US3865642A - Water based quenching composition and method - Google Patents
Water based quenching composition and method Download PDFInfo
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- US3865642A US3865642A US356625A US35662573A US3865642A US 3865642 A US3865642 A US 3865642A US 356625 A US356625 A US 356625A US 35662573 A US35662573 A US 35662573A US 3865642 A US3865642 A US 3865642A
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- 239000000203 mixture Substances 0.000 title claims abstract description 67
- 238000010791 quenching Methods 0.000 title claims abstract description 55
- 230000000171 quenching effect Effects 0.000 title claims abstract description 47
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 42
- 238000000034 method Methods 0.000 title claims abstract description 10
- 239000007787 solid Substances 0.000 claims abstract description 18
- 150000001875 compounds Chemical class 0.000 claims abstract description 13
- 229910052751 metal Inorganic materials 0.000 claims abstract description 11
- 239000002184 metal Substances 0.000 claims abstract description 11
- 239000011347 resin Substances 0.000 claims abstract description 9
- 229920005989 resin Polymers 0.000 claims abstract description 9
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 8
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 8
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 15
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 15
- 239000000463 material Substances 0.000 claims description 15
- 239000007822 coupling agent Substances 0.000 claims description 11
- -1 carbitol Chemical compound 0.000 claims description 6
- ZKCAGDPACLOVBN-UHFFFAOYSA-N 2-(2-ethylbutoxy)ethanol Chemical compound CCC(CC)COCCO ZKCAGDPACLOVBN-UHFFFAOYSA-N 0.000 claims description 5
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 claims description 5
- XXJWXESWEXIICW-UHFFFAOYSA-N diethylene glycol monoethyl ether Chemical compound CCOCCOCCO XXJWXESWEXIICW-UHFFFAOYSA-N 0.000 claims description 3
- 238000000926 separation method Methods 0.000 claims description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 2
- XLYOFNOQVPJJNP-PWCQTSIFSA-N Tritiated water Chemical compound [3H]O[3H] XLYOFNOQVPJJNP-PWCQTSIFSA-N 0.000 claims 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 229910000831 Steel Inorganic materials 0.000 description 4
- 239000010959 steel Substances 0.000 description 4
- 241000487918 Acacia argyrodendron Species 0.000 description 3
- 230000032683 aging Effects 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 235000011222 chang cao shi Nutrition 0.000 description 3
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 2
- 229910000838 Al alloy Inorganic materials 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 235000019589 hardness Nutrition 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 229910001104 4140 steel Inorganic materials 0.000 description 1
- 229910000615 4150 steel Inorganic materials 0.000 description 1
- 241000023467 Composia Species 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 1
- RVGRUAULSDPKGF-UHFFFAOYSA-N Poloxamer Chemical compound C1CO1.CC1CO1 RVGRUAULSDPKGF-UHFFFAOYSA-N 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 230000001464 adherent effect Effects 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical group [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000012612 commercial material Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 235000019645 odor Nutrition 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 238000004881 precipitation hardening Methods 0.000 description 1
- 239000002195 soluble material Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/56—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering characterised by the quenching agents
- C21D1/60—Aqueous agents
Definitions
- This invention broadly relates to a new quenching composition and a method of quenching heated metal using said composition.
- Another object of the present invention is to provide a new aqueous quenching composition which does not leave a tenacious film on the hot worked metal after quenching.
- Another object of the present invention is to provide an improved aqueous quenching composition which possesses excellent quenching properties for steel parts and also for aluminum parts, and which is considerably more economical to produce than previously known aqueous quenching compositions.
- Another object of the present invention is to provide an improved aqueous quenching composition and a concentrated form thereof, which composition and concentrate are highly stable and do not have the ingredients thereof separated out after substantial periods of shelf-life.
- Another object of the present invention is to provide an improved method of quenching heated metal utilizing a quenching composition as discovered and disclosed herein.
- the present invention comprises a water based quenching composition which includes water soluble polyvinyl alcohol resin, a solid water soluble polyoxyalkylene compound having a molecular weight from about 1,000 to less than 95,000, a coupling agent, and the balance water.
- the present invention comprises a method of quenching'heated metal comprised of contacting the heated metal with an aqueous quenching solution comprising water having dissolved therein a water soluble polyvinyl alcohol resin and a solid water soluble polyoxyalkylene compound having a molecular weight from about 1,000 to less than 95,000.
- composition disclosed in this invention is highly stable and has a long shelf-life which is highly desirable, and in fact highly necessary in order to obtain commercial acceptance in the market place.
- composition of this invention is also more economical to produce and has a more effective quenching rate than the patents above.
- the composition of this invention is a more effective quench retardant, because the composition is unique in that a less concentrated solution is required in order to effectively slow down the quench in comparison with prior water based aqueous quenching compositions.
- inventive composition disclosed herein is unexpectantly advantageous for use in aluminum quenching in comparison with prior art compositions, in that the composition disclosed herein produces equal hardnesses, using a less concentrated quenching solution, with equivalent distortion and with less film formation in comparison with the prior art water based quenching compositions.
- the materials used in the inventive composition herein are such that a much lower percentage of nonaqueous solids is required to retard the quench to the same degree as would be necessary with other water based quenching compositions. Based on this discovery tions.
- the polyvinyl alcohol resin which is utilized in the invention must be a water soluble resin and broadly it should be present within the range of about 0.02 percent to less than 2.7 percent by weight of the quenching composition.
- the solid water soluble polyoxyalkylene compound which has been discovered for use in accordance with the invention herein should be a polyoxyalkylene material having a molecular weight from about 1,000 to less than 95,000. Preferably this molecular weight should be within the range of about 2,000 to about 50,000 and best results are obtained using a material having a molecular weight within the range of about 2,000 to about 16,000.
- Suitable polyoxyalkylene compounds for use in the present invention may be prepared as described in US. Pat. No. 2,674,619, the disclosure of which is incorporated herein by reference. It is preferred that the polyoxyalkylene material be one in which the hydrophobic element of the compound isa polypropylene polymer. It has been. discovered to be important in i order to achieve the benefits of this invention that the polyoxyalkylene compound be a solid water soluble material.
- the amount of the polyoxyalkylene compound used in the inventive composition should broadly be within the range of about 0.0l to less than 1.8 percent by weight of the quenching composition.
- the coupling agent which is used in this invention should have a molecular weight of less than 900; and,
- ethylene glycol ethyl butyl cellosolve
- diethylene glycol ethyl ether carbitol
- propylene glycol and dipropylene glycol.
- the amountof the coupling agent used in the composition herein should normally be at a level of about 0.01 percent by weight of the composition. or higher.
- the coupling agent may be present within the range of about 0.0] to about 5 percent by weight of the composition.
- composition additives such as a rust inhibitor material, a stabilizer material, and/or additives to prevent bacterial growth and odors.
- EXAMPLE I EXAMPLE 2 Material Parts by Weight (a) Water 85.70 (b) Pluronic F 68 LF 4.70 (c) Elvanol 50-42 7.10 (d) Carbitol 2.0
- a water based quenching composition consisting essentially of in weight percent:
- a method of quenching heated metal-comprised of and dipropylene glycol contacting the heated metal with a water based and the balance water, quenching composition consisting essentially of in to said composition having a percent total non-volatile weight percent: solids of less than 5 percent by weight of the composia. about 0.02 to 2.7 percent water soluble polyvinyl tion.
- composition of claim 1 wherein, b. about 0.01 to 1.8 percent solid water soluble polysaid molecular weight of the solid polyoxyalkylene oxyalkylene compound having a molecular weight compound is between about 2,000 and about from about 1,000 to less than 95,000, l6,000.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
A stable quenching composition comprised of an aqueous solution which contains dissolved therein: a water soluble polyvinyl alcohol resin, a solid water soluble polyoxyalkylene compound having a molecular weight from about 1,000 to less than 95,000, with the balance of the composition being water; and, a method of quenching heated metal with the quenching composition disclosed herein.
Description
United States Patent [191 Foreman WATER BASED QUENCHING COMPOSITION AND METHOD [75] Inventor: Robert W. Foreman, Bloomfield Hills, Mich.
[73] Assignee: Park Chemical Co., Detroit, Mich.
[22] Filed: May 2, 1973 [21] Appl. N0.: 356,625
Related U.S. Application Data [63] Continuation-in-part of Ser. No. 156,037, June 23,
1971, abandoned.
[52] U.S. Cl 148/28, 148/18, 252/76,
252/79 [51] Int. Cl 323k 35/24 [58] Field of Search 148/18, 25, 28, 19, 29,
[56] References Cited UNITED STATES PATENTS 2,600,290 6/1952 Cornell 148/18 [451 Feb. 11, 1975 2,770,564 ll/l956 Gordon .4 148/18 3,022,205 2/1962 Chase et a1. l48/20.6 3,220,893 11/1965 Blackwood et al 148/28 3,224,910 12/1965 McEwen 148/28 3,475,232 10/1969 Lewis et al 148/18 Primary ExaminerWalter R. Satterfield Attorney, Agent, or Firm-Harness, Dickey & Pierce [57] ABSTRACT 3 Claims, N0 Drawings WATER BASED QUENCHING COMPOSITION AND METHOD BACKGROUND OF THE INVENTION This application is a continuation in part of copending application Ser. No. 156,037, filed June 23, 1971', now abandoned.
This invention broadly relates to a new quenching composition and a method of quenching heated metal using said composition.
In the past it has been known to utilize a water solution of polyvinyl alcohol resin as an aqueous quenching composition (Corneil U.S. Pat. No. 2,600,290), and while such compositions are still useful in various applications at the present time, they also possess a serious disadvantage due to their tendency to form a tenaciously adherent film on the hot worked metal following quenching. Thus there has been a clear need in the art for many years for an aqueous quenching composition which would not leave the tenacious film on the hot worked metal after quenching and which at the same time would be economical to produce so that it would receive acceptance in the market place.
Accordingly it is an object of this invention to provide an improved aqueous quenching composition which is economically advantageous to produce.
Another object of the present invention is to provide a new aqueous quenching composition which does not leave a tenacious film on the hot worked metal after quenching. I
Another object of the present invention is to provide an improved aqueous quenching composition which possesses excellent quenching properties for steel parts and also for aluminum parts, and which is considerably more economical to produce than previously known aqueous quenching compositions.
Another object of the present invention is to provide an improved aqueous quenching composition and a concentrated form thereof, which composition and concentrate are highly stable and do not have the ingredients thereof separated out after substantial periods of shelf-life.
Another object of the present invention is to provide an improved method of quenching heated metal utilizing a quenching composition as discovered and disclosed herein.
Other objects, features, and advantages of the present invention will become apparent from the subsequent description and the appended claims.
The state of the art is indicated by the following references, and which are cited here of record: Lewis et a1 U.S. Pat. No. 3,475,232; Corneil U.S. Pat. No. 2,600,290; Gordon U.S. Pat. No. 2,770,564; Erdmann U.S. Pat. No. 2,793,147; 1 Freeman U.S. Pat. No.
2,799,606; Bailey U.S. Pat. No. 2,914,491; Chase et al U.S. Pat. No. 3,022,205; Blackwood et al U.S. Pat. No. 3,220,893; British Pat. No. 716,354. Said patent disclosures are hereby incorporated herein by reference.
SUMMARY OF THE INVENTION Briefly stated the present invention comprises a water based quenching composition which includes water soluble polyvinyl alcohol resin, a solid water soluble polyoxyalkylene compound having a molecular weight from about 1,000 to less than 95,000, a coupling agent, and the balance water.
From a method aspect, briefly stated, the present invention comprises a method of quenching'heated metal comprised of contacting the heated metal with an aqueous quenching solution comprising water having dissolved therein a water soluble polyvinyl alcohol resin and a solid water soluble polyoxyalkylene compound having a molecular weight from about 1,000 to less than 95,000.
In accordance with the invention disclosed herein it has now been discovered that the amount of film formation is insignificant when quench compositions containing less than 5 percent and preferably less than about 2 percent by weight non-aqueous solids or nonvolatiles are used as is normally the case, whereas, prior art quenching compositions form a hard varnish like film that is extremely difficult to remove.
It has also been found that the composition disclosed in this invention is highly stable and has a long shelf-life which is highly desirable, and in fact highly necessary in order to obtain commercial acceptance in the market place.
The composition of this invention is also more economical to produce and has a more effective quenching rate than the patents above. The composition of this invention is a more effective quench retardant, because the composition is unique in that a less concentrated solution is required in order to effectively slow down the quench in comparison with prior water based aqueous quenching compositions.
It has also'been found that the inventive composition disclosed herein is unexpectantly advantageous for use in aluminum quenching in comparison with prior art compositions, in that the composition disclosed herein produces equal hardnesses, using a less concentrated quenching solution, with equivalent distortion and with less film formation in comparison with the prior art water based quenching compositions.
Compatibility and storage tests of formulations made in a manner similar to the composition of the present invention using a polyglycol material (in place of the specific polyoxyalkylene material discovered for use in connection with the present invention) as in U.S. Pat. No. 3,220,893 show that the concentrated compositions made in this manner are unstable. Also, when a polyol material having a molecular weight of approximately 100,000 was attempted for use in the composition of the present invention, as disclosed in U.S. Pat. No. 3,022,205, storage and compatability tests also showed that the formulation so attempted was unstable.
Hardenability and quenching tests run with the composition of this invention on SAE 1045 steel parts, SAE 4140 steel parts and aluminum alloy material 606], have shown that the quenching composition of this in vention is superior to prior art water based quenching compositions in ability to retard the quench.
Work on oil hardening type steels, such as SAE 4150 and SAE 5150, have shown that the quenching composition of this invention used in an amount equaling about 2 percent by weight non-aqueous solids, will produce oil like hardnesses with no quench cracking depending on the size of the sample parts quenched.
The materials used in the inventive composition herein are such that a much lower percentage of nonaqueous solids is required to retard the quench to the same degree as would be necessary with other water based quenching compositions. Based on this discovery tions.
The times in seconds to quench from 1500F to the following temperatures relative to the difference from H O, provides the following:
Times in Seconds (Increase Over H O) Non-Volatile Solids Temp. 0.55% 1.38%
Change Ex. No. Comp. Ex. No. 2 Comp. 2.5%
To: Hereinbelow Hereinbelow Ucon A* Blackwood Patent No. 3,220,893 Commercial Material In aluminum quenching the dragout carryover is approximately 50 percent less using the composition of this invention in comparison with prior art water based compositions. Water based quenching compositions are commonly used in the aircraft and associated industries in quenching aluminum heat treatable alloys such as aluminum alloy 6061, followed by aging at room temperature (natural aging) or precipitation hardening (artificial aging) producing what are known as T4 and T6 heat treated conditions respectively. In such an application as this the water based quenching composition of the present invention is highly advantageous over prior art compositions in that the composition of this invention provides a rapid quench while still minimizing quench distortion.
DESCRIPTION OF PREFERRED EMBODIMENTS The polyvinyl alcohol resin which is utilized in the invention must be a water soluble resin and broadly it should be present within the range of about 0.02 percent to less than 2.7 percent by weight of the quenching composition.
The solid water soluble polyoxyalkylene compound which has been discovered for use in accordance with the invention herein should be a polyoxyalkylene material having a molecular weight from about 1,000 to less than 95,000. Preferably this molecular weight should be within the range of about 2,000 to about 50,000 and best results are obtained using a material having a molecular weight within the range of about 2,000 to about 16,000. Suitable polyoxyalkylene compounds for use in the present invention may be prepared as described in US. Pat. No. 2,674,619, the disclosure of which is incorporated herein by reference. It is preferred that the polyoxyalkylene material be one in which the hydrophobic element of the compound isa polypropylene polymer. It has been. discovered to be important in i order to achieve the benefits of this invention that the polyoxyalkylene compound be a solid water soluble material.
The amount of the polyoxyalkylene compound used in the inventive composition should broadly be within the range of about 0.0l to less than 1.8 percent by weight of the quenching composition.
The coupling agent which is used in this invention should have a molecular weight of less than 900; and,
may be any one of a number of different materials such as ethylene glycol, ethyl butyl cellosolve, diethylene glycol ethyl ether, carbitol, propylene glycol, and dipropylene glycol.
The amountof the coupling agent used in the composition herein should normally be at a level of about 0.01 percent by weight of the composition. or higher. Prefer ably the coupling agent may be present within the range of about 0.0] to about 5 percent by weight of the composition.
In accordance with the inventive composition discovered and disclosed herein it is also in many instances desirable to include in the composition additives such as a rust inhibitor material, a stabilizer material, and/or additives to prevent bacterial growth and odors.
In order to further illustrate the invention, the following Examples are provided. It is to be understood, however, that the Examples are included for illustrative purposes and are not intended to be limiting of the scope of the invention as set forth in the subjoined claims. I
EXAMPLE I EXAMPLE 2 Material Parts by Weight (a) Water 85.70 (b) Pluronic F 68 LF 4.70 (c) Elvanol 50-42 7.10 (d) Carbitol 2.0
Dilute with water to desired percent non-volatiles of (b), (c) and (d).
While it will be apparent that the preferred embodiments of the invention disclosedare well calculated to fulfill the objects above stated, it will be appreciated that the invention is susceptible to modification, variation and change without departing from the proper scope or fair meaning of the subjoined claims.
What is claimed is:
l. A water based quenching composition consisting essentially of in weight percent:
a. about 0.02 to 2.7 percent water soluble polyvinyl alcohol resin, b. about 0.01 to 1.8 percent solid water soluble polyoxyalkylene compound having a molecular weight from about 1,000 to less than 95,000, c. at least about 0.0] up to about 5 percent coupling agent for preventing separation between components (a) and (b), said coupling agent having a molecular weight of less than 900 and being different than components (a) and (b) and being selected from at least one material of the group consisting 6 of ethylene glycol, ethyl butyl cellosolve, diethylagent for preventing separation between compoene glycol ethyl ether, carbitol, propylene glycol, nents (a) and (b), said coupling agent having a moand dipropylene glycol, lecular weight of less than 900 and being different and the balance water, than components (a) and (b) and being selected said composition having a percent total non-volatile 5 from at least one material of the group consisting solids of less than 5 percent by weight of the composiof ethylene glycol, ethyl butyl cellosolve, diethyltion. ene glycol ethyl ether, carbitol, propylene glycol.
2. A method of quenching heated metal-comprised of and dipropylene glycol, contacting the heated metal with a water based and the balance water, quenching composition consisting essentially of in to said composition having a percent total non-volatile weight percent: solids of less than 5 percent by weight of the composia. about 0.02 to 2.7 percent water soluble polyvinyl tion.
alcohol resin, 3. The composition of claim 1 wherein, b. about 0.01 to 1.8 percent solid water soluble polysaid molecular weight of the solid polyoxyalkylene oxyalkylene compound having a molecular weight compound is between about 2,000 and about from about 1,000 to less than 95,000, l6,000.
c. at least about 001 up to about 5 percent coupling
Claims (3)
1. A WATER BASED QUENCHING COMPOSITION CONSISTING ESSENTIALLY OF IN WATER PERCENT: A. ABOUT 0.02 TO 2.7 PERCENT WATER SOLUBLE POLYVINYL ALCOHOL RESIN, B. ABOUT 0.01 TO 1.8 PERCENT SOLID WATER SOLUBLE POLYOXYALKYLENE COMPOUND HAVING A MOLECULAR WEIGHT FROM ABOUT 1,000 TO LESS THAN 95,000, C. AT LEAST ABOUT 0.01 UP TO ABOUT 5 PERCENT COUPLING AGENT FOR PREVENTING SEPRATION BETWEEN COMPONENTS (A) AND (B), SAID COUPLING AGENT HAVING A MOLECULAR WEIGHT OF LESS THAN 900 AND BEING DIFFERENT THAN COMPONENTS (A) AND (B) AND BEING SELECTED FROM AT LEAST ONE MATERIAL OF THE GROUP CONSISTING OF ETHYLENE GLYCOL, ETHYL BUTYL CELLOSOLVE, DIETHYLENE GLUCOL ETHYL ETHER, CARBITOL, PROPYLENE GLYCOL, AND DIPROPYLENE GLYCOL, AND THE BALANCE WATER, SAID COMPOSITION HAVING A PERCENT TOTAL NON-VOLATILE SOLDS OF LESS THAN 5 PERCENT BY WEIGHT OF THE COMPOSITION.
2. A method of quenching heated metal comprised of contacting the heated metal with a water based quenching composition consisting essentially of in weight percent: a. about 0.02 to 2.7 percent water soluble polyvinyl alcohol resin, b. about 0.01 to 1.8 percent solid water soluble polyoxyalkylene compound having a molecular weight from about 1,000 to less than 95,000, c. at least about 0.01 up to about 5 percent coupling agent for preventing separation between components (a) and (b), said coupling agent having a molecular weight of less than 900 and being different than components (a) and (b) and being selected from at least one material of the group consisting of ethylene glycol, ethyl butyl cellosolve, diethylene glycol ethyl ether, carbitol, propylene glycol, and dipropylene glycol, and the balance water, said composition having a percent total non-volatile solids of less than 5 percent by weight of the composition.
3. The composition of claim 1 wherein, said molecular weight of the solid polyoxyalkylene compound is between about 2,000 and about 16,000.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US356625A US3865642A (en) | 1971-06-23 | 1973-05-02 | Water based quenching composition and method |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US15603771A | 1971-06-23 | 1971-06-23 | |
| US356625A US3865642A (en) | 1971-06-23 | 1973-05-02 | Water based quenching composition and method |
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| Publication Number | Publication Date |
|---|---|
| US3865642A true US3865642A (en) | 1975-02-11 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US356625A Expired - Lifetime US3865642A (en) | 1971-06-23 | 1973-05-02 | Water based quenching composition and method |
Country Status (1)
| Country | Link |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1983000825A1 (en) * | 1981-09-08 | 1983-03-17 | Houghton E F Inc | Method of quenching |
| EP0179545A1 (en) * | 1984-10-12 | 1986-04-30 | E.F. HOUGHTON & Co. | Aqueous quenchants containing polyoxazolines and N-vinyl heterocyclic polymers |
| US6692588B1 (en) * | 1999-07-12 | 2004-02-17 | Nutool, Inc. | Method and apparatus for simultaneously cleaning and annealing a workpiece |
| US11118253B2 (en) | 2017-10-23 | 2021-09-14 | Novelis Inc. | Reactive quenching solutions and methods of use |
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|---|---|---|---|---|
| US2600290A (en) * | 1950-08-08 | 1952-06-10 | Du Pont | Process for quench-hardening steel |
| US2770564A (en) * | 1954-07-06 | 1956-11-13 | Gordon Mack | Method of quenching metals |
| US3022205A (en) * | 1958-05-14 | 1962-02-20 | Gen Motors Corp | Method of quenching and quenching liquid |
| US3220893A (en) * | 1963-11-29 | 1965-11-30 | Union Carbide Corp | Metal quenching medium |
| US3224910A (en) * | 1963-02-18 | 1965-12-21 | Monsanto Co | Quenching process |
| US3475232A (en) * | 1966-11-23 | 1969-10-28 | Houghton & Co E F | Method of quenching |
-
1973
- 1973-05-02 US US356625A patent/US3865642A/en not_active Expired - Lifetime
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2600290A (en) * | 1950-08-08 | 1952-06-10 | Du Pont | Process for quench-hardening steel |
| US2770564A (en) * | 1954-07-06 | 1956-11-13 | Gordon Mack | Method of quenching metals |
| US3022205A (en) * | 1958-05-14 | 1962-02-20 | Gen Motors Corp | Method of quenching and quenching liquid |
| US3224910A (en) * | 1963-02-18 | 1965-12-21 | Monsanto Co | Quenching process |
| US3220893A (en) * | 1963-11-29 | 1965-11-30 | Union Carbide Corp | Metal quenching medium |
| US3475232A (en) * | 1966-11-23 | 1969-10-28 | Houghton & Co E F | Method of quenching |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1983000825A1 (en) * | 1981-09-08 | 1983-03-17 | Houghton E F Inc | Method of quenching |
| US4404044A (en) * | 1981-09-08 | 1983-09-13 | E. F. Houghton & Co. | Method of quenching |
| EP0179545A1 (en) * | 1984-10-12 | 1986-04-30 | E.F. HOUGHTON & Co. | Aqueous quenchants containing polyoxazolines and N-vinyl heterocyclic polymers |
| US6692588B1 (en) * | 1999-07-12 | 2004-02-17 | Nutool, Inc. | Method and apparatus for simultaneously cleaning and annealing a workpiece |
| US11118253B2 (en) | 2017-10-23 | 2021-09-14 | Novelis Inc. | Reactive quenching solutions and methods of use |
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|---|---|---|---|
| AS | Assignment |
Owner name: SECURITY PACIFIC NATIONAL BANK, AS ADMINISTRATIVE Free format text: SECURITY INTEREST;ASSIGNOR:PARK CHEMICAL COMPANY;REEL/FRAME:005224/0544 Effective date: 19890628 |
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| AS | Assignment |
Owner name: PARK CHEMICAL COMPANY, MICHIGAN Free format text: RELEASED BY SECURED PARTY;ASSIGNOR:SECURITY PACIFIC NATIONAL BANK;REEL/FRAME:005461/0651 Effective date: 19900605 |