US603526A - Joseph r - Google Patents
Joseph r Download PDFInfo
- Publication number
- US603526A US603526A US603526DA US603526A US 603526 A US603526 A US 603526A US 603526D A US603526D A US 603526DA US 603526 A US603526 A US 603526A
- Authority
- US
- United States
- Prior art keywords
- pieces
- pyroxylin
- compounds
- marble
- imitation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- FJWGYAHXMCUOOM-QHOUIDNNSA-N [(2s,3r,4s,5r,6r)-2-[(2r,3r,4s,5r,6s)-4,5-dinitrooxy-2-(nitrooxymethyl)-6-[(2r,3r,4s,5r,6s)-4,5,6-trinitrooxy-2-(nitrooxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-3,5-dinitrooxy-6-(nitrooxymethyl)oxan-4-yl] nitrate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O)O[C@H]1[C@@H]([C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@@H](CO[N+]([O-])=O)O1)O[N+]([O-])=O)CO[N+](=O)[O-])[C@@H]1[C@@H](CO[N+]([O-])=O)O[C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O FJWGYAHXMCUOOM-QHOUIDNNSA-N 0.000 description 16
- 239000003086 colorant Substances 0.000 description 14
- 239000004579 marble Substances 0.000 description 14
- 238000004519 manufacturing process Methods 0.000 description 13
- 229920001220 nitrocellulos Polymers 0.000 description 12
- 229940079938 nitrocellulose Drugs 0.000 description 12
- 239000000975 dye Substances 0.000 description 11
- 239000007787 solid Substances 0.000 description 9
- 150000001875 compounds Chemical class 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 238000003490 calendering Methods 0.000 description 7
- 239000012634 fragment Substances 0.000 description 6
- -1 pyroXylin compound Chemical class 0.000 description 5
- 229920002160 Celluloid Polymers 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 238000004040 coloring Methods 0.000 description 3
- 238000005520 cutting process Methods 0.000 description 3
- 238000007598 dipping method Methods 0.000 description 2
- 235000019441 ethanol Nutrition 0.000 description 2
- 230000001788 irregular Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000010409 thin film Substances 0.000 description 2
- 241001369972 Deudorix epijarbas Species 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- WLKAMFOFXYCYDK-UHFFFAOYSA-N [5-amino-4-[[3-[(2-amino-4-azaniumyl-5-methylphenyl)diazenyl]-4-methylphenyl]diazenyl]-2-methylphenyl]azanium;dichloride Chemical compound [Cl-].[Cl-].CC1=CC=C(N=NC=2C(=CC([NH3+])=C(C)C=2)N)C=C1N=NC1=CC(C)=C([NH3+])C=C1N WLKAMFOFXYCYDK-UHFFFAOYSA-N 0.000 description 1
- 239000011046 carnelian Substances 0.000 description 1
- 239000009136 dragon's blood Substances 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 241000894007 species Species 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44F—SPECIAL DESIGNS OR PICTURES
- B44F9/00—Designs imitating natural patterns
- B44F9/04—Designs imitating natural patterns of stone surfaces, e.g. marble
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
Definitions
- My present invention relates to a novel method of manufacturing pyroxylin compounds in imitation of marble.
- FIG. 1 is a view showing several pieces of pyroxylin compounds of diiferent body colors, part of said pieces being dyed upon the surface.
- Fig. 2 is a View showing a portion of a sheet formed from said pieces by calendering.
- Fig. 3 is a View of a portion of a sheet cut or planed from a block of pyroxylin produced from sheets similar to those in Fig. 2.
- pyroxylin compounds having solid colors corresponding with the tints of the marble I wish to imitate are cut or otherwise formed in fragments or pieces of suitable size, each color being kept separate, and these fragments or pieces are placed in a sieve or other similar receptacle and dipped in a dye.
- This dye may be the same for each solid color of the pyroXylin compound, or different colors may be used, and the arrangement is such that the pieces within the sieve may be wholly immersed and then withdrawn to allow the dye to drain off quickly.
- I may dip all the pieces of each solid color in the same or in different dyes, or I may dip part only and leave more or less of said pieces without dyeing.
- the pieces of pyroxylin compound will each be found to have an extremely thin film of coloring-matter over the entire surface, as may be seen by cutting away a small portion of one of the angles.
- the pieces are ready for subsequent treatment, and they are immediately placed in the rolls and calendered until they are united in a homogeneous sheet. A number of these sheets are placed in the press and treated in the ordinary manner for cutting.
- said process consisting in forming pyroxylin compounds .of suitable solid colors into fragments or pieces, dipping said pieces in a dye dissolved in a solvent of pyroxylin, and calendering the dipped fragments or pieces together to form sheeting, substantially as described.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Color Printing (AREA)
- Paper (AREA)
Description
(No Model.)
J. R. FRANCE.
METHOD OF MANUFACTURING -PYROXYLIN COMPOUNDS IN IMITATION 0F MARBLE.
No.603,526. PatentedMay 3,1898.
W" Inventor.
UNiTnD A STATES PATENT OFFICE.
JOSEPH R. FRANCE, OF NEW YORK, N. Y., ASSIGNOR TO THE ARLINGTON MANUFACTURING COMPANY, OF SAME PLACE.
METHOD OF MANUFACTURING PYROXYLlN COMPOUNDS IN lMlTATlON OF MARBLE SPEGIFICATION forming part of Letters Patent No. 603,526, dated May 3, 1898.
Application filed October 29, 1895. Serial No. 567,279. (No specimens.)
To all whom it may concern:
Be it known that I, J OSEPH R. FRANC a citizen of the United States, residing at New York, in the county of New York and State of New York, have invented new and useful Improvements in Methods of Manufacturing Pyroxylin Compoundsin Imitation of Marble, of which the following is a specification.
My present invention relates to a novel method of manufacturing pyroxylin compounds in imitation of marble.
In the manufacture of pyroxylin compounds-such as those known upon the market as pyralin, celluloid, &c.-there has been created a wide demand for such compounds in imitation of marble as Well as other substances like cornelian, agate, and the like. There have been many references to this material as a substitute for marble and others of the substances named, but these substitutes have been produced either by calendering two or more distinct colorings together, such as imitations of cloudy amber or tortoiseshell, or by laying up, as it is termed in-the art, strips of Various colors edgewise in the press in lines which are nearly straight or but slightly broken, so that when pressed into a solid block sheets cut from the latter show the striations and different colors. Until recently, however, there has been no production of a pyroxlin compound successfully imitating marbles or agates. Those skilled in the art will readily understand that if crude sheets of pyralin are run up in solid colors and then cut into small pieces and the pieces calendered together or calendered together in large sheets a fairly good imitation of marble may be obtained; but when the block is cut into sheets it lacks the fine pencilings and irregular markings, usually of a dark color, which are necessary in order to obtain a perfeet imitation, but which have not as yet been produced by any known process of manufacture. t
It is the purpose of my present invention to provide a novel process for the manufacture of pyroXylin compounds in perfect imitation of various species of marble, said invention comprising also the novel product of such process.
To enable those skilled in the art to which my invention pertains to fully understand and practice said invention, I will proceed to describe the same in'detail, making reference for this purpose to the accompanying drawings, in which- Figure 1 is a view showing several pieces of pyroxylin compounds of diiferent body colors, part of said pieces being dyed upon the surface. Fig. 2 is a View showing a portion of a sheet formed from said pieces by calendering. Fig. 3 is a View of a portion of a sheet cut or planed from a block of pyroxylin produced from sheets similar to those in Fig. 2.
In practicing my invention I select pyroxylin compounds having solid colors corresponding with the tints of the marble I wish to imitate. These compounds are cut or otherwise formed in fragments or pieces of suitable size, each color being kept separate, and these fragments or pieces are placed in a sieve or other similar receptacle and dipped in a dye. This dye may be the same for each solid color of the pyroXylin compound, or different colors may be used, and the arrangement is such that the pieces within the sieve may be wholly immersed and then withdrawn to allow the dye to drain off quickly. I may dip all the pieces of each solid color in the same or in different dyes, or I may dip part only and leave more or less of said pieces without dyeing. In preparing the dye I use any solvent of pyroxylin, ethyl alcohol being preferred, and for coloring I prefer dyes which are soluble in alcohol, such as nigrosen, Bismarck brown, dragons blood, and many others which will readily suggest themselves to an operator familiar with the art. When thus prepared, the pieces of pyroxylin compound will each be found to have an extremely thin film of coloring-matter over the entire surface, as may be seen by cutting away a small portion of one of the angles. When thus prepared, the pieces are ready for subsequent treatment, and they are immediately placed in the rolls and calendered until they are united in a homogeneous sheet. A number of these sheets are placed in the press and treated in the ordinary manner for cutting. WVhen the latter operation is performed, it will be seen that the fine thin films of coloring-matter present the appearance of fine markings separating the different colors and running in many directions irregularly, disappearing at some points and again reappearing, the varied markings and the solid colors being mingled with all the infinite variety of blending seen in the most highly-prized variegated marbles. By a proper selection of tints in the dyes used and by varying the size of the pieces of pyroxylin compound the operator can readily produce the most perfect imitations of all the variegated marbles known.
It should be noted that the action of the solvents used in preparing the dyes in which the pieces are dipped leaves the latterin the very best condition for rolling, and the sheeting produced is of the best quality, being perfectly homogeneous throughout and without the slightest weakness or tendency to separate upon the lines of marking.
It should be noted that in the imitation of marbles having an alabaster-like base with more or less translucence, like many of the Phrygian marbles, it will be desirable to use a suitable quantity of pieces of pyroxylin which are free from color and without any dye applied to the surface. In some cases also it may be necessary to vary the degree of translucency, which can readily be effected by means perfectly familiar to every one skilled in the art of manufacturing compounds of pyroxylin.
This improvement largely increases the great variety of purposes for which pyralin and similar compounds can be used, and it supplies a want which has long been felt, but which hasnot hitherto been filled.
What I claim is 1. The process described for manufacturing pyroxylin compounds in imitation of marble,
said process consisting in forming pyroxylin compounds .of suitable solid colors into fragments or pieces, dipping said pieces in a dye dissolved in a solvent of pyroxylin, and calendering the dipped fragments or pieces together to form sheeting, substantially as described.
' 2. The process described for manufacturing pyroxylin compounds in imitation of marble, said process consisting in producingpyroxylin compounds of different colors following the colors of the marble to be imitated, forming said compounds in fragments or pieces, dipping pieces of each solid color in a dye dissolved in a solvent of pyroxylin, calendering the whole number of pieces together to form a sheeting, compressing the sheeting into blocks and cutting the latter, substantially as described.
3. As a new article of manufacture a sheet of pyroxylin compound in imitation of marble consisting of fragments or pieces of pyroxylin compounds of one or more solid body colors following the colors of the marble to be imitated, said pieces having had applied to them an external coloring which when the pieces are blended together toform a sheet appear in irregular streaks and lines variously arranged and intermingled in the sheet and running through the body color or colors, substantially as described.
' In testimony whereof I have hereunto set my hand in presence of two subscribing witnesses.
JOSEPH R. FRANCE.
Witnesses:
R. J. SIoKELs, W. L. HEBBERD.
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US603526A true US603526A (en) | 1898-05-03 |
Family
ID=2672157
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US603526D Expired - Lifetime US603526A (en) | Joseph r |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US603526A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| USD714559S1 (en) * | 2013-07-26 | 2014-10-07 | Awi Licensing Company | Panel with faux marble pattern |
| USD715563S1 (en) * | 2013-07-26 | 2014-10-21 | Awi Licensing Company | Panel with faux marble pattern |
-
0
- US US603526D patent/US603526A/en not_active Expired - Lifetime
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| USD714559S1 (en) * | 2013-07-26 | 2014-10-07 | Awi Licensing Company | Panel with faux marble pattern |
| USD715563S1 (en) * | 2013-07-26 | 2014-10-21 | Awi Licensing Company | Panel with faux marble pattern |
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