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US3585007A - Gas generator - Google Patents

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Publication number
US3585007A
US3585007A US758291A US3585007DA US3585007A US 3585007 A US3585007 A US 3585007A US 758291 A US758291 A US 758291A US 3585007D A US3585007D A US 3585007DA US 3585007 A US3585007 A US 3585007A
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housing
tube
sleeve
liquid
gas
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US758291A
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Jesse Gross
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MORTON E FRANK
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MORTON E FRANK
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    • GPHYSICS
    • G09EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09BEDUCATIONAL OR DEMONSTRATION APPLIANCES; APPLIANCES FOR TEACHING, OR COMMUNICATING WITH, THE BLIND, DEAF OR MUTE; MODELS; PLANETARIA; GLOBES; MAPS; DIAGRAMS
    • G09B23/00Models for scientific, medical, or mathematical purposes, e.g. full-sized devices for demonstration purposes
    • G09B23/24Models for scientific, medical, or mathematical purposes, e.g. full-sized devices for demonstration purposes for chemistry

Definitions

  • the invention comprises injection molded members wherein, for purposes of demonstrating gas generan tion, the apparatus comprises a base which supports a tubular housing in vertical position. Concentrically supported within such housing are concentric tubular members for holding a solid to react with an acid wherein the acid has access to the solid. Generated gas is thus per mitted toescape through a exible tube extending from a cap which encloses the upper end of the housing. A pinch clamp on the tube can prevent ow until a desired pressure is realized.
  • FIG. 1 is an elevation in cross-section of the gas genn erator
  • FIG. 2 is a plan view showing a pinch member for shutting off ow of generated gas.
  • FIG. 3 is a modification of a portion of the construction wherein a disposable cartridge having a solid reactant material therein is illustrated in perspective.
  • the invention comprises a cylindrical plastic base integrally molded with a concentric housing 17 extending vertically upright therefrom and having a neck 19 closed at the top by a cap 20.
  • a concentric insert sleeve 24 having a sealing t at interface 27 with a well or cavity 28 of the base, and being spaced from the housing.
  • Sleeve 24 forms a cup or chamber 29 for holding a quantity of reactive liquid 30 around an inwardly spaced concentric tube 34 which holds a quantity of solid material 38.
  • the liquid has access to the solid through a small or pinhole bore 40 at the bottom of tube 34.
  • the reaction forms a gas that rises upwardly and issues through the bore of the integral cap nipple 4-4 to be trapped by means of a exible length of hose 47 squeezed shut by a pinch clamp 50 having a slot 53, all in a manner Iobvious in FIGS. l and 2.
  • the several members 17, 24, 34 have a slight taper to firmly grip and seal with each other in a well known manner.
  • the device is well sealed as to its co-acting parts and also vented for purposes of safety.
  • the housing member 17 has a shoulder at 57 sealingly abutting a radial flange 58 of sleeve 24 and cemented thereto.
  • the upper end of tube 34 has a tight sealing t at 60 with a downwardly extending skirt 63 of cap 20.
  • a pair of safety vent ports 70 are provided in the cap so that in the event of dangerous buildup of gas back "ice pressure, tube 47 being pinched closed, such gas can escape downwardly through port 40 and then up through the liquid 30 and out of the housing through vents 70, via chamber 71.
  • Air expansion vents 73 are also provided in the base to permit air escape from the space 75 between housing 17 and sleeve 24 when air is heated due to the chemical re action occurring in the apparatus.
  • double wall protection against gas pressure is provided by housing 17 and sleeve 24.
  • the chamber 30 would contain dilute hydrochloric acid and tube 34 would have a quantity of mossy zinc.
  • Other agents can, of course, be used.
  • the insert 24 can have molded calibration rings dso that proper volumes of water and acid to be mixed can be accurately gauged.
  • the cap 20 and tube 34 can be permanently cemented together at the interface 60 to effect a disposable cartridge with the solid material 38 provided therein ready to use.
  • Such an integral construction is shown in FIG. 3 and has the advantage that the difficulty of cleaning the tube is eliminated. Since the tube is of plastic the scrubbing re quired would impair transparency and since the disposable elements are low cost the advantage is apparent. This is particularly so since the apparatus is primarily for class demonstration and certain reactions may produce colored gases, in which cases visibility is important.
  • the cap 20 and tube 17 effect an egress means for gen ⁇ erated gas
  • the tube 34 forms the inner wall of a substantially toroidal liquid holding chamber 30 in conjunction with a chamber outer wall afforded by the sleeve 24.
  • the unitary structure of the cap and tube are well adapted to effect a disposable cartridge which readily coacts in assembly with the sleeve and housing to form a safe and rugged structure for the purpose intended.
  • a gas generating apparatus comprising a housing, a tube therein for holding a solid reactant material and having a port, said tube having egress means for gas generated in said tube, a sleeve in said housing disposed inter ⁇ mediate said housing and said tube; support connection means between said housing and sleeve whereby said sleeve is supported in said housing; said housing and sleeve effecting a double wall enclosure around said tube; wherein said sleeve effects a wall of a chamber for holding a liquid to react with a solid in said tube by access through said port, a base for said housing having a well, said support connection means for said sleeve comprising one end of said sleeve being socketed in said well and having a liquid tight connection therein and said support connection means further comprising a ange at the other end of said sleeve having a gas tight connection with the interior walls of said housing, said port of said tube being disposed substantially within the confines of said well, said chamber for
  • said egress means comprising a cap having a sealing friction t with said housing, said tube having an end permanently bonded to said cap to form a unitary structure.
  • cap and tube being of transparent plastic material and effecting a unitary cartridge disposable after said solid material is consumed, and a charge of solid reactant material in said tube.

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  • Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • General Physics & Mathematics (AREA)
  • Mathematical Analysis (AREA)
  • Mathematical Physics (AREA)
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  • Computational Mathematics (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Mathematical Optimization (AREA)
  • Medicinal Chemistry (AREA)
  • Pure & Applied Mathematics (AREA)
  • Business, Economics & Management (AREA)
  • Chemical & Material Sciences (AREA)
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  • Theoretical Computer Science (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)

Abstract

A SIMPLE AND ECONOMICAL APPARATUS PARTICULARLY FOR SCIENCE CLASS DEMOSTRATION OF THE GENERATION OF GASES BY REACTION OF CHEMICALS, VIZ., A SOLID AND A LIQUID. FOR EXAMPLE, ZINC AND HYDROCHLORIC ACID TO GENERATE HYDROGEN. A PARTICULAR FEATURE OF THE INVENTIOND RESIDES IN THE USE OF READILY MASS-PRODUCED PLASTIC ELEMENTS OF A SIMPLE GEOMETRIC FORM, SUCH AS TUBES, ETC., PREFERABLY TRANSPARENT, INVOLVING BASICALLY A CONCENTRICITY OF MEMBERS WHEREIN SUCH MEMBERS HOLD RESPECTIVE ENTITIES FOR EFFECTING THE FUNCTION OF GENERATING A GAS. ANOTHER FEATURE INVOLVES PROVISION OF A DISPOSABLE CATRIDGE FURNISHED WITH A FILLING OF MATERIAL TO REACT WITH A LIQUID.

Description

NVENTOR JESSE GROSS BY ATT( )RNL'Y FIG. 3
United States Patent O U.S. Cl. 23-282 9 Claims ABSTRACT OF THE DISCLOSURE A simple and economical apparatus particularly for science class demonstration of the generation of gases by reaction of chemicals, viz., a solid and a liquid. For example, zinc and hydrochloric acid to generate hydrogen. A particular feature of the inventiond resides in the use of readily mass-produced plastic elements of a simple geometric form, such as tubes, etc., preferably transparent, involving basically a concentricity of members wherein such members hold respective entities for effecting the function of generating a gas. Another feature involves provision of a disposable cartridge furnished with a filling of material to react with a liquid.
Briefly, the invention comprises injection molded members wherein, for purposes of demonstrating gas generan tion, the apparatus comprises a base which supports a tubular housing in vertical position. Concentrically supported within such housing are concentric tubular members for holding a solid to react with an acid wherein the acid has access to the solid. Generated gas is thus per mitted toescape through a exible tube extending from a cap which encloses the upper end of the housing. A pinch clamp on the tube can prevent ow until a desired pressure is realized.
A detailed description of the invention now follows in conjunction with the appended drawing in which:
FIG. 1 is an elevation in cross-section of the gas genn erator;
FIG. 2 is a plan view showing a pinch member for shutting off ow of generated gas; and
FIG. 3 is a modification of a portion of the construction wherein a disposable cartridge having a solid reactant material therein is illustrated in perspective.
Referring to FIG. l, the invention comprises a cylindrical plastic base integrally molded with a concentric housing 17 extending vertically upright therefrom and having a neck 19 closed at the top by a cap 20. Within the housing is a concentric insert sleeve 24 having a sealing t at interface 27 with a well or cavity 28 of the base, and being spaced from the housing. Sleeve 24 forms a cup or chamber 29 for holding a quantity of reactive liquid 30 around an inwardly spaced concentric tube 34 which holds a quantity of solid material 38. The liquid has access to the solid through a small or pinhole bore 40 at the bottom of tube 34.
The reaction forms a gas that rises upwardly and issues through the bore of the integral cap nipple 4-4 to be trapped by means of a exible length of hose 47 squeezed shut by a pinch clamp 50 having a slot 53, all in a manner Iobvious in FIGS. l and 2.
The several members 17, 24, 34 have a slight taper to firmly grip and seal with each other in a well known manner.
The device is well sealed as to its co-acting parts and also vented for purposes of safety. Thus, the housing member 17 has a shoulder at 57 sealingly abutting a radial flange 58 of sleeve 24 and cemented thereto. The upper end of tube 34 has a tight sealing t at 60 with a downwardly extending skirt 63 of cap 20.
A pair of safety vent ports 70 are provided in the cap so that in the event of dangerous buildup of gas back "ice pressure, tube 47 being pinched closed, such gas can escape downwardly through port 40 and then up through the liquid 30 and out of the housing through vents 70, via chamber 71.
Air expansion vents 73 are also provided in the base to permit air escape from the space 75 between housing 17 and sleeve 24 when air is heated due to the chemical re action occurring in the apparatus. Thus, double wall protection against gas pressure is provided by housing 17 and sleeve 24.
For gas generation, eg.. hydrogen, the chamber 30 would contain dilute hydrochloric acid and tube 34 would have a quantity of mossy zinc. Other agents can, of course, be used.
It is contemplated that the insert 24 can have molded calibration rings dso that proper volumes of water and acid to be mixed can be accurately gauged.
The cap 20 and tube 34 can be permanently cemented together at the interface 60 to effect a disposable cartridge with the solid material 38 provided therein ready to use. Such an integral construction is shown in FIG. 3 and has the advantage that the difficulty of cleaning the tube is eliminated. Since the tube is of plastic the scrubbing re quired would impair transparency and since the disposable elements are low cost the advantage is apparent. This is particularly so since the apparatus is primarily for class demonstration and certain reactions may produce colored gases, in which cases visibility is important.
While the construction preferably contemplates a double wall safety arrangement wherein base 10 and sleeve 24 are permanently bonded to housing 17 as an integral unit efectinga pair of venting chambers 71 and 75 and etfecting a double thick wall around the bottom of acid chamber 30, it will be understood that separate pieces could be used to be assembled when required.
From the description above it will be apparent that the cap 20 and tube 17 effect an egress means for gen` erated gas, while the tube 34 forms the inner wall of a substantially toroidal liquid holding chamber 30 in conjunction with a chamber outer wall afforded by the sleeve 24. Accordingly, the unitary structure of the cap and tube are well adapted to effect a disposable cartridge which readily coacts in assembly with the sleeve and housing to form a safe and rugged structure for the purpose intended.
I claim:
1. A gas generating apparatus comprising a housing, a tube therein for holding a solid reactant material and having a port, said tube having egress means for gas generated in said tube, a sleeve in said housing disposed inter` mediate said housing and said tube; support connection means between said housing and sleeve whereby said sleeve is supported in said housing; said housing and sleeve effecting a double wall enclosure around said tube; wherein said sleeve effects a wall of a chamber for holding a liquid to react with a solid in said tube by access through said port, a base for said housing having a well, said support connection means for said sleeve comprising one end of said sleeve being socketed in said well and having a liquid tight connection therein and said support connection means further comprising a ange at the other end of said sleeve having a gas tight connection with the interior walls of said housing, said port of said tube being disposed substantially within the confines of said well, said chamber for holding a liquid comprising the spacing between said sleeve and tube.
2. An apparatus as set forth in claim 1, said base, said housing and said sleeve being permanently bonded to form an integral unit.
3. An apparatus as set forth in claim 1, further comprising closure means for closing one end of said sleeve and said closure means having a vent passage communicating with said chamber for venting excess gas pressure.
4. An apparatus as set forth in claim 1, further comprising a vent chamber between said sleeve and said housing having a vent port for venting air pressure effected by the heat of chemical reaction in said apparatus.
5. An apparatus as set forth in claim 1, further comprising means for closing one end of said sleeve having a vent passage communicating with said chamber for venting excess gas pressure, the spacing between said sleeve and said housing effecting a vent chamber communicating with the atmosphere external to said housing for venting air pressure effected by the heat of chemical reaction in said apparatus.
6. An apparatus as set forth in claim 1, further comprising means for closing one end of said housing and having a vent communicating with said liquid holding chamber for venting excess gas pressure; the spacing between said sleeve and said housing effecting a vent chamber, and means for venting air pressure from said latter vent chamber to the atmosphere external to said housing wherein said air pressure is effected by the heat of chemical reaction in said apparatus.
7. An apparatus as set forth in claim 1, said egress means comprising a cap having a sealing friction t with said housing, said tube having an end permanently bonded to said cap to form a unitary structure.
8. An apparatus as set forth in claim 7, said port being at an opposite end of said tube.
, 9. An apparatus as set forth in claim 8, said cap and tube being of transparent plastic material and effecting a unitary cartridge disposable after said solid material is consumed, and a charge of solid reactant material in said tube.
References Cited UNITED STATES PATENTS 705,570 7/1902 Feldkamp 23-282 895,331 8/1908 Beltzer 23-282 916,291 3/1909 Von Foregger 23-282 933,077 9/1909 Jaubert 23-282 978,641 12/1910 Poe 23-282 1,029,692 6/1912 Kirkwood 23-282 2,463,863 3/1949 Gibaldo 23-282 2,516,934 8/1950 Weaver 23-282 3,180,710 4/1965 Brown et al. 23-282 3,370,925 2/1968 Trueblood 2 3-282X 3,476,520 11/1969 Hovey 23-282 FOREIGN PATENTS 279,678 10/1914 Germany 23-282 MORRIS O. WOLK, Primary Examiner B. S. RICHMAN, Assistant Examiner U.S. Cl. XR..
US758291A 1968-09-09 1968-09-09 Gas generator Expired - Lifetime US3585007A (en)

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Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3719410A (en) * 1971-11-10 1973-03-06 Farrand Optical Co Inc Mixing and measuring apparatus
US3787186A (en) * 1972-02-02 1974-01-22 Us Navy Calcium hydride gas generator
US3890102A (en) * 1971-12-31 1975-06-17 Erno Raumfahrttechnik Gmbh Catalytic action gas generator
US4556537A (en) * 1982-10-15 1985-12-03 Idemitsu Kosan Company Limited Reactor
US4842844A (en) * 1985-08-02 1989-06-27 The Boeing Company Method of generating hydrogen
US4882240A (en) * 1985-08-02 1989-11-21 The Boeing Company Closed cycle electrical power system
US5102627A (en) * 1987-10-15 1992-04-07 The Coca-Cola Company Supply of controlled medium-pressure CO2 gas in simple, convenient, disposable packaging
US5186902A (en) * 1987-10-15 1993-02-16 The Coca-Cola Company Supply of controlled, medium-pressure CO2 gas in simple, convenient disposable packaging
US5188257A (en) * 1987-10-15 1993-02-23 The Coca-Cola Company Supply of controlled, medium-pressure carbon dioxide gas in simple, convenient disposable packaging
US5270069A (en) * 1987-10-15 1993-12-14 The Coca-Cola Company Method for supplying carbonating gas to a beverage container
US5286473A (en) * 1993-02-01 1994-02-15 Nobuyasu Hasebe Process for the production of hydrogen
US5350587A (en) * 1987-10-15 1994-09-27 The Coca-Cola Company Method of dispensing carbonated beverage using a gas generator
CN104091505A (en) * 2014-08-04 2014-10-08 韦忠平 Multifunctional experimental reactor

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3719410A (en) * 1971-11-10 1973-03-06 Farrand Optical Co Inc Mixing and measuring apparatus
US3890102A (en) * 1971-12-31 1975-06-17 Erno Raumfahrttechnik Gmbh Catalytic action gas generator
US3787186A (en) * 1972-02-02 1974-01-22 Us Navy Calcium hydride gas generator
US4556537A (en) * 1982-10-15 1985-12-03 Idemitsu Kosan Company Limited Reactor
US4842844A (en) * 1985-08-02 1989-06-27 The Boeing Company Method of generating hydrogen
US4882240A (en) * 1985-08-02 1989-11-21 The Boeing Company Closed cycle electrical power system
US5102627A (en) * 1987-10-15 1992-04-07 The Coca-Cola Company Supply of controlled medium-pressure CO2 gas in simple, convenient, disposable packaging
US5186902A (en) * 1987-10-15 1993-02-16 The Coca-Cola Company Supply of controlled, medium-pressure CO2 gas in simple, convenient disposable packaging
US5188257A (en) * 1987-10-15 1993-02-23 The Coca-Cola Company Supply of controlled, medium-pressure carbon dioxide gas in simple, convenient disposable packaging
US5270069A (en) * 1987-10-15 1993-12-14 The Coca-Cola Company Method for supplying carbonating gas to a beverage container
US5350587A (en) * 1987-10-15 1994-09-27 The Coca-Cola Company Method of dispensing carbonated beverage using a gas generator
US5286473A (en) * 1993-02-01 1994-02-15 Nobuyasu Hasebe Process for the production of hydrogen
CN104091505A (en) * 2014-08-04 2014-10-08 韦忠平 Multifunctional experimental reactor

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