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US3520666A - Bismuth alloy impregnated grinding wheel - Google Patents

Bismuth alloy impregnated grinding wheel Download PDF

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Publication number
US3520666A
US3520666A US646068A US3520666DA US3520666A US 3520666 A US3520666 A US 3520666A US 646068 A US646068 A US 646068A US 3520666D A US3520666D A US 3520666DA US 3520666 A US3520666 A US 3520666A
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wheel
grinding
grinding wheel
alloy
wheels
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US646068A
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Richard S Meyer
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American Abrasive Corp
Dresser Industries Inc
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American Abrasive Corp
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Assigned to DRESSER INDUSTRIES, INC. reassignment DRESSER INDUSTRIES, INC. ASSIGNMENT OF ASSIGNORS INTEREST. Assignors: BENDIX CORPORATION, THE, A CORP. OF DE.
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/009After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24BMACHINES, DEVICES, OR PROCESSES FOR GRINDING OR POLISHING; DRESSING OR CONDITIONING OF ABRADING SURFACES; FEEDING OF GRINDING, POLISHING, OR LAPPING AGENTS
    • B24B3/00Sharpening cutting edges, e.g. of tools; Accessories therefor, e.g. for holding the tools
    • B24B3/34Sharpening cutting edges, e.g. of tools; Accessories therefor, e.g. for holding the tools of turning or planing tools or tool bits, e.g. gear cutters
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/51Metallising, e.g. infiltration of sintered ceramic preforms with molten metal
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81Coating or impregnation
    • C04B41/85Coating or impregnation with inorganic materials
    • C04B41/88Metals

Definitions

  • FIG. 1 is a schematic of apparatus used to produce the grinding wheels of the present invention.
  • FIG. 2 is a perspective view of a grinding wheel of the present invention.
  • this invention involves a standard grinding wheel impregnated with a low melting point, bismuthbase alloy that is electrically conductive.
  • electrolytic grinding proceeds somewhat differently than form grinding in the conventional manner. While an electrolytic grinding wheel is used in the conventional manner, the wheel, which has a conductive filler therein, acts as a cathode, the grinding table as an anode, and the liquid coolant as an electrolyte. Under this set-up, when current is passed through the system, a deplating operation results.
  • an electrolytic grinding wheel which is produced from a standard porous abrasive wheel is impregnated with a low melting point bismuth-base alloy.
  • bismuthbase alloys having melting points of from F. to 220 F. are the most desirable from two standpoints.
  • porous grinding wheels may be easily and readily impregnated with such alloys by the use of simple equipment; and second, the melting points of such alloys permit safe handling without danger of serious burns and/or fire in the event of accident or spillage.
  • the wheel 10 to be impregnated is placed between two steel plates 12 and 14 having gaskets 16 and 18 thereon.
  • the upper plate 12 has a riser pipe 20 connected thereto.
  • the wheel 10 is clamped between the plates 12 and 14 with its hub 13 registered with the lower end of the riser pipe 20.
  • the complete unit is then placed in an oven at 200 F. to 210 F. to bring its temperature to a point in excess of the melting point of the alloy employed so as to prevent solidification of the alloy during impregnation.
  • the apparatus After the apparatus has been uniformly heated, it is removed from the oven and melted alloy of the type described above is added to the riser pipe 20 and forced under pressure into the pores of the wheel 10, impregnating the wheel radially outwardly from the hub 13.
  • the application of from 5 to 20 pounds of air pressure from the air hose 26 has been found suitable to effect complete permeation of the wheel.
  • a low melting point bismuth-base alloy is preferred in the production of the grinding wheels of this invention. While eutectic and non-eutectic alloys may be used, it has been found that due to the sharp melting point characteristic of eutectic alloys, their use is preferable.
  • an electrolytic grinding wheel of the present invention As an example of an electrolytic grinding wheel of the present invention, a batch of standard vitrified aluminum oxide, type 1 shape wheel, 7 inches in diameter and /2 inch thick, was impregnated with a bismuth-base alloy of the following composition: 50% bismuth, 26.7% lead, 13.3% tin and 10.0 cadmium.
  • This particular alloy is marketed by the Cerro de Pasco Copper Corporation under the trade name Cerrobend. Being an eutectic alloy with a melting point of 158 F., it has been a traditional choice for such applications as fusible elements in sprinkler heads, fire door releases, and the like.
  • an electrically conductive impregnant substantially filling the pores of said grinding wheel, comprising an alloy having a melting point in the range of 130-222 F. in which the predominant material is bismuth, said alloy also containing lead, tin and cadmium.
  • the electrically conductive impregnant comprises a eutectic alloy composed of bismuth, 26.7% lead, 13.3% tin and 10.0% cadmium.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Polishing Bodies And Polishing Tools (AREA)

Description

July 14, 1970 R. s. MEYER 3,520,666
BISMUTH ALLOY IMPREGNATED GRINDING WHEEL Filed June 14, 1967 VFYTOR F/g a/ a 5 Meyer United States Patent 3,520,666 BISMUTH ALLOY IMPREGNATED GRINDING WHEEL Richard S. Meyer, Westfield, Mass., assignor, by mesne assignments, to American Abrasive Corporation, a corporation of Delaware Filed June 14, 1967, Ser. No. 646,068 Int. Cl. B24d 3/08 US. Cl. 51295 3 Claims ABSTRACT OF THE DISCLOSURE A porous abrasive grinding wheel impregnated with a low melting point bismuth-base alloy which acts as an electrical conductor for use in electrolytic grinding.
In recent years, the so-called super metals, and alloys made with these methods, have become more and more important in space age and related applications. This increased importance has given rise to many problems however, in that unlike standard metals and alloys, they are not readily workable by conventional machining techniques.
One of the problem machining areas is that of grinding parts fabricated from the super metals and alloys. Particularly, it was found that the use of the standard grinding wheels, such as aluminum oxide, silicon carbide, and the like, was very time consuming. In attempting to overcome the time factor involved with these wheels, diamond grinding wheels were employed. While diamond grinding did reduce the time factor, cost factors and wheel reconditioning have negated its wide acceptance.
At this point, the industries involved decided that the most economical and practical method of grinding the super metals and alloys was by means of electrolytic erosion or deplating.
Today, there are many electrolytic grinding wheels commercially available. A common example of these wheels may be described as vitrified aluminum oxide type which are impregnated with electrically conductive inks. Such wheels are typified by US Pat. 3,216,854.
While most all of the electrolytic grinding wheels heretofore produced have been sufficient to accomplish their primary purpose of grinding the super metals and alloys, most have given rise to problems of one kind or another. For example, in many wheels the impregnation procedure requires complex high pressure equipment, or the impregnating materials are expensive.
It is an object of the invention to provide an inexpensive yet effective electrolytic grinding wheel.
It is a further object of this invention to provide an electrolytic grinding wheel which is easily produced.
The above and other objects and advantages of the invention will become more clear when considered with the remaining disclosure and the drawings, in which:
FIG. 1 is a schematic of apparatus used to produce the grinding wheels of the present invention; and
FIG. 2 is a perspective view of a grinding wheel of the present invention.
Basically, this invention involves a standard grinding wheel impregnated with a low melting point, bismuthbase alloy that is electrically conductive.
As is known, electrolytic grinding proceeds somewhat differently than form grinding in the conventional manner. While an electrolytic grinding wheel is used in the conventional manner, the wheel, which has a conductive filler therein, acts as a cathode, the grinding table as an anode, and the liquid coolant as an electrolyte. Under this set-up, when current is passed through the system, a deplating operation results.
3,520,666 Patented July 14, 1970 The rate of stock removed in such a system is governed by Faradays law, rather than wheel performance, and can be expressed as follows:
W Mlt/F j where W=weight of material removed, grams, M=atomic weight of material, grams, I=current, amperes,
t=time, second F=95,500 coulombs/gram equivalent, and j=valence of material.
From the above, it can be seen that the weight of material removed is directly proportional to the current supplied. Therefore, it has been found desirable to use a material having a low resistivity as a conductive filler in electrolytic grinding Wheels. Such materials have in the main been silver, copper and aluminum. While these materials and mixtures of same have low resistance, the cost of preparing them for impregnation in a grinding wheel is quite expensive and calls for the use of complex heat and pressure equipment.
In accordance with this invention, an electrolytic grinding wheel which is produced from a standard porous abrasive wheel is impregnated with a low melting point bismuth-base alloy.
While it is realized that alloys employed in the present invention must sacrifice some resistivity to the materials mentioned above, the advantages gained by the use of the low melting point alloys outweigh the loss in resistivity.
In general, it has been found that bismuthbase alloys having melting points of from F. to 220 F. are the most desirable from two standpoints. First, porous grinding wheels may be easily and readily impregnated with such alloys by the use of simple equipment; and second, the melting points of such alloys permit safe handling without danger of serious burns and/or fire in the event of accident or spillage.
As depicted in FIG. 1, the wheel 10 to be impregnated is placed between two steel plates 12 and 14 having gaskets 16 and 18 thereon. The upper plate 12 has a riser pipe 20 connected thereto. Detachably mounted at the other end of the riser pipe 20, is a pipe cap 22 and an air hose 24 with a pressure regulator 26 therein.
To use the apparatus, the wheel 10 is clamped between the plates 12 and 14 with its hub 13 registered with the lower end of the riser pipe 20. The complete unit is then placed in an oven at 200 F. to 210 F. to bring its temperature to a point in excess of the melting point of the alloy employed so as to prevent solidification of the alloy during impregnation. After the apparatus has been uniformly heated, it is removed from the oven and melted alloy of the type described above is added to the riser pipe 20 and forced under pressure into the pores of the wheel 10, impregnating the wheel radially outwardly from the hub 13. The application of from 5 to 20 pounds of air pressure from the air hose 26 has been found suitable to effect complete permeation of the wheel. When the alloy is observed to be uniformly exuding from the face of the wheel 28, the air pressure is released and the wheel is removed from the clamping apparatus and allowed to cool at room temperature. Prior to solidification of the alloy, any excess is scraped from the sides of the wheel 10.
By the use of the above described apparatus, it was found that the preparation of the wheels as described provides uniform distribution of the alloy throughout the wheel. This, of course, is highly desirable in that the balance of the wheel is not materially affected by the impregnation.
As mentioned above, a low melting point bismuth-base alloy is preferred in the production of the grinding wheels of this invention. While eutectic and non-eutectic alloys may be used, it has been found that due to the sharp melting point characteristic of eutectic alloys, their use is preferable.
As an example of an electrolytic grinding wheel of the present invention, a batch of standard vitrified aluminum oxide, type 1 shape wheel, 7 inches in diameter and /2 inch thick, was impregnated with a bismuth-base alloy of the following composition: 50% bismuth, 26.7% lead, 13.3% tin and 10.0 cadmium. This particular alloy is marketed by the Cerro de Pasco Copper Corporation under the trade name Cerrobend. Being an eutectic alloy with a melting point of 158 F., it has been a traditional choice for such applications as fusible elements in sprinkler heads, fire door releases, and the like.
After the above wheels had been impregnated and allowed to cool, they were tested for rotational stress strength in accordance with the requirements of the American Standard Safety Code for the Use, Care and Protection of Abrasive Wheels. The wheels, which were designed to operate at 7,700 s.f.p.m., were tested at 12,200 s.f.p.m. and no adverse effect was noted. In addition, one of the wheels so produced was spin tested to destruction at 20,700 s.f.p.m.
After the wheels were tested for rotational stress strength, one was placed on a Brown & Sharpe surface grinder adapted for electrolytic grinding by the addition of a 150 amp Anocut Power Pack Unit. At a wheel speed of 7,700 s.f.p.m., tool steel containing 15% tungsten was plunge ground at a depth of .035 inch and 1 inch/minute traverse. During the test, it was noted that there was no problem in drawing the full capacity of 150 amperes of current and that sparking was minimal.
While the above disclosure has been primarily directed to an aluminum oxide wheel impregnated with a low melting point, bismuth-base alloy, it is to be understood that other types of grinding wheels, such as vitrified silicon carbide wheels, also may be utilized.
What is claimed is:
1. In a vitrified abrasive porous grinding wheel composed of materials selected from the group consisting of aluminum oxide and silicon carbide, an electrically conductive impregnant, substantially filling the pores of said grinding wheel, comprising an alloy having a melting point in the range of 130-222 F. in which the predominant material is bismuth, said alloy also containing lead, tin and cadmium.
2. In a vitrified abrasive porous grinding wheel as set forth in claim 1 in which said alloy is a eutectic alloy.
3. In a vitrified abrasive porous grinding wheel as set forth in claim 1 wherein the electrically conductive impregnant comprises a eutectic alloy composed of bismuth, 26.7% lead, 13.3% tin and 10.0% cadmium.
References Cited UNITED STATES PATENTS 2,340,384 2/1944 Hillix 51-309 3,317,295 5/1967 Kuzmick 51309 DONALD J. ARNOLD, Primary Examiner US. Cl. X.R. 51308, 309
US646068A 1967-06-14 1967-06-14 Bismuth alloy impregnated grinding wheel Expired - Lifetime US3520666A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4057666A (en) * 1973-10-29 1977-11-08 Xerox Corporation Magnetic brush developer roll for electrostatic reproduction machines
US4247303A (en) * 1974-09-04 1981-01-27 Inoue-Japax Research Inc. Method of forming an electrically conductive abrasive wheel
US4588420A (en) * 1982-07-22 1986-05-13 Superior Finishers, Inc. Methods of manufacturing abrasive articles
GB2380491A (en) * 2001-07-27 2003-04-09 Amir Abbas Shirzadi Ghoshouni Surface treatment of oxidisable materials

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2340384A (en) * 1939-04-10 1944-02-01 American Steel & Wire Co Lapping tool
US3317295A (en) * 1963-10-17 1967-05-02 Paul L Kuzmick Grinding wheel having an antimony or bismuth trioxide bond

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2340384A (en) * 1939-04-10 1944-02-01 American Steel & Wire Co Lapping tool
US3317295A (en) * 1963-10-17 1967-05-02 Paul L Kuzmick Grinding wheel having an antimony or bismuth trioxide bond

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4057666A (en) * 1973-10-29 1977-11-08 Xerox Corporation Magnetic brush developer roll for electrostatic reproduction machines
US4247303A (en) * 1974-09-04 1981-01-27 Inoue-Japax Research Inc. Method of forming an electrically conductive abrasive wheel
US4588420A (en) * 1982-07-22 1986-05-13 Superior Finishers, Inc. Methods of manufacturing abrasive articles
GB2380491A (en) * 2001-07-27 2003-04-09 Amir Abbas Shirzadi Ghoshouni Surface treatment of oxidisable materials
GB2380491B (en) * 2001-07-27 2005-06-15 Amir Abbas Shirzadi Ghoshouni Surface treatment of oxidising materials

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Owner name: DRESSER INDUSTRIES, INC., THE DRESSER BLDG. 1505 E

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST.;ASSIGNOR:BENDIX CORPORATION, THE, A CORP. OF DE.;REEL/FRAME:004026/0144

Effective date: 19820806