a drier.
- a paint compound possessing drying properties, composed of a non-drying fattyoil and oxid of zinc, combined substantially in the proportions specified.
- a paint compound possessing drying properties, composed of a non-drying fatty oil and oxid of zinc, combined substantially in the proportions specified, and a drier.
- a paint compound possessing drying properties, composed of cotton-seed oil and a pigment eapableof forming a hard metallic soap therewith, combined substantially in the proportions specified.
- a paint compound possessing drying properties, composed of cotton-seed oil and a pigment capable of forming a hard metallic soap therewith, combined substantiallyin the proportions specified; and a drier.
- a paint compound possessing drying properties, cdmposed of cotton-seed oil and oxid of zinc, combined substantially in the proportions specified.
- a paint compound possessing drying properties, composed of cotton-seed oil and oxid of zinc, combined substantially in the proportions specified; and a drier.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paints Or Removers (AREA)
- Lubricants (AREA)
Description
Y i "OFFICE.
" ILLIAMN' BLA'KEMAN, JR, on NEW YORK,N.
YAEBOCESS'OFJEFFECT'ING Tut DRYING F NONI-DRYING; OILIISIAND PRODUCT PRODUCED BY SUCH PROCESS.
county, and State of NewYork, have invent" ed a new anduseful Process of Making Dry ring Paint Compounds from Non-Drying Fatty 'srno'xrxcmrron forming partofLetters-Patent No.702,172, dated June 10,1902.
' Application filed'Maroh 5,190 1. Serial No.'49,708. (No sp ecimensj I TQ allrwhon t itfmay concern: Beitknown thatI-,WI 'LIAMN;BLAKEMAN, Jr. of the borough of Manhattan, in the city,
Oils and anew and usefnl Product Produced by Such Process, which invention is fully set forth in the followingspecifi'cation.
The object of this'invention is to utilizethe non-drying fatty oils as paint-oils by'so combining them with certain"pigments-that the compounds formed when applied as paints will dryand harden and produce economical and satisfactory results. i I
The invention will first be described in detail and then'set'forth in the claims.
' The drying-of oil combined-with a pigment when spread as a paint results from three actionse-namely, an increase of surface area exposed, the formation of a metallic soap or insoluble saponaceouscompound, andthe absorption of oxygen-and-in the majority of technical works referringto' the subject and as at'present understoodin trade circles the absorption'of oxygenisregarded as the primary and most import-ant step.- My investigations and experiments have demonstrated, however, that the formation of a metallic soap or insoluble saponaceous compound between the pigment and the oil is the first step in the drying of a paint and'that the absorption ofoxygen is a secondarystep. I have also discovered that the character of the soap formed,
' whether a hard soap or a soft orv glutinous soap,is,also of the highest importance, for if a soft or glutinous insoluble soap be formed by a pigmentwithits oil vehicle no amount of oxygen subsequently absorbed or imparted can dry-and harden the paint, and I have f urth er discovered that certain substancesused as pigments in paints, while they will form hard soaps-when ground in the drying oils the drying of the latter. Thus lead oxids and salts in the'proportion's in which they are used as pigments in paints form hard soaps with linseed or other drying oils, but'for,m soft soaps when incorporated in anon-drying fatty oil. These facts appear to have been owing to the formation of a' soft metallic soap between the lead and the oil. Ihave discovered that certain metallic and earthy oxids and salts if incorporated with a non-drying ioverlooked in all attempts heretofore made fatty oil'in proper proportionstoconstitute a paint will'form a hard insoluble soap with 'the oil, andthus cause the compound when spread as a paint to dry and harden. Hence by employing these substances as pigments in proper pr'oportionsand rejecting white lead and other pigments which formsoft-soaps with the non-drying fatty oils these oils may be employed as paint-oils.
- V The non-drying fatty oils at present falling within the economicalscope of my process are cotton-oil, sunflower-oil, corn-oil, and-the The pigments which may be used are I like. such'metallic and earthy oxids and salts as willform hard insoluble soaps when ground in the oil. Examples of such pigments are oxid of zinc or zinc-white, zinc carbonate,
manganese carbonate, calcium carbonate,V barium carbonate, barium sulfate, strontium carbonate, and aluminium oxid,the pigment which I have found most suitable being oxid of zinc. Y. I
In carrying out my lnventionl first'select a non-drying fatty oil and one or more pig ments capable of forming ahardmetallic soap therewith, and I then thoroughly incorporate such pigment or pigments with the oil by grinding or in any other suitable manner. The result of thissimple process is that when the compound s0 produced is spread as aipaint a hard insoluble soap or saponac'eous compound is formed between the non-drying fatty oil and the pigment, and the mixture willthor oughly dry and ha'rden.'
' The oil and pigment should be combined in substantially equal" parts-for example, one hundred parts of cottonseed oil and one hundred to one hundred and twenty parts of zinc-white-in order. that a compound may be ,7
formed of the proper consistency to be ap-' plied as a paint, it being understood, of course, that following the universal custom in trade too circles the pigment may be first ground in only a portion of the oilsay fifteen to twenty parts-to form a thick paste or f pigment ground in oil and the balance of the oil be subsequently added, so that when the paint is ready for spreading it will consist of substantially equal parts of oil and pigment. By reason of a difference in density from sixty to eighty parts of either barium, manganese, calcium, or strontiu m carbonate will be equivalent to one hundred parts of zincwhite. Hence I do not limit myself to exact proportions of oil and pigment. It will also be understood that suitable proportions of two or more pigmeutsfor example, sixty parts of zinc-white and forty parts of chalk-can be combined and that two or more non-drying fatty oils-for example, eighty parts of cotton-oil and twenty parts of sunflower-oilmay be mixed to form the vehicle.
The time of drying of the paint will be reduced considerably if a drier be added to the oil or to the pigment or to the compound formed, and the drier used for this purpose may be any animal, vegetable, metallic, or mineral substance that will perform the function of hastening the drying or hardening of the compound, a commercial liquid drier, such as turpentine-japan, being well adapted for this purpose.
Having thus fully described my invention, I claim- 1. The process herein described of making a paint compound possessing drying and hardening properties, which consists in combining, substantially in the proportions specified, a non-drying fatty oil and a pigment capable of forming a hard metallic soap therewith.
2. The process herein described of making a paint compound possessing drying and hardening properties, which consists in combining, substantially in the proportions specified, a non-drying fatty oil and a pigment capable of formingahard metallic soap therewith, and adding a drier.
3. The process herein described of making a paint compound possessing drying and hardening properties, which consists in combin- I a paint compound possessing drying and hardening properties, which consists in combining, substantially in the proportions specified, anon-drying fatty oil and oxid of zinc, and adding a drier.
5. A paint compound, possessing drying properties, composed of a non-drying fatty oil and a pigment capable of forming a hard metallic soap therewith, combined substantially in the proportions specified.
6. A paint compound, possessing drying properties, composed of a non-drying fatty oil and a pigment capable of forming a hard metallic soap therewith, combined substantially in the proportions specified, and a drier.
7. A paint compound, possessing drying properties, composed of a non-drying fattyoil and oxid of zinc, combined substantially in the proportions specified.
8. A paint compound, possessing drying properties, composed of a non-drying fatty oil and oxid of zinc, combined substantially in the proportions specified, and a drier.
9. A paint compound, possessing drying properties, composed of cotton-seed oil and a pigment eapableof forming a hard metallic soap therewith, combined substantially in the proportions specified.
10. A paint compound, possessing drying properties, composed of cotton-seed oil and a pigment capable of forming a hard metallic soap therewith, combined substantiallyin the proportions specified; and a drier.
11. A paint compound, possessing drying properties, cdmposed of cotton-seed oil and oxid of zinc, combined substantially in the proportions specified.
12. A paint compound, possessing drying properties, composed of cotton-seed oil and oxid of zinc, combined substantially in the proportions specified; and a drier.
WM. N. BLAKEMAN, JR.
\Vitnessesz' FRANCIS P. REILLY, GEORGE A. STIMPSON.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US4970801A US702172A (en) | 1901-03-05 | 1901-03-05 | Process of effecting the drying of non-drying oils and product produced by such process. |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US4970801A US702172A (en) | 1901-03-05 | 1901-03-05 | Process of effecting the drying of non-drying oils and product produced by such process. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US702172A true US702172A (en) | 1902-06-10 |
Family
ID=2770703
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US4970801A Expired - Lifetime US702172A (en) | 1901-03-05 | 1901-03-05 | Process of effecting the drying of non-drying oils and product produced by such process. |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US702172A (en) |
-
1901
- 1901-03-05 US US4970801A patent/US702172A/en not_active Expired - Lifetime
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