US3334167A

US3334167A - Method and apparatus for preparing pencil pitch

Info

Publication number: US3334167A
Application number: US323342A
Authority: US
Inventors: Gale G Kenney
Original assignee: Koppers Co Inc
Current assignee: Beazer East Inc
Priority date: 1963-11-13
Filing date: 1963-11-13
Publication date: 1967-08-01
Anticipated expiration: 1984-08-01
Also published as: DE1257419B; GB1061620A; FR1416055A

Description

G. G. KENNEY Aug. 1, 1967 2 Sheets-Sheet 1 Filed Nov. 13, 1963 win QwQ QI a6 mmvQEw E Al INVENTOR. ALE a. KENNEY flu, f5 K WIIIIIIIIIIJ WM mm vQEm Aug. 1, 1967 METHOD Filed Nov.

G. G. KENNEY 3,334,167

AND APPARATUS FOR PREPARING PENCIL PITCH 2 Sheets-Sheet 7;

INVENTOR. GALE 6. IENNEY BY AW ki g United States Patent 3,334,167 METHOD AND APPARATUS FOR PREPARING PENCIL PITCH Gale G. Kenney, Ingomar, Pa., assignor to Koppel-s Company, Inc., a corporation of Delaware Filed Nov. 13, 1963, Ser. No. 323,342 3 Claims. (Cl. 264-167) This invention relates generally to the shaping of resinous products, such as pitch, and more particularly to a method of extruding pitch to obtain rods having a solid core.

Coal tar pitch is the heavy dark residue resulting from the distillation of coal tar. It is a lustrous, brittle mass when it is cold but, dependent upon the degree of heat to which it is subjected, may become a semisolid to syrupy matsst These characteristics create problems since the manufacturer that makes use of the pitch is generally located some distance from the tar distillation facilities. Thus, the finding of a convenient and practical means for transporting the pitch has long been a problem. One solution has been to flow the molten pitch from the still directly into railway tank cars. This has the disadvantage that the pitch solidifies on cooling, so the tank cars must then be heated at the destination to remelt the pitch so that it may be unloaded. Another solution has been to cast the pitch in large concrete bays and comminute the casting by mechanical means to sizes which can be conveniently handled. This creates problems since a large number of fines are produce-d which fill the voids between the larger pieces and due to the cold flow properties of the pitch cause them to fuse together.

The preferred method of forming pitch into shape for handling and transportation is known as the pencil pitch process. This involves flowing molten pitch through a plura'lity of circular nozzles and as a plurality of circular streams into a tank of cold water which cools the .pitch streams'into solids having a cylindrical shape. These pencils are then removed from the water bath and conveyed to storage'or to a hopper .car for transport.

Although this pencil pitch process is perhaps the most convenient, it has a number of disadvantages, resulting mainly from the fact that when the pitch streams solidify on entering the water bath, the surface hardens to a hard shell while the center is still liquid. Thus, when the center hardens it shrinks, leaving a substantially cylindrical =hole running along the axis of the pencils. The diameter of the hole, being at times as much as a third of the diameter of the pencils themselves, weakens the pencils so they are easily broken in transit to produce a large percentage of fines. It also has the serious drawback of entrapping water within the pencils which cannot be removed by any convenient drying means. The presence of this water, which may be as much as two to five percent of the dry weight of the pitch, causes steam and odor problems when the pitch is later processed. Since the pitch must be remelted at a temperature above the boiling point of water for forming into a finished shape, the water vapor evolved carries with it an odoriferous distillate from the pitch. A still further disadvantage is that the uniform cylindrical shape of the pencils presents a large area of contact surface which due to cold flow properties of the pitch will cause the pitch pencils to stick together when they are shipped during warm weather.

This invention avoids the foregoing difficulties by producing a pitch pencil having a solid core and a surface contour which is highly irregular.

In accordance with the invention, molten pitch is formed into a plurality of streams having a substantially ova-l shape. These streams are directed into a cooling zone maintained at a temperature below the melting point of the pitch where they solidify and the solid pencils are removed from the cooling zone and dried.

The objects and novel features of the invention will appear more fully from the following detailed description when the same is read in connection with the accompanying drawings. It is to be understood that the drawings are not intended as a definition of the invention, but are for purposes of illustration only.

In the drawings wherein like parts are labeled alike:

FIGURE 1 is a highly schematic flow diagram illustrating the process of producing pencil pitch,

FIGURE 2 is a vertical cross-section of an embodiment of the novel extrusion apparatus,

FIGURE 3 is a cross-section taken on line III-III of FIG. 2,

FIGURE 4 is an illustration of a pitch pencil made in accordance with the invention, and

FIGURE 5 is a cross-section taken on line VV of FIG. 4.

Referring now to FIG. 1, coal tar pitch is conveyed to storage tank 13 and then to extrusion tank 15 by means of line 17. Conventional carrot valves 18 are opened and pitch flows through circular pipes 21 and through extruding nozzles 37, FIG. 2, as streams 23 into cooling tank 25, which is filled with water 26. Streams 23 are cooled by water in tank 25. The streams solidify and fall to the bottom of the tank. The solid rods thus formed are broken into lengths and conveyed to bucket elevator 27 by means of screw conveyor 29. Bucket elevator 27 transports the pencils to a belt conveyor 31. The moisture is removed from the pitch pencils by air blower 33 after which they are conveyed to storage.

Referring now to FIG. 2, for details of embodiment of the novel apparatus, nozzle 37 is attached to feed tank 15 by means of circular pipe 21 and coupling 39. Nozzle 37 comprises pipe 40, which is connected to a feed tip 41 by means of coupling 43 and bushing 45, and steam jacket 47. Jacket 47 is provided with a steam inlet 49 and a condensate outlet 51. The upper portion 50 of feed tip 41 is substantially tubular in shape having a circular cross-section. The lower portion 52 terminates in an oval orifice 53. The cross section of the orifice is illustrated in FIG. 3. The inner diameter of feed tip 41 is gradually shortened aiong one diameter and lengthened along a diameter normal to the first so that a smooth transition is made from the circular cross section at 50 to the oval cross section at 52. The cross sectional areas of the oval-shaped orifice and the circular upper portion are substantially the same.

As an example of the practice of the process of the invention, twenty five hundred gallons of pitch (M.P. 265 F.) at a temperature of 380 F. were placed in extrusion tank 15 having forty-four nozzles 37. The carrot valves 18 at the top of openings 21 were opened and steam was introduced into jacket 47 to heat pipe 49 and to prevent solidification of the pitch in pipe 49. Pitch ata rate of approximately 3,000 gallons per hour flowed down through nozzles 37 and out orifice 53 of tips 41 into the cooling water 26. The orifices 53 of tips 41 had widths W of .25" and lengths L of .989 giving them each a cross sectional area equal to a circle of 7 diameter. The surface of the cooling water was located two inches below the end of feed tips 41 and its temperature was maintained at between -120 F. by circulating it to a conventional cooling tower. The solidified streams were broken into lengths by screw 29, carried to bucket elevator 27, lifted to belt conveyor 31 where the lengths were blown dry by air blower 33 are loaded into hopper cars.

The shape of the pencils produced in this manner is shown in FIGS. 4 and 5. It is believed that the twisted spiral form of the pencils is due to the shrinkage of the pitch on cooling. The average length of the pencils is between two and six inches. The surface of the pencils has a bright shiny black finish as compared with the dull sheen of the circular pencils.

The temperature of the cooling water and pitch will depend on the type of pitch being extruded, as shown in Table I below.

As can be seen from the table, pitch temperatures between about 120 and 250 F. above the melting point of the pitch give the correct viscosity properties to produce satisfactory pencils. The cooling water temperature is maintained from about 85 F. to about 125 F.

The distance between the ends of the nozzles and the surface of the cooling water can be varied between about A; inch to about eight inches. If the distance is less than about A; inch, permitting the nozzles and water to come in contact, the pitch foams on the surface of the water, rather than producing a pencil. If the distance is greater than eight inches, the soft pitch will tend to change from an oval to a cylindrical stream prior to entering the water bath, in which case the same problem as encountered in the old process will occur, in that the outer cylindrical surface of the pencil will harden, leaving a soft core which will shrink on cooling to produce a hole through its center. Due to gravitational eflfects the pitch streams will become smaller as the distance from othe ends of the nozzles to the water increases. The cross-sectional area of the stream with the nozzles eight inches above the water will be approximately 25 percent smaller than the crosssectional areas of the orifices thus producing thinner pencils. Proportional decreases in size will occur when the distance between the nozzles and water is varied between about inch to about eight inches.

With regard to the dimensions of the orifice 53, the width diameter W is critical and can be varied from about A; to about inch with the optimum at inch. The length L can be varied from about A to six inches but conveniently is inversely varied with the width W to maintain a constant cross-sectional area. If the width W is less than inch, plugging difficulties are encountered. If the width W is greater than inch, uniform cooling throughout the pitch stream cannot be achieved and the center of the stream remains soft, as in the case of the cylindrical pencils, and when it hardens it shrinks to cause a hole through the center.

The foregoing has described an improved process for producing pitch pencils which overcomes the difficulties associated with prior methods. The pitch is transformed into a shape which is convenient for shipping and which can be easily air dried to a moisture content of less than .05 percent. In previous processes, the moisture content varied between two and five percent due to water being trapped in the hollow core of the pencils. The twisted solid core product is stronger than the old round type and is subject to less breakage in handling resulting in fewer fines, which tend to clog machinery. The twisted spiral form of the pencils have less tendency to stick together during shipment, since there is a much smaller amount of surface in contact between the pencils than in the old cylindrical type.

I claim:

1. Method of making solid core pitch pencils from molten pitch comprising advancing said pitch in the form of a stream having a substantially oval cross-section, said cross-section having a width from about /3 to about inches and a length from about inch to about six inches and cooling said stream in a liquid cooling Zone located from about A; inch to about eight inches below the top of said stream, said liquid being maintained below the melting point of said pitch whereby said pitch solidifies to a rod having a solid core and an irregular surface contour.

2. Method of making solid core pitch pencils from molten pitch comprising advancing said pitch, at a temperature of from about to about 250 F. above the melting point of said pitch in the form of a stream having a substantially oval cross-section, said cross-section having a width of about A3 to about /3 inch and a length of about A inch to about six inches, into water, whose surface is located from about A; inch to about eight inches below the top of said stream and whose temperature is maintained from about 85 to about F. whereby said pitch solidifies to a rod having a solid core and an irregular surface contour.

3. Apparatus for making solid core pitch pencils from molten pitch comprising a nozzle having a substantially oval shaped orifice, said orifice having a width of about /a to about inch and a length of about inch to about six inches, means for advancing said pitch in the form of a stream through said nozzle so that the stream has a substantially oval shaped cross-section of substantially the same dimensions as said orifice, a tank, means for flowing water into said tank so that the surface of the water in said tank is located from about inch to about eight inches below said orifice and the temperature of said water is maintained from about 85 to about 125 F., whereby said pitch contacts said water and solidifies to a rod having a solid core and an irregular surface contour.

References Cited UNITED STATES PATENTS 1,964,659 6/1934 Brumber-ger 18-8 3,029,124 4/1962 Farrow 264178 3,156,750 1l/1964 Cuculo 264178 ROBERT F. WHITE, Primary Examiner.

G. AUVILLE, Assistant Examiner,

Claims

1. METHOD OF MAKING SOLID CORE PITCH PENCILS FROM MOLTEN PITCH COMPRISING ADVANCING SAID PITCH IN THE FORM OF A STREAM HAVING A SUBSTANTIALLY OVAL CROSS-SECTION, SAID CROSS-SECTION HAVING A WIDTH FROM ABOUT 1/8 TO ABOUT 3/8 INCHES AND A LENGTH FROM ABOUT 1/4 INCH TO ABOUT SIX INCHES AND COOLING SAID STREAM IN A LIQUID COOLING ZONE LOCATED FROM ABOUT 1/8 INCH TO ABOUT EIGHT INCHES BELOW THE TOP OF SAID STREAM, SAID LIQUID BEING MAINTAINED BELOW THE MELTING POINT OF SAID PITCH WHEREBY SAID PITCH SOLIDIFIES TO A ROD HAVING A SOLID CORE AND AN IRREGULAR SURFACE CONTOUR.