[go: up one dir, main page]

US3728264A - Pipe cleaning fluid - Google Patents

Pipe cleaning fluid Download PDF

Info

Publication number
US3728264A
US3728264A US00117106A US3728264DA US3728264A US 3728264 A US3728264 A US 3728264A US 00117106 A US00117106 A US 00117106A US 3728264D A US3728264D A US 3728264DA US 3728264 A US3728264 A US 3728264A
Authority
US
United States
Prior art keywords
alcohol
cleaning fluid
nicotine
pipe cleaning
tannin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US00117106A
Inventor
J Widlocher
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Application granted granted Critical
Publication of US3728264A publication Critical patent/US3728264A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2/00Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic
    • B01J2/02Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic by dividing the liquid material into drops, e.g. by spraying, and solidifying the drops
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24FSMOKERS' REQUISITES; MATCH BOXES; SIMULATED SMOKING DEVICES
    • A24F9/00Accessories for smokers' pipes
    • A24F9/04Cleaning devices for pipes
    • A24F9/12Devices for cleaning tobacco pipes by steam, air, or water
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/38Products with no well-defined composition, e.g. natural products
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/40Products in which the composition is not well defined
    • C11D7/44Vegetable products

Definitions

  • nicotine which is one of the natural alkaloids of tobacco, is a violent poison which is soluble in alcohol, in ether and in gasoline.
  • the present invention diminishes these disadvantages and is characterized by the fact that tannin, that is to say digallic acid, is dissolved in a suitable solvent, which may be alcohol, and is adapted to clean pipes and cigarette holders.
  • a suitable solvent which may be alcohol
  • This tannin reacts with the nicotine accumulated in the pipes or the cigaretteholders at the moment at which the nicotine dissolves in the alcohol, to form an insoluble harmless compound which eventually falls to'the bottom of the container in which one soaksflthe cleaners used to frictionally remove the accumulated nicotine, and in which the insoluble compound which results from the reaction between the nicotine and part of thetannin contained in the alcoholic solution then accumulates.
  • the aroma of the tannin which has not reacted with the nicotine and which remains in the alcoholic solution, as well as the aroma of the impurities from said vegetative products masks that of the normal impurities in the alcohol when these different impurities, after vaporization of said alcohol, impregnate the material of which the pipes and cigarette holders are made, thus considerably reducing the deterioration in the natural aroma of the tobacco smoke.
  • the tannin in solution in the alcohol is obtained by macerating the sawdust of very old briar root which has been perfectly dried.
  • the volume of sawdust is preferably between onefourth and onehalf the volume of the alcoholic solvent.
  • the total quantity of tannin dissolved in the alcohol must be sufficient to be able to react with the quantity of nicotine accumulated, but, on the other hand, if this concentration is too great it may also impair the aroma of the tobacco smoke, in the absence of a small quantity of essential oil of the tobacco flower capable of overcoming this disadvantage.
  • the product according to the invention may be used to preventively impregnate the superficial pores of the passageways of these pipes or cigarette holders so that, after complete evaporation of the solvent used, the particles of tannin dissolved therein are deposited on the walls of these pores.
  • the nicotine contained in the smoke instead of being immediately frictionally deposited upon walls of these passageways is at least partially neutralized by the presence of the tannin retained in said pores and is transformed into an inoffensive. product, .thus' delaying the moment at which nicotine itself is off the solution thus obtained.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Cigarettes, Filters, And Manufacturing Of Filters (AREA)
  • Manufacture Of Tobacco Products (AREA)
  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)

Abstract

Pipe cleaning fluid comprises digallic acid, and other impurities derived from ground briar root and the like, dissolved in a suitable solvent.

Description

United States Patent 1191 1111 3,728,264
l 1 Referen ces Cited Widlocher 5] Apr. 17, 1973 541 PIPE CLEANING FLUID 388,759 8/1888 Cameronm. ..252 83 [76] Inventor: Jean Florent Widloclmr, 133, Rue 570l32 12/893 Hagemann d6 ChercheMidi Paris France 1,078,893 11/1913 Allen ..260/473.6
762,635 6/1904 Hurst et al 252/83 [22] Filed: Feb. 19, 1971 1,816,394 7/1931 Muller ..260/473.6 [21] AppLNoi 117,106 2,947,764 7/1960 Zencyak ..260 47 3.6
1 I. i Primary Examiner-George F. Lesmes Foreign Appllcahon Pnonty Data Assistant Examiner-=1. P.Bram1ner Feb. 26, 1970' France .7007003 Arwmey-H0l0mbe, Wetherill & Brisebois [52] US. Cl. ..252/83, 210/58, 260/4716 [57] ABSTRACT [51 Int. Cl. ..C02b 5/06 58 Field of Search ..252/s3-, 260/473.6; Cleamng Comp-S65 dlgalhc am, other 210/58 impurities derived from. ground briar root and the like,
dissolved in a suitable solvent 1 3 Claims, No Drawings 6 ,UNlTED STATES PATENTS 57,219 8/1866 Thomas ..252/83 PIPE CLEANING FLUID SUMMARY OF THE INVENTION It is well known that nicotine is among those substances which accumulate in the passageways of pipes and cigarette holders, and in the bowls of pipes, and that this accumulation decreases the harmfulness of the smoke.
However, over a long period of time, this accumulation reduces the crosssectional area of the passageways available for the passage of smoke.
It then becomes necessary to periodically clean these passageways, as well as the metallic filters, which are commonly incorporated therein, so as to make the pipe or cigarette holder draw easily again.
It is known that nicotine, which is one of the natural alkaloids of tobacco, is a violent poison which is soluble in alcohol, in ether and in gasoline.
' From among these three solvents, it is logical to think first of ethyl alcohol for dissolving the nicotine accumulated in the passageways, because of the disagreeable odor of ether and the oily nature of gasoline.
Unfortunately, regardless of the concentration of a commercial alcohol, even if the material defining the inner passageway of a pipe or a cigarette holder does not actually retain some of the alcohol because of rapid vaporization of this solvent in the air, it retains after having been in contact with the alcohol a characteristic alcohol odor which is due to the impurities dissolved therein, and which impregnates the material after evaporation of all the alcoholic solvent.
The present invention diminishes these disadvantages and is characterized by the fact that tannin, that is to say digallic acid, is dissolved in a suitable solvent, which may be alcohol, and is adapted to clean pipes and cigarette holders. This tannin reacts with the nicotine accumulated in the pipes or the cigaretteholders at the moment at which the nicotine dissolves in the alcohol, to form an insoluble harmless compound which eventually falls to'the bottom of the container in which one soaksflthe cleaners used to frictionally remove the accumulated nicotine, and in which the insoluble compound which results from the reaction between the nicotine and part of thetannin contained in the alcoholic solution then accumulates.
Experience has shown that it is necessary to macerate in alcohol for a sufficient time, for example a month, the sawdust of certain vegetative products, such as nutgall, oak bark, briar root. The tannin which is found therein becomes dissolved in the alcohol, together with certain other constituents contained in these vegetative products. If the resulting solution is then applied to the nicotine accumulated in a pipe or cigarette holder for cleaning purposes, it is found that the aroma of the tannin which has not reacted with the nicotine and which remains in the alcoholic solution, as well as the aroma of the impurities from said vegetative products, masks that of the normal impurities in the alcohol when these different impurities, after vaporization of said alcohol, impregnate the material of which the pipes and cigarette holders are made, thus considerably reducing the deterioration in the natural aroma of the tobacco smoke.
In a preferred embodiment of the invention the tannin in solution in the alcohol is obtained by macerating the sawdust of very old briar root which has been perfectly dried.
r of oak bark rather than the gallnut, so as to avoid im In this case, independently of the aroma of the-tannin, that of the impurities from the briar root makes it possible to reconstitute a taste very comparable to that v of the smoke of a pipe which has. not been in contact with alcohol and is made of this material.
Since pure tanninis soluble not only in alcohol but partially soluble in water, it is possible to use any commercial alcohol having a titer equal to at least 40 and less than 90.
The volume of sawdust is preferably between onefourth and onehalf the volume of the alcoholic solvent.
However, the applicant has found that, even when using the sawdust of briar root, it is not always possible 1 to completely mask the particular aroma due to the impurities in the alcohol used, which impregnate said pipes or said cigarette holders after complete vaporization of the alcohol. To obtain better results it is recom mended to add to the alcoholic solution obtained by macerating the sawdust and by decantation, a tiny trace of essential oil of tobacco flower, which product is known to all perfumers and is sold by specialized manufacturers or wholesale druggists.
It is easy to understand that the use of a trace of another essential oil involves the risk of rendering the taste of the tobacco smoke less natural. It will also be noted that the duration of the macerating process and the quantity of sawdust to be macerated maybe varied with respect to the volume of alcohol used within broad limits, dependent upon whether the vegetative product used is more or less rich-intannin.
In like manner, the total quantity of tannin dissolved in the alcohol must be sufficient to be able to react with the quantity of nicotine accumulated, but, on the other hand, if this concentration is too great it may also impair the aroma of the tobacco smoke, in the absence of a small quantity of essential oil of the tobacco flower capable of overcoming this disadvantage.
Finally, it will be readily understood that, independently of the tannin, it is preferable to use thesawdust pregnating the pipes and cigarette holder tobe cleaned with strongly aromatic impurities which are capable of impairing the taste of the tobacco smoke after this cleaning. It should be noted that, independently of its use for the cleaning of encrusted pipes and'cigarette holders, the product according to the invention may be used to preventively impregnate the superficial pores of the passageways of these pipes or cigarette holders so that, after complete evaporation of the solvent used, the particles of tannin dissolved therein are deposited on the walls of these pores. It is easy to understand that, in this case, the nicotine contained in the smoke, instead of being immediately frictionally deposited upon walls of these passageways is at least partially neutralized by the presence of the tannin retained in said pores and is transformed into an inoffensive. product, .thus' delaying the moment at which nicotine itself is off the solution thus obtained.
2. Solution as claimed in claim 1 in which the volume of said particles is at least equal to the volume of said alcohol.
3. Solution as claimed in claim 1 which includes a trace of the essential oil of tobacco flower

Claims (2)

  1. 2. Solution as claimed in claim 1 in which the volumE of said particles is at least equal to the volume of said alcohol.
  2. 3. Solution as claimed in claim 1 which includes a trace of the essential oil of tobacco flower.
US00117106A 1970-02-26 1971-02-19 Pipe cleaning fluid Expired - Lifetime US3728264A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7007003A FR2080203A5 (en) 1970-02-26 1970-02-26

Publications (1)

Publication Number Publication Date
US3728264A true US3728264A (en) 1973-04-17

Family

ID=9051342

Family Applications (1)

Application Number Title Priority Date Filing Date
US00117106A Expired - Lifetime US3728264A (en) 1970-02-26 1971-02-19 Pipe cleaning fluid

Country Status (8)

Country Link
US (1) US3728264A (en)
BE (1) BE762663A (en)
CA (1) CA935727A (en)
DE (1) DE2108299A1 (en)
DK (1) DK131802C (en)
FR (1) FR2080203A5 (en)
GB (1) GB1289434A (en)
NL (1) NL146211B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5167872A (en) * 1985-10-31 1992-12-01 The Procter & Gamble Company Comprising anionic surfactant polymeric nonionic surfactant and betaine surfactant

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US57219A (en) * 1866-08-14 Improved composition for removing incrustations from boilers
US388759A (en) * 1888-08-28 Preventive
US570132A (en) * 1896-10-27 Jqqqqoqoooofll
US762635A (en) * 1903-11-20 1904-06-14 Lindsay R Hurst Incrustation preventive.
US1078893A (en) * 1912-01-05 1913-11-18 Charles Francis Allen Process of producing tannin and the product.
US1816394A (en) * 1929-02-09 1931-07-28 Muller Oskar Albert Process for working up materials containing lignin and cellulose
US2947764A (en) * 1955-11-10 1960-08-02 Grenco Inc Method of producing, separating and recovering reaction products from bark

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US57219A (en) * 1866-08-14 Improved composition for removing incrustations from boilers
US388759A (en) * 1888-08-28 Preventive
US570132A (en) * 1896-10-27 Jqqqqoqoooofll
US762635A (en) * 1903-11-20 1904-06-14 Lindsay R Hurst Incrustation preventive.
US1078893A (en) * 1912-01-05 1913-11-18 Charles Francis Allen Process of producing tannin and the product.
US1816394A (en) * 1929-02-09 1931-07-28 Muller Oskar Albert Process for working up materials containing lignin and cellulose
US2947764A (en) * 1955-11-10 1960-08-02 Grenco Inc Method of producing, separating and recovering reaction products from bark

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5167872A (en) * 1985-10-31 1992-12-01 The Procter & Gamble Company Comprising anionic surfactant polymeric nonionic surfactant and betaine surfactant

Also Published As

Publication number Publication date
DK131802C (en) 1976-03-01
CA935727A (en) 1973-10-23
GB1289434A (en) 1972-09-20
DE2108299A1 (en) 1971-09-09
FR2080203A5 (en) 1971-11-12
NL7102134A (en) 1971-08-30
NL146211B (en) 1975-06-16
DK131802B (en) 1975-09-08
BE762663A (en) 1971-07-16

Similar Documents

Publication Publication Date Title
US4123592A (en) Process for incorporating flavorant into cellulosic substrates and products produced thereby
US3319630A (en) Tobacco smoke filter
US2228383A (en) Tobacco smoke filtering
EP0436599A1 (en) Tobacco smoke filters and process for production thereof
US4662384A (en) Smoking articles
ATE7260T1 (en) FLAVORING COMPOSITION FOR TOBACCO, PROCESS FOR PRODUCTION THEREOF AND TOBACCO PRODUCT CONTAINING SUCH COMPOSITION.
US4184495A (en) Process for incorporating flavorant into cellulosic substrates and products produced thereby
US3728264A (en) Pipe cleaning fluid
Campbell et al. Polycyclic hydrocarbons in cigar smoke
CN113117500A (en) Composition with peculiar smell removing effect, preparation method and application thereof
US5150723A (en) Process for the production of tobacco smoke filters
US4819667A (en) Treatment of tobacco to reduce tar and nicotine content
CN106263024A (en) A kind of reduce the method for phenol content in cigarette smoke
JPS6194660A (en) Deodorant
US2872928A (en) Means and methods for extracting from tobacco smoke deleterious ingredients
CA2045429C (en) Nicotine and tar removal process
US2015524A (en) Smoker's novelty
US3661160A (en) Tobacco smoke filter
KR19980065152A (en) Deodorant using wood vinegar
WO2006097010A1 (en) AN INSTANT ADDITIVE SOLUTION FOR THE FILTER OF CIGARETTl, ITS PRODUCTION METHOD AND USE
FR2699372A1 (en) Extn. of nicotine and tar from tobacco leaves
CH387518A (en) Process for the preparation of tobacco which is at least partially free from carcinogenic substances as well as from substances capable of being transformed into such substances, and tobacco obtained by this process
GB2122473A (en) Improvements relating to smoking articles
WO2001021018A1 (en) Material for filters used to filter tobacco smoke
JPH058667B2 (en)