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US3232717A - Uranium monocarbide thermionic emitters - Google Patents

Uranium monocarbide thermionic emitters Download PDF

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US3232717A
US3232717A US194448A US19444862A US3232717A US 3232717 A US3232717 A US 3232717A US 194448 A US194448 A US 194448A US 19444862 A US19444862 A US 19444862A US 3232717 A US3232717 A US 3232717A
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rhenium
uranium carbide
volume
uranium
tungsten
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US194448A
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Robert F Hill
Stan J Paprocki
Donald L Keller
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Motors Liquidation Co
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General Motors Corp
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Priority to US194448A priority Critical patent/US3232717A/en
Priority to GB18455/63A priority patent/GB971531A/en
Priority to DEG37728A priority patent/DE1240967B/en
Priority to FR934740A priority patent/FR1356734A/en
Priority to US423403A priority patent/US3243292A/en
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J45/00—Discharge tubes functioning as thermionic generators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J9/00—Apparatus or processes specially adapted for the manufacture, installation, removal, maintenance of electric discharge tubes, discharge lamps, or parts thereof; Recovery of material from discharge tubes or lamps
    • H01J9/02—Manufacture of electrodes or electrode systems
    • H01J9/04—Manufacture of electrodes or electrode systems of thermionic cathodes
    • H01J9/042—Manufacture, activation of the emissive part
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S75/00—Specialized metallurgical processes, compositions for use therein, consolidated metal powder compositions, and loose metal particulate mixtures
    • Y10S75/95—Consolidated metal powder compositions of >95% theoretical density, e.g. wrought
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/12—All metal or with adjacent metals
    • Y10T428/12014—All metal or with adjacent metals having metal particles
    • Y10T428/12028—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, etc.]
    • Y10T428/12063—Nonparticulate metal component
    • Y10T428/12069—Plural nonparticulate metal components
    • Y10T428/12076—Next to each other
    • Y10T428/12083—Nonmetal in particulate component
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/12—All metal or with adjacent metals
    • Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/12771—Transition metal-base component
    • Y10T428/12778—Alternative base metals from diverse categories

Definitions

  • This invention relates to devices yfor converting heat energy to electrical energy and, more particularly to an improved electron emitter element for such devices.
  • a thermionic converter which comprises a noble gas plasma diode, the electron emitter element of which includes a iissionable material so as to generate the noble gas plasma by fission fragment ionization.
  • the mass of the iissionable material in the diode or a combination of such diodes can be made suiiiciently large to sustain chain reaction fission and thereby generate the heat for conversion to electrical energy.
  • the basic requirements -for the emitter material for such a device are: It must have the ability to adequately supply electrons at the operating temperature, must be chemically and mechanically stable, must have electrical and thermal conductivity and must have a high surface density of exposed ssionable material.
  • a further object of the invention is to provide an improved method for making su-ch an electron emitter.
  • Uranium carbide by itself, has two of the aforementioned essential qualities needed for the electron emitter, namely, ability to supply electrons and high density of iissionable material. However, by itself it has insuilicient mechanical strength. Uran-ium carbide is, of course, a ceramic and, as is true -of most all ceramics, it is particularly susceptible to thermal cracking. In accordance with the present invention, the additional required properties are provided by physically combining certain metals with the uranium carbide to form a cermet. We have found that the choice of metals is extremely limited for the reason that uranium carbide is quite reactive at high temperatures, and it is essential that the metal not undergo interaction with the uranium carbide either during processing or during operation.
  • the electron emitter of this invention comprises a dense cermet body of uranium carbide and rhenium, tungsten, or rhenium-tungsten alloys, the -former being preferred. Further inaccordance with the invention, this cermet body is provided with a niobium cladding, a thin layer of the rhenium or tungsten, preferably the latter, being interposed between the cermet body and the cladding in order to prevent diifusion and reaction between the niobium and the uranium carbide during manufacture and operation of the emitter.
  • the cermet body can contain from 10% to 80% by volume uranium carbide, the upper end of this range being preferred particularly where the emitter is for use in a nuclear reactor type thermionic converter wherein the heat is supplied by nuclear fission.
  • the thermionic converter comprises a hermetically sealed envelope 2 lilled with a noble gas and having two electrical leads 4 and 6 extending therethrough.
  • the top lead 4 Iconnects to an electron collector 8 which has some suitable cooling means associated therewith, such cooling means being illustrated by the plurality of heat radiating fins 10.
  • the bottom electrical lead 6 is connected to the electron emitter 12 which is in the form of a flat disc with its upper surface in spaced relationship to the bottom flat surface of the collector.
  • the emitter ⁇ 12 comprises a dense cermet body 14 of 80% by Volume uranium carbide and 20% by volume rhenium with a niobium cladding 16 Icovering its side and bottom surfaces, a layer of tungsten foil 18 being pressed between the body 14 and the cladding. Further details of the structure of the emitter will be apparent from the following description of the method for its manufacture:
  • uranium carbide pure uranium metal in the fornrof small discs or rods can be employed as a starting material. Prior to melting, the surface of the metal should be carefully cleaned by electropolishing or by a careful wash in dilute nitric acid. Spectroscopie carbon in rod form can be employed as the starting carbon material.
  • the rod is rst outgassed by heating to a temperature of about 2000o C. in high Vacuum and is then ground to powder form in an inert atmosphere; Carefully controlled quantities of the uranium metal and carbon powder are placed in an are furnace in a puried argon atmosphere where they are arc-melted together to form a uranium carbide button. A graphite-tipped electrode is used in order to minimize contamination.
  • the composition of the uranium carbide produced will, of course, depend upon the weights of uranium metal and carbon powder in the furnace charge. With 4.8
  • the uranium carbide formed will be predominantly uranium monocarbide; when slightly more than 4.8 weight percent carbon is used, a second phase with composition UC2 will appear at the grain boundaries within the UC matrix and there will sometimes also appear a third phase, U2C3.
  • the precise stoichiometric composition of the uranium carbide is not important to the present invention and hence the term uranium carbide as used herein is intended to comprelhend both the monoand di-carbides as well as the intermediates such as U2C3.
  • the uranium carbide is pulverized to fine grain size, on the order of minusy 300 mesh, preferably in a dry box since the pulverized uranium carbide is pyrophoric.
  • the pulverized uranium carbide is uniformly admixed with rhenium powder, also about minus 300 mesh grain size, in the proportions desired, preferably uranium carbide and 20% rhenium.
  • This mixing of the powders should also be performed in a dry box and for further protection against the pyrophoric nature of the uranium carbide it is desirable that about 1% by weight of a suitable organic material such as Carbowax (polyethylene glycol) be included in the mixture.
  • Carbowax polyethylene glycol
  • the Carbowax also serves as a binder for the mixture.
  • the powder mixture is then cold pressed in a steel die at about 60,000 pounds per square inch to thereby form a green compact having a density of approximately 70% theoretical.
  • the green compact so formed is inserted snugly into a niobium cup lined with a thin layer of tungsten foil and this assembly is then heated in a vacuum sufficiently to drive out the Carbowax.
  • a niobium lid preferably also lined with tungsten foil, is then placed over the niobium cup and is bonded to the cup by electron beam welding to effect an hermetic seal. Since the electron beam welding is performed in a vacuum, the interior of the cup is in an evacuated state at the conclusion of this sealing operation.
  • the assembly should preferably be leak-checked after the welding to make certain that it is hermetically sealed.
  • the resulting niobium encapsulated green compact is placed in an autoclave and is pressure bonded in a helium atmosphere at 10,000 pounds per square inch pressure and 2700 F.
  • This heating and isostatic pressing operation causes the niobium encapsulation to collapse and the green compact to sinter and form a dense cermet body.
  • the cermet body has a density which is about 99% of theoretical.
  • both rhenium and tungsten have extremely low chemical reactivity with uranium carbide. Between the two, rhenium is preferable because it has the lowest chemical reactivity; however, it is less desirable because of its higher nuclear cross section. It is because of this that rhenium with its extremely low reactivity is the preferred metal for the cermet, whereas tungsten with its lower nuclear cross section is preferred for the barrier layer between the cermet and the cladding. The somewhat higher reactivity of the tungsten serves to no serious disadvantage where it is used as the barrier layer and the lower cross section outweighs what little disadvantage there is.
  • a cermet body useful as an electron emitter in a thermionic device consisting essentially of from to 80% by volume uranium carbide and from 20% to 90% by volume of a metal selected from the group consisting of rhenium, tungsten and rhenium-tungsten alloys.
  • a cermet body useful as an electron emitter in a thermionic device consisting essentially of from 10% to 80% by volume uranium carbide and from 20% to 90% by volume rhenium.
  • a cermet body useful as an electron emitter in a thermionic device said body containing about 80% by volume uranium carbide and about 20% by Volume of a metal selected from the group consisting of rhenium, tungsten and rhenium-tungsten alloys.
  • a cermet body useful as an electron emitter in a thermionic device said body containing about by volume uranium carbide and about 20% by volume rhenium.
  • An electron emitter for a thermionic device comprising a cermet body consisting essentially of from 10% to 80% by volume uranium carbide and from 20% to by volume metal, a niobium cladding on said cermet body and a thin barrier layer of metal between said body and said cladding, the metal of said barrier layer and of said cermet being selected from the group consisting of rhenium, tungsten and rhenium-tungsten alloys.
  • An electron emitter for a thermionic device comprising a cermet body consisting essential of from 10% to 80% by volume uranium carbide and from 20% to 90% by volume rhenium, a niobium cladding on said cermet body and a thin barrier layer of tungsten between said body and said cladding.
  • An electron emitter for a thermionic device comprising a cermet body containing about 80% by volume uranium carbide and about 20% by volume metal, a niobium cladding on said cermet body and a thin barrier layer of metal between said body and said cladding, the metal of said barrier layer and of said cermet being selected from the group consisting of rhenium, tungsten and rhenium-tungsten alloys.
  • An electron emitter for a thermionic device comprising a cerment body containing about 80% by volume uranium carbide and about 20% by volume rhenium, a niobium cladding on said cermet body and a thin barrier layer of tungsten between said body and said cladding.
  • a cermet body useful as an electron emitter in a thermionic device said body containing from 10% to 80%, by volume, uranium carbide and the balance substantially a metal selected from the group consisting of rhenium, tungsten and rheniumtungsten alloys.

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  • Manufacturing & Machinery (AREA)
  • Solid Thermionic Cathode (AREA)

Description

` Feb. 1, 1966 R. F. HILL. ETAL 3,232,717
URANIUM MONOGARBIDE THERMIONIC EMITTERS Filed May 14, 1962 IN VENTORS A TTORNE United States Patent Oiilice 3,232,717l Patented Feb. l, 1966 3,232,7 17 URANIUM MONGCARBIDE THERMIONIC EMITTERS Robert F. Hill, Warren, Mich., and Stan J. Paprocki, and
Donald L. Keller, Columbus, Ohio, assignors, by direct and mesne assignments, to General Motors Corporation,
Detroit, Mich., a corporation of Delaware Filed May 14, 1962, Ser. No. 194,448 9 Claims. (Cl. 29-182.3)
This invention relates to devices yfor converting heat energy to electrical energy and, more particularly to an improved electron emitter element for such devices.
In United States patent application Serial No. 802,958, tiled March 30, 1959, now Patent No. 3,093,567, in the names of Francis E. Jablonski and Charles B. Leffert and assigned to the assignees of the present invention, there is described and claimed a thermionic converter which comprises a noble gas plasma diode, the electron emitter element of which includes a iissionable material so as to generate the noble gas plasma by fission fragment ionization. Further in accordance with that invention, the mass of the iissionable material in the diode or a combination of such diodes can be made suiiiciently large to sustain chain reaction fission and thereby generate the heat for conversion to electrical energy.
The basic requirements -for the emitter material for such a device are: It must have the ability to adequately supply electrons at the operating temperature, must be chemically and mechanically stable, must have electrical and thermal conductivity and must have a high surface density of exposed ssionable material.
It is an object of the present invention to provide an improved electron emitter which has this combination of important properties to a marked degree and which is therefore particularly useful in a noble gas plasma diode of the aforementioned type. A further object of the invention is to provide an improved method for making su-ch an electron emitter.
Uranium carbide, by itself, has two of the aforementioned essential qualities needed for the electron emitter, namely, ability to supply electrons and high density of iissionable material. However, by itself it has insuilicient mechanical strength. Uran-ium carbide is, of course, a ceramic and, as is true -of most all ceramics, it is particularly susceptible to thermal cracking. In accordance with the present invention, the additional required properties are provided by physically combining certain metals with the uranium carbide to form a cermet. We have found that the choice of metals is extremely limited for the reason that uranium carbide is quite reactive at high temperatures, and it is essential that the metal not undergo interaction with the uranium carbide either during processing or during operation. More specifically, we have found that the two metals which suiiice are rhenium and tungsten. Briefly then, the electron emitter of this invention comprises a dense cermet body of uranium carbide and rhenium, tungsten, or rhenium-tungsten alloys, the -former being preferred. Further inaccordance with the invention, this cermet body is provided with a niobium cladding, a thin layer of the rhenium or tungsten, preferably the latter, being interposed between the cermet body and the cladding in order to prevent diifusion and reaction between the niobium and the uranium carbide during manufacture and operation of the emitter. The cermet body can contain from 10% to 80% by volume uranium carbide, the upper end of this range being preferred particularly where the emitter is for use in a nuclear reactor type thermionic converter wherein the heat is supplied by nuclear fission.
The above and other objects and features of the invention will appear more clearly from the following detailed description thereof made with reference to the drawing which shows a side view in section of an electron emitter constructed in accordance with the invention and incorporated in a noble gas plasma diode which is shown schematically.
Referring now to the drawing, the thermionic converter comprises a hermetically sealed envelope 2 lilled with a noble gas and having two electrical leads 4 and 6 extending therethrough. The top lead 4 Iconnects to an electron collector 8 which has some suitable cooling means associated therewith, such cooling means being illustrated by the plurality of heat radiating fins 10. The bottom electrical lead 6 is connected to the electron emitter 12 which is in the form of a flat disc with its upper surface in spaced relationship to the bottom flat surface of the collector. Hence, when the noble gas between the emitter and the collector is ionized and the emitter is heated, there is a ow of electrons from the emitter to the collector thereby generating an electrical current, all as described in the aforementioned patent application.
In accordance with the present invention the emitter `12 comprises a dense cermet body 14 of 80% by Volume uranium carbide and 20% by volume rhenium with a niobium cladding 16 Icovering its side and bottom surfaces, a layer of tungsten foil 18 being pressed between the body 14 and the cladding. Further details of the structure of the emitter will be apparent from the following description of the method for its manufacture:
To form the uranium carbide, pure uranium metal in the fornrof small discs or rods can be employed as a starting material. Prior to melting, the surface of the metal should be carefully cleaned by electropolishing or by a careful wash in dilute nitric acid. Spectroscopie carbon in rod form can be employed as the starting carbon material. The rod is rst outgassed by heating to a temperature of about 2000o C. in high Vacuum and is then ground to powder form in an inert atmosphere; Carefully controlled quantities of the uranium metal and carbon powder are placed in an are furnace in a puried argon atmosphere where they are arc-melted together to form a uranium carbide button. A graphite-tipped electrode is used in order to minimize contamination. The composition of the uranium carbide produced will, of course, depend upon the weights of uranium metal and carbon powder in the furnace charge. With 4.8
weight percent carbon, the uranium carbide formed will be predominantly uranium monocarbide; when slightly more than 4.8 weight percent carbon is used, a second phase with composition UC2 will appear at the grain boundaries within the UC matrix and there will sometimes also appear a third phase, U2C3. The precise stoichiometric composition of the uranium carbide is not important to the present invention and hence the term uranium carbide as used herein is intended to comprelhend both the monoand di-carbides as well as the intermediates such as U2C3.
The uranium carbide is pulverized to fine grain size, on the order of minusy 300 mesh, preferably in a dry box since the pulverized uranium carbide is pyrophoric. Next the pulverized uranium carbide is uniformly admixed with rhenium powder, also about minus 300 mesh grain size, in the proportions desired, preferably uranium carbide and 20% rhenium. This mixing of the powders should also be performed in a dry box and for further protection against the pyrophoric nature of the uranium carbide it is desirable that about 1% by weight of a suitable organic material such as Carbowax (polyethylene glycol) be included in the mixture. In addition to coating the grains of uranium carbide and thereby protect against combustion, the Carbowax also serves as a binder for the mixture.
The powder mixture is then cold pressed in a steel die at about 60,000 pounds per square inch to thereby form a green compact having a density of approximately 70% theoretical.
The green compact so formed is inserted snugly into a niobium cup lined with a thin layer of tungsten foil and this assembly is then heated in a vacuum sufficiently to drive out the Carbowax. A niobium lid, preferably also lined with tungsten foil, is then placed over the niobium cup and is bonded to the cup by electron beam welding to effect an hermetic seal. Since the electron beam welding is performed in a vacuum, the interior of the cup is in an evacuated state at the conclusion of this sealing operation. The assembly should preferably be leak-checked after the welding to make certain that it is hermetically sealed.
The resulting niobium encapsulated green compact is placed in an autoclave and is pressure bonded in a helium atmosphere at 10,000 pounds per square inch pressure and 2700 F. This heating and isostatic pressing operation causes the niobium encapsulation to collapse and the green compact to sinter and form a dense cermet body. At the conclusion of the operation the cermet body has a density which is about 99% of theoretical. After removing from the autoclave and then cooling, the top or lid portion of the niobium cladding is sliced away so as to form the structure as shown in the drawing.
As indicated above, both rhenium and tungsten have extremely low chemical reactivity with uranium carbide. Between the two, rhenium is preferable because it has the lowest chemical reactivity; however, it is less desirable because of its higher nuclear cross section. It is because of this that rhenium with its extremely low reactivity is the preferred metal for the cermet, whereas tungsten with its lower nuclear cross section is preferred for the barrier layer between the cermet and the cladding. The somewhat higher reactivity of the tungsten serves to no serious disadvantage where it is used as the barrier layer and the lower cross section outweighs what little disadvantage there is.
It will be understood that while the particulars of the invention have been described specifically with reference to a preferred embodiment thereof, various modifications may be made, all within the full and intended scope of the claims which follow.
We claim:
1. A cermet body useful as an electron emitter in a thermionic device, said body consisting essentially of from to 80% by volume uranium carbide and from 20% to 90% by volume of a metal selected from the group consisting of rhenium, tungsten and rhenium-tungsten alloys.
2. A cermet body useful as an electron emitter in a thermionic device, said body consisting essentially of from 10% to 80% by volume uranium carbide and from 20% to 90% by volume rhenium.
3. A cermet body useful as an electron emitter in a thermionic device, said body containing about 80% by volume uranium carbide and about 20% by Volume of a metal selected from the group consisting of rhenium, tungsten and rhenium-tungsten alloys.
4. A cermet body useful as an electron emitter in a thermionic device, said body containing about by volume uranium carbide and about 20% by volume rhenium.
5. An electron emitter for a thermionic device comprising a cermet body consisting essentially of from 10% to 80% by volume uranium carbide and from 20% to by volume metal, a niobium cladding on said cermet body and a thin barrier layer of metal between said body and said cladding, the metal of said barrier layer and of said cermet being selected from the group consisting of rhenium, tungsten and rhenium-tungsten alloys.
6. An electron emitter for a thermionic device comprising a cermet body consisting essential of from 10% to 80% by volume uranium carbide and from 20% to 90% by volume rhenium, a niobium cladding on said cermet body and a thin barrier layer of tungsten between said body and said cladding.
7. An electron emitter for a thermionic device comprising a cermet body containing about 80% by volume uranium carbide and about 20% by volume metal, a niobium cladding on said cermet body and a thin barrier layer of metal between said body and said cladding, the metal of said barrier layer and of said cermet being selected from the group consisting of rhenium, tungsten and rhenium-tungsten alloys.
8. An electron emitter for a thermionic device comprising a cerment body containing about 80% by volume uranium carbide and about 20% by volume rhenium, a niobium cladding on said cermet body and a thin barrier layer of tungsten between said body and said cladding.
9. A cermet body useful as an electron emitter in a thermionic device, said body containing from 10% to 80%, by volume, uranium carbide and the balance substantially a metal selected from the group consisting of rhenium, tungsten and rheniumtungsten alloys.
References Cited by the Examiner UNITED STATES PATENTS 2,115,828 5/1938 Prescott 252-505 2,682,511 6/ 1954 Gronin 252-517 2,863,816 12/ 1958 Stacy 176-70 2,873,518 2/1959 Schilling et al. 29-420.5 2,928,168 3/1960 Gray 176-91 XR 2,991,601 7/1961 Glatter et al.
2,993,786 7/1961 Robolf et al. 176-89 XR 3,067,505 12/ 1962 Schenk 29-420.5 3,126,349 3/1964 Kirchner 252-301.1 3,129,188 4/1964 Sowman etal 252-301.1
OTHER REFERENCES Nuclear Fuel Elements by Hausner et al., November 1959, Reinhold Publ. Corp., New York, pp. 197 and 199.
Nucleonics, vol. 19, No. 12, December 1961, pp. 66, 70, 72, and 73.
CARL D. QUARFORTH, Primary Examiner.
L. DWAYNE RUTLEDGE, OSCAR O. VERTIZ,
Examiners.

Claims (1)

1. A CERMET BODY USEFUL AS AN ELECTRON EMITTER IN A THERMOINIC DEVICE, SAID BODY CONSISTING ESSENTIALLY OF FROM 10% TO 80% BY VOLUME URANIUM CARBIDE AND FROM 20% TO 90% BY VOLUME OF A METAL SELECTED FROM THE
US194448A 1962-05-14 1962-05-14 Uranium monocarbide thermionic emitters Expired - Lifetime US3232717A (en)

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Application Number Priority Date Filing Date Title
US194448A US3232717A (en) 1962-05-14 1962-05-14 Uranium monocarbide thermionic emitters
GB18455/63A GB971531A (en) 1962-05-14 1963-05-09 Thermionic electron emitter elements and their manufacture
DEG37728A DE1240967B (en) 1962-05-14 1963-05-11 Electron emitting electrode for thermionic converters
FR934740A FR1356734A (en) 1962-05-14 1963-05-14 electron-emitting thermionic element and method of making it
US423403A US3243292A (en) 1962-05-14 1964-11-05 Method of making a thermionic device

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Cited By (11)

* Cited by examiner, † Cited by third party
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US3332883A (en) * 1963-11-07 1967-07-25 Gen Electric Co Ltd Uranium carbide-tungsten nuclear fuel composition
US3382154A (en) * 1964-07-03 1968-05-07 Bbc Brown Boveri & Cie Thermionic energy converter
US3387148A (en) * 1964-11-26 1968-06-04 Siemens Ag Converter fuel element for nuclear reactors and method of producing the same
US3488549A (en) * 1968-01-15 1970-01-06 Gen Electric Dispenser cathode material and method of manufacture
DE1564070B1 (en) * 1966-03-26 1970-09-10 Erno Raumfahrtteehnik Gmbh Radionuclide battery with thermionic energy conversion
US3621322A (en) * 1968-09-12 1971-11-16 Patent Treuhand Ges Fuer Elektrische Gluehlampen Mbh High-pressure compact arc lamp with electrodes containing tantalum carbide
US3892838A (en) * 1971-10-16 1975-07-01 Japan Atomic Energy Res Inst Method of producing thermally stable uranium carbonitrides
US4092560A (en) * 1974-01-15 1978-05-30 Chemokomplex Vegyipari Gepes Berendezes Export-Import Vallalat Vapor discharge lamp cermet electrode-closure and method of making
US4189398A (en) * 1965-04-15 1980-02-19 The United States Of America As Represented By The United States Department Of Energy Nuclear fuel composition
US4663559A (en) * 1982-09-17 1987-05-05 Christensen Alton O Field emission device
EP4214721A4 (en) * 2020-09-21 2025-04-23 Austin Lo ANEUTRONIC NUCLEAR FUEL

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US2115828A (en) * 1935-04-13 1938-05-03 Bell Telephone Labor Inc Electron emitting cathode and method of preparation
US2682511A (en) * 1950-12-16 1954-06-29 Raytheon Mfg Co Thermionic cathodes
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US2873518A (en) * 1954-02-26 1959-02-17 Patent Treuhand Ges Fuer Elektrische Gluehlampen Mbh Wire electrode for electric discharge lamps
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US2991601A (en) * 1956-05-14 1961-07-11 Glatter Jacob Process of forming powdered material
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