US3388001A - Method of making piezoelectric layers by flame spraying - Google Patents
Method of making piezoelectric layers by flame spraying Download PDFInfo
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- US3388001A US3388001A US468609A US46860965A US3388001A US 3388001 A US3388001 A US 3388001A US 468609 A US468609 A US 468609A US 46860965 A US46860965 A US 46860965A US 3388001 A US3388001 A US 3388001A
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- Prior art keywords
- piezoelectric
- flame spraying
- substrate
- flame
- titauate
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- 238000010285 flame spraying Methods 0.000 title claims description 19
- 238000004519 manufacturing process Methods 0.000 title claims description 7
- 239000000463 material Substances 0.000 claims description 22
- 239000000758 substrate Substances 0.000 claims description 22
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 3
- 239000001301 oxygen Substances 0.000 claims description 3
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- 229910052788 barium Inorganic materials 0.000 description 13
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 13
- 238000000034 method Methods 0.000 description 11
- 238000000576 coating method Methods 0.000 description 9
- 239000002245 particle Substances 0.000 description 8
- 239000013078 crystal Substances 0.000 description 6
- RKTYLMNFRDHKIL-UHFFFAOYSA-N copper;5,10,15,20-tetraphenylporphyrin-22,24-diide Chemical compound [Cu+2].C1=CC(C(=C2C=CC([N-]2)=C(C=2C=CC=CC=2)C=2C=CC(N=2)=C(C=2C=CC=CC=2)C2=CC=C3[N-]2)C=2C=CC=CC=2)=NC1=C3C1=CC=CC=C1 RKTYLMNFRDHKIL-UHFFFAOYSA-N 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- 230000008021 deposition Effects 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 239000010408 film Substances 0.000 description 2
- 229910001026 inconel Inorganic materials 0.000 description 2
- 239000011236 particulate material Substances 0.000 description 2
- WSMQKESQZFQMFW-UHFFFAOYSA-N 5-methyl-pyrazole-3-carboxylic acid Chemical compound CC1=CC(C(O)=O)=NN1 WSMQKESQZFQMFW-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 230000001464 adherent effect Effects 0.000 description 1
- JRPBQTZRNDNNOP-UHFFFAOYSA-N barium titanate Chemical compound [Ba+2].[Ba+2].[O-][Ti]([O-])([O-])[O-] JRPBQTZRNDNNOP-UHFFFAOYSA-N 0.000 description 1
- 229910002113 barium titanate Inorganic materials 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 230000001427 coherent effect Effects 0.000 description 1
- QFXZANXYUCUTQH-UHFFFAOYSA-N ethynol Chemical group OC#C QFXZANXYUCUTQH-UHFFFAOYSA-N 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- HFGPZNIAWCZYJU-UHFFFAOYSA-N lead zirconate titanate Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Ti+4].[Zr+4].[Pb+2] HFGPZNIAWCZYJU-UHFFFAOYSA-N 0.000 description 1
- GQYHUHYESMUTHG-UHFFFAOYSA-N lithium niobate Chemical compound [Li+].[O-][Nb](=O)=O GQYHUHYESMUTHG-UHFFFAOYSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- UKDIAJWKFXFVFG-UHFFFAOYSA-N potassium;oxido(dioxo)niobium Chemical compound [K+].[O-][Nb](=O)=O UKDIAJWKFXFVFG-UHFFFAOYSA-N 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- LSGOVYNHVSXFFJ-UHFFFAOYSA-N vanadate(3-) Chemical class [O-][V]([O-])([O-])=O LSGOVYNHVSXFFJ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/51—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on compounds of actinides
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/46—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on titanium oxides or titanates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/48—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on zirconium or hafnium oxides, zirconates, zircon or hafnates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/50—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on rare-earth compounds
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N30/00—Piezoelectric or electrostrictive devices
- H10N30/01—Manufacture or treatment
- H10N30/07—Forming of piezoelectric or electrostrictive parts or bodies on an electrical element or another base
- H10N30/074—Forming of piezoelectric or electrostrictive parts or bodies on an electrical element or another base by depositing piezoelectric or electrostrictive layers, e.g. aerosol or screen printing
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N30/00—Piezoelectric or electrostrictive devices
- H10N30/80—Constructional details
- H10N30/85—Piezoelectric or electrostrictive active materials
- H10N30/853—Ceramic compositions
- H10N30/8536—Alkaline earth metal based oxides, e.g. barium titanates
Definitions
- the present invention relates to a method of making piezoelectric layers and more especially relates to a flame spraying process whereby such layers or coatings may be readily and conveniently made.
- a primary object of our invention is to provide a flame spraying method of making thin piezoelectric layers, films or coatings.
- a more specific object of our invention is to provide a flame spraying method of making piezoelectric barium titauate multicrystalline coatings.
- Another object of our invention is to provide an improved flame spraying method of forming piezoelectric thin films wherein the material being so sprayed is impinged upon a heated substrate and the cooling rate of the coating so controlled as to prevent or deter conversion of the sprayed material from a piezoelectric to a nonpiezoelectric crystal structure.
- flame spraying as used in the present specification and claims is meant the passage of particulate materials through a continuous flame generating device such as an oxyacetylene torch, oxyhydrogen torch or a plasma flame unit and the deposition of said materials as an adherent, coherent coating upon the substrate being so treated.
- a continuous flame generating device such as an oxyacetylene torch, oxyhydrogen torch or a plasma flame unit and the deposition of said materials as an adherent, coherent coating upon the substrate being so treated.
- Such flame generating members are well known.
- the present process represents an improvement over the flame spraying techniques disclosed in US. Patent 2,904,449.
- Our invention is based upon our discovery that by flame spraying for example barium titauate (BaTiO onto a heated substrate that we can maintain the piezoelectric properties of the material.
- Barium titauate BaTiO onto a heated substrate that we can maintain the piezoelectric properties of the material.
- Mere flame spraying of such materials upon a chilled substrate destroys the piezoelectric properties of the sprayed layer.
- flame spraying onto a heated substrate we are able to maintain such desirable piezoelectric properties.
- This feature is a controlled cooling rate phenomenon whereby one controls crystallographic transformation.
- EXAMPLE 1 Particulate barium titauate of a particle size ranging from 44 to microns was passed through a oxyhydrogen flame onto an Inconel substrate.
- the gun to substrate distance was maintained at from 2 to 3 inches and we used a gas ratio of 55 cubic feet per hour oxygen to 100 cubic feet per hour hydrogen.
- the Inconel was in disc form, inch thick and was maintained at a temperature of from 1100 F. to 1300 F. while the barium titauate was being deposited thereon.
- an essential feature of our invention is the flame spraying of crystal structure material which can easily be converted under controlled conditions to avoid the formation of the high temperature crystal structure.
- the flame spraying of crystal structure material which can easily be converted under controlled conditions to avoid the formation of the high temperature crystal structure.
- the deposited barium titauate was found to be porous and did not adhere well to the substrate and at approximately 14 grams per minute reduced barium titauate was formed.
- a range of from 20 to 35 grams per minute can be employed to make the present piezoelectric coatings.
- our process is applicable for the deposition of titanates, niobates, vanadates and zirconates characterized by a perovskite crystallographic structure and to the solid solutions of such materials.
- examples of such materials are barium titauate, potassium titauate, sodium tantalate, potassium niobate, lead titauate, lithium tantalate, lithium niobate, cadmium niobate and lead zirconate titanates.
- These materials are flame sprayed onto a heated substrate maintained at such a temperature to prevent rapid chilling of the impinging particles with the resulting formation of a non-piezoelectric crystal structure.
- the substrate material employed must be capable of withstanding the particular heating involved.
- the method of making a layer of piezoelectric material upon a substrate which comprises the steps of: flame spraying an oxygen containing material of perovskite structure onto a heated substrate while maintaining said substrate at a temperature whereby said material is not chilled in a non-piezoelectric crystal phase and permitting the resulting layer to cool.
- the method of making a multicrystalline piezoelectric layer upon a substrate which comprises the steps of: flame spraying particles of a material selected from the group consisting of titanates, tantalates, niobates and zirconates which material is characterized by a relatively low temperature piezoelectric structure and a relatively high temperature non-piezoelectric structure onto a heated substrate while maintaining said substrate during spraying at such an elevated temperature whereby said particles upon impingement and deposition are not chilled in the high temperature, non-piezoelectric structure, and then permitting said layer to cool.
- a material selected from the group consisting of titanates, tantalates, niobates and zirconates which material is characterized by a relatively low temperature piezoelectric structure and a relatively high temperature non-piezoelectric structure onto a heated substrate while maintaining said substrate during spraying at such an elevated temperature whereby said particles upon impingement and deposition are not chilled in the high temperature, non-piezoelectric structure, and then permitting said layer to cool.
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Ceramic Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Plasma & Fusion (AREA)
- Composite Materials (AREA)
- Coating By Spraying Or Casting (AREA)
Description
United States Patent 3,388,001 METHOD 0F MAKHJG PIEZOELECTRIC LAYERS BY FLAME SPRAYING Seymour Blum, Giencoe, Adi Mountvala, Chicago, and
Robert McKinley, Broadview, 111., assignors to IIT Research Institute, Chicago, 111., a nonprofit corporation of lllinois No Drawing. Filed June 30, 1965, Ser. No. 468,609 4 Claims. (Cl. 117-213) The present invention relates to a method of making piezoelectric layers and more especially relates to a flame spraying process whereby such layers or coatings may be readily and conveniently made.
Accordingly a primary object of our invention is to provide a flame spraying method of making thin piezoelectric layers, films or coatings.
A more specific object of our invention is to provide a flame spraying method of making piezoelectric barium titauate multicrystalline coatings.
Another object of our invention is to provide an improved flame spraying method of forming piezoelectric thin films wherein the material being so sprayed is impinged upon a heated substrate and the cooling rate of the coating so controlled as to prevent or deter conversion of the sprayed material from a piezoelectric to a nonpiezoelectric crystal structure.
These and other objects, features and advantages of our invention will become apparent to those skilled in this art from the following detailed disclosure thereof.
As is well known to those skilled in this art, it has been most difficult to prepare thin piezoelectric coatings of perovskite type structures by known techniques. In distinction to such problems we have discovered that by the flame spraying of particulate materials as herein taught, that such films may be readily fabricated.
By the term flame spraying as used in the present specification and claims is meant the passage of particulate materials through a continuous flame generating device such as an oxyacetylene torch, oxyhydrogen torch or a plasma flame unit and the deposition of said materials as an adherent, coherent coating upon the substrate being so treated. Such flame generating members are well known. Generally speaking the present process represents an improvement over the flame spraying techniques disclosed in US. Patent 2,904,449.
Our invention is based upon our discovery that by flame spraying for example barium titauate (BaTiO onto a heated substrate that we can maintain the piezoelectric properties of the material. Mere flame spraying of such materials upon a chilled substrate destroys the piezoelectric properties of the sprayed layer. On the other hand by flame spraying onto a heated substrate we are able to maintain such desirable piezoelectric properties. This feature is a controlled cooling rate phenomenon whereby one controls crystallographic transformation.
Before proceeding further in a discussion of our process reference should first be had to an example thereof:
EXAMPLE 1 Particulate barium titauate of a particle size ranging from 44 to microns was passed through a oxyhydrogen flame onto an Inconel substrate. The gun to substrate distance was maintained at from 2 to 3 inches and we used a gas ratio of 55 cubic feet per hour oxygen to 100 cubic feet per hour hydrogen. The Inconel was in disc form, inch thick and was maintained at a temperature of from 1100 F. to 1300 F. while the barium titauate was being deposited thereon. We determined that the thin, dense layer of barium titauate was p1ezoelectr1c.
3,388,001 Patented June 11, 1968 ICC It is known that barium titauate at room temperature exists in the tetragonal crystal form. At temperatures of approximately 126 C. the tetragonal form converts to the cubic and at temperatures of approximately 1400 C. the latter in turn converts to the hexagonal crystalline structure. It is the tetragonal form which is piezoelectric. If one merely flame sprays barium titauate onto a chilled substrate in their passage through the flame the barium titauate particles are converted to the hexagonal crystalline form, a non-piezoelectric embodiment. Conversion of the hexagonal to the cubic is most sluggish and for practical purposes can be said to be almost non-existent. On the other hand the intermediate temperature cubic structure readily reverts to the piezoelectric tetragonal. Accordingly an essential feature of our invention is the flame spraying of crystal structure material which can easily be converted under controlled conditions to avoid the formation of the high temperature crystal structure. We have found that by the avoidance of the quenching of the barium titauate, for example, in the high temperature hexagonal form and that is by flame spraying onto a heated substrate, that We can maintain the piezoelectric qualities of the material being sprayed. After the flame spraying onto the heated substrate the material may be air-cooled and while in layer form it reverts to the piezoelectric tetragonal structure.
In addition to using a heated substrate in the carrying out of our process we have also found that it is important to control the particle feed rate into the flame. 1f the feed rate is too low the particles become very hot thus increasing the probability of obtaining reduced BaTiO a material which is non-piezoelectric. If on the other hand the feed rate is too high the temperature of the particles in the flame would be too low and a dense coating would not be obtained. Both reduced barium titauate and reduced but porous BaTiO layer do not have the desirable piezoelectric properties we wish to provide. Preferably we use a deposition rate of approximately 23 grams per minute in order to make the desired new coatings of this invention. At 40 grams per minute the deposited barium titauate was found to be porous and did not adhere well to the substrate and at approximately 14 grams per minute reduced barium titauate was formed. A range of from 20 to 35 grams per minute can be employed to make the present piezoelectric coatings.
Even more specifically, our process is applicable for the deposition of titanates, niobates, vanadates and zirconates characterized by a perovskite crystallographic structure and to the solid solutions of such materials. Examples of such materials are barium titauate, potassium titauate, sodium tantalate, potassium niobate, lead titauate, lithium tantalate, lithium niobate, cadmium niobate and lead zirconate titanates. These materials are flame sprayed onto a heated substrate maintained at such a temperature to prevent rapid chilling of the impinging particles with the resulting formation of a non-piezoelectric crystal structure. Obviously the substrate material employed must be capable of withstanding the particular heating involved.
It will be understood that various modifications and variations may be effected without departing from the spirit or scope of the novel concepts of our invention.
We claim as our invention:
1. The method of making a layer of piezoelectric material upon a substrate which comprises the steps of: flame spraying an oxygen containing material of perovskite structure onto a heated substrate while maintaining said substrate at a temperature whereby said material is not chilled in a non-piezoelectric crystal phase and permitting the resulting layer to cool.
2. The method of making a multicrystalline piezoelectric layer upon a substrate which comprises the steps of: flame spraying particles of a material selected from the group consisting of titanates, tantalates, niobates and zirconates which material is characterized by a relatively low temperature piezoelectric structure and a relatively high temperature non-piezoelectric structure onto a heated substrate while maintaining said substrate during spraying at such an elevated temperature whereby said particles upon impingement and deposition are not chilled in the high temperature, non-piezoelectric structure, and then permitting said layer to cool.
3. The method as defined in claim 2 wherein said material being flame sprayed is barium titanate.
4. The method as defined in claim 2 wherein said ma- 15 terial being flame sprayed is a lead titanate zirconate.
4 References Cited UNITED STATES PATENTS 2,904,449 9/1959 Bradstreet 117-46 3,246,114 5/1966 Matuay 219-76 FOREIGN PATENTS 345 ,65 3 2/ 1920 Germany.
OTHER REFERENCES 10 Metco Bulletin 10F 1M, August 1963, Powders for Flame Spraying, 1963, 2 pages.
RALPH S. KENDALL, Primary Examiner.
ALFRED L. LEAVITT, Examiner.
A. GOLIAN, Assistant Examiner.
Claims (1)
1. THE METHOD OF MAKING A LAYER OF PIEZOELECTRIC MATERIAL UPON A SUBSTRATE WHICH COMPRISES THE STEPS OF: FLAME SPRAYING AN OXYGEN CONTAINING MATERIAL OF PEROVSKITE STRUCTURE ONTO A HEATED SUBSTATE WHILE MAINTAINING SAID SUBSTRATE AT A TEMPERATURE WHEREBY SAID MATERIAL IS NOT CHILLED IN A NON-PIEZOELECTRIC CYRSTAL PHASE AND PERMITTING THE RESULTING LAYER TO COOL.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US468609A US3388001A (en) | 1965-06-30 | 1965-06-30 | Method of making piezoelectric layers by flame spraying |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US468609A US3388001A (en) | 1965-06-30 | 1965-06-30 | Method of making piezoelectric layers by flame spraying |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US3388001A true US3388001A (en) | 1968-06-11 |
Family
ID=23860503
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US468609A Expired - Lifetime US3388001A (en) | 1965-06-30 | 1965-06-30 | Method of making piezoelectric layers by flame spraying |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US3388001A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3487238A (en) * | 1967-07-27 | 1969-12-30 | Gulton Ind Inc | Ceramic transducer elements and accelerometers utilizing same |
| US3617376A (en) * | 1967-03-16 | 1971-11-02 | North American Rockwell | Antisublimation coating and method for thermoelectric materials |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE345653C (en) * | 1919-11-25 | 1922-03-27 | Nicolaus Meurer | Device for executing cover layers made of enamel, glass, quartz, hard metal and the like, which are produced by means of spraying onto heat-resistant workpieces and are connected to the latter by welding. like |
| US2904449A (en) * | 1955-07-26 | 1959-09-15 | Armour Res Found | Method and compositions for flame spraying |
| US3246114A (en) * | 1959-12-14 | 1966-04-12 | Matvay Leo | Process for plasma flame formation |
-
1965
- 1965-06-30 US US468609A patent/US3388001A/en not_active Expired - Lifetime
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE345653C (en) * | 1919-11-25 | 1922-03-27 | Nicolaus Meurer | Device for executing cover layers made of enamel, glass, quartz, hard metal and the like, which are produced by means of spraying onto heat-resistant workpieces and are connected to the latter by welding. like |
| US2904449A (en) * | 1955-07-26 | 1959-09-15 | Armour Res Found | Method and compositions for flame spraying |
| US3246114A (en) * | 1959-12-14 | 1966-04-12 | Matvay Leo | Process for plasma flame formation |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3617376A (en) * | 1967-03-16 | 1971-11-02 | North American Rockwell | Antisublimation coating and method for thermoelectric materials |
| US3487238A (en) * | 1967-07-27 | 1969-12-30 | Gulton Ind Inc | Ceramic transducer elements and accelerometers utilizing same |
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